• Journal of the Korean Institute of Gas
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• v.21 no.5
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• pp.95-103
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• 2017

A lot of hazardous materials have been used for product processing and utility plant. Many accidents including toxic release, fire and explosions occur in the ammonia related facility and plant. Various safety and environment management program including PSM, SMS, ORA etc. are being implemented for risk management and accident prevention in the production industry. Also much study and research have been carried about risk assessment of accident scenario in the academic and research area. In this paper, firstly risk level was assessed by using a typically used KORA program and LOPA PFD method for the selected ammonia unloading and storage facility. And then risk reduction measures for the risk assessed facility were studied in 3 aspects and some measures were proposed. Those Risk Reduction measures are including a leak detection and emergency isolation, water spray, dilution tank, dike and trench, scattering protection in hardware impovement aspect, and a applicable risk criteria, conditional modifier for existing LOPA PFD, alternative supporting modeling program in risk estimation methodology aspect, and last RBPS(Risk Based Process Safety) program, re-doing of process hazard analysis, management system compliance audit in managerial activity aspect.

• Journal of the Korean Applied Science and Technology
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• v.33 no.4
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• pp.836-847
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• 2016

Water soluble oil was obtained by pyrolysis of biomass. The characteristics of emulsified fuel by mixing water soluble oil and MDO(marine diesel oil) and engine emissions were studied with engine dynamometer. Saw dust was used as biomass. Water soluble oil was obtained by condensing of water and carbon content with pyrolysis of saw dust at $500^{\circ}C$. Emulsion fuel was obtained by emulsifying MDO and water soluble oil by the water soluble oil mixing ratio of 10 to 20% of MDO. Exhaust gas detection was performed with engine dynamometer. While combustion, micro-explosion took place in the combustion chamber by water in the emulsion fuel, emulsion fuel scattered to micro particles and it caused to smoke reduction. The heat produced from water vapour reduce the temperature of internal combustion chamber and it caused to inhibition of NOx production. It can be verified by the lower exhaust temperature of each ND-13 mode using emulsion fuel than that of MDO fuel. The NOx and smoke concentration were reduced by increasing water soluble oil content in the emulsion fuel. The power also decreased according to the increment of water soluble oil content of emulsion fuel because emulsion fuel has low calorific value due to high water content than MDO. As a result of ND-13 mode test with 20% bio oil content, it was achieved 25% reduction in NOx production, 60% reduction in smoke density, and 15% reduction in power loss.

• Journal of the Korean Institute of Gas
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• v.21 no.6
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• pp.52-60
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• 2017

In diffusion process exhaust line during semiconductor manufacturing process, In order to improve the transportation efficiency in the piping by removing "The reaction by-product, $ZrO_2$ and The unreacted material, TEMAZ, TMA, $O_3$, etc" and "Powder being deposited", the piping temperature was raised to $80^{\circ}C$ or more by using the heater jacket, and the bellows at the rear end of the vacuum pump ruptured. So conducted a case study and try to prevent the similar accidents from occurring through case studies. The causes of the accident were analyzed as follows: the inflow of outside air due to the generation of a gap on the suction side of the vacuum pump and heating the pipe with the heater jacket resulted in the overpressure in the pipe due to the volumetric expansion of the gas generated by decomposition of the unreacted TEMAZ, It can be assumed that the most vulnerable bellows of the piping has been ruptured. In order to prevent such accidents, This study is aimed to identify the cause of pipeline rupture accident and to establish safety measures for the prevention of similar accidents by evaluating physical hazards of TEMAZ, which is assumed to be the cause of pipe rupture accident.

• Journal of the Korean Institute of Gas
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• v.25 no.2
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• pp.13-21
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• 2021

Because of the recent expansion of hydrogen vehicle supply, the installation of hydrogen filling station is expected to gradually expand. This study attempts to predict the damage scale and propose a safer design form based on the scenario that assumes the worst case of a hydrogen station. A Flacs solver using computational fluid dynamics (CFD) was used to predict the damage scale, and the accuracy was verified by comparing it with the experimental results of previous researchers. The damage scale prediction was conducted for hydrogen leakage and explosion, and the prediction target was the KR model based on the measured values. And as a comparative review model, a roofless model was selected without a ceiling. As a result of analyzing the two models, it was possible to confirm the accumulation and retention of hydrogen gas up to 60 vol% or more in the KR model, whereas in the case of the Roofless model, the phenomenon of discharge and diffusion to the outside of the charging station by riding the wall after leakage. I was able to check. In conclusion, it was reviewed that the type of hydrogen charging station without ceiling is more advantageous for safety than the hydrogen filling station model.

• Korean Chemical Engineering Research
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• v.59 no.2
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• pp.200-208
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• 2021

Compare to the gaseous hydrogen, liquid hydrogen has various advantages: easy to transport, high energy density, and low risk of explosion. However, the hydrogen liquefaction process is highly energy intensive because it requires lots of energy for refrigeration. On the other hand, the cold energy of the liquefied natural gas (LNG) is wasted during the regasification. It means there are opportunities to improve the energy efficiency of the hydrogen liquefaction process by recovering wasted LNG cold energy. In addition, hydrogen production by natural gas reforming is one of the most economical ways, thus LNG can be used as a raw material for hydrogen production. In this study, a novel hydrogen production and liquefaction process is proposed by using LNG as a raw material as well as a cold source. To develop this process, the hydrogen liquefaction process using hydrocarbon mixed refrigerant and the helium-neon refrigerant is selected as a base case design. The proposed design is developed by applying LNG as a cold source for the hydrogen precooling. The performance of the proposed process is analyzed in terms of energy consumption and exergy efficiency, and it is compared with the base case design. As the result, the proposed design shows 17.9% of energy reduction and 11.2% of exergy efficiency improvement compare to the base case design.

