• Title/Summary/Keyword: 가스 크로마토그래피

Search Result 237, Processing Time 0.03 seconds

Chemical Composition and Antifungal Activity of Plant Essential Oils against Malassezia furfur (비듬균(Malassezia furfur)에 대한 식물 오일들의 항균활성 및 활성오일의 성분 분석)

  • Lee, Jeong-Hyun;Lee, Jae-Sug
    • Microbiology and Biotechnology Letters
    • /
    • v.38 no.3
    • /
    • pp.315-321
    • /
    • 2010
  • Malassezia furfur is an important causal factor for seborrheic dermatitis. Nowadays, the drugs available to treat this fungal infection are few. Several studies have documented the biological activity of essential oils. However, its antifungal properties are not completely understood, especially its anti-Malassezia activity. The aim of this study were to evaluate the effect of the plant essential oils on the growth of M. furfur using disk diffusion method and analyze by Gas chromatography-mass spectrometry (GC-MS) most active essential oils. In first screening, the 17 plant essential oils have possesses inhibitory activity against M. furfur at 2 mg/mL. Among the plant essential oils, oil of Citrus auranifoli was most active against M. furfur and its activity showed dose dependency. This anti-malassezial activity was high than that of itraconazole at 2 mg/mL. Oil of Citrus auranifolia also was phytochemically examined by GC-MS analysis, its main constituents were identified as limonene, ${\gamma}$-terpinene and terpinolene. It can be concluded that essential oils of Citrus auranifolia may have interesting applications to control fungal-derived diseases.

Quantitative Determination of Flatulence Factors in Legume Seeds and Soy Products (두류 및 대두제품중 가스발생인자의 함량 분석)

  • Bae, Ji-Hyun;Lee, Su-Rae
    • Korean Journal of Food Science and Technology
    • /
    • v.19 no.5
    • /
    • pp.387-391
    • /
    • 1987
  • The contents of flatulence factors such as raffinose and stachyose were determined by two-dimensional thin-layer chromatography using a guide-strip technique for some legume seeds and soy products consumed in Korea. Raffinose contents in bean samples were 1.34% in domestic soybean, 1.17% in imported soybean, 0.65% in kidney bean, 0.49% in red bean and 0.49% in mung bean. Stachyose contents were 4.1% in doemstic soybean, 3.6% in imported soybean, 3.0% in kidney bean, 2.9% in red bean and 1.9% in mung bean. The flatulence factors were not detected in soy sauce whereas soy paste contained 46.6mg% of raffinose and none of stachyose. The contents of raffinose and stachyose were 26.7mg% and 53.7mg% in soy curd and 26.5mg% and 41.7mg%, respectively, in soy milk.

  • PDF

Analysis of Automotive Paints using Pyrolysis-Gas Chromatography (열분해-가스크로마토그라피에 의한 자동차 페인트 분석)

  • Shon, Sung-Kun;Park, Ha-Sun;Lee, Jin-Sook;Hong, Sung-Wook;Park, Sung-Woo;Cho, Sung-Hye
    • Analytical Science and Technology
    • /
    • v.13 no.1
    • /
    • pp.101-107
    • /
    • 2000
  • The automotive paints could be generally differentiated by color, layer sequence and chemistry of the paint layers comprising each of the topcoat and the primer system. The successful identification of hit-andrun a and traffic accidental vehicles from evidential paint fiagments is greatly facilitated with a comprehensive laboratory collection of reference paint samples and the technique for direct analysis without sample preparation. The Pyrolysis-Gas Chromatography(PGC) is a precise and reliable method for performing both quantitative and qualitative analysis of polymeric materials and forensic samples. Our Forensic Laboratory is conducting the examination and identification of 73 reference paint samples; 4 colors of each domestic automotive make that is popular in Korea, by Curie Point Pyrolyzer(JHP-3) and GC with capillary column(ultra alloy-5). This method can be used not only to compare paint traces with their suspected sources, but also to identify the type, make and model of the automotive car.

