• Journal of Korean Society of Transportation
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• v.34 no.2
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• pp.107-122
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• 2016

This study aims to develop a framework to estimate mobile source emissions with the macroscopic travel demand model including enhanced estimates of intra-zonal travel emissions using Space Syntax analysis. It is acknowledged that "the land-use and transportation interaction model explains the influence of urban structure on accessibility and mobility pattern". Based upon this theory, the estimation model of intra-zonal travel emissions is presented with the models of total travel distance, total travel demand, and average travel speed of intra-zonal trips. Thess statistical models include several spatial indices derived from the Space Syntax analysis. It explains that urban spatial structure is a critical factor for intra-zonal travel emissions, which is lower in compact zone with smaller portion of land area, lower sprawl indicator, and more grid-type of road network. Also the suggested framework is applied in the evaluation of the effectiveness of bicycle lane project in Suwon, Korea. The estimated emissions including intra-zonal travel is as double as the results only with inter-zonal demands, which shows better performance of the suggested framework for more realistic outcomes. This framework is applicable to the estimation of mobile source emissions in nation-wide and the assessment of transportation-environment policies in regional level.

• Geophysics and Geophysical Exploration
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• v.12 no.1
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• pp.105-113
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• 2009

The interpretation of observed waveform characteristics identified in refraction and wide-angle reflection data increases confidence in the crustal structure model obtained. When calculating traveltimes and raypaths, wavefront methods on a regular grid based on graph theory are robust even with complicated structures, but basically compute only first arrivals. In this paper, we develop new algorithms to compute traveltimes and raypaths not only for first arrivals, but also for fast and later reflection arrivals, later refraction arrivals, and converted waves between P and S, using the modified wavefront method based on slowness network nodes mapped on a multi-layer model. Using the new algorithm, we can interpret reflected arrivals, Pg-later arrivals, strong arrivals appearing behind Pn, triplicated Moho reflected arrivals (PmP) to obtain the shape of the Moho, and phases involving conversion between P and S. Using two models of an ocean-continent transition zone and an oceanic ridge or seamount, we show the usefulness of this algorithm, which is confirmed by synthetic seismograms using the 2D Finite Difference Method (2D-FDM). Characteristics of arrivals and raypaths of the two models differ from each other in that using only first-arrival traveltime data for crustal structure analysis involves risk of erroneous interpretation in the ocean-continent transition zone, or the region around a ridge or seamount.

• Korean Chemical Engineering Research
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• v.55 no.2
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• pp.270-274
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• 2017

Formic acid has been known as one of key sources of hydrogen. Among various monometallic catalysts, hydrogen can be efficiently produced on Pd catalyst. However, the catalytic activity of Pd is gradually reduced by the blocking of active sites by CO, which is formed from the unwanted indirect oxidation of formic acid. One of promising solutions to overcome such issue is the design of alloy catalyst by adding other metal into Pd since alloying effect (such as ligand and strain effect) can increase the chance to mitigate CO poisoning issue. In this study, we have investigated formic acid deposition on the bimetallic $Pd/Pd_3Fe$ core-shell nanocatalyst using DFT (density functional theory) calculation. In comparison to Pd catalyst, the activation energy of formic acid dehydrogenation is greatly reduced on $Pd/Pd_3Fe$ catalyst. In order to understand the importance of alloying effects in catalysis, we decoupled the strain effect from ligand effect. We found that both strain effect and ligand effect reduced the binding energy of HCOO by 0.03 eV and 0.29 eV, respectively, compared to the pure Pd case. Our DFT analysis of electronic structure suggested that such decrease of HCOO binding energy is related to the dramatic reduction of density of state near the fermi level.

• Korean Journal of Materials Research
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• v.11 no.8
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• pp.629-635
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• 2001

