• Title/Summary/Keyword: 거품

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Interfacial Properties of Imidazoline Cationic Surfactant (Imidazoline 양이온 계면활성제의 계면 특성)

  • Kim, Ji Sung;Lim, Jong Choo
    • Korean Chemical Engineering Research
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    • v.47 no.1
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    • pp.38-45
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    • 2009
  • In this study, interfacial properties were measured for imidazoline type cationic surfactant system which has been widely used as a fabric softener, a dispersant, an anti-static agent, a bleach activator, and an emulsifier. The CMC of imidazoline surfactant was near $6{\times}10^{-5}mol/L$ and the surface tension at CMC was about 32 mN/m. It was found that surface tension was not affected by surfactant concentration but decreased with an increase in pH. The interfacial tension between 1 wt% aqueous solution and n-dodecane was shown to be about 0.01 mN/m and equilibration time was not affected by pH. Phase behavior experiment in a binary aqueous surfactant system showed that only micellar solution of $L_1$ phase was found under conditions of temperature and pH investigated during this study. Only a two-phase region consisting of lower-phase microemulsion in equilibrium with excess oil phase existed under the same conditions, when oil was added to the binary surfactant system. The foam stability measured with 1 wt% surfactant solution increased with pH, which is consistent with surface tension measurement result. QCM(quartz crystal microbalance) measurement showed that surfactant adsorption increased with surfactant concentration but decreased with pH. According to the friction measurement, best fabric softening effect by imidazoline surfactant system was found under alkali conditions.

Expectation-Based Model Explaining Boom and Bust Cycles in Housing Markets (주택유통시장에서 가격거품은 왜 발생하는가?: 소비자의 기대에 기초한 가격 변동주기 모형)

  • Won, Jee-Sung
    • Journal of Distribution Science
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    • v.13 no.8
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    • pp.61-71
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    • 2015
  • Purpose - Before the year 2000, the housing prices in Korea were increasing every decade. After 2000, for the first time, Korea experienced a decrease in housing prices, and the repetitive cycle of price fluctuation started. Such a "boom and bust cycle" is a worldwide phenomenon. The current study proposes a mathematical model to explain price fluctuation cycles based on the theory of consumer psychology. Specifically, the model incorporates the effects of buyer expectations of future prices on actual price changes. Based on the model, this study investigates various independent variables affecting the amplitude of price fluctuations in housing markets. Research design, data, and methodology - The study provides theoretical analyses based on a mathematical model. The proposed model uses the following assumptions of the pricing mechanism in housing markets. First, the price of a house at a certain time is affected not only by its current price but also by its expected future price. Second, house investors or buyers cannot predict the exact future price but make a subjective prediction based on observed price changes up to the present. Third, the price is determined by demand changes made in previous time periods. The current study tries to explain the boom-bust cycle in housing markets with a mathematical model and several numerical examples. The model illustrates the effects of consumer price elasticity, consumer sensitivity to price changes, and the sensitivity of prices to demand changes on price fluctuation. Results - The analytical results imply that even without external effects, the boom-bust cycle can occur endogenously due to buyer psychological factors. The model supports the expectation of future price direction as the most important variable causing price fluctuation in housing market. Consumer tendency for making choices based on both the current and expected future price causes repetitive boom-bust cycles in housing markets. Such consumers who respond more sensitively to price changes are shown to make the market more volatile. Consumer price elasticity is shown to be irrelevant to price fluctuations. Conclusions - The mechanism of price fluctuation in the proposed model can be summarized as follows. If a certain external shock causes an initial price increase, consumers perceive it as an ongoing increasing price trend. If the demand increases due to the higher expected price, the price goes up further. However, too high a price cannot be sustained for long, thus the increasing price trend ceases at some point. Once the market loses the momentum of a price increase, the price starts to drop. A price decrease signals a further decrease in a future price, thus the demand decreases further. When the price is perceived as low enough, the direction of the price change is reversed again. Policy makers should be cognizant that the current increase in housing prices due to increased liquidity can pose a serious threat of a sudden price decrease in housing markets.