  • PDF

Optimization of Gas-Liquid Chromatographic Parameters for the Multiresidue Analysis of 24 Pesticides (잔류농약 24성분의 다성분 동시분석을 위한 기체크로마토그래피 조건의 최적화)

  • Lee, Eun-Ju;Kim, Woo-Seong;Park, Kun-Sang;Oh, Jae-Ho;Kim, Dai-Byung
    • The Korean Journal of Pesticide Science
    • /
    • v.4 no.2
    • /
    • pp.11-17
    • /
    • 2000
  • Optimum parameters were investigated for the simultanious analysis of 24 pesticide residuces using gas-liquid chromatography with electron capture detection. Electronic pressure control(EPC) on column enhanced resolution of 24 analyzes. Using DB-17, SPB-608, and Ultra-2 capillary column without EPC incomplete separation was observed in some pairs of pesticides. When EPC function was adopted, no severe overlapping was observed on SPB-608 column in every pesticides except vinclozolin/acetochlor pair. Total running time was 45 min, much shorter than $69{\sim}81$ min when used without EPC. Limit of determination of each analyze ranged $0.1{\sim}12.9$ ng/mL.

  • PDF

The Analysis on VOCs That Occurs in Leather Cultural Heritage with SPME (고체상미세추출법(SPME)을 이용한 피혁 재질로부터 발생된 휘발성 유기화합물 분석기술 연구)

  • Chung, Yong-Jae
    • Journal of Conservation Science
    • /
    • v.28 no.2
    • /
    • pp.113-118
    • /
    • 2012
  • Cultural heritages emit volatile organic compounds(VOCs) during degradation as chemical, biological factors. These VOCs in the atmosphere are degradation factors for another materials. But non-destructive organic analysis methods are uncommon, and have difficulties for field application. In this study, solid phase micro-extraction(SPME) and gas chromatography( GC) are carried out for analysis of VOCs which are emitted from leather, and prove SPME field holder's efficiency. I analize leather archival objects at The National Archives of Korea by cross-checking GC and SPME methods. It could be confirmed that the compounds are (E)-2-nonenal, butyl hydroxy toluene emitted itself from leather.

Investigation on Formation Behaviors of Synthesized Natural Gas Hydrates (합성 천연가스의 하이드레이트 형성 거동 연구)

  • Lee, Jong-Won;Lee, Ju-Dong
    • Korean Chemical Engineering Research
    • /
    • v.50 no.5
    • /
    • pp.890-893
    • /
    • 2012
  • Gas hydrates are solid crystal structures formed by enclathration of gaseous guest species into 3-dimensional lattice structure of hydrogen-bonded water molecules. These compounds can be potentially used as an energy storage/transportation medium because they can hold a large amount of gas in a small volume of the solid phase. In addition, huge amount of natural gas, buried in seabeds or permafrost region in the form of the solid hydrate, is regarded as a future energy source. In this study, synthesized natural gas, whose composition is 90.0 mol% of methane, 7.0 mol% of ethane, and 3.0 mol% of propane, was used to identify formation behaviors of natural gas hydrates for the purpose of applying the gas hydrate to a storage/transportation medium of natural gas. According to the experimental results obtained by means of the solid-state NMR and high-resolution powder XRD methods, it is found that formed natural gas hydrates have crystal structure of the structure-II hydrate, and that methane occupies both small and large cages, while the others only occupy large ones. In addition, both the NMR spectroscopy and the gas chromatograph showed that there exists preferential occupation among the natural gas components during the hydrate formation. Compositional changes after the hydrate formation revealed that the preferential occupation is in order of propane, ethane, and methane (propane is the most preferential guest species when forming natural gas hydrates).

A Study on the Odorization Levels and Management in the Facility using Liquified Natural Gas(LNG) (액화천연가스(LNG) 사용시설내의 부취농도 분포 및 관리방법에 관한 연구)

  • Won, Seung Yeon;Shin, Hun Yong
    • Journal of the Korean Institute of Gas
    • /
    • v.23 no.6
    • /
    • pp.25-32
    • /
    • 2019
  • In many mass-consumption gas facilities, natural gas is not supplied through the pipeline of the gas corporation. LNG is supplied from the gas corporation through the tank lorry to be vaporized. In order to prevent human or property damage due to gas leakage at these facilities, a study was conducted to analyze the concentration of odorant injected at the initial and consumption points. An analysis was performed to confirm the change in odorant concentration according to the pipe position in the gas facility when a constant flow rate flowed. For this study the gas samples were taken with aluminium cylinders(4.5 L) which were created a vacuum at the pressure regulator in which the odorants was injected and the points using the gas. Odorant levels of the samples were analyzed by Gas chromatography(Main Body : Agilent 7890A, Detector : ANTEC 7090).We suggest that the small facilities using LNG need to make the management system by the types of facilities for maintaining the odorization system.

