• Title/Summary/Keyword: 가스채널

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Fabrication and Electrochemical Analysis of Back-gate FET Based on Graphene for O2 Gas Sensor

  • Kim, Jin-Hwan;Choe, Hyeon-Gwang;Kim, Jong-Yeol;Im, Gi-Hong;Jeon, Min-Hyeon
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.271-271
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    • 2014
  • 본 연구에서는 최근 다양한 전자 소자로써의 연구가 진행되고 있는 그라핀을 SiO2/Si 기판 위에 전자빔 식각(Electron-Beam Lithography)을 이용하여 후면 게이트 전극 구조의 그라핀 채널을 갖는 삼단자 소자를 형성하고 가스 유입이 가능한 진공 Probe Measurement System을 이용하여 금속 전극과 그라핀 간의 접촉저항 (Rc) 및 길이가 다른 채널저항(Rch)를 구하고, 채널 길이, 가스 유량, 온도, 게이트 전압에 따른 I-V 변화를 측정함으로써, 후면 게이트 전극 구조의 그라핀 채널을 갖는 삼단자 소자의 가스 센서로서의 가능성을 연구하였다. 후면 게이트 전극 구조의 그라핀 채널을 갖는 삼단자 소자는 전자빔 식각(Electron-Beam Lithography)에 의해 패턴을 제작하고 Evaporator를 이용하여 전극을 증착 하였다. 소자의 소스 (Source)와 드레인 (Drain)은 TLM (Transfer Length Method)패턴을 이용하여 인접한 두 개의 전극간 범위를 변화시키는 형태로 제작함으로써 소스-드레인간 채널 길이가 다르게 하였다. 이 때 전극의 크기는 가로, 세로 각각 $20{\mu}m$, $40{\mu}m$이며 전극간 간격은 $20/30/40/50/60{\mu}m$로 서로 다르게 배열 하였다. 제작된 그라핀 소자는 진공 Probe Measurement System 내에서 게이트 전압(VG)를 변화시킴으로써 VG 변화에 따른 소자의 특성을 평가하였는데, mTorr 상태의 챔버 내로 O2 가스를 주입하여 그라핀의 Dangling bond 및 Defect site에 결합 된 가스로 인한 전기적 특성의 변화를 측정하고, 이 때 가스의 유량을 50 sccm에서 500 sccm 까지 변화시킴으로써 전기적 특성 변화를 측정하여 센서 소자의 민감도를 평가하였다. 또한, 서로 다르게 배열한 소스-드레인 간의 채널 길이로 인하여 채널과의 접촉 면적에 따른 센서 소자의 민감도 또한 평가할 수 있었다. 그리고 챔버 내 온도를 77 K에서 400 K까지 변화시킴으로써 온도에 따른 소자의 작동 범위를 확인하고 소자의 온도의존성을 평가하였다.

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Numerical Analysis of Molten Carbonate Fuel Cell Stack Using Computational Fluid Dynamics (CFD를 이용한 용융탄산염 연료전지 스택의 수치모사)

  • Lee, Kab-Soo;Cho, Hyun-Ho
    • Journal of the Korean Electrochemical Society
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    • v.8 no.4
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    • pp.155-161
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    • 2005
  • In this paper, commercial CFD program FLUENT v5.3 is used for simulation of MCFC stack. Besides using conservation equations included in FLUENT by default, mass change, mole fraction change and heat added or removed due to electrochemical reactions and water gas shift reaction are considered by adding several equations using user defined function. The stacks calculated are 6 and 25 kW class coflow stack which are composed of 20 and 40 unit cells respectively. Simulation results showed that pressure drop took place in the direction of gas flow, and the pressure drop of cathode side is more larger than that of anode side. And the velocity of cathode gas decreased along with the gas flow direction, but the velocity of anode gas increased because of the mass and volume changes by the chemical reactions in each electrodes. Simulated temperature profile of the stack tended to increase along with the gas flow direction and it showed similar results with the experimental data. Water gas shift reaction was endothermic at the gas inlet side but it was exothermic at the outlet side of electrode respectively. Therefore water gas shift reaction played a role in increasing temperature difference between inlet and outlet side of stack. This results suggests that the simulation of large scale commercial stacks need to consider water gas shift reaction.

Numerical Simulation of Water Transport in a Gas Diffusion Layer with Microchannels in PEMFC (마이크로채널이 적용된 고분자 전해질 연료전지 가스확산층의 물 이송에 대한 전산해석 연구)

  • Woo, Ahyoung;Cha, Dowon;Kim, Bosung;Kim, Yongchan
    • Journal of the Korean Electrochemical Society
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    • v.16 no.1
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    • pp.39-45
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    • 2013
  • The water management is one of the key issues in low operating temperature proton exchange membrane fuel cells (PEMFCs). The gas diffusion layer (GDL) allows the reactant gases flow to the reaction sites of the catalyst layer (CL). At high current density, generated water forms droplets because the normal operating temperature is $60{\sim}80^{\circ}C$. If liquid water is not evacuated properly, the pores in the GDL will be blocked and the performance will be reduced severely. In this study, the microchannel GDL was proposed to solve the flooding problem. The liquid water transport through 3-D constructed conventional GDL and microchannel GDL was analyzed varying air velocity, water velocity, and contact angle. The simulation results showed that the liquid water was evacuated rapidly through the microchannel GDL because of the lower flow resistance. Therefore, the microchannel GDL was efficient to remove liquid water in the GDL and gas channels.

