• Title/Summary/Keyword: 가스분리

Search Result 811, Processing Time 0.022 seconds

Studies on the Lipid Components of Potato Tubers - III. Composition of Polarlipids in Free and Bound Lipids - (감자의 지방질(脂肪質) 성분(成分)에 관한 연구(硏究) - 제(第) 3 보(報) : 유리(遊離) 및 결합(結合) 지질(脂質)중의 극성(極性) 지질(脂質)의 조성(組成)에 관하여 -)

  • Lee, Sang-Young;Shin, Hyo-Sun
    • Korean Journal of Food Science and Technology
    • /
    • v.11 no.4
    • /
    • pp.304-313
    • /
    • 1979
  • The compositions of the polar lipids in the free and bound lipids from four varieties of experimentally cultivated potatoes were identified and quantified by thin layer- and gas-liquid chromatographies. The results were summarized as follows : 1. The glycolipids contained in the free and bound lipids were fractionated and identified as esterified sterol glycoside, monogalactosyl diglyceride, sterol glycoside, digalactosyl diglyceride, and trigalactosyl diglyceride, of which the highest content to the total lipid quantity were 5.8% of esterified sterol glycoside in the free lipid and 6.1% of trigalactosyl diglyceride in the bound lipid. The content of monogalactosyl diglyceride in the free and bound lipids was almost the same, whereas the content of esterified sterol glycoside was higher in the free lipid than in the bound lipid, and the contents of sterol glycoside, digalactosyl diglyceride, and trigalactosyl diglyceride were higher in the bound lipid than in the free lipid on the contrary. 2. The phospholipid contained in the free and bound lipids were fractionated and identified as phosphatidyl ethanolamine, phosphatidyl glyceride, phosphatidyl choline, and phosphatidyl inositol, but the phosphatidyl glyceride was not detected in the free lipid. The highest content in the total lipid quantity was 3.3 % of phosophatidyl choline in the case of the free lipid, while 14.9 % of the phosphatidyl ethanolamine contained in the bound lipid was the highest. All other constituents of phospholipid were contained in larger quantity in the bound lipid than in the free lipid. 3. The fatty acid composition of glycolipid in the free and bound lipids was also the same as that of the total free and bound lipids. The differences were that the content of palmitic acid was higher in the glycolipid of the free lipid than in the total free lipid and the content of linoleic acid was lower in the glycolipid.

  • PDF

A Case Study on the Effective Liquid Manure Treatment System in Pig Farms (양돈농가의 돈분뇨 액비화 처리 우수사례 실태조사)

  • Kim, Soo-Ryang;Jeon, Sang-Joon;Hong, In-Gi;Kim, Dong-Kyun;Lee, Myung-Gyu
    • Journal of Animal Environmental Science
    • /
    • v.18 no.2
    • /
    • pp.99-110
    • /
    • 2012
  • The purpose of the study is to collect basis data for to establish standard administrative processes of liquid fertilizer treatment. From this survey we could make out the key point of each step through a case of effective liquid manure treatment system in pig house. It is divided into six step; 1. piggery slurry management step, 2. Solid-liquid separation step, 3. liquid fertilizer treatment (aeration) step, 4. liquid fertilizer treatment (microorganism, recirculation and internal return) step, 5. liquid fertilizer treatment (completion) step, 6. land application step. From now on, standardization process of liquid manure treatment technologies need to be develop based on the six steps process.

Analysis of all PCB Congeners in Air Samples by HRGC/HRMS (대기 시료 중 PCBs 전 이성체 분석에 관한 연구)

  • Kim, Kyoung-Soo;Song, Byung-Joo;Kim, Jong-Guk
    • Analytical Science and Technology
    • /
    • v.16 no.4
    • /
    • pp.309-319
    • /
    • 2003
  • This study was performed to describe analysis method of 209 PCB congeners in ambient air samples. The samples were collected by high volume air sampler in Chonju city. Extracted samples were cleaned by silicagel cleanup modified with sulfuric acid and activated carbon cleanup processing. The cleaned samples were analyzed by high resolution gas chromatography and high resolution mass spectrometry (HRGC/HRMS) with DB-5 column (60 m, 0.25 mm i.d., 0.25 m film thickness) to analyze the 209 kinds of PCB congeners. PCBs levels of air samples were detected to the range between 0.003 and $0.163pg-TEQ/m^3$. The PCBs congener of 162 kinds were detected in samples analysed using DB-5 column and 37 kinds peaks were overlapped with congeners more than one. It is difficult to isolate PCB 118/106 and PCB 105/127 in coplanar PCB, so it is likely to overestimate the concentration.. The distribution of coplanar-PCB congeners in origin source samples (Kanechlor and exhaust gas from incinerator) was compared with that in air samples, and PCB 81, PCB 77, PCB 126, and PCB 169 were higher in incinerator samples.

