• Proceedings of the Korean Reliability Society Conference
• /
• 2006.05a
• /
• pp.362-370
• /
• 2006

차량의 충격과 진동을 완화하고 링크의 조정역할을 하는 Rubber Bushing제품의 내구성이 약하게 되면 Control arm에서의 이탈사고나 차량의 떨림, 소음으로 인한 고객 불만이 발생하게 된다. 따라서, 국내외 시장에서의 경쟁력 향상을 위해 Rubber Bushing에 대한 내구성, 정특성, 동특성의 개선을 위한 기술의 개발이 요구되고 있다. 본 연구의 목적은 Rubber Bushing을 개발하는데 있어서 종전의 재료설계, 형상설계 및 공정설계에 대한 분석을 행하고, 실험계획법(DOE)을 활용하여 가장 적은 샘플의 시험으로 최적의 설계요소를 찾아내는 방법을 연구하는데 있다. Bushing의 품질특성이 재료, 형상 및 공정에서 어떠한 조건을 가질 때 특성치가 가장 높은 바람직한 반응을 얻을 수 있는 가를 연구하여 최적반응 조건을 결정하고자 한다.

• Proceedings of the KIEE Conference
• /
• 2005.11b
• /
• pp.3-5
• /
• 2005

21세기의 무한 경쟁 환경에서 기업의 생존은 고객 만족에 의해 좌우된다고 해도 과언이 아니다. 한편, 고객 만족을 달성하기 위해서는 고객의 욕구가 어떻게 변화하고 있는가를 충실히 파악하여야 한다. 헌재의 고객은 제품의 기본 기능과 가격 똥의 요소뿐만 아니라, 제품의 품질, 특히 신뢰성에 매우 민감한 반응을 보이고 있으며, 각 기업은 이러한 추세를 반영하여 제품의 보증기간을 경쟁적으로 연장하고 있다. 신뢰성이란 제품이 얼마나 오랫동안 고장 없이 의도한 기능을 발휘할 수 있는가를 나타낸다. 즉, 신뢰성이란 시간적 품질을 의미하며 제품이 충분한 신뢰성을 가지고 있지 못할 경우, 과도한 클레임으로 인한 보증비용의 증가와 같은 단기적인 손해뿐만 아니라, 고객 불만족, 고객 이탈, 기업 경쟁력 상실 통으로 야기되는 장기적인 손실에 이르기까지 매우 큰 피해를 감수해야 한다. 따라서 제품의 신뢰성은 기업의 생존과 경쟁력 우위를 확보하기 위한 중요한 전략적 요소로 다루어 져야 한다. 신뢰성 활동은 크게 신뢰성 평가와 신뢰성 설계 두 가지로 나눌 수 있다. 전자는 현재 개발 또는 양산 중인 제품의 신뢰성 수준이 어느 정토인가를 파악하자 하는 활동이며, 후자는 제품에 신뢰성을 높이기 위한 일련의 활동을 포함한다. 한편, 신뢰성 평가는 모든 신뢰성 업무에서 앞서 선행적으로 이루어 져야 하는 기초적 활동이며, 본 과제에서는 자사의 전자식 전력량계(LSEW12)와 디지털 보호계전기(GIPAM2200)를 대상으로 신뢰성 평가에 관한 연구를 수행하였다.

• Journal of the Korean Geotechnical Society
• /
• v.16 no.4
• /
• pp.157-170
• /
• 2000

In this study, we conducted a combined adsorption-sequential extraction analysis(CASA) to investigate temperature effects of single and competitive adsorption of zinc and copper on natural clays. As a result, it was found out that in a single adsorption of zinc, the adsorption was mostly in the exchangeable phase, with increase n temperature. In a competitive adsorption of zinc, this trend was so strong that the exchangeable phase adsorption increase up to 80~90%. On the other hand, about 50% of copper was adsorbed in the carbonate occluded phase in single and competitive adsorptions. In the single adsorption the adsorption of carbonate occluded phase increased by 5% with the temperature increase and in the competitive adsorption the increase rate is about twice. The adsorption of zinc and copper on natural clays is an endothermic reaction with the exception of exchangeable phase adsorption.

• The Journal of the Korea Contents Association
• /
• v.19 no.6
• /
• pp.632-643
• /
• 2019

This study is analysis how the competitive factors of fitness center's affect customer satisfaction and re-use intention. Accordingly, It surveyed fitness center customers in Pusan and Kyungnam, and analyzed amount 422 questionnaires with the SPSS WIN 23.0 and AMOS WIN 23.0 program, so it reached these conclusions. First, the accessibility of location characteristic showed that it had a relevant influence on the customer satisfaction, but the visibility didn't have a relevant influence on it. Second, the spatiality and convenience of the facility characteristic showed that they influenced customer satisfaction. Third, the responsiveness and professionalism of the service characteristic factor showed that they had a relevant influence on the customer satisfaction, but the reliability and empathy didn't have a relevant influence on it. Fourth, the customer satisfaction had a relevant influence on the reuse intention. According to this study, we found that the competition factor was bound up with the customer satisfaction and reuse intention. In the end, grasping customers' satisfaction and preferred utilization pattern should be reflected actively in the fitness center management.

