• Title/Summary/Keyword: 건식제련

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Recovery of Tin from Tin Oxide Resulted from Glass Manufacturing Process by Pyrometallurgy (유리생산공정 폐주석산화물에서 건식제련에 의한 주석회수기술)

  • Lee, Sang-Ro;Kim, Sang-Yeol;Lee, Man-Seung;Park, Man-Bok
    • Resources Recycling
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    • v.24 no.2
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    • pp.23-28
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    • 2015
  • Most of the domestic need for tin rely on imports. In this work, a pyrometallurgical process was investigated to recover pure tin from the tin oxides in tin bath which results from the production of flat glass and LCD panel. From the results on the effect of reaction temperature, the highest recovery percentage of tin was obtained at $1350^{\circ}C$. The recovery percentage of tin was improved to 88% by employing the first and second smelting step. Electrorefining of the crude tin thus obtained led to pure tin with purity higher than 99.9%.

A Study on the Optimization of a Flash Smelting Process for Copper Production (구리 자용제련 공정의 최적화에 관한 연구)

  • 서경원;조석연
    • Journal of Energy Engineering
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    • v.4 no.1
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    • pp.153-161
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    • 1995
  • 건식 제련법에 의한 자용제련 공정에 대하여 공정비용을 최소화시키고 최적 조업조건을 제시할 수 있는 최적화 모델을 개발하였다. 본 모델은 Outokumpu 공정을 기본으로 하여 물질 및 에너지 수지식과 비용 방정식을 포함하였으며 주어진 공정조건에서 공업용 산소량, 탄화수소 연료량, 원료 정광의 구리함량, matte의 구리함량 및 전기료 등이 공정비용에 미치는 영향을 계산할 수 있었다. 모델에 의한 계산결과 25% 구리정광을 원료로 하여 자용제련을 할 경우 matte의 최적 구리함량은 65%, 산화용 가스의 최적 산소함량은 53.4%, 최소 공정비용은 $9.22/ton정광이었다.

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Current Status of Zinc Smelting and Recycling (아연의 제련 및 리사이클링 현황)

  • Sohn, Ho-Sang
    • Resources Recycling
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    • v.28 no.5
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    • pp.30-41
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    • 2019
  • Global production of zinc is about 13 million tons and zinc is the fourth-most widely used primary metal in the world following iron, aluminum and copper. When zinc is recycled to produce secondary zinc, it can save about 75 % of the total energy that is needed to produce the primary zinc from ore, and in therms of $CO_2$ emissions reduced by about 40 %. However, since zinc is mainly used for galvanizing of steel, the recycling rate of zinc is about 25 %, which is lower than other metals. The raw materials for recycling of zinc include dusts generated in the production of steel and brass, sludge in the production process of non-ferrous metals, dross in the melting of zinc ingots or hot dip galvanizing, waste batteries, and metallic scrap. Among them, steelmaking dust and waste batteries are most actively recycled up to now. Most of the recycling process uses pyrometallurgical methods. Recently, however, much attention has been given to a combined process of pyrometallurgical and hydrometallurgical processes.

Recovery of High Purity Sn by Multi-step Reduction of Sn-Containing Industrial Wastes (건식 환원 공정을 이용한 고순도 주석 회수)

  • Lee, Sang-Ro;Lee, Man-Seung;Kim, Hyun You
    • Resources Recycling
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    • v.24 no.3
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    • pp.11-15
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    • 2015
  • In order to develop a technology for the recovery of pure tin from the Sn containing industrial wastes (SIWs), a process consisted of high temperature reduction and electrorefining was investigated. The tin which exists as oxide in SIWs was successfully reduced by two consecutive high temperature treatments and 92.7% of the tin was recovered. The purity of the tin thus obtained was increased to 99.87% by electrorefining. By applying the results obtained in this work, a commercial process can be developed to produce pure tin metals from domestic spent resources, which can reduce the amount of tin imported from abroad.

Current Status of Nickel Smelting Technology (니켈 제련기술의 현황)

  • Sohn, Ho-Sang
    • Resources Recycling
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    • v.30 no.2
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    • pp.3-13
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    • 2021
  • Nickel is widely used due to its excellent toughness, malleability and enhanced corrosion resistance. Therefore, nickel is indispensable in our daily lives, and it is widely used in basic to advanced applications such as stainless steel, super alloys and electronic devices. Recently, nickel has been widely used as the major material in secondary batteries and capacitors. The use of nickel continues to rise and has increased from 800 thousand tonnes per year worldwide in the 1970s to about 2 million tonnes in the 2010s. However, nickel is a representative rare metal and ranks 23rd among the abundant elements in the earth's crust. This study reviews the current status of the nickel smelting processes as well as the trend in production amount and use. Nickel is extracted by a wide variety of smelting methods depending on the type of ore. These smelting methods are essential for the development of new recycling processes that can extract nickel from secondary nickel resources.