Removal of Impurities from Waste Carbon Sludge for the Recycling (폐 카본슬러지의 재활용을 위한 不純物 분리 제거)

  • 이성오;국남표;오치정;김선태;신방섭
    • Resources Recycling
    • /
    • v.10 no.3
    • /
    • pp.51-59
    • /
    • 2001
  • Impurities removal from waste carbon black was carried out to produce high-grade carbon black. A large amount of hydrophilic carbon black is produced as a byproduct of the hydrogen production process by flame decomposition of water. Due to its impurities content such as sulphur, iron, ash, etc., it can only be used as low-grade carbon or burnt out. High-grade hydrophilic carbon black is 3~5 times more expensive than oil-based carbon black because of high production cost associated with process complexly and pollutant treatment. Hydrophilic carbon is normally used for conductive materials for batteries, pigment for plastics, electric wire covering, additives for rubber, etc. In these applications, impurity content must be blow 1 fe. In this study, magnetic separation, froth flotation and ultrasonic treatment were employed to remove impurities from the low-grade hydrophilic carbon black. Results showed that the ash, iron and sulphur content of product decreased to less than 0.01 wt.%, 0.01 wt.% and 0.3 wt % respectively and the surface area of product was about 930 $m^2$/g for conductive materials.

  • PDF

Development and performance evaluation of the porous tube dilutor for real-time measurements of fine particles from high humidity environments (고수분 환경에서 미세먼지 실시간 측정을 위한 다공 튜브형 희석장치의 개발 및 성능 평가)

  • Woo, Chang Gyu;Hong, Ki-Jung;Kim, Hak-Joon;Kim, Yong-Jin;Han, Bangwoo;An, Jeongeun;Kang, Su Ji;Chun, Sung-Nam
    • Particle and aerosol research
    • /
    • v.13 no.3
    • /
    • pp.105-110
    • /
    • 2017
  • Real-time measurements of fine particles from stack emission gases are necessary due to the needs of continuous environmental monitoring of PM10 and PM2.5. The porous tube dilutor using hot and cold dilutions was developed to measure fine particles without condensable particles from highly humid emission gases and compared to the commercialized ejector-type dilutor. Particle size distributions were measured at the emission gases from a diesel engine and a coal-fired boiler. The porous tube dilutor could successfully measure the accumulation mode particles including relatively large particles more than $3{\mu}m$ without nuclei particles, while the ejector dilutor detected some condensable particles and could not detect large particles. The porous tube dilutor could successfully remove the already condensed water droplet particles generated by a humidifier in a $30m^3$ chamber.

Advanced Treatment of Liquid Fertilizer from Livestock Night Soil Treatment Facility by Membrane Separation Processes (분리막 공정을 이용한 축산분뇨 처리장 액비의 고도처리)

  • Kim, Joo-Hye;Kim, Seung-Geon;Lee, Ho-Won
    • Membrane Journal
    • /
    • v.24 no.2
    • /
    • pp.142-150
    • /
    • 2014
  • This paper is to develop the process suitable for the advanced treatment of liquid fertilizer from the livestock night soil treatment facility (biogas plant). Nanofiltration (NF) and reverse osmosis (RO) process was used, respectively, for the advanced treatment of liquid fertilizer. And membrane bioreactor (MBR) with and without biomedia were tested, respectively, for the pretreatment. It was found that almost T-N of the liquid fertilizer was composed of ammoniacal nitrogen. Transmembrane pressure of MBR with biomedia increased slowly during the operation time, while that of MBR without biomedia increased rapidly at the initial time. But there was no difference observed in the removal efficiencies of COD, T-N, and T-P irrespective of the dosage of biomedia. When the liquid fertilizer was pretreated by MBR with biomedia, the removal efficiencies of COD, T-N, and T-P were 99.8, 86.5%, and 99.8% by NF, and 99.9, 86.8%, and 99.8% by RO, respectively. Compared with the effluent quality standards of the livestock night soil treatment facility, the water quality treated by MBR and NF/RO process met the standard for COD and T-P, but exceeded the permitted standard for T-N. In order to meet the effluent quality standard for T-N, it is necessary to change the MBR operation cycle or to add the secondary treatment by NF/RO.