• Journal of the Korean Institute of Gas
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• v.26 no.4
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• pp.58-63
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• 2022

With the emergence of environmental problems caused by fine dust worldwide, LNG, which is cheaper and less pollution than diesel, is attracting attention as the next generation energy of automobiles and is expanding its supply. However, it is difficult to operate smoothly due to the lack of infrastructure for LNG charging stations in Korea and the limited size of containers that can be installed according to regulations. In Korea, research and development on the contents of containers for the smooth operation of natural gas vehicles are underway, but there is a problem that the container directly receives the impact of the vehicle collision and explodes, causing a major disaster. Therefore, in this study, the safety of the container was verified by deriving the strain and stress values through ANSYS Explicit Dynamics analysis. As a result, a maximum stress of 565.37MPa occurred in the container, and it is expected that plastic deformation will occur as it exceeds the yield stress of STS304 used as a material for the container, which is beyond 505MPa. When an impact caused by a collision between a vehicle and a container is applied, it is considered necessary to design a support or reinforcement because the container may be damaged or defective.

• Journal of the Computational Structural Engineering Institute of Korea
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• v.36 no.4
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• pp.273-282
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• 2023

Probabilistic safety assessment (PSA) has been widely used to evaluate the seismic risk of nuclear power plants (NPPs). However, studies on seismic PSA for process plants, such as gas plants, oil refineries, and chemical plants, have been scarce. This is because the major disasters to which these process plants are vulnerable include explosions, fires, and release (or dispersion) of toxic chemicals. However, seismic PSA is essential for the plants located in regions with significant earthquake risks. Seismic PSA entails probabilistic seismic hazard analysis (PSHA), event tree analysis (ETA), fault tree analysis (FTA), and fragility analysis for the structures and essential equipment items. Among those analyses, ETA can depict the accident sequence for core damage, which is the worst disaster and top event concerning NPPs. However, there is no general top event with regard to process plants. Therefore, PSA cannot be directly applied to process plants. Moreover, there is a paucity of studies on developing fragility curves for various equipment. This paper introduces PSA for gas plants based on FTA, which is then transformed into Bayesian network, that is, a probabilistic graph model that can aid risk-informed decision-making. Finally, the proposed method is applied to a gas plant, and several decision-making cases are demonstrated.

• Journal of Korean Society of Environmental Engineers
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• v.27 no.10
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• pp.1081-1089
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• 2005

In order to examine the application feasibility of Orimulsion fuel in a commercial boiler using heavy fuel oil, a numerical and experimental research efforts have been made especially to figure out the fundamental combustion characteristics of this fuel in a small-scale boiler. One of the notable combustion features of Orimulsion fuel is the delayed appearance of flame location with the flame shape of rather broad distribution, which is found experimentally and confirmed by numerical calculation. This kind of flame characteristics is considered due to the high moisture content included inherently in the process of Orimulsion manufacture together with micro-explosion by the existence of fine water droplets. In order to investigate the effect on the combustion characteristics of Orimulsion, a series of parametric investigation have been made in terms of important design and operational variables such as injected amount of fuel, types of atomization fluid, and phonemenological radiation model employed in the calculation, etc. The delayed feature of peak flame can be alleviated by the adjustment of the flow rate of injected fuel and the generating features of CO, $SO_2$ and NO gases are also evaluated in the boiler. When the steam injection as atomizing fluid is used, the combustion process is stabilized with the reduced region of high flame temperature. In general, the calculation results are physically acceptable and consistent but some refinements of phenomenological models are necessary for the better resolution of pollutant formation. From the results of this small-scale Orimulsion boiler, it is believed that a number of useful information are obtained with the working computer program for the near future application of Orimulsion fuel to a conventional boiler.

• Fire Science and Engineering
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• v.31 no.3
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• pp.73-78
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• 2017

In this paper, the fire risk using a bimetal type thermometer for construction installation is presented. Because construction equipment is used widely in the field and the site is exposed to explosions and fire by combustible gas or fume, strong restrictions on the structure and usage are applied. Moreover, the risk of fire increases as precise temperature measurements are poorly conducted via an inner temperature sensor inside construction furnace. Therefore, this paper presents the results of structural analysis of a bimetal temperature sensor which is used widely in construction installation and temperature measurement experiments relative to the material property of the target object. The results revealed the relatively precise temperature of the liquid object, whereas those of the gas and solid object showed a lower temperature compared to the real temperature. This shows that bimetal-type temperature sensor is more suitable for measuring a liquid state object than measuring a gas or solid state object.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.16 no.7
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• pp.4950-4959
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• 2015

The importance of public infrastructures' protection against crash or blast loads has been emerging issue as structures are becoming bigger and population densities in downtown cities are growing up. However, there exists no sufficient study which considers the developments of protective building materials, that are essential for protective design and construction. To assess the protection performance and the applicability as protective materials of high performance fiber reinforced cementitious composites(HPFRCC), this study performed the impact tests with 40 mm gas-gun propelled projectile crash machine. From this study, it has observed that both high compressive strength of cement matrix and fiber reinforcement are beneficial for the improvement of impact resistance.