• Title/Summary/Keyword: 강유전 특성

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Ferroelectric Properties of SBT Capacitors with Annealing Conditions (SBT 커패시터의 열처리 조건에 따른 강유전 특성)

  • Lee, Sung-Ill
    • Journal of the Korean Society of Safety
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    • v.19 no.1
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    • pp.72-76
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    • 2004
  • The $Sr_{0.7}Bi_{2.6}Ta_2O_9$(SBT)thin films are deposited on pt-coated electrode(Pt/$TiO_2/SiO_2/Si$) using a RF magnetron sputtering method. The electrical properties of SBT capacitors with annealing conditions were studied. In the XRD pattern, the SBT thin films in all annealing temperatures had (105) orientation. In the SEM images, Bi-layered perovskite phase was crystallized at $750^{\circ}C$,/TEX> and grains largely grew in oxygen annealing atmosphere. The maximum renanent polarization and the coercive electric field with annealing conditions are 12.40C/$cm^2$ and 30kV/cm, respectively. The dielectric constant and leakage current density with Pt electrode is 340 and 2.13${\times}10^{-10}A/cm^2$, respectively.

A Study on the Electrical and the Optical Characteristics of W/65/35 PLZT Ferroelectric Thin Films (X/65/35 PLZT 강유전 박막의 전기 및 광학 특성에 관한 연구)

  • Hur, Woon-Haing;Choi, Hyung-Wook;Paik, Dong-Soo;Kim, Jun-Han;Park, Chang-Yub
    • Proceedings of the KIEE Conference
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    • 1994.11a
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    • pp.209-211
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    • 1994
  • X/65/35 PLZT ferroelectric thin films were fabricated by sol-gel processing. Thin films were crystallized after rapid thermal processing at $750^{\circ}C$ for 5 min. The microstructure, the relative dielectric constant the curie point, the hysteresis curve and the optical transmittance of thin films were investigated.

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Effects of microstructures on ferroelectric properties of PZT thin films prepared by PLD (PLD에 의해 제조된 PZT 박막의 미세구조가 강유전 특성에 미치는 영향)

  • 백동수;김민철;신현용;박용웅;윤석진
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1999.11a
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    • pp.224-227
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    • 1999
  • Ferroelectric Pb(Zr$\sub$0.52/Ti$\sub$0.48/)O$_3$ thin films were fabricated by pulsed laser deposition, mainly varying process conditions such as substrate temperature, oxygen pressure, and laser energy, PZT films annealed at more than 600$^{\circ}C$ were crystallized into pure perovskite phases regardless of deposition temperatures. Lower deposition temperature of 400$^{\circ}C$ accompanied with post-annealing at 650$^{\circ}C$ resulted in denser microstructures with extremely small grains compated to those of thin films annealed at higher deposition temperatures. Hysteresis curves of thin film with small grains exhibitied good squareness and low leakage characteristics.

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Enhancement of the ferroelectric properties of $Pb(Zr,Ti)O_3$ thin films with $Pb(La,Ti)O_3$ buffers fabricated by pulsed laser deposition (PLT buffer층의 삽입에 따른 강유전 PZT박막의 특성 향상)

  • Lim, Sung-Hoon;Lee, Eun-Sun;Chung, Hyun-Woo;Lee, Sang-Yeol
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.07a
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    • pp.67-69
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    • 2004
  • The $Pb(Zr,Ti)O_3$ thin films were fabricated with $Pb(La,Ti)O_3$ buffers in-situ onto $Pt/Ti/SiO_2/Si$ substrates by pulsed laser deposition technique using a Nd:YAG laser with energy density of $2.5J/cm^2$, and deposited for 10 minutes at $550^{\circ}C$ of substrate temperature. And then, the films have been annealed at $550^{\circ}C$ in oxygen ambient pressure. The remanent polarization value is increased by using buffer layers but coercive field of films is slightly increased.

