• Composites Research
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• v.37 no.3
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• pp.238-245
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• 2024

In this study, as part of the development of a monitoring system for the efficient maintenance of steel pipes, an experimental study was conducted to evaluate the performance of steel pipes treated with modified polyethylene coating. In the case of the conventional mechanical pre-coating method, there was a deterioration in polyethylene adhesion during expansion testing, which led to the application of a chemical pre-treatment process using a calcium-mixed phosphate zinc film to resolve this issue. SEM and EDX analyses showed that the densest structure was observed at a Zn/Ca ratio of 1.0, and improved heat resistance compared to the conventional method was confirmed. Additionally, to prevent coating detachment during expansion, an evaluation of adhesion and elongation was conducted on steel pipes with modified polyethylene coating, incorporating materials such as elastomers based on maleic anhydride grafting, metal oxides, blocking agents, and slip agents. Experimental results showed that the specimen (S4) containing all modified materials exhibited more than a 25% performance improvement compared to the specimen (S2) containing only metal oxides. Lastly, the development and performance evaluation of wedge-shaped socketing and pressing wheels, which are part of the pipe fixing accessories, were conducted to prevent surface coating damage on the completed pipes.

• Proceedings of the Korean Fiber Society Conference
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• 1998.10a
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• pp.114-117
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• 1998

양모의 수축은 양모를 습윤 처리할 때 양모 스케일의 모근과 모단방향의 마찰계수가 다르기 때문에 일어나는 현상이므로 양모의 스케일을 화학적으로 개질하여 두 방향의 마찰계수의 차를 감소시키면 양모의 수축을 감소시킬 수 있다. 이와 같은 원리로 방축효과를 주는 양모의 방축 가공제로는 90% 이상이 염소 또는 염소를 발하는 물질인데 이 가공으로 인한 폐수는 환경문제를 일으키는AOX를 함유하고 있어서 이를 대체하고자 하는 연구가 여러 곳에서 진행되고 있다. (중략)

• Proceedings of the Korean Radioactive Waste Society Conference
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• 2015.10a
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• pp.369-370
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• 2015

• Korean Journal of Materials Research
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• v.2 no.2
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• pp.101-109
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• 1992

Polyethylene terephthalate(PET) is a well known commercial polymer widely available as fibre and as a major polymer with diverse applications. In this experiment, for the modification of PET, the pentanediol isomers, 1,5-pentanediol(1,5-PD) and neopentyl glycol(NPG), were introduced as third monomers. Crystallization rate decreased by the added NPG of PET modified by NPG units. In the case of PET modified by 1,5-PD, crystallization rate had been slightly increased at all temperatures until the 1,5-PD was added about 10 mol%. The decreased crystallization rate is thought to be due to branched from methyl group of neopentyl, which greatly retards the crystallization by growing onto the crystal surface of the diffused polymer chain.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.15 no.11
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• pp.6952-6957
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• 2014

In photocatalysis, the addition of metal matter to $TiO_2$ can alter the surface properties. As such, the metal can increase the rate of the photodegradation reaction. In this study, a range of modified $TiO_2$ photocatalysts were prepared and tested to improve the activity of photodegradation at a batch-typed photoreactor. To obtain a good sol solution of the $TiO_2$ photocatalyst, several types of dispersion agents and stabilizers were investigated. The photocatalyst solutions were modified with isoproply alcohol as the dispersion agent and sodium silicate as the stabilizer. The effects of various metallic elements on enhancing the photocatalytic activity of $TiO_2$ on the degradation of toluene were examined. Palladium-added $TiO_2$ was found to be the best, whereas copper or tungsten-added also showed good results. In the case of palladium addition, the increase in removal efficiency was 25%. On the other hand, Fe-added $TiO_2$ showed a notable decrease in photocatalytic degradation. Additional doping of copper or tungsten on the $Pd/TiO_2$ had no positive effect on the photodegradation activity.

• Journal of the Korean Geosynthetics Society
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• v.12 no.2
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• pp.25-33
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• 2013

This study introduces strength characteristics of the anti-washout grouting material using viscous modifiers and its characteristics mixed with coarse materials. Especially, this study focused on the strength characteristics of the grouts mixed with sea water. It is found that the anti-washout grout mixed with sea water has enough strength and good resistance to segregation just like that with fresh water. Also, a small scale test was performed to evaluate the solidification characteristic of the anti-washout grout mixed with coarse fill materials. It is also found that the strength of anti-washout grout mixed with coarse fill materials is greater and better segregation resistance than those of conventional grout with fill materials.