To improve the ductility of $A1_3Hf$ intermetallics, which are the potential high temperature structural materials, the mechanical alloying behavior. the effect of Cu addition on the $Ll_2$ phase formation and the behavior of vacuum hot-pressed consolidation were investigated. During the mechanical alloying by SPEX mill, the $Ll_2 A1_3Hf$ intermetallics with the grain size of 7~8nm was formed after 6 hours of milling in Al-25at.%Hf system. The $Ll_2$ Phase of Al_3Hf$ intermetallics with the addition of 12.5at.%Cu, similar to that of the binary Al-25at.% Hf, was formed, but the milling time necessary for the formationof the $Ll_2$ phase was delayed form 6 hours to 10 hours. The lattice parameter of ternary $Ll_2(Al+Cu)_3Hf$ intermetallics decreased with the increase of Cu content. The onset temperature of $Ll_2$ to $D0_{23}$ phase in $Al_3Hf$ intermetallics was around 38$0^{\circ}C$, the temperature upon completion varied from 48$0^{\circ}C$ to 5$50^{\circ}C$ as the annealing time. The onset temperature of $Ll_2$ to $D0_{23}$ phase transformation in $(Al+ Cu)_3Hf$ intermetallics increased with the amount of Cu and the highest onset temperature of $700^{\circ}C$ was achieved by the Cu addition of 10at.%. The relative density increased from 89% to 90% with the Cu addition of 10at.% in $Al_3Hf$ intermetallics hot-pressed in vacuum under 750MPa at 40$0^{\circ}C$ for 3 hours. The relative density of 92.5% was achieved without the phase transformation and the grain growth as the consolidation temperature increased from 40$0^{\circ}C$ to 50$0^{\circ}C$ in $(Al+Cu)_3Hf$ intermetallics hot-pressed in vacuum under 750MPa for 3 hours.

• The Journal of Engineering Geology
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• v.33 no.1
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• pp.105-119
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• 2023

Water supply is decreasing due to climate change, and coastal and island regions are highly dependent on groundwater, reducing the amount of available water. For sustainable water supply in coastal and island regions, it is necessary to accurately diagnose the current condition and efficiently distribute and manage water. For a precise analysis of the groundwater flow in the coastal island region, submarine fresh groundwater discharge was calculated for the Seongsan basin in the eastern part of Jeju Island. Two methods were used to estimate the thickness of the fresh groundwater. One method employed vertical interpolation of measured electrical conductivity in a multi depth monitoring well; the other used theoretical Ghyben-Herzberg ratio. The value using the Ghyben-Herzberg ratio makes it impossible to accurately estimate the changing salt-saltwater interface, and the value analyzed by electrical conductivity can represent the current state of the freshwater-saltwater interface. Observed parameter was distributed on a virtual grid. The average of submarine fresh groundwater discharge fluxes for the virtual grid was determined as the watershed's representative flux. The submarine fresh groundwater discharge and flux distribution by year were also calculated at the basin scale. The method using electrical conductivity estimated the submarine fresh groundwater discharge from 2018 to 2020 to be 6.27 × 10⁶ m³/year; the method using the Ghyben-Herzberg ratio estimated a discharge of 10.87 × 10⁶ m³/year. The results presented in this study can be used as basis data for policies that determine sustainable water supply by using precise water budget analysis in coastal and island areas.

• Applied Microscopy
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• v.39 no.4
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• pp.341-348
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• 2009

The crystal structure of nano-crystalline, $BaTiO_3$, with the average particle size of 100 nm was investigated using electron diffraction techniques. We characterized the precession electron diffraction system and then carried out the structure determination using precession electron diffraction and conventional selected area electron diffraction. As a result, it was revealed that $BaTiO_3$ nano-crystalline exist as a mixture of tetragonal structure and cubic structure by precession electron diffraction technique. In addition, it could be turned out that $BaTiO_3$ nano-crystalline is a core-shell structure consisted of a tetragonal phased core and a cubic phased surface layer by theoretical calculation. The thickness of the cubic surface layer was approximately 8.5 nm and the lattice parameters of cubic and tetragonal phases were a=3.999${\AA}$ and a=3.999${\AA}$, c=4.022${\AA}$, respectively. Finally, it is expected that precession electron diffraction is more useful technique for structure determination of complicated nano-crystalline materials because of its higher spatial resolution and minimization of dynamical scattering effect.

