• Proceedings of the Korean Vacuum Society Conference
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• 2012.08a
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• pp.185-185
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• 2012

중공 발광 나노 물질은 특유의 구조적 특성(낮은 밀도, 높은 비표면적, 다공성 물질, 낮은 열팽창계수 등)과 광학적 성질을 이용하여 디스플레이 패널, 광결정, 약물전달체, 바이오 이미징 라벨 등의 다양한 적용이 가능하다. 이러한 적용에 있어 균일한 크기와 형태의 중공 입자는 필수 조건으로 여겨진다. 지금까지 합성된 중공 발광 입자에는 BaMgAl10O17 : Eu2+-Nd3+, Gd2O3 : Eu3+, $EuPO_4{\cdot}H_2O$과 같은 것들이 있으나 크기 조절이 어렵고, 그 균일성이 확보되지 못하였다. 균일한 크기의 중공 발광 입자를 만들기 위해 SiO2나 emulsion을 템플릿으로 이용하여 황화카드뮴, 카드뮴 셀레나이드 중공 입자를 합성한 예가 있으나, 양자점의 독성으로 인하여 바이오분야 응용에는 적합하지 않다. YAG는 모체로써 형광체에서 가장 많이 이용되는 물질로, 화학적 안정성과 낮은 독성, 높은 양자 효율 등 많은 장점을 갖고 있다. 특히 세륨이 도핑된 YAG형광체의 경우 WLED, 신틸레이터, 바이오산업에 적용이 가능하다. 그러나 지금까지 중공 YAG:Ce3+형광체를 합성한 예가 없었다. 본 연구에서는 단분산 수화 알루미늄 (Al(OH)3) 입자 위에 세륨이 도핑 된 이트륨 베이직 카보네이트 ($Y(OH)CO_3$)를 균일하게 코팅한 후 열처리를 하여 균일한 크기의 Y3Al5O12:Ce3+(YAG) 중공 입자를 합성하였다. 열처리 온도에 따른 고분해능 투과 전자 현미경(HRTEM), X-선 회절(XRD), 고분해능 에너지 분광법(HREDX) 분석결과, 중공 YAG: Ce3+입자는 Kirkendall 효과에 의해 형성됨을 확인하였다. 전계방사형 주사 전자 현미경(FE-SEM) 측정을 통해, 열처리 후에도 입자의 크기와 형태가 균일함을 확인하였으며, 공초점 현미경 관찰을 통해 중공 형태를 명확히 확인 할 수 있었다. Photoluminescence (PL) 분광법과 형광 수명 이미징 현미경(FLIM)을 이용한 광 특성 분석결과, 합성된 입자는 400-500 nm에서 흡수 파장 (456 nm에서 최대 강도)과 500-700 nm 범위의 발광 파장(544 nm에서 최대 강도)을 나타냈고, 상용 YAG: Ce3+(70 ns)에 준하는 74 ns의 잔광 시간(decay time)이 측정되었다. 단분산 수화 알루미늄 입자의 크기를 조절하여 최종 합성된 YAG: Ce3+의 크기를 조절할 수 있었다. 지름 약 600 nm의 Al(OH)3를 사용한 경우, $1,300^{\circ}C$에서 열처리를 한 후 평균 지름 590 nm의 중공입자를 합성하였고, 약 170 nm의 Al(OH)3를 이용하여, 더 낮은 온도인 $1,100^{\circ}C$에서의 열처리를 통해 평균지름 140 nm의 중공 YAG: Ce3+입자를 합성하였다. 본 연구를 통하여 합성된 균일한 크기의 YAG 중공입자는 LED와 같은 광전변환 소자 및 다기능성 바이오 이미징 등의 나노바이오 소자 분야에 활용될 수 있음이 기대된다.

