• Applied Chemistry for Engineering
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• v.7 no.6
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• pp.1147-1155
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• 1996

In the spray drying with rotating wheel atomizer of cheese powder, the relationships among variables were analyzed with Response Surface Methodology in which several independent variables such as total solid content, wheel rotation speed, and outlet temperature influenced dependent variables such as particle diameter, moisture content, bulk density, and viscosity of suspended liquid. Significance and correlation were tested according to central composite design. As a results of analyzing the correlations between independent and dependent variables, particle diameter and moisture content of cheese powder were decreased with increasing wheel rotation speed, and bulk density was decreased with increasing outlet temperature. Viscosity of suspended liquid were increased with increasing wheel rotation speed and total moisture content. In correlation among dependent variables, moisture content was proportional to bulk density, and particle diameter was inversly proportional to moisture content and bulk density.

• Resources Recycling
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• v.12 no.4
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• pp.30-37
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• 2003

A kinetics study on the dissolution reaction of zinc-ferrite has been made with aqueous sulfuric acid in various temperature and concentration. Fraction reacted(R) and apparent rate constant(K) increased with increasing temperature and concentration of sulfuric acid solution. The rate of dissolution is shown by $1-(1-K)^{1/3}=Kt$ for the initial stage of the reaction in aqueous sulfuric acid, where K is apparent rate constant, R is fraction reacted and t is reaction time, respectively. Activation energy associated with reaction was determined to be 16.3 kcal/mole. The dissolution of zinc-ferrite in sulfuric acid solution is dissolved by sto-ichiometric composition, but Fe and Zn did not dissolved, respectively.

• Investigative Magnetic Resonance Imaging
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• v.18 no.3
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• pp.208-218
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• 2014

Purpose : To evaluate the relationship between the speed of enhancement of hepatic hemangiomas on gadolinium-enhanced MRI and ADC values by using various parameters, including the D, f, $D^*$ and $ADC_{fit}$ on intravoxel incoherent motion (IVIM) MR Imaging. Materials and Methods: The institutional review board approved this retrospective study. A total of 47 hepatic hemangiomas from 39 patients were included (20 men and 19 women). The hemangiomas were classified into three types according to the enhancement speed of the hepatic hemangiomas on gadolinium-enhanced dynamic T1-weighted images: rapid (Type A), intermediate (Type B), and slow (Type C) enhancement. The D, f, $D^*$ and $ADC_{fit}$ values were calculated using IVIM MR imaging. The diffusion/perfusion parameters and ADC values were compared among the three types of hemangiomas. Results: Both the $ADC_{fit}$ and D values of type C were significantly lower than those of type A (P = 0.0022, P = 0.0085). However, for the f and $D^*$, there were no significant differences among the three types. On DWI with all b values (50, 200, 500 and $800sec/mm^2$), the ADC values of type C were significantly lower than those of the type A (P < 0.012). For b values with $800sec/mm^2$, the $ADC_{800}$ values of the type C hemangiomas were significantly lower than those of type B (P = 0.0021). We found a negative correlation between hepatic hemangioma enhancement type and $ADC_{50}$ (${\rho}=-0.357$, P = 0.014), $ADC_{200}$ (${\rho}=-0.537$, P = 0.0001), $ADC_{500}$ (${\rho}=-0.614$, P = 0.0001), and $ADC_{800}$ (${\rho}=-0.607$, P = 0.0001). Therefore, four ADC values of $ADC_{50}$, $ADC_{200}$, $ADC_{500}$, and $ADC_{800}$ were decreased with decreasing enhancement speed. Conclusion: Hepatic hemangiomas had variable ADCs according to the type of enhancement, and the reduced ADCs in slowly enhancing hemangiomas may be related to the reduced pure molecular diffusion (D).

• The Korean Journal of Rheology
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• v.7 no.3
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• pp.181-191
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• 1995

점탄성유체의 물성치들 중 정압열팽창계수 및 밀도는 자연대류 열전달 연구에 전단 속도 0에서의 점도는 점탄성유체에 대한 모델들 사용 시 필요하다. 본 연구에서는 점탄성유 체이며 마찰 감소 첨가제, 유전자 분리용액동으로 사용하는 Separan AP-273 용액의 정압열 팽창계수, 밀도 및 전단속도 0에서의 점도에대한 농도 및 온도의 영향을 조사하였다. 작동유 체의 물성치들은 10~6$0^{\circ}C$의 온도범위와 100~20,000wppm의 농도범위에서 측정되었다. 작 동유체의 물성치들에 미치는 열주기와 노화의 영향을 조사하기 위해서 정압열팽창계수와 전 단속도 0에서의 점도를 교대로 두 번씩 측정했다. 정압열팽창계수 및 밀도를 측정하는 장치 의 측정 정밀도는 증류수에 대한 측정치와 문헌에 나타난 자료를 비교하여 얻었고 이는 $\pm$ 2%이내였다. Separan AP-273용액의 정압열팽창계수 및 밀도는 증류수의 값들로 대치될수 있다. 작동유체의 정압열팽창계수와 밀도는 열주기와 노화의 영향을 받지 않았다. 낙하식 점 도계를 사용해 측정한 겉보기점도 값들을 나타내느 flow curve에서 전단속도가 0이 되는방 향으로 겉보기점도를 외삽시켜 Separan AP-273용액에 대한 전단속도0에서의 점도를 얻었 다. 정압열팽창계수 측정 전후에 측정한 작동유체에 대한 전단속도 0에서의 점도는 열주기 와 노화로 인해 퇴화되었다.