• Journal of Korean Ophthalmic Optics Society
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• v.7 no.2
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• pp.209-215
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• 2002

This study investigated the crystal growth, crystalline structure and the basic optical properties of $SnSe/BaF_2$ epilayers. The SnSe epilayer was grown on $BaF_2$(111) insulating substrates using a hot wall epitaxy(HWE) technique. It was found from the analysis of X-ray diffraction patterns that $SnSe/BaF_2$ epilayer was growing to single crystal with orthorhombic structure oriented [111] along the growth direction. Using Rutherford back scattering(RBS), the atomic ratios of the SnSe was found to be stoichiometric, almost 50 : 50. The best values for the full width at half maximum (FWHM) of the DCXRD was 163 arcsec for SnSe epilarer. The epilayer-thickness dependence of the FWHM of the DCXRD shows that the quality of the $SnSe/BaF_2$ is as expected. The dielectric function ${\varepsilon}$(E) of a semiconductor is closely related to its electronic energy band structure and such relation can be drawn from features around the critical points in the optical spectra. The real and imaginary parts(${\varepsilon}_1$ and ${\varepsilon}_2$) of the dielectric function ${\varepsilon}$ of SnSe were measured. These data are analyzed using a theoretical model known as the model dielectric function(MDF). The optical constants related to dielectric function such as the complex refractive index(n*-n+ik), absorption coefficient (${\alpha}$) and normal- incidence reflectivity (R) are also presented for $SnSe/BaF_2$.

• The Journal of the Acoustical Society of Korea
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• v.30 no.1
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• pp.33-41
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• 2011

To substitute TLS in the hybrid system which is combined with Sagnac interferometer and fiber bragg grating (FBG) it is necessary to investigate how the laser source (TLS and CW) and sensor material variate the response of fiber optic sensor. Two different hollow cylinder type mandrel materials are proposed which are PTFE and PTFE+carbon and 18 m optical fiber is wounded at the mandrel surface. CW laser source experiments had been done in the oil tank which is filled with transformer oil in the 1 kHz~20 kHz frequency range. Also Sagnac interferometer fiber optic sensor is combined with FBG called hybrid system and TLS used as a light source. Based on the experimental results PTFE sensor showed more higher magnitude of detection signal rather than carbon sensor and this result is agreement with the McMahon's theoretical results. Phase variation is inversely proportional to the elastic modulus of the mandrel material. In PTFE fiber sensor, tunable laser source showed more higher performance rather than CW case. Therefore, TLS fiber optic sensor can be applied to the hybrid system which is combined with Sagnac and FBG.

• Journal of Korea Water Resources Association
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• v.38 no.12 s.161
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• pp.985-994
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• 2005

We examined problems of the principal component analysis(PCA), which is able to analyze at the low dimensionality as a methodologv to assess hydrologic time series, and introduced the theory and characteristics of independent component analysis(ICA) that can supplement problems of principal component analysis. We also applied the global sea surface temperature(SST) of the Nino region and assessed the correlation between El $\tilde{n}ino$-Southern Oscillation(ENSO) and SST. The results of examining separation-ability of principal components using mixed signals indicate that the independent component analysis is statistically superior compared to that of the principal component analysis. Finally, we assessed correlation between ENSO and global anomaly SST. The independent component analysis was applied to the $5^{\circ}{\times}5^{\circ}$(latitude and longitude) global anomaly SST in the Nino+3.4 region that is the El $\tilde{n}ino$ observation section. We assessed the correlation with the ENSO years. These results of the analysis show that only one independent component($86\%$) was able to represent the entire behavior and was consistent with the main ENSO years. Finally, we carried out independent component analysis for summer seasonal rainfalls at nine stations and could extract ICs to reflect geographical characteristics. The increasing trend has been shown at IC-1 and IC-2 since 1970s.

• Science of Emotion and Sensibility
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• v.18 no.4
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• pp.3-14
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• 2015

This study has extracted observation data by spatial factor for the analysis of subjects' selective attention with the objects of public space at the entrance of subway stations. The methods extracting observation data can be summarized as the following. First, the frequency analysis by lattice was prevalent for those methods, but there is a limitation to the analysis of the observation data. On the contrary, the method extracting observation data by factor applied in this study can make it clear if any sight is concentrated on any particular factors in a space. Second, the results from the extracted data corresponding to the observation area can be objectified while the method setting up the observation area by applying the radius of fovea. Third, time-sequential trace of observation results of relevant factors was possible through hourly analysis of spatial factors. The consideration of the results of "corresponding spatial scope" which is the object of this study will reveal that the more the observation time, the less the degree of attention it receives. Fourth, the frequency of observation superiority was applied for the analysis of the sections with selective attention by time scope; this revealed that men and women had intensive observation in time scope I (52.4 %) and in time scope IV (24.0 %), respectively.