• Journal of Korean Society of Steel Construction
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• v.25 no.4
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• pp.335-346
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• 2013

AASHTO LRFD and Korean Bridge Design Code (Limit State Design) specify to consider Truck and Lane load simultaneously determined from reliability-based live load model, and impact shall be applied to the truck load while it shall not be applied to the lane load. In this paper, vehicle-bridge interaction analysis under moving truck and lane loads were performed to estimate impact factor of the cables and girders for the selected multi-cable-stayed composite bridges with 230m, 400m and 540m main span. A 6-d.o.f. vehicle was used for truck load and a series of single-axle vehicles was applied to simulate equivalent lane load. The effect of damping ratio on the impact factor was estimated and then the essential parameters to impact factor, i.e., road surface roughness and vehicle speed were considered. The road surface roughness was randomly generated based on ISO 8608 and it was applied to the truck load only in the vehicle-bridge interaction analysis. The impact factors evaluated from dynamic interaction analysis were also compared with those by the influence line method that is currently used in design practice to estimate impact factor in cable-stayed bridge.

• Journal of Korean Society of Steel Construction
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• v.23 no.2
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• pp.199-210
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• 2011

The cables in cable-stayed bridges are under high stress and are very sensitive to vibration due to their small section areas compared with other members. Therefore, it is reasonable to evaluate the cable impact factor by taking into account the dynamic effect due to moving-vehicle motion. In this study, the cable impact factors were evaluated via moving-vehicle-load analysis, considering the design parameters, i.e., vehicle weight, cable model, road surface roughness, vehicle speed, longitudinal distance between vehicles. For this purpose, two steel composite cable-stayed bridges with 230- and 540-m main spans were selected. The results of the analysis were then compared with those of the influence line method that is currently being used in design practice. The road surface roughness was randomly generated based on ISO 8608, and the convergence of impact factors according to the number of generated road surfaces was evaluated to improve the reliability of the results. A9-d.o.f. tractor-trailer vehicle was used, and the vehicle motion was derived from Lagrange's equation. 3D finite element models for the selected cable-stayed bridges were constructed with truss elements having equivalent moduli for the cables, and with beam elements for the girders and the pylons. The direct integration method was used for the analysis of the bridge-vehicle interaction, and the analysis was conducted iteratively until the displacement error rate of the bridge was within the specified tolerance. It was acknowledged that the influence line method, which cannot consider the dynamic effect due to moving-vehicle motion, could underestimate the impact factors of the end-cables at the side spans, unlike moving-vehicle-load analysis.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.28 no.6A
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• pp.799-808
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• 2008

The analysis of vehicular loads reflecting the domestic traffic circumstances is necessary for the development of adequate design live load models in the analysis and design of cable-supported bridges or the development of fatigue load models to predict the remaining lifespan of the bridges. This study intends to develop an ANN(artificial neural network)-based Bridge WIM system and Influence line-based Bridge WIM system for obtaining information concerning the loads conditions of vehicles crossing bridge structures by exploiting the signals measured by strain gauges installed at the bottom surface of the bridge superstructure. This study relies on experimental data corresponding to the travelling of hundreds of random vehicles rather than on theoretical data generated through numerical simulations to secure data sets for the training and test of the ANN. In addition, data acquired from 3 types of vehicles weighed statically at measurement station and then crossing the bridge repeatedly are also exploited to examine the accuracy of the trained ANN. The results obtained through the proposed ANN-based analysis method, the influence line analysis method considering the local behavior of the bridge are compared for an example cable-stayed bridge. In view of the results related to the cable-stayed bridge, the cross beam ANN analysis method appears to provide more remarkable load analysis results than the cross beam influence line method.

• Clean Technology
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• v.12 no.1
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• pp.19-25
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• 2006

In this study, photo-cuarable urethane methacrylate oligomers were synthesized from polyether type polyol (PP series, GP series), isocyanate (2,4-toluene diisocyanate) and hydroxy acrylate (hydroxypropyl methacrylate). We measured basic property including color, viscosity and refractive index of resulting urethane methacrylate. Also we measured tensile strength, elongation, and Young's modulus after photo curing. Photo curing speed was investigated using photo-DSC (TA instrument). In the case of similar polyol structure, as the molecular weight of polyol is increased, tensile strength, Young's modulus, curing rate were decreased, but elongation was increased. As the number of functionality of urethane methacrylate oligomer is increased, tensile strength, Young's modulus, curing rate were increased, but elongation was decreased.