Effect of Gas Channel/Rib Width in Solid Oxide Fuel Cells (고체산화물 연료전지에서 가스채널/리브 폭의 영향에 관한 연구)

  • Jeon, Dong Hyup;Shin, Dong-Ryul;Ryu, Kwang-Hyun;Song, Rak-Hyun
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.41 no.2
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    • pp.109-115
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    • 2017
  • Using the computational fluid dynamics (CFD) technique, we performed a numerical simulation in anodesupported solid oxide fuel cell (SOFC). The effect of gas channel/rib width on the cell performance and temperature uniformity was investigated in planar type SOFC. The open source CFD toolbox, OpenFOAM, was used as a numerical analysis tool. As a result, the effect of gas channel/rib width on the cell performance and temperature uniformity was not significant if the oxygen depletion is not occurring. On the other hand, the usage of a wide rib and operation at high current density may lead to performance degradation due to oxygen depletion.

Numerical Study of Land/Channel Flow-field Optimization in Polymer Electrolyte Fuel Cells (PEFCs) (I) -The Effects of Land/Channel Flow-field on Current Density and HFR Distributions- (고분자전해질형연료전지의 가스 채널 최적화를 위한수치적연구(I) -가스 채널 치수가 전류밀도와 HFR 분포에 미치는영향성-)

  • Ju, Hyun-Chul
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.32 no.9
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    • pp.683-694
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    • 2008
  • The performance and durability of Polymer Electrolyte Fuel Cells (PEFCs) are strongly influenced by the uniformity of current density, temperature, species distributions inside a cell In order to obtain uniform distributions in them, the optimal design of flowfield must be a key factor. In this paper, the numerical study of land/channel flowfield optimizations is performed, using a multi-dimensional, multi-phase, non-isothermal PEFC model. Numerical simulations reveal more uniform current density and HFR(High Frequency Resistance) distributions and thus better PEFC performance with narrower land/channel width where the less severe oxygen depletion effect near the land region and more uniform contact resistance variation along the in-plane direction are achieved. The present study elucidates detailed effects of land/channel width and assist in identifying optimal flow-field design strategies for the operation of PEFCs.

Numerical Analysis-Based Design of PEMFC Channel, Fabrication of Channels, and Performance Test Using SU-8 (수치해석을 통한 PEMFC 채널의 설계와 SU-8을 이용한 채널 제작 및 성능 평가)

  • Choi, In-Jea;Wang, Hak-Min;Choi, Kap-Seung;Kim, Hyung-Man
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.34 no.4
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    • pp.349-354
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    • 2010
  • Fuel cells have attracted enormous interest as new power sources because the cells can be used to solve the problem of environmental pollution as well as the natural-resource exhaustion problem. In this study, hydrogen-gas flow in microchannels of different shapes was numerically analyzed to improve the efficiency of a microfuel cell. Flow characteristics in six microchannels of different shapes but under identical boundary conditions were simulated. The analysis result shows that the flow characteristics such as velocity, uniformity, and flow rate, greatly depend upon the channel shape. This implies that the efficiency of microfuel cell can be expected to be increased by adopting the optimal configuration of channel shape for hydrogen-gas flow. The experimental results show that power density of a PEMFC with a microflow channel is higher than that of a PEMFC without a microflow channel; however, a durable catalyst is required in MEA.

Structural Analysis of Gasket and GDL for Enhanced Performance of PEMFC (고분자 전해질 연료전지 가스켓 및 GDL의 구조 해석)

  • Yoon, Jin-Young;Park, Jungsun
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.36 no.7
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    • pp.642-650
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    • 2008
  • In this paper, structural behavior of Gasket and GDL of a PEMFC stack is studied to improve the performance and to secure the safety. In the Gasket analysis Mooney-Rivlin strain energy function is used to consider hyperelasticity of load and displacement. The material properties is determined by testing specimens of the gasket at uni-axial and equi-biaxial mode and compared with finite element analysis results. By measuring a thickness change, the material property of GDL is determined. The pressure drop of a unit cell is measured along the channel for the clamping force. A cross sectional change of channel base on the experimental data is obtained experimentally and compare with FEM analysis results.

Experimental Study on Single Channel DPF Device Applying the Method of Internal 2-Way Rotary Valve (회전형 밸브를 적용한 단일채널내 2-Way 방식의 DPF장치에 대한 실험적 연구)

  • Ham, Seong-Hun;Youm, Kwang-Wook
    • Journal of the Korean Institute of Gas
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    • v.19 no.6
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    • pp.110-115
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    • 2015
  • In this paper it is proposed to solve the problem of particulate matter reducing apparatus of the current DPF. One exhaust gas passage 2-way controlled to purify the exhaust gas generated during combustion efficiently. Through the control of the rotary valve within a single device, it is possible to prevent the exhaust pressure increases due to particulate matter accumulate inside the developing DPF. Develop DPF device capable of inducing a high efficiency of the output in order to improve the problem of reducing the engine output and fuel efficiency.