• Title/Summary/Keyword: 가소성

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The Studies of the Water-Vapour Transmission Rate and It's Proofness on the Various Commercial Polymer Films (상업용 고분자 필름의 투습속도 및 방습도에 관한 연구)

  • Hwan Kyu Suh;Jung Keun Lee
    • Journal of the Korean Chemical Society
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    • v.23 no.5
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    • pp.329-337
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    • 1979
  • The water-vapour transmission ratios (WVTR) of the various commercial polymer films have been investigated at the constant pressure and relative humidity (RH). Water proofnesses, the reciprocals of WVTR for the various samples, were determined using a cup device and maintaining the sample films at a constant temperature ($40{\pm}1^{\circ}C$) and a constant R. H ($90{\pm}2%$) for 24 hours. The following order of the relative proofness was observed; oriented polypropyrene (O.PP) > high density polyethylene (HDPE, Inflation) > high density polyethylene (HDPE. T-die) > casted polypropylene (C. PP) > nonoriented polyester (N. PET) > low density polyethylene (LDPE) > oriented polyester (O. PET) > rigid polyvinyl chloride (Rigid PVC) > semirigid polyvinyl chloride (Semirigid PVC) > nonrigid polyvinyl chloride (Nonrigid PVC) > oriented nylon (O. Nylon) > nonoriented nylon (N. Nylon). And water proofness order was also observed to decrease with the temperature rising; HDPE (T-die) > C. PP > O. PET > LDPE > O. Nylon. The activation energies of LDPE, HDPE (T-die), C. PP, O. PET and O.Nylon films were 12.0, 11.1, 11.4, 11.7, 14.1 kcal/mole, respectively. The WVTR's of the films were increased with the polarity of polymer and the addition of plasticizer in PVC, decreased with the increase of the film thickness and mechanical orientation. The WVTR's of the laminated films O. PP/LDPE, N.Nylon/LDPE, C.PP/LDPE were also more dependent on the film thickness than the WVTR's of the single films.

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The Effects of Complex Motor Training on Motor Function and Synaptic Plasticity After Neonatal Binge-like Alcohol Exposure in Rats (복합운동훈련이 신생 흰쥐의 알코올성 소뇌손상 후 운동기능 및 신경연접가소성에 미치는 영향)

  • Lee, Sun-Min;Koo, Hyun-Mo;Kwon, Hyuk-Cheol
    • Physical Therapy Korea
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    • v.12 no.3
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    • pp.56-66
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    • 2005
  • The purposes of this study were to test that complex motor training enhance motor function significantly, to test change in cerebellum, and to test the synaptic plasticity into the immunohistochemistry response of synaptophysin. Using an animal model of fetal alcohol syndrome - which equates peak blood alcohol concentrations across developmental period - the effects of alcohol on body weight during periods were examined. The effect of complex motor training on motor function and synaptic plasticity of rat exposed alcohol on postnatal days 4 through 10 were studied. Newborn rats were assigned to one of two groups: (1) normal group (NG), via artificial rearing to milk formula and (2) alcohol groups (AG), via 4.5 g/kg/day of ethanol in a milk solution. After completion of the treatments, the pups were fostered back to lactating dams, where they were raised in standard cages (two-and three animals per cage) until they were postnatal 48 days. Rats from alcohol group of postnatal treatment then spent 10 days in one of two groups: Alcohol-experimental group was had got complex motor training (learning traverse a set of 6 elevated obstacles) for 4 weeks. The alcohol-control group was not trained. Before consider replacing with "the experiment/study", (avoid using "got" in writing) the rats were examined during four behavioral tests and their body weights were measured, then their coronal sections were processed in rabbit polyclonal antibody synaptophysin. The synaptophysin expression in the cerebellar cortex was investigated using a light microscope. The results of this study were as follows: 1. The alcohol groups contained significantly higher alcohol concentrations than the normal group. 2. The alcohol groups had significantly lower body weights than the normal group. 3. In alcohol groups performed significantly lower than the normal group on the motor behavioral test. 4. In alcohol-control group showed significantly decreased immunohistochemistric response of the synaptophysin in the cerebellar cortex compared to the nomal group. These results suggest that improved motor function induced by complex motor training after postnatal exposure is associated with dynamically altered expression of synaptophysin in cerebellar cortex and that is related with synaptic plasticity. Also, these data can potentially serve as a model for therapeutic intervention.