Combustion Characteristics of Methane-Air Mixture in a Constant Volume Combustion Chamber(3) : Exhaust Emission (정적연소기에서의 메탄-공기 혼합기의 연소특성(3) : 배기배출물)

  • 최승환;전충환;장영준
    • Transactions of the Korean Society of Automotive Engineers
    • /
    • v.12 no.2
    • /
    • pp.1-8
    • /
    • 2004
  • A cylindrical constant volume combustion chamber was used to investigate the exhaust emission characteristics of homogeneous charge, stratified pattern and inhomogeneous charge under various conditions using gas chromatography. In the case of homogeneous charge condition, the $CO_2$ concentration is proportional to excess air ratio and overall charge pressure, the $CO_2$ concentration is proportional to excess air ratio and the UHC concentration is inversely proportional to ignition time and overall charge pressure. In the case of stratified pattern, the RI(rich injection) condition shows better exhaust emission characteristics, especially $CO_2$, than that of HI (homogeneous injection) or LI (lean injection) conditions. In inhomogeneous charge conditions, when initial charge pressure is increased, $CO_2$ and UHC concentration is reduced but $O_2$ concentration is increased. And when the excess air ratio of initial charge mixture is 3.0, UHC and $CO_2$concentration show lowest values.

Development of Biodiesel Production Equipment from Animal Fats and Consideration for Reaction Condition of Animal Biodiesel (동물성 유지를 원료로 한 바이오 디젤 제조 장치 개발 및 바이오 디젤의 반응조건 고찰)

  • Kim, Yong Hun;Cho, Young Hak
    • Journal of the Korean Society of Manufacturing Technology Engineers
    • /
    • v.22 no.1
    • /
    • pp.119-124
    • /
    • 2013
  • In this paper, we analysed fatty acid methyl ester contents in the biodiesel which is produced from the newly developed biodiesel production equipment. The lard oil was used as the raw material through various experimental conditions. Thirty one experiments were conducted, which were based on the experimental conditions that designed by central composite design method. The effects of four independent variables, including reaction temperature, reaction time, oil to methanol molar ratio, and catalytic amount, were investigated at five levels using central composite design (CCD). Fatty acid methyl ester content was chosen dependent variable. Although the results of analysis of the surface with an irregular surface geometry showed that the biodiesel was partially impure after the reaction due to the natural characteristics of the lard oil as the raw material, we could confirm the relationship between them from the facts that the production amount of fatty acid methyl ester changes according to reaction temperature, reaction time, oil to methanol molar ratio, and catalytic amount.

Comparison of Fatty Acid Composition of Phospholipids from Human Mature Milk, Infant Formulas and Market Milk. (인유, 조제 분유 및 시유의 인 지방질의 지방산 조성의 비교)

  • Yoon, Tai-Heon;Im, Kyung-Ja
    • Journal of the Korean Applied Science and Technology
    • /
    • v.2 no.1
    • /
    • pp.33-36
    • /
    • 1985
  • The fatty acid composition of Phospholipids from human mature milk, modified milk formula and market milk were analyzed by gas-liquid chromatography. The levels of 8:0, 10:0, 19:0, 20:0 and 22:0 were significantly higher in modified milk formula than in human milk. The levels of 14:0 and 16:0 were significantly lower in modified milk formula than in human milk. Modified milk formula had a higher $18:2{\omega}6$ content than human milk (17.9 versus 7.9%). The metabolites of the ${\omega}$9-, ${\omega}$6-$ and ${\omega}$3-series showed lower levels in modified milk formula than in human milk. The fatty acid composition of phospholipids from modified milk formula was similar to that of market milk.