• Title/Summary/Keyword: 경화거동

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Dynamic Character Analysis of 3-beam Slab Orbits depending on the Hardening of Rail Pad Stiffnesses (3중보 슬래브궤도의 레일패드강성의 경화에 따른 동적거동 특성분석)

  • Choi, Hyun-Su;Choi, Jin-Yu;Kim, Jung-Hun;Park, Dae-Geun;Kang, Young-Jong
    • Proceedings of the KSR Conference
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    • 2008.11b
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    • pp.870-873
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    • 2008
  • 레일패드는 궤도전체의 탄성확보 뿐만 아니라 열차하중에 의해 침목으로 전달되는 충격을 완화시켜 침목과 도상의 파손을 방지하는 역할을 하는데, 통과톤수의 증가와 기후적 요인에 의하여 패드가 열화되면 패드의 강성이 증가하게 된다. 패드의 강성이 증가하게 되면 레일을 통해 침목으로 전달되는 충격하중이 증가하게 되어 침목의 파손을 유발할 수 있을 뿐만 아니라 침목하면의 도상에도 과도한 충격하중을 전달하여 도상의 손상을 가속화시킬 수 있다. 또한 레일패드의 강성변화는 궤도의 소음과 레일의 파상마모의 진전에도 영향을 미치게 된다. 따라서 레일패드의 공용기간 중에 적정한 강성을 유지할 필요가 있으며, 통과톤수의 증가에 따른 레일패드의 경화도를 산정하는 방법과 레일패드의 경화가 궤도에 미치는 영향을 정량적으로 분석하여 레일패드의 교체주기에 관한 기준을 마련할 필요가 있다. 본 연구에서는 슬래브의 질량과 일정속도대역에서의 패드강성의 민감도분석을 하여 그 결과를 비교하고 레일패드경화에 따른 대상궤도의 동적거동을 수치해석을 통하여 패드강성과 차량주행속도에 따른 윤중의 변동량과 레일의 변위, 가속도 그리고 침목의 변위, 가속도의 변화정도를 분석해 보았다. 궤도시스템의 동적해석을 위한 해석 프로그램으로는 네덜란드 델프트 공과대학에서 개발된 궤도시스템 전용 해석 프로그램인 DARTS(The dynamic analysis of a rail track structure)를 사용하였다. 대상궤도는 국내 1단계 경부고속철도에서 사용되고 있는 3중보 무도상궤도를 사용하였다.

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The investigation of plastic spin behavior of body centered polycrystal with simplified accommodatio model (정적 결정수용모델에 의한 체심입방격자 다결정의 소성스핀 거동에 관한 연구)

  • Nam, Y. Y.
    • Journal of Ocean Engineering and Technology
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    • v.10 no.2
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    • pp.42-52
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    • 1996
  • 소성스핀을 취급하기 위한 이론을 살펴보면 개념적으로 현저히 다른 세가지로 압축된다. 또한 재료직조 현상이 소성스핀의 근원이라고 알려져 있지만, 그 지배인자와 발생근원에 대하여 아직 충분히 연구되어 있지 않다. 따라서 앞으로의 연구에 올바른 방향을 제시하기 위하여 소성스핀의 기본적인 거동에 대한 연구가 요구된다. 본 연구에서는 체심입방격자 다결정의 소성스핀 시뮬레이션을 통하여, 소성스핀의 거동을 조사하였는데, 재료직조, 변형경화, 변형속도, 하중역전 등의 영향을 검토하였다. 소성발생원인으로 재료직조현상이 강조되었고, 이에 관련한 주요지배인자를 제시하였다. 무차원 소성스핀은 변형속도, 재료경화에 영향을 받으나 재료직조와 관련한 인자와 비교하여 그 영향이 작게 나타났다.