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Effect of Rainfall after Cutting on Feed Value of Italian ryegrass (예취 후 강우가 이탈리안 라이그라스의 사료가치에 미치는 영향)

  • Park, Hyung Soo;Kim, Ji Hye;Choi, Ki Choon;Kim, Hyeon Seop
    • Journal of The Korean Society of Grassland and Forage Science
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    • v.36 no.4
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    • pp.293-297
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    • 2016
  • This study was conducted to determine the effect of rainfall after cutting on nutritive value of Italian ryegrass (Lolium multiflorum) hay. Fresh Italian ryegrass was treated with 3 days natural rainfall (56.5, 14.0 and 1.6 mm) after cutting without tedding. Rainfall effect on Italian ryegrass quality was evaluated based on Neutral detergent fiber (NDF) and acid detergent fiber (ADF), crude protein (CP), crude fat (CF), crude ash (CA) and non-fiber carbohydrate (NFC). The quality of Italian ryegrass was decreased with extending raining days. The content of neutral detergent fiber (NDF) was increased from 0.4 to 4.7% by 1 day advancement in raining. CF content was decreased from 8.1 to 32.8%. CP and CA contents did not change, but NFC content was decreased from 0.5 to 8.4%. The quality damage by the number of raining days after cutting Italian ryegrass was the lowest on the first day from exposure to rain.

[ $CO_2$ ] Recovery from LNG-fired Flue Gas Using a Multi-staged Pilot-scale Membrane Plant (파일럿규모의 다단계 막분리 공정을 통한 LNG 연소 배가스로부터 이산화탄소의 회수연구)

  • Kim, Jeong-Hoon;Choi, Seung-Hak;Kim, Beom-Sik;Lee, Soo-Bok;Lee, Yong-Taek
    • Membrane Journal
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    • v.17 no.3
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    • pp.197-209
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    • 2007
  • In this study, a multi-staged pilot-scale membrane plant was constructed and operated for the separation of $CO_2$ from LNG-fired boiler flue gas of 1,000 $Nm^3/day$. The target purity and recovery ratio of $CO_2$ required for the pilot plant were 99% and 90%, respectively. For this purpose, we previously developed the asymmetric polyethersulfone hollow fibers and evaluated the effects of operating pressure and feed concentration of $CO_2$ on separation performance[1,2]. The permeation data obtained were also analyzed in relation with the numerical simulation data using counter-current flow model[3,4]. Based on these results, we designed and prepared the demonstration plant consisting of dehumidification process and four-staged membrane process. The operation results using this plant were compared with the numerical simulation results on multi-staged membrane process. The experimental results matched well with the numerical simulation data. The concentration and the recovery ratio of $CO_2$ in the final stage permeate stream were ranged from $95{\sim}99%$ and $70{\sim}95%$, respectively, depending on the operating conditions. This study demonstrated the applicability of the membrane-based pilot plant for $CO_2$ recovery from flue gas.

Microstructure and plasma resistance of Y2O3 ceramics (Y2O3 세라믹스의 미세구조 및 플라즈마 저항성)

  • Lee, Hyun-Kyu;Lee, Seokshin;Kim, Bi-Ryong;Park, Tae-Eon;Yun, Young-Hoon
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.24 no.6
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    • pp.268-273
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    • 2014
  • $Y_2O_3$ ceramic specimens were fabricated from the granular powder, obtained by spray drying process from the slurry. The slurry was prepared by mixing PVA binder, NaOH for Ph control, PEG and $Y_2O_3$ powder. The $Y_2O_3$ specimen was shaped in size of ${\phi}14mm$ and then sintered at $1650^{\circ}C$. The characteristics, microstructure, densities and plasma resistance of the $Y_2O_3$ specimens were investigated with the function of forming pressure and sintering time. $Y_2O_3$ specimens were exposed under the $CHF_3/O_2/Ar$ plasma, the dry etching treatment of specimens was carried out by the physical reaction etching of $Ar^+$ ion beam and the chemical reaction etching of $F^-$ ion decomposed from $CHF_3$. With increasing sintering time, $Y_2O_3$ specimens showed relatively high density and strong resistance in plasma etching test.