Growth of artificial Pb$ZrO_3$/Pb$TiO_3$ superlattices by pulsed laser deposition and their electrical properties (펄스레이져 증착법을 이용한 Pb$ZrO_3$/Pb$TiO_3$ 산화물 인공격자의 성장 및 전기적 특성)

  • 최택집;이광열;이재찬
    • Proceedings of the Materials Research Society of Korea Conference
    • /
    • 2003.11a
    • /
    • pp.54-54
    • /
    • 2003
  • 최근 새로운 개념에 물성 구현을 위한 강유전체 산화물 인공격자의 연구가 활발히 진행되고 있다. 본 연구에서는 펄스레이져 증착법을 이용하여 산소분압 100 mTorr와 증착온도 50$0^{\circ}C$에서 LSCO/MgO 기판 위에 PbTiO$_3$(PTO) 와 PbZrO$_3$(PZO)을 주기적으로 적층하여 강유전체 산화물 인공격자를 형성하였다. 인공격자의 주기는 1~100 unitcell 까지 변화시켰다. 적층주기와 두께 변화에 따른 PZO/PTO 인공격자의 성장과 전기적 특성에 대하여 관찰하였다. X선 회절분석을 통하여 PZO/PTO 인공격자는 주기가 25 unit cell 이하의 적층구조에서 초격자의 형성으로 인한 위성피크가 관찰되었으며, 그 이하의 낮은 주기(1~10 unitcell)에서는 위성피크와 강한 (100)과 (200) 성장거동을 보였다. 높은 주기에서는 c축 성장된 PTO와 a축 성장된 PZO 각각의 성장거동을 보였다. 적층 주기가 감소함에 따라 a축 성장된 PTO와 c축 성장된 PZO가 초격자를 형성하였다. 적층주기가 감소함에 따라 유전상수와 잔류분극값이 향상되었다. 유전상수는 1 unitcell 주기에서 800정도의 값을 보였고, 잔류분극값은 2 unitcell 주기에서 2Pr=38.7 $\mu$C/$\textrm{cm}^2$ 정도의 가장 큰 값을 나타냈다. 적층주기가 2 unitcell에서 두께가 감소함에 따라 유전상수가 감소하였고, 20 nm 까지 분극반전에 의한 capacitance-voltage 특성곡선의 이력 현상(강유전성)을 관찰하였다. 이러한 산화물 인공초격자에서의 유전상수와 잔류분극값의 향상에 대하여 논의 할 것이며, 임계크기효과 관점에서 나노사이즈(50 nm~5 nm)에서 인공초격자의 전기적 분극의 안정성에 대하여 또한 논의 할 것이다.소수성 가스의 경우70% 이상 향상되었음을 알 수 있었으며, 본 연구를 통해 광분해를 이용한 스크러버가 기존설비의 장.단점을 충분히 보완 가능한 환경 설비임을 확인할 수 있었다. duty로 구동하였으며, duty비 증가에 따라 pulse의 on-time을 고정하고 frequency를 변화시켰다. dc까지 duty비가 증가됨에 따라 방출전류의 양이 선형적으로 증가하였다. 전압을 일정하게 고정시키고 각 duty비에서 시간에 따라 방출전류를 측정한 결과 duty비가 높을수록 방출전류가 시간에 따라 급격히 감소하였다. 각 duty비에서 방출전류의 양이 1/2로 감소하는 시점을 에미터의 수명으로 볼 때 duty비 대 에미터 수명관계를 구해 높은 duty비에서 전계방출을 시킴으로써 실제의 구동조건인 낮은 duty비에서의 수명을 단시간에 예측할 수 있었다. 단속적으로 일어난 것으로 생각된다.리 폐 관류는 정맥주입 방법에 비해 고농도의 cisplatin 투여로 인한 다른 장기에서의 농도 증가 없이 폐 조직에 약 50배 정도의 고농도 cisplatin을 투여할 수 있었으며, 또한 분리 폐 관류 시 cisplatin에 의한 직접적 폐 독성은 발견되지 않았다이 낮았으나 통계학적 의의는 없었다[10.0%(4/40) : 8.2%(20/244), p>0.05]. 결론: 비디오흉강경술에서 재발을 낮추기 위해 수술시 폐야 전체를 관찰하여 존재하는 폐기포를 놓치지 않는 것이 중요하며, 폐기포를 확인하지 못한 경우와 이차성 자연기흉에 대해서는 흉막유착술에 더 세심한 주의가 필요하다는 것을 확인하였다. 비디오흉강경수술은 통증이 적고, 입원기간이 짧고, 사회로의 복귀가 빠르며, 고위험군에 적용할 수 있고, 무엇보다도 미용상의 이점이 크다는 면에서 자연기흉에 대해 유용한 치료방법임에는 틀림이 없으나 개흉술에 비해 재발율이 높고 비용이 비싸다는 문제가 제기되고 있는 만큼 더 세심한 주의와 장기 추적관찰이 필요하리라 사료된

  • PDF

Changes of Biological and Chemical Properties during Composting of Livestock Manure with Isolated Native Microbe (토착미생물별 가축분 퇴비화 과정중 생물화학적 특성 변화)