Characteristics of Whey Protein (WPC-30) Hydrolysate from Cheese Whey (치즈유청으로부터 제조한 유청단백질 가수분해물의 특성에 관한 연구)

  • Yoon, Yoh-Chang;An, Sung-Il;Jeong, A-Ram;Han, Song-Ee;Kim, Myeong-Hee;Lee, Chang-Kwon
    • Journal of Animal Science and Technology
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    • v.52 no.5
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    • pp.435-440
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    • 2010
  • Whey protein concentrate (WPC) is widely used to increase the nutritional and functional properties of food. In this study, the physiochemical and functionality of WPC-30 hydrolysates were examined to evaluate the possibility of application in the food industry. The WPC-30 was manufactured using ultrafiltration and spray-drying, and then hydrolyzed with proteolytic enzyme including alcalase, flavourzyme, nuetrase and protamex. Enzymatic hydrolysis had a significant influence on the physicochemical properties as evident from the increased foaming capacity, solubility. Alcalase caused highest protein hydrolysis (3.26%) and the bitterness. Foaming capacity was largest in WPC-30 hydrolysate treated with flavourzyme. Protein solubility at various levels of pH was highest in protamex-treated WPC-30 hydrolysate. However, the solubility of WPC-30 hydrolysates was significantly improved in alkaline condition than in acidic and neutral conditions. The study revealed that spray dried enzyme modified WPC can be used in various functional food.

Effects of Wind Depending on Tracers in an Application of LSPIV (LSPIV 적용시 Tracers에 따른 바람의 영향)

  • Kim, Young-Sung;Yang, Jae-Rheen
    • Proceedings of the Korea Water Resources Association Conference
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    • 2007.05a
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    • pp.836-840
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    • 2007
  • Large-Scale Particle Image Velocimetry (LSPIV)는 Particle Image Velocimetry (PIV)를 자연하천이나 실험실에서 넓은 영역($4m^2{\sim}45,000m^2$)에 적용할 수 있도록 확장시킨 것으로 지난 10여년 이상 세계적으로 널리 이에 대한 연구가 진행되고 있다. PIV는 seeding, illumination, recording 그리고 image processing으로 구성된다. LSPIV(Large Scale PIV)는 PIV의 기본원리를 근거로 하여 기존의 PIV에 비하여 실험실 내에서의 수리모형실험이나 일반 하천에서의 유속측정과 같은 큰 규모의 흐름해석을 할 수 있도록 seeding, illumination에 대한 조정이 필요하고, 촬영된 image에 대한 왜곡을 없애는 작업이 필요하다. LSPIV는 PIV의 네가지 단계를 포함하여 seeding, illumination, recording, image transformation, image processing 및 post-processing의 여섯 단계로 구성되어진다 (Li, 2002). LSPIV를 일반 하천에 적용시, 자연발생적인 tracers - 난류로 인한 표면 교란, 부유물, 수공구조물로 인해서 발생하는 자연 발생되는 거품 - 가 풍부해서 seeding이 불필요한 경우를 제외하고는 정확한 유속장의 해석을 위하여 인공적인 seeding을 필요로 한다. 일반적으로 Seeding 재료로 많이 이용되는 것은 wood mulch, Ecofoam, grain-straw 등이다. 하천에서 자연발생적 혹은 인위적 seeding을 하였을 때 이들 tracers의 물리적인 속성으로 바람에 쉽게 영향을 받고 이로 인하여 실제의 물표면유속을 대표하지 못하는 경우가 있다. 이에 실험실의 개수로에서 여러 가지 이용 가능한 tracers에 대하여 바람에 의한 오차 발생의 정도를 조사하였다. 실험에 사용된 seeding 재료로는 black polypropylene, Ecofoam, white polystyrene의 세가지를 이용하였다. black polypropylene (SG=0.92)과 white polystyrene (SG=0.0125)은 폭 1 m 이내의 개수로 실험 장치에서 유속장의 해석에 많이 이용되고 Ecofoam (SG=0.0065)은 수리 모형실험에서 많이 이용된다. seeding 물질에 따른 바람의 영향을 분석하기 위해서 폭 60cm의 개수로에서 seeding 물질을 변경하면서 펌프의 조작에 의해 3가지 단면평균유속을 발생시키고, 각 평균유속조건에 대해 4가지의 바람세기 - 바람이 없을 때와 팬의 바람세기를 1단, 2단, 3단으로 조정 - 를 발생시켰으며, 개수로위에서 촬영한 이미지의 상류측기준점으로부터 0.3556m 하류 지점을 횡단하는 단면의 표면유속을 측정하여 비교하였고, 그 단면의 중앙에서 물표면 바로 위 지점의 풍속을 측정하였다. 각 Seeding 물질에 대해 팬을 켜지 않았을 때, 즉 바람의 영향이 없을 때 측정한 표면유속을 바람의 세기가 변한 경우의 기준 표면유속으로 이용하였다. 본 연구의 결과 비중이 0.01 내외인 Ecofoam과 white polystyrene에 비해 비중이 0.92인 black polypropylene은 대부분이 물속에 잠겨 있어 흐름과 거의 일치하여 움직임을 알 수 있었다. 또한 흐름의 평균유속이 0.165 m/s의 저유속에서 바람이 tracers에 미치는 영향이 평균유속 0.558m/s인 경우보다 커서, 바람의 세기의 증가에 따라 표면유속 측정값이 급속히 감소되었다. 흐름의 평균유속이 큰 경우에는 바람이 tracer에 마치는 영향이 현격히 줄어듬을 보이고 있다. 결론적으로 유속이 증가함에 따라 바람의 영향은 감소하나, 바람의 영향을 최소화시키기 위해서는 가급적 비중이 큰 물질(0.5

