• Title/Summary/Keyword: 가스교환

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Preparation of Hybrid Cation Ion Exchange Fibers by Web Spray and Their Adsorption Properties for Ammonia Gas (Web Spray 법을 이용한 복합 양이온교환섬유의 제조 및 암모니아 흡착특성)

  • Park, Seong-Wook;Lee, Hoo-Kun;Rhee, Young-Woo;Jung, Boo-Young;Hwang, Taek-Sung
    • Polymer(Korea)
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    • v.31 no.6
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    • pp.479-484
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    • 2007
  • In this study, the hybrid ion exchange fibers (HIEF) were prepared by using web spraying muthod with hot melt adhesive. Characteristics of HIEF and their adsorption properties for ammonia gas were investigated. The ion exchange capacity (IEC) of HIEF was increased with increasing the resin contents and their values were higher than those of pure resin and ion exchange fabrics. The removal efficiency for ammonia gas increased with an increase in packing density of hybrid ion exchange fabrics in the column. The adsorption breakthrough time was 270 min, which was slower than those of the resin and fibers. The maximum value of adsorption for ammonia gas was 94%. The breakthrough time was also increased with increasing the concentration and flow rate of ammonia gas. The reaction constant(k) for ammonia gas was increased with increasing the concentration and flow rate of the gas, while it was decreased an the mass was increased.

Study on Heat Exchanging Characteristics of Automobile Exhaust Heat Recirculation Device (자동차 배기열 재순환장치의 열교환 특성에 관한 연구)

  • Hong, Young-Jun;Choi, Doo-Seuk;Jung, Young-Chul;Kim, Jong-Il
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.12 no.10
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    • pp.4302-4307
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    • 2011
  • Recently, various technologies for the fuel efficiency improvement are being developed. The purpose of this study is to evaluate the heat exchanging performance of a exhaust heat recirculation device and to propose a model with optimized performance. The device has been designed to warm up engine coolant as quickly as possible using wasted exhaust heat. To achieve these goals, heat transfer characteristics has been analyzed using CFD for the flow direction effect and in/out location effect of coolant. A method improving the effectiveness of heat exchange has been proposed. As a result, the highest efficiency in heat exchange was observed on condition that exhaust heat affects the coolant directly with a separate flow path between exhaust gas and coolant and that coolant flow rate is relatively low.

High Efficiency Hybrid Ion Exchange Chemical Filter for Removal of Acidic Harmful Gases (산성유해가스 제거를 위한 고효율 음이온교환 복합 폼 화학필터의 제조)

  • Jung, Youn Seo;Kim, In Sik;Hyeon, Seung Mi;Hwang, Taek Sung
    • Applied Chemistry for Engineering
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    • v.28 no.5
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    • pp.539-546
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    • 2017
  • In this study, an outstanding anion exchange chemical filter was prepared for acidic gas removal. Commercial anion exchange resin was attached to polyurethane (PU) foam by using different types of pressure sensitive adhesive (PSA). The water and chemical resistance and also adhesive elongation were investigated. Also, the behavior of HCl and HF adsorption was evaluated as functions of the initial concentration and flow rate. ATE-701, AT-4000C and HCA-1000 showed 900, 1,500% and 2,400% of the elongation, respectively. It was confirmed that the desorption ratio of HCA-1000 was less than 6% and had excellent durability in water and chemical resistance tests. The adsorption occurred faster as the concentration and flow rate of HCl and HF increased. But 100% adsorption equilibrium occurred after 110 minutes, regardless of the concentration and flow rate. In addition, SEM morphology showed that the adhesive was uniformly dispersed, while the porous structure of the ion exchange resin was maintained, and the chemical filter exhibited excellent durability for the adsorption/desorption process.

유해가스 흡착용 이온교환 부직포의 합성 및 흡착특성

  • Yang, Gab-Seok;Kim, Min
    • Proceedings of the Korean Institute of Industrial Safety Conference
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    • 2003.10a
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    • pp.160-163
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    • 2003
  • 산업시설의 급속한 팽창과 더불어 날로 증가하는 환경오염 문제는 대기 배출오염원과 그 종류가 다양해지고 있어 점차 인체에 유해한 대기 오염이 중요한 사회적 문제가 되고 있다. 오염물질 중 암모니아를 포함한 유해 가스는 화학공정에서 뿐만 아니라 양돈양계장, 비료공장, 사료제조공장, 분뇨처리장 등으로 그 발생원이 다양하며 질소를 함유한 유기물이 생물학적으로 분해될 때 생성된다.(중략)