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Synthesis and Curing Behavior of UV-curable Polycarbonate-based Polyurethane Methacrylate : Effect of Polyol Molecular Weight, Contents of Photoinitiator and Monomers on the Flexibility and Properties (자외선 경화형 폴리카보네이트계 폴리우레탄 메타아크릴레이트의 합성과 경화거동 : 폴리올 분자량, 광개시제 및 모노머 함량이 유연성과 물성에 미치는 영향)

  • Park, Eun-Suk;Hwang, Hyeon-Deuk;Park, Cho-Hee;Lee, Yong-Hee;Moon, Je-Ik;Kim, Hyun-Joong
    • Journal of Adhesion and Interface
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    • v.12 no.2
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    • pp.47-55
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    • 2011
  • UV-curable coatings have been used in various industries due to their advantages such as high mechanical property, good solvent resistance, fast curing process and low volatile organic compounds. However, a lack of flexibility of UV-cured films is a weak point for the pre-coated system of roll-to-roll process. In this study, UV-curable polycarbonate-based methacrylates were synthesized with polycarbonate diol, isophorone diisocyanate and 2-hydroxyethylmethacrylate to improve flexibility of the UC-cured films. The effects of polyol molecular weight, content of photoinitiator and monomers on the UV-curing behavior, flexibility and properties were investigated. The UV-curing behavior was measured by a photo-DSC, the pendulum hardness, tensile strength, viscoelastic properties were also evaluated.

Effect of Reinforcement details on the Seismic Performance of Precast Strain-Hardening Cementitious Composite(SHCC) Infill Walls (보강상세에 따른 프리캐스트 변형경화형 시멘트 복합체 끼움벽의 내진성능)

  • Kim, Sun-Woo;Yun, Hyun-Do;Song, Seon-Hwa;Yun, Yeo-Jin
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.13 no.3 s.55
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    • pp.209-216
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    • 2009
  • Flexible frames on their own offer little resistance to lateral forces, resulting often in large deflections and rotations at the joints. On the other hand, walls subjected to lateral loads fail mainly in shear at relatively small displacements. Therefore, when the nonductile frames and wall act together, the combined action of the composite system differs significantly from that of the frame or wall alone. The objective of the study is to evaluate seismic response of infill walls with notched midsection. Reinforcement detail of wall was main variable in the experiment. Also SHCC was used in order to prevent damage concentration into notched midsection of walls. Test results, SHCC infill walls show the multiple crack patterns as expected. However, PIW-ND specimen exhibits less story drift, stiffness and energy dissipation capacity than those of PIW-NC specimen.

Studies on Cure Behaviors and Rheological and Mechanical Properties of Epoxy/Polyurethane Blend System initiated by Latent Thermal Catalyst (열잠재성 촉매에 의한 에폭시/폴리우레탄 블랜드계의 경화거동, 유변학적 및 기계적 물성에 관한 연구)

  • Gang, Jun-Gil;Gwon, Su-Han;Park, Su-Jin
    • Journal of the Korean Chemical Society
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    • v.46 no.3
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    • pp.233-240
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    • 2002
  • In this work, the cure kinetics and rheological and mechanical properties of diglycidylether of bispheonol A (DGEBA, EP)/polyurethane (PU) blends were investigated. The 1 wt% N-benzylpyrazinium hexafluoroantiminate (BPH) was used as a latent thermal catalyst. Latent properties were performed by measurement of the conversion as a function of reaction temperature using DSC. And the rheological properties of the blend systems were investigated under isothermal conditions using a rheometer. Crosslinking activating energies (Ec) were also determined from the Arrhenius equation based on gel time and curing temperature. The impact strengths were measured as mechanical properties of the casting specimens. The BPH in the blend systems could be an excellent latent thermal catalyst without any co-initiator. The rheological results showed that Ec was highest when PU content was 30 wt% which was in good agreement with the impact strengths. This was probably due to the intermolecular hydrogen bonding between the hydroxyl group in PU and EP, resulting in increasing the crosslinking density.

Correlation between Overload Retardation and Hardening Exponent (과부하로 인한 균열지연과 변형경화지수와의 상호관계)

  • Sang-Chul,Kim;Jin-Man,Jeong;Moon-Sik,Han
    • Bulletin of the Society of Naval Architects of Korea
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    • v.26 no.2
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    • pp.41-48
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    • 1989
  • This paper investigates the relationship between strain hardening exponents(n) of various marine materials and fatigue crack retardation effect after applying single overload. Using the four different sheet materials, following results are obtained. (1) The fatigue crack propagation rate after applying single overload was retarded and the effects of this retardation were closely related to the strain hardening exponent. (2) The larger the strain hardening exponents were, the more were the fatigue crack retardation effects after applying single overload. (3) The considerable crack closure with the applying of a overload was observed in matrals with large strain hardening exponent. When n is smaller than 0.1, the fatigue crack retardation effects are negligible. On the contrary, when n is larger than 0.2 the fatigue crack retardation effects are significant.