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Characteristics of Byproduct After NaBH4 Hydrolysis Reaction Using Unsupported Catalyst (비담지 촉매를 이용한 NaBH4 가수분해반응에서 부산물의 특성)

  • Lee, Hye-Ri;Park, Dae-Han;Ju, Won;Na, Il-Chai;Park, Kwon-Pil
    • Korean Chemical Engineering Research
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    • v.55 no.1
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    • pp.13-18
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    • 2017
  • Sodium borohydride, $NaBH_4$, shows a number of advantages as hydrogen source for UAV PEMFC (Unmaned Aerial Vehicle Proton Exchange Membrane Fuel Cells). In order to use for UAV, the weight and volume of byproduct should be small after $NaBH_4$ hydrolysis reaction. Therefore, the weight and volume of byproduct were studied after $NaBH_4$ hydrolysis reaction using unsupported catalyst. The effect of catalyst type, concentration of $NaBH_4$, concentration of NaOH and thickness of catalyst pack on the weight and volume of byproduct were studied. Most of byproduct was $NaB(OH)_4$ and superficial volume of byproduct increased due to foam evolved from byproduct. The weight and volume of byproduct were not affected by concentration of NaOH used stabilizer. The weight of byproduct decreased as concentration of $NaBH_4$ solution increased, but maximum volume of byproduct obtained at 23 wt% of $NaBH_4$. Suitable defoaming agent reduced the volume of byproduct.

Numerical Modeling of Free Surface Flow over a Broad-Crested Rectangular Weir (사각형 광정위어를 통과하는 자유수면 흐름 수치모의)