  • Han, Hyo-Shim;Lee, Kyung-Dong
    • Korean Journal of Soil Science and Fertilizer
    • /
    • v.45 no.6
    • /
    • pp.1126-1135
    • /
    • 2012
  • In order to produce high-quality fermenting composts, bacteria strains with high activities of extracellular enzymes (cellulase, chitinase, amylase, protease and lipase) were isolated from the soils in 6 provinces of Korea, and characterized by 16S rRNA gene sequence analysis and properties. The selected 7 stains inoculated to livestock manure for 2' fermenting time, and experimental treatment divided into 3 groups, B1, B2 and B3, according to microbial activity and enzyme type. Our results showed that microbe applications (B1, B2 and B3) can increase (p<0.05) both rhizomes (17-38%) and enzyme activities (50-81%) in compost after fermenting time, respectively, compared to non-microbe treatment (control). The microbe application also decreased significantly (p<0.05) the $NH_3$ and $H_2S$ gas contents 13.4 and 27.3% compared with control, and the Propionic acid and Butyric acid gas contents 14.5 and 19.6%, respectively, as compared to the control. The microbial degradation rate (%) of pesticides and heavy metals increased significantly (p<0.05) after fermenting time, respectively, as compared to the control. Especially, microbe applications were more effective in total rhizomes yields and bioactivities than non-microbe treatment. Thus the results of this study could help in development of potential bioinoculants and composting techniques that maybe suitable for crop production, and protectable for earth environment under various conditions.

Study on Sludge Reduction by Sludge Solubilization and Change of Operation Conditions of Sewage Treatment Process (하수슬러지 가용화와 하수처리 운전조건 개선을 통한 하수슬러지 발생저감 연구)

  • Choi, In-Su;Jung, Hoe-Suk;Han, Ihn-Sup
    • Journal of Korean Society of Environmental Engineers
    • /
    • v.31 no.12
    • /
    • pp.1113-1122
    • /
    • 2009
  • In order to find the way to solve the problem of sewage sludge discharge into the ocean, the sludge solubilization by ultrasonic and the improvement methods of wastewater treatment process were studied. In the membrane bioreactor the sludge retention time was stepwise increased from 5.1 day to 442 days where the biomass average concentration has been increased from $c_B$=3.4 $gTSSL^{-1}$ to $c_B$=14.5 $gTSSL^{-1}$ respectively. At the same time, the biomass yield coefficients were reduced from 0.5-0.7 at SRT=5.1 day to 0.005-0.007 at SRT=442 days which means the reduction of sludge production. Oxygen mass transfer coefficients and ${\alpha}$-factor were investigated with changing stirrer speed to find the relation between the high biomass concentration and aeration efficiency in the propeller loop reactor. As a result of sludge solubilization, the solubilization of sludge by ultrasound was increased with increasing energy input and it led to improved anaerobic digestion rate with more biogas production than that of nonsolubilized sewage sludge.

Estimation of Fugitive Emission Factors of HFC-134a from Scrap Cold Drinking Vending Machine at Use- and Disposal-Phase (음료용 폐자동판매기에서의 HFC-134a 사용 및 폐기단계 탈루배출계수 결정에 대한 연구)

  • Lee, Youngphyo;Kim, Eui-Kun;Kim, Seungdo;Byun, Seokho;Kim, Hyerim;Park, Junho;Lee, Dongwon
    • Journal of Korean Society of Environmental Engineers
    • /
    • v.35 no.5
    • /
    • pp.350-355
    • /
    • 2013
  • Little information is available for emission pathway even if HFC-134a that is known as one of the major greenhouse gases has been broadly used in Korea. This paper attempts to clarify the emission characteristics of HFC-134a used for refrigerant of cold drinking vending machines (CDVMs) at the use- and disposal-phase. We measured the residual amounts in the scrap CDVMs of 47 by applying commercial recover for refrigerant. The first-order kinetic model was introduced and the emission rate would be proportional to the remaining quantity of refrigerant. The emission factor at the use-phase was determined indirectly to be $6.9{\pm}0.7$ %/yr within a confidence interval of 95%, using information on residual amount and elapsed operation time at the disposal point. Correspondingly, the annual emission rate of HFC-134a per CDVM was determined to be 11.6 g. The average residual rate of HFC-134a in scrap CDVMs was assessed to be $62.5{\pm}2.2%$, leading to a potential emission amount of 144.8 g per scrap CDVM. The chemical compositions of refrigerants from scrap passenger vehicles are quite similar to those of new refrigerants, suggesting that the refrigerants from scrap passenger vehicles could be reused. During the recovering process of refrigerant, the recovered refrigerant was contaminated by compressor lubricant that accounted for about 30% in weight. It is necessary to separate the refrigerant from the recovered material contaminated by lubricant for recycling and reuse the refrigerant.