• Proceedings of the Membrane Society of Korea Conference
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• 1997.10a
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• pp.111-113
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• 1997

1. 서론 : "Engaged type"의 2축 RDM은 housing의 부피에 대한 막면적을 극대화시키고 회전방향을 엇갈리게 함으로서 유체의 겉보기속도를 증가시키고 막표면에서 난류와 2차흐름을(secondary flow)를 형성시켜 농도분극층이 감소하여 막오염을 최소화할 수 있다. 본 연구에서는 2축 RDM으로 실제 열간 압연유 폐수를 적용하여 농축실험을 하였으며 투과 특성과 농축수의 열간 압연유 입자 분포의 변화를 조사하였다.변화를 조사하였다.

• The Korean Journal of Rheology
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• v.6 no.2
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• pp.157-164
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• 1994

인체 동맥혈관내 혈액의 유동현상을 수치적으로 해석하기 위해서는 혈액의 유변학 적 성질을 구성방정식으로 나타내어야한다. 본 연구에서는 혈액의 점성계수를 표현하기 위 하여 비뉴턴유체의 점성을 나타내는 식으로서 Carreau 모델, 수정 Cross 모델, 수정 Powell-Eyring 모델과 수정멱법칙모델을 사용하였고 원형관내 혈액의 정상유동을 수치모사 하기 위하여 겉보기점성계수를 이용하는 구성방정식을 운동량방정식에 적용하였다. Carreau 모델과 수정멱법칙모델을 적용할 때 레이놀즈수의 변화가 중심선상의 속도와 길이방향의 압 력변화에 미치는 영향을 고찰하였다. 전단율이 높은영역에서 혈액의 겉보기점성계수를 효과 적으로 나타낼수 있는 수정멱법칙모델을 제시하였다.

• KSBB Journal
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• v.14 no.6
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• pp.639-642
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• 1999

Optimization of the chitosanoligosaccharide production was studied with chitosanase. The optimum conditions for the enzymic reaction have been determined. Enzyme stability was maintained above 90% after 6 days at pH 5.0. The optimum initial reaction rate was appeared in 1.0% of chitosan solution. The production yield of chitosanoligosaccharides was over at 0.4%~2.0% of chitosan. At 4.0% of chitosan solution, however, the production yield was decreased to 64.6%. To increase the yield, stepwise addition of substrate into the reactor was investigated. In this case, the yield was increased from 64.6% to 83.2% and the final concentrations of chitosanoligosaccharide was 12.26 mg/mL. By TLC analysis, most of the chitosanoligosaccharides produced were 3-5 mers.

• Journal of the Korean Ceramic Society
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• v.35 no.6
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• pp.569-574
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• 1998

The thickness of flame zone reaction rate and apparent activation energy in the formation reaction of $Ti_3AI$ intermetallic compound were investigated using SHS method which sustains the reaction spontaneously and utilizes the heat generated by thye exothermic reaction itself. In this reaction the thickness of flame zone was 1.4 mm and the reaction rate was $0.4g/\textrm{cm}^2{\cdot}sec$. Also the apparent activation energy calculated using from the experimental data obtained by controlling the realtive green density was 40kJ/mol.

• Korean Journal of Ecology and Environment
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• v.39 no.4 s.118
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• pp.450-461
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• 2006

In this study, sorption kinetics of lead (Pb) and cadmium (Cd) onto coastal sediments were investigated at pH 5.5 using laboratory batch adsorbers. Four different models: one-site mass transfer model (OSMTM), pseudo-first-order kinetic model (PFOKM) ,pseudo-second-order kinetic model (PSOKM) and two compartment first-order kinetic model (TCFOKM) were used to analyze the sorption kinetics. As expected from the number of model parameters involved, the three-parameter TCFOKM was better than the two-parameter OSMTM, PFOKM and PSOKM in describing sorption kinetics of Pb and Cd onto sediments. Most sorption of Pb and Cd was rapidly completed within the first three hours, followed by slow sorption in the subsequent period of sorption. All models predicted that the sorbed amount at the apparent sorption ($q_{e,s}$) equilibria increased as the CEC and surface area of the sediments increased, regardless of initial spiking concentration ($C_0$) and heavy metal and the sediment type. The sorption rate constant ($k_s,\;hr^{-1}$) in OSMTM also increased as the CEC and BET surface area increased. The rate constant of pseudo-first-order sorption ($k_{p1,s},\;hr^{-1}$) in PFOKM were not correlated with sediment characteristics. The results of PSOKM analysis showed that the rate constant of pseudo-second-order sorption ($k_{p2,s},\;g\;mmol^{-1}\;hr^{-1}$) and the initial sorption rate ($v_{o,s},\;mg\;g^{-1}\;hr^{-1}$) were not correlated with sediment characteristics. The fast sorption fraction ($f_{1,s}$) in TCFOKM increased as CEC and BET surface increased regardless of initial aqueous phase concentrations. The sorption rate constant of fast fraction ($k_{1,s}=10^{0.1}-10^{1.0}\;hr^{-1}$) was much greater than that of slow sorption fraction ($k_{2,s}=10^{-2}-10^{-4}\;hr^{-1}$) respectively.

• Korean Journal of Food Science and Technology
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• v.16 no.4
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• pp.451-456
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• 1984

Rheological properties of gelatinized rice starch solutions were investigated with Brookfield rotational viscometer. The 8% starch solution showed thixotropic behavior with yield stress. The alkali gelatinized starch was more thixotropic than the thermal gelatinized one. The time dependent characteristics of starch solutions followed Tiu's model. The value of rate constant $(a_1)$ in Tiu's model increased linearly with shear rate, and was exponentially dependent on concentration and temperature. Temperature dependency of rate constant and apparent viscosity followed Arrhenius type equation and the activation energy were about 14.3 and 6.8 Kcal/g mole, respectively. The $a_1-value$ was found to be useful to evaluate changes in structaral decay on the shearing time of gelatinized rice starch solutions.