  • Paik, Joongcheol;Lee, Nam Joo
    • Journal of Korea Water Resources Association
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    • v.48 no.4
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    • pp.281-290
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    • 2015
  • Numerical simulations of free surface flow over a broad-crested rectangular weir are conducted by using the volume of fraction (VOF) method and three different turbulence models, the k-${\varepsilon}$, RNG k-${\omega}$ and k-${\omega}$ SST models. The governing equations are solved by a second-order accurate finite volume method and the grid sensitivity study of solutions is carried out. The numerical results are evaluated by comparing the solutions with experimental and numerical results of Kirkgoz et al. (2008) and some non-dimensionalized experimental results obtained by Moss (1972) and Zachoval et al. (2012). The results show that the present numerical model can reasonably reproduce the experimental results, while three turbulent models yield different numerical predictions of two distinct zones of flow separation, the first zone is in front of the upstream edge of the weir and the second is created immediately behind the upstream edge of the weir where the flow is separated to form the separation bubble. The standard k-${\varepsilon}$ model appears to significantly underestimate the size of both separation zones and the k-${\omega}$ SST model slightly over-estimates the first separation zone in front of the weir. The RNG k-${\varepsilon}$ model predicts both separation zones in overall good agreement with the experimental measurement, while the k-${\omega}$ SST model yields the best numerical prediction of separation bubble at the upstream edge of the weir.

Surface Chemistry in Biocompatible Nanocolloidal Particles (생체 적합한 나노입자와 계면화학)

  • Kim Jong-Duk;Jung Jae Hyun
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.30 no.3 s.47
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    • pp.295-305
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    • 2004
  • Colloid and surface chemistry have been focused on surface area and surface energy. Local surface properties such as surface density, interaction, molecular orientation and reactivity have been one of interesting subjects. Systems of such surface energy being important would be listed as association colloid, emulsion, particle dispersion, foam, and 2-D surface and film. Such nanoparticle systems would be applied to drug delivery systems and functional cosmetics with biocompatible and degradable materials, while nanoparticles having its size of several nm to micron, and wide surface area, have been accepted as a possible drug carrier because their preparation, characteristics and drug loading have been inves-tigated. The biocompatible carriers were also used for the solubilization of insoluble drugs, the enhancement of skin absorption, the block out of UV radiation, the chemical stabilization and controlled release. Nano/micro emulstion system is classified into nano/microsphere, nano/microcapsule, nano/microemulsion, polymeric micelle, liposome according to its prep-aration method and size. Specially, the preparation method and industrial applications have been introduced for polymeric micelles self-assembled in aqueous solution, nano/microapsules controlling the concentration and activity of high concen-tration and activity materials, and monolayer or multilayer liposomes carrying bioactive ingredients.

The Changes of Timespace and Locality in the Yoseba, Kotobuki (요세바 고도부키에서의 시공간과 로컬리티의 변화)

  • Jo, Hyun-Mi
    • Journal of the Korean association of regional geographers
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    • v.22 no.2
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    • pp.383-396
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    • 2016
  • The most direct influence on the development of Yoseba Kotobuki was the end of World War II. As city rebuilding projects began vibrantly overlapping, the vitalization in Kotobuki was adopted by the laborers coming in from various parts throughout of the country. Just as the period of economic revival from the special demand created by the Korean War got underway, the aftermath of the worldwide economic recession due to the oil crisis had a direct effect on even the labor market. Moreover, as the vitality of the labor market gradually fizzled out from the long-term economic recession caused by the burst of the economic bubble, the labor base that had once been the pillar of the Japanese economy began to age and could no longer perform this role. As these aging laborers came to receive public assistance, the doya managers began repairing the doya and Kotobuki began to change again. The historical times which affected the changes in Yoseba Kotobuki's locality are in the lives of its members--the laborers--and the times themselves, which operate on the micro level; however, in those times, the national and the global time of the nation-state interact and are linked in multiple layers.

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Optimization of Ingredient Mixing Ratio for Preparation of Steamed Foam Cake with Added Saltwort (Salicornia herbacea L.) (함초 첨가 거품형 찜케이크의 재료 혼합비율의 최적화)