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Synthesis, Cure Behavior, and Rheological Properties of Fluorine-Containing Epoxy Resins (불소함유 에폭시 수지의 합성, 경화 거동 및 유변학적 특성)

  • 박수진;김범용;이재락;신재섭
    • Polymer(Korea)
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    • v.27 no.3
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    • pp.176-182
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    • 2003
  • The fluorine-containing epoxy resin, 2-trifluorotoluene diglycidylether (FER) was prepared by reaction of 2-chloro-${\alpha}$,${\alpha}$,${\alpha}$-trifluorotoluene with glycerol diglycidylether in the presence of pyridine catalyst. Curing behavior of FER/DDM system was investigated using dynamic and isothermal DSC. Cure activation energy (Ea) was determined by Flynn-Wall-Ozawa's equation. The rheological properties of FER/DDM system were studied under isothermal condition using a rheometer. Cross-linking activation energy (Ec) was determined from the Arrhenius equation based on gel time and curing temperature. As a result, the chemical structure of FER was confirmed by FT-IR, $\^$13/C NMR, and $\^$19/F NMR spectroscopy. The cure activation energy of FER/DDM system was 55.4 kJ/mol and conversion and conversion rate were increased with the curing temperature. The cross-linking activation energy of FER/DDM system was 41.6 kJ/mol and gel time was decreased with the curing temperature.

Studies on Rheological Properties and Cure Behaviors of Difunctional Epoxy/Biodegradable Poly(butylene succinate) Blends (2관능성 에폭시/생분해성 폴리부틸렌 숙시네이트 블렌드의 유변학적 특성 및 경화거동에 관한 연구)

  • 박수진;김승학;이재락;민병각
    • Composites Research
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    • v.15 no.6
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    • pp.8-15
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    • 2002
  • In this work, the effect of biodegradable poly(butylene succinate)(PBS) in difunctional epoxy(21:P) resin was investigated in terms of rheological properties, cure kinetics, thermal stabilities, and mechanical interfacial properties. Rheological properties of the blend system were measured under isothermal condition using a rheometer. Cross-linking activation energies($\textrm{E}_c$) were determined from the Arrhenius equation based on gel time and curing temperature. The $\textrm{E}_c$ was increased in the presence of 10 wt% PBS as compared with neat 2EP. From the DSC results of the blends, the cure activation energies($\textrm{E}_a$) showed a similar behavior with $\textrm{E}_c$ due to the increased intermolecular interaction between 2EP and PBS. The decomposed activation energies($\textrm{E}_t$) for the thermal stability derived from the integral method of Horowitz-Metzger equation, were also increased in 10 wt% PBS. In addition, 20 wt% PBS showed the highest critical stress intensity factor($\textrm{E}_{IC}$). which was explained by increasing the fracture toughness of the 2EP/PBS blend systems.

Preparation and Curing Behavior of Polyurethane Coatings by Polyester/Lactone Polyol and HDI-biuret (폴리에스테르/락톤 폴리올과 HDI-Biuret에 의한 폴리우레탄 도료의 제조 및 경화거동)

  • 최용호;김대원;황규현;박홍수;김태옥
    • Polymer(Korea)
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    • v.24 no.1
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    • pp.72-81
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    • 2000
  • Benzoic acid polyester/lactone polyol were synthesized by polycaprolactone 0201 as diol, trimethylolpropane as triol, adipic acid as dibasic acid, and benzoic acid as monobasic acid. Polyisocyanate prepolymer Desmodur N-100 of HDI-biuret type was used in this study. Two-component polyurethane coatings were prepared by blending benzoic acid polyester/polycaprolactone, polyisocyanate, wetting/dispersing agent, white pigment, and flowing agent. Various properties were examined on the film coated with the prepared polyurethane. They showed excellent physical properties such as abrasion resistance, accelerated weathering resistance, and yellowness index. They also showed good physical properties such as flexibility, impact resistance, 60$^{\circ}$ specular gloss, cross hatch adhesion, hydrocarbon resistance, and lightness index difference. Hardness of coating showed a little poor character. The introduction of polycaprolactone 0201 as diol in the polyurethane coatings improved the hydrocarbon resistance, impact resistance, and flexibility of coatings. According to the drying and curing behavior with the contents of benzoic acid, they seem to have reasonable coating properties such as drying time of 2 to 4 hours and pot-life time of 20 to 37 hours.

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