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특집:에너지플랜트 및 핵심기자재 기술 - 플랜트용 열교환기 기술

  • Yun, Seok-Ho;Lee, Gong-Hun
    • 기계와재료
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    • v.24 no.1
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    • pp.64-71
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    • 2012
  • 열교환기은 대부분의 플랜트에서 공정효율을 결정하는 핵심기자재이다. 이에 따라 플랜트 전체 효율을 향상시키기 위한 고효율 열교환기에 대한 연구개발이 꾸준히 이루어지고 있으며, 최근 들어 심해저플랜트 등의 고압환경용, 가스액화 플랜트 등에 적용되는 극저온용, 가스터빈 등에 적용되는 초고온용 등 극한환경에서 사용되는 플랜트용 고신뢰용 열교환기에 대한 니즈가 증가하고 있다. 따라서, 국내업체들의 플랜트 기자재 시장 진입 및 점유율 확대를 위해 이러한 극한환경용 열교환기에 대한 원천기술 확보 전략이 필요하다. 이를 위해 본 연구에서는 플랜트용 열 교환기 기술현황에 대해 살펴보고자 한다.

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A Study on the Characterization of Atmospheric Dry Deposition for Polycyclic aromatic hydrocarbons Measured in Seoul (서울 지역의 PAHs(Polycyclic aromatic hydrocarbons)의 건식 침적량 특성의 연구)

  • 이승묵;이지이;한영지;배수야;윤희정;정장표;이동수
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 2000.04a
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    • pp.94-96
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    • 2000
  • Polycyclic aromatic hydrocarbons(다환방향족 탄화수소류: 이하 PAHs)는 여러 가지 오염원에서 배출되어 환경계에서 이동하는 중요한 화합물질 그룹중의 하나이다. 대부분의 PAHs는 발암물질이라고 의심이 가는 물질로써 여러 가지 형태의 배열로 연결되어 있는 두개 혹은 그 이상의 방향족 고리로 구성되어 있다 PAHs의 대기에서의 침적은 가스상과 입자상 물질의 비나 눈에 의한 제거, 입자상 물질의 건식침적 및 가스상 물질의 대기-수체간 교환에 의하여 이루어진다. (중략)

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국제학술회의 참관기 - 제45차 터보 엑스포 2000

  • Jo, Hyeong-Hui
    • The Science & Technology
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    • v.33 no.8 s.375
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    • pp.39-41
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    • 2000
  • 지난 5월 8일부터 4일간 독일 뮌헨에서 열린 제45차 터보 엑스포 2000은 가스터빈의 개발 및 신기술에 대한 정보교환을 목적으로 전 세계에서 2천여명이 참석하여 6백70여편의 논문발표와 2백여 회사가 참가한 전시회 및 22session에서의 가스터빈 사용자 심포지엄으로 개최되었다. 제46차 학술대회는 2001년 6월초에 미국 뉴올리안즈에서 개최될 예정이다.

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Adsorption Characteristics of Nitrogen monoxide over Dealuminated and Alkali/Alkaline-earth Metal ion Exchanged Y-Zeolites (탈알루미늄 및 알칼리/알칼리토금속 양이온을 교환한 Y형 제올라이트의 NO흡착 특성)

  • Kim, Cheol-Hyun;Lee, Chang-Seop
    • Journal of the Korean Institute of Gas
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    • v.9 no.4 s.29
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    • pp.17-25
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    • 2005
  • The dealuminated and alkali/alkaline-earth metal exchanged Y-zeolites were prepared as a catalyst. Elemental compositions and structures of the prepared catalysts were analyzed by the various spectroscopic techniques such as inductively coupled plasma-atomic emission spectroscopy(ICP-AES), X-ray fluorescence(XRF) and X-ray diffraction(XRD), and the desorption behaviors of adsorbed species on the catalyst surfaces were investigated via NO-TPD experiment. Comparing with the composition of the starting material of NaY zeolite, the magnitudes of Si/Al ratio in catalytic materials were increased after dealumination. The Si/Al ratio of catalytic materials after dealumination followed by Cs and Ba cation exchange were additionally decreased. Dealumination to catalysts induced a destruction of basic frame due to a detachment of aluminum, which results in reducing framework structure, while increasing non-framework structure. This phenomenon becomes more serious with increasing time of steam treatment and even more significant for the cation exchanged catalysts. In NO-TPD experiments, the desorption peaks of NO which indicates an activity point of catalysts shifted to the low temperature region after dealumination and cation exchange. The desorption peaks of the NO-TPD profiles taken after steam treatment also shifted to the low temperature region as the steam treatment time increased. In dealuminated and cation exchanged Y-zeolites, the catalytic activities were more influenced by exchanged cation and the formation of non-framework structure.