Analyses of Physical Properties of Copper-contained Sludge Pelletized for Applied Pyro-metallurgical Process (건식제련용 동 함유 슬러지 펠렛 제조 및 물리적 특성평가)

  • Kim, Suyun;Kim, Youngjin;Kim, Seunghyun;Lee, Jaeryeong
    • Resources Recycling
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    • v.28 no.2
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    • pp.31-39
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    • 2019
  • The pelletizing of printed circuit board (PCB) sludge was researched for copper recovery in pyrometallurgical process. This pelletizing was carried out by using self-manufactured compression-type apparatus after pre-treatments (drying, water scrubbing, size classification) were proceeded. The physical properties (compression strength and drop-breakage test) were tested with a change of sludge sizing and the number of compression. In the case of using the undersized sludge of #140, its properties were improved to 0.6 MPa and 9.3 times. Moreover, they increased to 0.82 MPa and 19.0 times by using the #140 ~ 325 sludge. These imply that the packing density increases due to the elimination of large-sized sludge (#140), and also the weight of required binder decreases by the removal of fine-sized sludge (#325).

A Study on Classification of Limonite and Saprolite from Nickel Laterite Ores (뉴칼레도니아산 니켈라테라이트광의 분급 연구)

  • Seo, Joobeom;Kim, Kee-seok;Bae, In-kook;Lee, Jae-young;Kim, Hyung-seok
    • Resources Recycling
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    • v.25 no.1
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    • pp.40-47
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    • 2016
  • Nickel laterite ore is classified into two principal ore types: saprolite (silicate ore) and limonite (oxide ore). Saprolite-type ore characterized by high magnesia and silica contents is treated by pyrometallurgy process. On the other hand, limonite-type ore is subjected to hydrometallurgy process to produce nickel products. Hydrometallurgy process requires that a raw material to meet the demands that Si+Mg contents lower than 10% and Fe content over than 40%. It is therefore required that separation of saprilite-type ore to use nickel laterite ore as a raw material for hydrometallurgy process. In this study, separation of sparolite-type ore and limonite-type ore from nickel laterite ore from New Caledonia has been tried by dry classification. The results show that -5 mm size fraction and +5 mm size fraction of the nickel laterite ore contains mainly limonite-type ore and saprolite-type ore, respectively. To understand the moisture content of the raw ore on the dry classification, nickel laterite ore with different moisture contents of 23.0% and 9.1% were subjected to the dry classification. The results show that drying of the ore makes the separation more efficient as the amount of the fine product, that can be subjected to hydrometallurgy process without further separation or drying operations, was increased.

Current Status of Lead Smelting and Recycling (납의 제련 및 리사이클링 현황)

  • Sohn, Ho-Sang
    • Resources Recycling
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    • v.28 no.4
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    • pp.3-14
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    • 2019
  • Lead is one of the common non-ferrous metals used in modern industry. The usage of lead continues to increase and has risen from 5 million tonnes per year worldwide in the 1970s to 11 million tonnes in the 2010s. In principle lead is virtually 100 % recyclable as an element without loss of quality. The recycling of lead scrap reduces the energy consumption and environmental burden, comparing to the primary metal production. Therefore production of secondary lead from scrap has been steadily growing and at present it meets approximately 60 % of usage worldwide. Lead scrap (mainly lead-acid battery) is smelted in primary and secondary smelter. Most secondary lead smelting were performed in a shaft-type furnace (blast furnace), rotary furnace and reverberatory furnace. The lead bullion is either cast into ingots and re-melted in refining kettles or refining is performed on the hot lead bullion immediately after production. This work provides an overview of the primary lead production and recycling process.

Recovery of Rare Earth Metal from Used Automotive Three-Way Catalyst (자동차용 폐 삼원촉매로부터의 희귀금속 회수공정 기술 동향)

  • Hong, Yeon Ki
    • Journal of Institute of Convergence Technology
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    • v.1 no.1
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    • pp.13-17
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    • 2011
  • The car industry is one of the technological applications which more rare earth metals employes as three-way catalysts. Therefore, the recovery of rare earth metals from the used automotive three-way catalysts could be important source to obtain these metals. This work presents the analysis of market and demand for rare earth metal in automotive three-way catalyst and introduces the dry and the wet processes for the recovery of rare earth metals from used three-way catalyst. Finally, the alternative methods to conventional wet processes was simply suggested based on the economic and ecological point of view.

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