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Thickness dependence of the piezoelectric characteristic for PZT films using by rf magnetron sputtering (RF 마그네트론 스퍼터링으로 증착한 두께에 따른 PZT 박막의 강유전 특성에 관한 연구)

  • Lee, Tae-Yong;Park, Young;Song, Joon-Tae
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.11a
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    • pp.313-316
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    • 2003
  • The lead zirconate titanate, $Pb(Zr_{0:52}Ti_{0:48})O_3$, films of $0.5\;{\mu}m,\;1\;{\mu}m$ and $2\;{\mu}m$ thickness were fabricated on $Pt/Ti/SiO_2/Si$ substrate by the rf magnetron sputtering method. The PZT films were annealed using by a rapid thermal annealing (RTA) method. The thickness dependence of the film structure, dielectric properties, Polarization-electric field hysteresis loops and capacitance-voltage characteristics were investigated over the thickness range of $0.5\;{\mu}m,\;1\;{\mu}m$ and $2\;{\mu}m$. According to the XRD patterns of the films, (110) peak intensity increases with film thickness increased. The increase of PZT films thickness leads to the decrease of the remanent polarization and the dielectric constant.

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The Efficiency Characteristics of the Ferroelectric Polymer Added Organic Solar-cells (강유전 고분자를 첨가한 유기태양전지의 효율 특성)

  • Park, Ja young;Jung, Chi Sup
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.29 no.9
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    • pp.589-594
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    • 2016
  • P3HT:PCBM bulk heterojunction solar cells added with ferroelectric polymer were fabricated and characterized. By incorporating P3HT:PCBM solar cell with P(VDF-TrFE) ferroelectric additive, the power conversion efficiency was increased up to nearly 50%. Photoacoustic analysis on this phenomena was carried out for the first time. Through this study, we find that the ferroelectricity of the polymer additive plays the key role in the enhancement of the power conversion efficiency of the organic solar cell by suppressing the non-radiative recombination of charge transfer exciton more effectively.

A study on the dielectric properties of the $(Sr_{0.50}Pb_{0.25}Ba_{0.25})TiO_3$ ceramics ($(Sr_{0.50}Pb_{0.25}Ba_{0.25})TiO_3$세라믹의 유전특성에 관한 연구)

  • 김세일;정장호;이성갑;배선기;이영희
    • Electrical & Electronic Materials
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    • v.8 no.3
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    • pp.267-271
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    • 1995
  • The electrical properties of (S $r_{0.50}$P $b_{0.25}$B $a_{0.25}$)Ti $O_{3}$ ceramics were studied. Specimens were prepared by the conventional mixed oxide method, and fired between 1300[.deg. C] - 1375[.deg. C], for 2[hr.]. The electrical and structural preperties of specimens were investigated with sintering temperature. Increasing the sintering temperature from 1300[.deg. C] to 1375[.deg. C], average grain size was increased from 2.61[.mu.m] to 4.53[.mu.m]. (S $r_{0.50}$P $b_{0.25}$B $a_{0.25}$)Ti $O_{3}$ specimen sintered at 1350[.deg. C] for two hours showed good dielectric constant(2147) and dielectric loss(1.7[%]) properties at 1[khz]. Sintered density and breakdown field strength were the highest value of 5.75[g/c $m^{3}$], 20[kV/cm], respectively. Dielectric properties with applied voltage were independent of the sintering temperature.temperature.

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Identification of Structural Characteristic Matrices of Steel Bar by Genetic Algorithm (유전알고리즘에 의한 강봉의 구조특성행렬 산출법)

  • Park, S.C.;Je, H.K.;Yi, G.J.;Park, Y.B.;Park, K.I.
    • Transactions of the Korean Society for Noise and Vibration Engineering
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    • v.20 no.10
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    • pp.946-952
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    • 2010
  • A method for the identification of structural characteristic parameters of a steel bar in the matrices form such as stiffness matrices and mass matrices from frequency response function(FRF) by genetic algorithm is proposed. As the method is based on the finite element method(FEM), the obtained matrices have perfect physical meanings if the FRFs got from the analysis and the FRFs from the experiments were well coincident each other. The identified characteristic matrices from the FRFs with maximun 40 % of random errors by the genetic algorithm are coincident with the characteristic matrices from exact FEM FRFs well each other. The fitted element diameters by using only 2 points experimental FRFs are similar to the actual diameters of the bar. The fitted FRFs are good accordance with the experimental FRFs on the graphs. FRFs of the rest 9 points not used for calculating could be fitted even well.