Contents and Migration of Heavy Metals and Phthalates in Children's Products and Phthalates in Children's Products (어린이용품 환경유해인자인 중금속과 프탈레이트의 함유량 및 전이량 조사)

  • Choi, In Seak;Choi, Sung Churl
    • Journal of Korean Society of Environmental Engineers
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    • v.36 no.2
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    • pp.127-138
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    • 2014
  • As increasing concerns about potential risks and hazards in children's products, the laws and regulations for heavy metals and phthalate retardants contained in the children's products have been reinforced in many countries. Especially, in Korea, environment and health laws and regulations for children's products was declared in 2009. This study was researched in terms of contents and migration of phthalates and heavy metals in 124 children's products sold in the Korean market. The results for contents of heavy metals showed that 123 products contained different 14 heavy metals depending on kinds of products. As the results of migration by sucking, the heavy metals in the products such as black, plastic dolls, wood toys, and bottom mat for swimming were transferred into extraction solution. Ba, Cu, Zn, and Sn were transferred from most of these products into the extraction solution and Co, Ni and Pb were additionally transferred into several products. As the results of migration through a skin, while Ba, Cu, and Zn were transferred from most products containing the heavy metals, as for accessories, Cr, Ba, Ni, Zn, and Cu were migrated. The results of contents of phthalates presented that 21 products contained DBP, DEHP and DINP. Only 2 products showed the migration of DEHP by sucking. DEHP in most products were transferred and DBP for 2 products and DINP for 7 products were migrated.

A Very Early-Maturing Italian Ryegrass (Lolium multiflorum Lam.) New Variety, 'Greenfarm3ho' (이탈리안 라이그라스 신품종 '그린팜 3호'의 생육특성과 수량성)

  • Ji, Hee Chung;Whang, Tae Young;Kim, Ki-Yong;Choe, Hyunsoak;Hong, Ki Hung;Choe, Kuh Wann;Lee, Ki-Won;Lee, Sang-Hoon
    • Journal of The Korean Society of Grassland and Forage Science
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    • v.35 no.1
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    • pp.31-35
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    • 2015
  • This experiment was carried out to breed a very early-maturing variety of Italian ryegrass (Lolium multiflorum Lam.) in the Grassland and Forage Crops Division, National Institute of Animal Science, RDA, Cheonan, Korea from 2012 to 2014. New variety "Greenfarm3ho" is a diploid variety with a green leaf color, a semi-erect growth habit in late autumn/fall, and an erect growth habit in early spring. With a heading date of April 27, Greenfarm3ho was categorized as an early-maturing variety. Compared with the "Greenfarm" control variety, Greenfarm3ho's flag-leaf width was narrower by 0.5 mm, its flag-leaf length was longer by 4.4 cm, and its plant length was longer by 3 cm; additionally, Greenfarm3ho's stem thickness was 0.1 mm thicker and it showed winter hardiness. The dry matter (DM) yield (8,976 kg/ha) of Greenfarm3ho was similar to that of Greenfarm. The in vitro dry matter digestibility (IVDMD), total digestible nutrient (TDN), and crude protein (CP) of Greenfarm3ho were 70.0%, 64.1%, and 1.0%, respectively, which are higher than those of Greenfarm by 2.9%, 2.0%, and 1.4%, respectively. The acid detergent fiber (ADF) and neutral detergent fiber (NDF) content of Greenfarm3ho were 31.4% and 53.3%, respectively, which are lower than those of Greenfarm by 2.5% and 3.0%, respectively.

A Very Early-Maturing Italian Ryegrass (Lolium multiflorum Lam.) New Variety, 'Green Farm' for Double Cropping System (이모작 작부체계에 적합한 극조생종 이탈리안 라이그라스 신품종 '그린팜'의 품종 특성)