• Elastomers and Composites
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• v.45 no.1
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• pp.17-24
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• 2010

Herein, the effect of the dispersion uniformity of the multi-wall carbon nanotube (MWCNT) on the thermal and electrical conductivity of polystyrene (PS)/MWCNT composite was investigated. The PS/MWCNT composites were prepared by solution mixing from dispersions of various MWCNTs in PS/tetrahydrofuran (THF) solution. Three types of MWCNTs were used; pristine MWCNT, hydroxyl functionalized MWCNT, which was functionalized with $KMnO_4$ in the presence of a phase transfer catalyst at room temperature, and pristine MWCNT with BYK-9077 as a dispersant. It was found that the stable dispersion state of MWCNT in PS/THF solutions significantly improved the thermal and electrical conductivity of the ultimate composites. It is noted that the thermal and electrical conductivity of PS/3 wt% pristine MWCNT composite with BYK-9077 were about 9.4 and 30~50% higher than those of PS/3 wt% pristine MWCNT composite, respectively.

• Polymer(Korea)
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• v.28 no.5
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• pp.374-381
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• 2004

Gas permeability of low density polyethylene (LDPE) film containing zeolite powder for $CO_2,\;O_2$ and $N_2$ were investigated. Zeolite powders modified by cations or surfactant were compounded with LDPE to produce $20 wt\%$ masterbatch. After blending the masterbatch with LDPE, zeolite filled films were prepared by the blown film process. Finally, the composite films containing zeolite loadings of 0, 3,5, and $10 wt\%$ were produced. A gas permeability apparatus based on the variable volume principle was designed to analyze the characteristics of films. Experiments showed a general trend that gas permeabilities first decreased and then increased as the zeolite content was increased. Surfactant modified zeolite showed a better interfacial adhesion with the matrix, but the film did not show a discernible difference in gas permeability compared with the other modified films. The difference of temperature dependences in the gas permeabilities of composite films was slightly smaller than that of LDPE film.

• Applied Chemistry for Engineering
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• v.10 no.5
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• pp.652-659
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• 1999

The trend of poisoning of reforming catalyst along with the position of anodic catalyst bed was studied. Keeping the conditions that steam to carbon ratio was 2.5, operating voltage was 0.75 V, current density was $140mA/cm^2$, the unit cell was operated during 24 hrs at a steady state. And then the cell was stopped, the catalysts packed in the position of inlet, middle and outlet were sampled individually and then the amount of carbon, Li and K poisoned were analysed. After 100 hrs operated, the catalysts at the same positions were analysed at the same manner. The result of this experiment was as followings. After 24 hrs operated, the poisoning amounts of Li and K in the catalyst were 0.27 wt% at inlet, 0.23 wt% at middle and the highest value 1.59 wt% at outlet. After 100 hrs, the amount of poisoning is the highest in the catalyst packed at the inlet of unit cell. The performance simulation of unit cell explained these trends of poisoning catalysts. The simulation told that the catalyst in the region of the inlet of unit cell treated the 90% of initial methane flow rate and the highest electrochemical reaction happened in this region. So the catalysts of this region were the most poisoned with carbon, Li and K and also the rate of poisoning is faster than that of the catalyst at other regions. The temperature at the region of outlet of unit cell was $30^{\circ}C$ higher than that of other regions, so more Li, and K vaporized than at other regions and little reforming reaction at this region made the catalysts poisoning rate low.

• Journal of the Korean Recycled Construction Resources Institute
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• v.4 no.4
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• pp.489-495
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• 2016

In this study, the Warm-Mix Asphalt was prepared using a modified Sulfur Binder mixed with an additive of a polymer component in sulfur, which is an industrial by-product generated in the crude oil refining process. The dynamic stability and durability characteristics of the prepared Warm-Mix Asphalt was evaluated by the indirect tensile strength, the tensile strength ratio before and after water immersion and freezing-thawing, and the dynamic stability by wheel tracking test. The Warm-Mix Asphalt Mixtures using Modified Sulfur Binder has a tensile strength ratio before and after water immersion of 0.88, which is about 1.13 times that of the Warm-Mix formed modified Asphalt, and the tensile strength ration before and after freezing-thawing is also 0.82, thus, all tensile strength ratios satisfied the KS quality standard value of 0.75 or more. The indirect tensile strength was 1.6MPa which was twice the KS quality standard value of 0.8MPa, and about 1.24 times higher than that of normal heated asphalt 1.29MPa. In addition, the dynamic stability by the wheel tracking test was 14,075 times/mm, which was about 15 times higher than that of normal heated asphalt and about 3 times higher than that of the Warm-Mix formed modified Asphalt, showing excellent resistance to plastic deformation such as fatigue cracks.