Direct-current Dielectrophoretic Motions of a Single Particle due to Interactions with a Nearby Nonconducting Wall (비전도성 벽과의 상호작용에 따른 단일 입자의 직류 유전영동 운동)

  • Kang, Sangmo
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.39 no.5
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    • pp.425-433
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    • 2015
  • In this paper, we have numerically investigated two-dimensional dielectrophoretic (DEP) motions of a single particle suspended freely in a viscous fluid, interacting with a nearby nonconducting planar wall, under an externally applied uniform direct-current electric field. Particularly, we solve the Maxwell equation with a large sharp jump in the electric conductivity at the particle-fluid interface and then integrate the Maxwell stress tensor to compute the DEP force on the particle. Results show that, under an electric field parallel to the wall, one particle is always repelled to move far away from the wall and the motion depends strongly on the particle-wall spacing and the particle conductivity. The motion strength vanishes when the particle is as conductive as the fluid and increases as the conductivity deviates further from that of the fluid.

NKNLTS 비납계 압전체의 도핑원소에 따른 특성평가

  • Lee, Yun-Gi;Park, Eun-Hye;Ryu, Seong-Rim;Gwon, Sun-Yong
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2009.11a
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    • pp.83-83
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    • 2009
  • 우수한 압전성을 가지는 PZT는 인체에 유해한 다량의 PbO을 함유하여 심각한 환경문제를 야기함은 물론 제조 공정 중 PbO 휘발 억제 시설 구비에 따른 경제적 부담 등 문제점이 지적되었다. 따라서 환경오염 및 가격경쟁력을 갖추기 위해 현재 무연 조성 세라믹스에 대한 많은 연구가 진행되고 있다. 최근 비납계 압전 세라믹의 연구는 비스무스 레이어형과 페로브스카이트 형 비납계 세라믹스의 연구가 활발히 진행되고 있다. 특히 $(Na,K)NbO_3$ 계는 페로브스카이트 구조를 가지는 비납계 세라믹으로 현재 많은 연구가 진행되고 있다. 이 물질은 PZT계와 유사하게 상전이(morphotropic phase boundary:MPB)영역을 가지고 있 으며 이 영역에서 높은 압전 특성을 보여주고 있다. 최근 $Na_{0.5}K_{0.5}NbO_3$$LiTaO_3$를 치환하여 우수한 압전 특성을 지니는 조성이 개발되고 있지만, 보통 소성법으로 제조된 세라믹스는 PZT계 세라믹스와 비교하여 특성이 떨어진다. 본 연구에서는 압전성이 우수한 $(Na_{0.44}K_{0.52}Li_{0.44})(Nb_{0.90}Sb_{0.06}Ta_{0.04})O_3$ 조성에 도너 도핑과 억셉터 도핑을 한 다음 전기기계결합계수, 압전상수, 유전상수의 변화를 평가하고, hardener 와 softener 특성이 본조성에서 나타나는지를 관찰하였다. 실험방법은 보통 소성법을 사용하였으며, 분쇄와 혼합은 직경 3 mm zirconia ball을 사용하여 볼밀 하였다. $850^{\circ}C$ 에서 5h 하소 후 $1100{\sim}1200^{\circ}C$ 에서 소결하고, 두께 1 mm로 연마한 다음 silver paste를 $650^{\circ}C$ 에서 소부하여 전극을 형성하였다. 제작된 시편은 $90^{\circ}C$의 실리콘유에서 3~4 kV/mm의 전계를 가해 20분간 분극 처리를 수행하였다. 제작된 시편의 압전전하 상수 값은 d33-meter(APC-8000)를 이용하여 측정하였고, 유전율, 전기기계결합계수 및 기계적품질계수 등은 임피던스 분석기 (impedance/gain phase analyzer)를 이용하여 특성을 측정 하였다. 또한 전압-분극 특성의 평가에는 강유전특성 측정기(ferroelectric tester: Precision-LC, Radiant Technologies, USA)를 이용하였다.

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