  • Ji, Hee-Chung;Lee, Sang-Hyun;Yoon, Sei-Hyung;Kim, Ki-Yong;Choi, Gi-Jun;Park, Hyung-Soo;Park, Nam-Gun;Lim, Young-Chul;Lee, Eun-Sup
    • Journal of The Korean Society of Grassland and Forage Science
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    • v.31 no.1
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    • pp.9-14
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    • 2011
  • This experiment was carried out to breed a very early maturing variety of Italian ryegrass (Lolium multiflorum Lam.) in Grassland and Forage Crops Division, National Institute of Animal Science, RDA, Cheonan from 2009 to 2010. A new variety, 'Green farm' is a diploid variety with green in leaf color and has erect and semi-erect growth habit in late autumn and early spring, respectively. 'Green farm' was on 28 April in heading date as a early-maturing variety. 'Green farm' was also wider by 0.4 mm in flag leaf width, longer by 0.8 cm in flag leaf length and shorter by 5 cm in plant height than those of control variety, 'Florida 80', respectively. 'Green farm' was thicker in stem thickness and stronger in winter hardness than those of the 'Florida 80'. Dry matter (DM) yield (11,790 kg/ha) of 'Green farm' was similar to that of 'Florida 80'. In vitro dry matter digestibility (IVDMD), total digestible nutrient (TDN) and crude protein (CP) of 'Green farm' were 68.7, 63.3 and 10.3% which are 1.9, 1.7 and 0.6% higher than those of 'Florida 80', respectively. Acid detergent fiber (ADF) and neutral detergent fiber (NDF) of 'Green farm' were 32.5 and 54.6% which are 2.2 and 4.3% lower than those of the 'Florida 80', respectively.

A Very Early-Maturing Italian Ryegrass (Lolium multiflorum Lam.) New Variety, 'Green farm II' (이탈리안 라이그라스 신품종 '그린팜 2호'의 생육특성과 수량성)

  • Ji, Hee Chung;Choi, Gi Jun;Lee, Sang Hyun;Kim, Ki-Yong;Lee, Ki Won;Park, Nam Gun;Lee, Eun Sup
    • Journal of The Korean Society of Grassland and Forage Science
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    • v.33 no.1
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    • pp.10-14
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    • 2013
  • This experiment was carried out to breed an early maturing variety of Italian ryegrass (Lolium multiflorum Lam.) in the Grassland and Forage Crops Division, National Institute of Animal Science, RDA, Cheonan from 2009 to 2011. A new variety, 'Green farm II' is a diploid with green leaves and has a semi-erect growth habit in late autumn and erect growth habit in early spring, respectively. 'Green farm II' was on the $28^{th}$ of April in the heading date as an early-maturing variety. 'Green farm II' was also wider by 0.6 mm in flag leaf width, shorter by 1 cm in flag leaf length and shorter by 1 cm in plant length than those of the control variety, 'Florida 80', respectively. 'Green farm II' was thicker by 0.7 mm in stem thickness and strong in winter hardness. Dry matter (DM) yield (11,452 kg/ha) of 'Green farm II' was similar to that of 'Florida 80'. In vitro dry matter digestibility (IVDMD), total digestible nutrients (TDN), and relative feed value (RFV) of 'Green farm II' were 70.6%, 63.9%, and 114% higher than those of 'Florida 80', respectively. Acid detergent fiber (ADF) and neutral detergent fiber (NDF) of 'Green farm II' were 31.7% and 52.6% which were 3.5% and 6.4% lower than those of 'Florida 80', respectively.

Pervaporation Characteristics of Water/ethanol Mixtures using PVA Membranes Crosslinked with Poly(styrene-maleic anhydride) (Poly (styrene-maleic anhydride)로 가교된 poly(vinyl alcohol) 막을 이용한 물/에탄올 혼합물의 투과증발 특성)

  • Kim, Sang-Gyun;Kim, Yong-Il;Lim, Gyun-Taek;Park, Sang-Wook
    • Applied Chemistry for Engineering
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    • v.10 no.3
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    • pp.374-381
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    • 1999
  • Poly(vinyl alcohol) (PVA) membranes crosslinked with poly(styrene-maleic anhydride) (PSMAn) were prepared, and the pervaporation characteristics of the membranes were studied for the separation of water/ethanol mixtures. The prepared PVA membranes showed that the permeation rate and separation factors were increased with increasing of PSMAn contents in the feed of 92/8 wt. % ethanol/water composition. However, when the water content in the feed composition was increased highly, the overall permeation rate was increased in the order of 2%>1%>0.5% in spite of the increase of the crosslinking contents, and the separation factor was decreased due to the higher sorbed water contents and the consequent plasticization action of membrane. Also, with respect to operating temperature, the permeation rate of the membranes obeyed the Arrhenius type. Especially, in the case of 2% crosslinked membrane, it was shown based on the pervaporation characteristics that both the permeation rate and separation factor were increased with increasing operating temperature from $30^{\circ}C$( to $50^{\circ}C$. From these results, it can be known that the hydrophilic groups introduced in the membrane by PSMAn highly affected the transport of permeants.

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