• Journal of the Korean Chemical Society
• /
• v.26 no.1
• /
• pp.7-17
• /
• 1982

In order to predict substituent and Lewis acid effects on the regiospecificity of the Diels-Alder reaction, and to investigate the competition for the complexation of Lewis acid between diene and dienophile, frontier orbital theory has been applied to thermal and catalyzed Diels-Alder reaction by means of CNDO/2 MO method. It has been found that: (1) Lewis acid coordinated preferentially with diene rather than dienophile when carbonyl oxygen of acetoxy substituted diene had larger negative atomic charges than that of dienophile. (2) Most of the reaction were neutral electron demand type, and hence 4-C, 2-C and quantitative secondary orbital interacion methods were generally in good accord with experiments. (3) Sulfur activated the adjacent terminal carbon atom greatly to increase diene LUMO-dienophile HOMO interaction through vacant-d-orbital participation, and played an important role in controlling regioselectivity of neutral electron demand reaction type.

• Journal of the Korean Chemical Society
• /
• v.36 no.4
• /
• pp.589-597
• /
• 1992

The rate constants of hydrolysis of phenyl-N-benzoylchlorothioformimidates were determined by UV spectrophotometry in 30% (v/v) aqueous dioxane at $25^{\circ}C$. On the basis of rate equation, general base catalysis, solvent effect, substituent effect, thermodynamic parameters, frontier orbital interaction and hydrolysis product analysis, it may be concluded that the hydrolysis of phenyl-N-benzoylchlorothioformimidates proceeds through $S_N1$ mechanism via azocarbocation intermidiate below pH 10.0, while above pH 10.00 the hydrolysis proceeds through nucleophilic addition-elimination ($Ad_{N-E}$) mechanism. In the range of pH from 10.0 to 11.0 these two reaction occur competitively.

• Journal of the Korean Chemical Society
• /
• v.33 no.1
• /
• pp.127-134
• /
• 1989

The rate constants of the nucleophilic addition reaction of 3-mercaptopropionic acid to the ${\beta},\;{\beta}$-diethoxycarbonylstryene derivatives (H, p-OCH$_3$, 3,4,5-(OCH$_3)_3$, 3,4-methylenedioxy) were determined by ultraviolet spectrophotometry, and rate equation which could be applied over a wide pH range was obtained. On the basis of pH-rate profile and the presence of general base catalysis, a plausible mechanism of this addition reaction was propound:Below pH 6.0 the reaction was initiated by the addition of neutral 3-mercaptopropionic acid molecule, and in the range of pH 6.0∼8.0, a neutral 3-mercaptopropionic acid molecule and a sulfide anion competitively attacked to the double bond. Above pH 8.0, the reaction proceeded through the addition of a sulfide anion.

• Journal of Navigation and Port Research
• /
• v.26 no.4
• /
• pp.363-372
• /
• 2002

Recently, mutual economy cooperation in Northeast Asia has leaded steady growth among main countries of it and rather promoted a single economy circle. In this region, Busan container port competes with min container ports in China, Taiwan and Japan in it for attracting transshipment container traffic of north-Shanghai in China and for-east Russia. Therefore, this paper aims to suggest competitive strategies for Busan container port to attract container traffic in Northeast Asia To do so, it evaluates the preference of important ports in the competitive situation and competitiveness edgy of important ports in Northeast Asia, and finally proposes the relative order of important factors. Based on the evaluation of it, first, the Busan ports hue tn strengthen port facilities to attract more traffic and in detail, reinforce the number of berth, yard areas and handling equipment Second, they also have to provide high quality of services to deliver cargos in time, not being damaged and swiftly response to shipowner and shipper's claim, Third, they need to review the strategy to adopt flexible tariff policy and to invest the profit from tariff in port service and facilities, as providing higher port tariff level by a regular rate.

• Journal of the Korean Chemical Society
• /
• v.17 no.3
• /
• pp.174-181
• /
• 1973

Dichlorodiacetatotitanium(IV) dissolves in alcohols with chemical reaction. Such solvolytic reaction of $TiCl_2(OAc)_2$with various alcohols has been studied by means of solution NMR spectroscopy and chemical analysis of the isolated products. The reaction of $TiCl_2(OAc)_2$ with primary alcohols has shown to be a quantitative two-step ligand substitution process as shown in the following: $TiCl_2(OAc)_2+ROH{\to}TiCl_2(OAc)_2(OR)+AcOH$ $TiCl_2(OAc)_2(OR)+ROH{\to}TiCl_2(OAc)_2+AcOH$The molecular form initially soluble in organic solvents has been found to be the monosubstituted species $TiCl_2(OAc)(OR)$. Alcoholysis with t-butyl alcohol has shown remarkable differences. When the mole ratio of t-butyl alcohol to $TiCl_2(OAc)_2$ is less than 1/2, the following reaction is dominant. $TiCl_2(OAc)_2+t-ButOH{\to}TiCl_2(OAc)_2+t-ButCl$However, at higher mole ratio another substitution process resembling the first step reaction with primary alcohols is competitively accompanied. The reaction with t-butyl alcohol also differs from that with primary alcohols in that only one either of the two chloro-or acetato-ligands in $TiCl_2(OAc)_2$ is subjected to substitution.

• Journal of Energy Engineering
• /
• v.29 no.1
• /
• pp.58-62
• /
• 2020

Among the exhaust gas, Carbon dioxide which is a causative factor in greenhouse effect. We study for synthesis of propylene carbonate with carbon dioxide which is captured and utilized in commercially valuable. The Experiment was proceeded as pilot scale with using homogeneous organic catalyst which is able to produce propylene carbonate in commercial and reaction conditions. Optimization condition for concentration of catalyst and reaction temperature, pressure was studied. We confirm that this process is eco-friendly method and commercial application due to the mild condition and also catalyst has a competitive price, reusability.