  • Kim, Yu-Suk;Kwak, Sung-Ho;Jang, Myung-Sook
    • Korean journal of food and cookery science
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    • v.22 no.5 s.95
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    • pp.666-680
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    • 2006
  • To obtain basic data for the utilization of saltwort (Salicornia herbacea L.) as a functional ingredient in steamed foam cake, the optimum component ratios for major raw ingredients (saltwort, salt, and wheat flour) as independent variables that affect the product quality were scientifically determined using RSM (response surface methodology) technique. A three-factor and five-level rotational central composite design was used for treatment arrangement. The complete design consisted of 16 experimental points. The three independent variables selected for the RSM experiment were amounts of saltwort (X$_1$, 5${\sim}$25 g), salt (X$_2$, 0${\sim}$10 g), and wheat flour (X$_3$, 470${\sim}$530 g). The optimum responses in specific gravity of the batter and volume, color, texture, and sensory evaluation result of the cake were obtained. The specific gravity and viscosity of the batter at p<0.01 was verified from the regression curve. The characteristic of the batter was influenced by all independent variables, but was extremely dependent on the amount of saltwort ordinary points of the surface responses from the batter formed the minimum points for specific gravities of the batter while viscosities of the batter appeared with the saddle points. Analysis of the response indicated that the amount of saltwort was the most influential factor over the physical properties of the cake, among the dependent variables. Ordinary points of the surface responses from the cake formed the maximum points for loaf volume, hardness gumminess, and chewiness, while Hunter colorimetric parameters appeared with the saddle points. The result indicated that level of the saltwort deviating more or less from the optimal amount decreased the volume and increased the specific gravity with less tender product. Ordinary points of the surface responses of the sensory evaluation scores from the cake formed the maximum points for appearance, flavor, softness, and overall acceptability, while color values appeared with the saddle points. The result also indicated that the level of the saltwort deviating more or less from the optimal amount reduced the preference for the product. Integration of the optimum responses common to all dependent variables that overlapped all the contour maps finally indicated that the combination of 8.3${\sim}$13.8 g saltwort, 2.5${\sim}$6.6 g salt, and 486.5${\sim}$511.5 g wheat flour under the selected preparation recipe optimized the physical and sensory properties in the teamed foam cakes. Practical preparation of the product with median amounts of the ingredients, i.e., 11.0 g saltwort, 4.6 g salt, and 499.0 g wheat flour resulted in similar qualities to the predicted responses. In conclusion, these study results indicated that preparation of steamed foam cake with added saltwort ingredient could potentially produce a more nutritious product with less salt. Further research is required to acquire the optimum levels for sub-ingredients to improve the product quality.

Synthesis and Properties of N-Acyl Glycine Used Triglyceride (트리글리세라이드를 이용한 N-아실 글리신의 합성 및 물성)

  • Shin, Hye-Rin;Park, Ye-Won;Jeong, Noh-Hee
    • Journal of the Korean Applied Science and Technology
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    • v.34 no.4
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    • pp.1058-1065
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    • 2017
  • Amino acid based surfactants as protein-surfactants is eco-friendly compound. So, amino acid based surfactants is expected as next generation surfactants. Amino acid based surfactants has high biodegradability, low toxicity and surface active properties. In this experiment, amino acid based surfactants, cocoyl glycine, was synthesized by glycine and triglyceride such as coconut oil and palm oil. And it was tested the surface tension, emulsifying properties, foam stability and HLB value. The synthesized surfactants was confirmed by FT-IR. Surface tension of surfactants synthesized by coconut oil on diluted aqueous solutions of surfactants was 31.2 dyne/cm at $1.0{\times}10^{-4}mol/L$. Surface tension of surfactants synthesized by palm oil on the diluted aqueous solutions of surfactants was 42.1 dyne/cm at $3.2{\times}10^{-5}mol/L$. Foam stability measured the foam height as time passed. Initial foam height of surfactants synthesized by coconut oil is 14.5 cm, and 10.7 cm after five minutes. Initial foam height of surfactants synthesized by palm oil is 3.0 cm, and 2.8 cm after five minutes. Foam height of surfactants synthesized by coconut oil was higher than surfactants synthesized by palm oil. But foam stability of surfactants synthesized by palm oil was better than surfactants synthesized by coconut oil. The emulsifying properties of synthesized surfactants are observed in benzene and soybean oil and emulsifying properties in organic solvent is better than in soybean oil.