• Journal of Korean Society of Steel Construction
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• v.16 no.4 s.71
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• pp.425-432
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• 2004

Large studs were suggested not only for the design of steel-concrete composite bridges with simplified sections but also for the shear connection in precast decks requiring uniform distribution of shear pockets. Based on the push-out test results on studs with diameters of more than 25 mm, partial composite beams with 40%-degree shear connection were fabricated, and static tests were performed. The ultimate strength and horizontal shear load redistribution of partial composite beams, which have parameters of stud shank diameters and distribution, were evaluated, and group failure in the shear span was observed. Since the flexural strength of composite beams are dependent on the strength of their shear connection, the strength of the stud connection was estimated and it showed considerably higher shear strength. From the load-slip curves, the sufficient ductility and load redistribution of large studs were confirmed. Uniformly distributed large studs can provide proper ultimate behavior of composite beams.

• Journal of the Korea Concrete Institute
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• v.19 no.3
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• pp.313-322
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• 2007

The PCS system, which consists of precast concrete column and steel beam, is a kind of composite structural systems. In this paper, experimental study has been conducted to analyze seismic performance of bolted beam-to-column connections for the PCS system. Based on experimental results from the seismic testing of eight interior PCS specimens, it shows that behavior of PCS system is satisfactory to seismic performance criteria of ACI such as strength deterioration, stiffness degradation and energy dissipation capacity except initial stiffness. All of the specimens maintain their strength at large levels of story drift without significant loss of stiffness and show high ductility level for inelastic behavior. The energy dissipation capacity is two times greater than requirement of ACI criterion. But the initial stiffness of all specimens does not satisfy ACI criterion, and this phenomenon is similar to the other composite structural systems such as RCS, CFT system.

• Journal of Korean Society of Steel Construction
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• v.29 no.5
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• pp.331-340
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• 2017

This study was performed in order to develop of the new modular construction system. For the modular construction method that is currently applied in the country, it is very expensive in terms of material costs and fire resistance because it uses only the steel C-type beam. In order to overcome this, and the practical application of new steel-PC hybrid module construction system. Improvement and development of the cross-section of the structural beam member in order to be carried out first. An experiment was carried out by making three specimens. Experiment result, the composite beam was dominated by the horizontal shear failure. It was evaluated through a nonlinear analysis and experimental & theoretical for the structural performance the composite beam member.

• Journal of the Korea Society of Computer and Information
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• v.16 no.2
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• pp.71-81
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• 2011

In order to easily create video tutorials, the algorithm is needed that video camera recording, white board images, video attachments, and document data are combined in real-time. In this study, we implemented the video lecture content creation system using wavelet-based lossless compression to composite multimedia objects in real-time and reproduce the images. Using commercially available PC can be useful when lecturers want to make video institutional contents, it can be operated easily and fastly. Therefore, it can be very efficient system for e-Learning and m-Learning. In addition, the proposed system including multimedia synthesis technology and real-time lossless compression technology can be applied to various fields, different kinds of multimedia creation, remote conferencing, and e-commerce so there are highly significant.

• Journal of Korean Tunnelling and Underground Space Association
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• v.10 no.3
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• pp.269-282
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• 2008

In general, the effects of steel ribs are not considered in the numerical analysis of tunnel design. However, attempts have been increased recently to consider these effects in the analysis of shallow tunnels in soft ground, based on the fact that the steel ribs embedded in the shotcrete take a role to support some portion of the redistributed load due to excavation. In such analyses, the steel ribs can be considered in four different methods: (1) a conventional method where the steel ribs are not considered, (2) a method using the equivalent composite cross section in which the bending moment of shotcrete is not considered, (3) a method using the equivalent composite cross section in which both the compressive stress and the bending moment for the shotcrete and steel rib are considered, and (4) a method using beam elements for the shotcrete and the steel rib, respectively. These methods are adopted in the numerical analysis using FLAC 2D to investigate stresses of both the shotcrete and the steel rib. The overall results show that the analyses are more practical and economical when the effects of steel rib are considered fer the methods (2), (3), and (4). Since the results of those analyses considering steel rib capacity may be different according to the ground condition, it will be necessary to consider the appropriate method among them in accordance with design conditions.