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The Effects of Inspiratory Pause on Airway Pressure and Gas Exchange under Same I:E ratio in Volume-controlled Ventilation (Volume-Controlled Mode의 기계환기시 동일환 I:E Ratio하에서 Inspiratory Pause가 기도압 몇 가스교환에 미치는 영향)

  • Choi, Won-Jun;Jung, Sung-Han;Lee, Jeong-A;Choe, Kang-Hyeon
    • Tuberculosis and Respiratory Diseases
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    • v.45 no.5
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    • pp.1022-1030
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    • 1998
  • Background : In volume-controlled ventilation, the use of inspiratory pause increases the inspiratory time and thus increases mean airway pressure and improves ventilation. But under the same I : E ratio, the effects of inspiratory pause on mean airway pressure and gas exchange are not certain. Moreover, the effects may be different according to the resistance of respiratory system. So we studied the effects of inspiratory pause on airway pressure and gas exchange under the same I : E ratio in volume-controlled ventilation. Methods: Airway pressure and arterial blood gases were evaluated in 12 patients under volume-controlled mechanical ventilation with and without inspiratory pause time 5%. The I : E ratio of 1 : 3, $FiO_2$, tidal volume, respiratory rate, and PEEP were kept constant. Results: $PaCO_2$ with inspiratory pause was lower than without inspiratory pause ($38.6{\pm}7.4$ mmHg vs. $41.0{\pm}7.7$ mmHg. p<0.01). P(A-a)$O_2$ was not different between ventilation with and without inspiratory pause $185.3{\pm}86.5$ mmHg vs. $184.9{\pm}84.9$ mmHg, p=0.766). Mean airway pressure with inspiratory pause was higher than without inspiratory pause ($9.7{\pm}4.0\;cmH_2O$ vs. $8.8{\pm}4.0\;cmH_2O$, p<0.01). The resistance of respiratory system inversely correlated with the pressure difference between plateau pressure with pause and peak inspiratory pressure without pause (r=-0.777, p<0.l), but positively correlated with the pressure difference between peak inspiratory pressure with pause and peak inspiratory pressure without pause (r=0.811, p<0.01). Thus the amount of increase in mean airway pressure with pause positively correlated with the resistance of respiratory system (r=0.681, p<0.05). However, the change of mean airway pressure did not correlated with the change of $PaCO_2$. Conclusion: In volume-controlled ventilation under the same I : E ratio of 1 : 3, inspiratory pause time of 5% increases mean airway pressure and improves ventilation. Although the higher resistance of respiratory system, the more increased mean airway pressure, the increase in mean airway pressure did not correlated with the change in $PaCO_2$.

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Design of the Stand-alone Autothermal Reformer for Natural Gas (자체 기동형 천연가스 자열개질기 설계)

  • Koo, Jeongboon;Kim, Youngae;Kwon, Hyunji;Kwak, Inseob;Sin, Jangsik
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.11a
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    • pp.113.1-113.1
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    • 2010
  • 본 연구에서는 중 소형 SOFC에 적용할 수 있는 연료 변환 시스템으로 자체 기동 및 독립운전이 가능한 천연가스 자열개질(ATR) 반응기를 $10Nm^3/hr$급으로 개발하고자한다. 설계된 천연가스 자열개질기는 자열개질 촉매를 코팅한 금속 모노리스형 촉매체를 반응기 내에 장착함으로써 반응열을 신속하게 제거 또는 공급할 수 있는 시스템으로 구성되었다. 이는 금속 모노리스의 뛰어난 열전도 능력에 의해 반응기 내의 촉매층 전체 온도 분포를 균일하게 유지할 수 있는 저에너지형 자열개질 반응기이다. 또한 빠른 기동 특성을 실현하기 위하여 전기 발열식 촉매체(EHC ; Electically Heated Catalyst)를 장착한 start-up 시스템을 적용하여 천연가스 자열개질 반응기의 신속한 기동과 장치 간편화를 실현하였으며, 합성 syngas의 배열 회수를 위한 최적 열교환 시스템을 설계/적용함으로써 에너지 효율 향상을 도모하였다. 이와 같은 촉매 및 구조 시스템을 가지는 천연가스 자열개질 반응용 소형 연료변환 시스템을 원통형의 이중관 구조로 구성하고, 독립운전 모드로 개발함으로써 소형 SOFC의 연료 변환장치의 적용에 용이하게 하고자 한다.

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