• Title/Summary/Keyword: 가성소다

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Study on the Optimum Pre-treatment Condition for Manufacture of Rice Hull Board (왕겨보드 제조를 위한 적정 전처리 조건에 관한 연구)

  • Lee, Hwa-Hyoung;Han, Kie-Sun
    • Journal of the Korean Wood Science and Technology
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    • v.28 no.3
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    • pp.9-13
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    • 2000
  • Wood demand is increasing more and more, but world has been confronted with decreasing forest resources. Korea has to depend upon foreign wood and wood-based products for more than 95 percent of total domestic demand per year. In order to heighten self-sufficiency for wood supply and demand, we have to develop wood substitutes. Rice hull is the cheapest agricultural by-product we can get in Korea, more over the production of rice hull amounts to 1 million tons per year. This study was carried out to utilize rice hull and to decide the optimum condition of rice hull pretreatment for manufacture of rice hull board. Steam explosion method gave the best result, and the next boiling treatment of 1 hour, the last 1 hour treatment with 1% NaOH solution. Optimum conditions of explosion method were 20kgf/$cm^2-1$ minute and 25kgf/$cm^2-1$ minute. Rice hull board made with exploded rice hull met the KS standard(KS F 3104, 1997) and showed the same strength as a control, PB. And also the 1 hour boiling treatment was more effective than the 1 hour treatment with 1% NaOH solution.

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The Synthesis and Characterization of Beta Alumina Powder by Microwave Extraction and Calcination Method (마이크로파 추출 및 하소법에 의한 베타 알루미나 분말 합성 및 특성)

  • 박희찬;박성수;정기석;김병우;이상은
    • Journal of the Korean Ceramic Society
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    • v.38 no.8
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    • pp.749-754
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    • 2001
  • 마이크로파 추출 및 하소 공정을 통하여 카올린으로부터 베타 알루미나 전구체 및 베타 알루미나 분말을 합성하였다. 황산 알루미늄 및 가성소다의 혼합 용액을 교반되는 에탄올 용액 중에 적하시켜서 $Al_2$(SO$_4$)$_3$.17$H_2O$$Na_2$SO$_4$.10$H_2O$의 균일한 침전물을 얻었다. $\beta$- 및 $\beta$\"-Al$_2$O$_3$상으로 구성된 베타 알루미나를 얻기 위하여 재래식 및 마이크로파 하소법으로 주어진 온도에서 약 2h 동안 침전물 시료를 하소하였다. 재래식 하소된 시료에 비하여 마이크로파 하소된 시료는 $\beta$\"-Al$_2$O$_3$상이 상대적으로 많이 존재하였다. 또한, 재래식 하소된 시료와 마이크로파 하소된 시료의 미세구조는 매우 상이하였다. 매우 상이하였다.

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Preparation of Hydrophilic Film using EVA (EVA를 이용한 친수성 필름의 제조)

  • Lee, Jin;Kim, Young-Sung;Choi, Chang-Nam
    • Proceedings of the Korean Society of Dyers and Finishers Conference
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    • 2012.03a
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    • pp.25-25
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    • 2012
  • 농업용 비닐하우스에 사용되는 EVA (ethylene-vinylacetate copolymer)고분자 필름의 무적성을 향상시킬 목적으로 EVA 및 PVAc (polyvinylacetate)필름을 가성소다 용액으로 가수분해하여 친수성을 검토하였다. EVA는 분말상의 고분자를 프레스로 압착하여 필름으로 성형하였으며, PVAc는 아세톤에 용해한 후에 필름으로 성형하였다. 가수분해에 따른 필름의 구조변화는 적외선 분광분석으로, 친수성 변화는 접촉각으로 평가하였다. 가수분해 시간이 증가함에 따라 친수성이 증가하였다. 이는 가수분해에 의해 소수성인 아세테이트기가 친수성인 수산기로 변했기 때문으로 생각되었다. 한편, 가수분해시킨 EVA 및 PVAc를 사용하여 프레스로 압착하여 제조한 필름에서는 친수성이 그다지 크게 증가하지 않았다.

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Hand and Physical Properties of Mercerized Cotton Fabric using KES (머서화 가공(加工) 면직물(綿織物)의 KES에 의(依)한 물리적(物理的) 특성(特性)과 태(態)의 변화(變化)에 대(對)한 연구(硏究))

  • Choi, Jeong-Im;Kim, Jong-Jun;Jeon, Dong-Won
    • Journal of Fashion Business
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    • v.11 no.1
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    • pp.125-135
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    • 2007
  • Each cotton fiber is a unicellular hair collected from the seed of cotton plant. The fiber contains many convolutions along its length. Mercer was the first to suggest caustic soda treatment of cotton in commercial application. Mercerization has been commercially used since Lowe's suggestion to endow cotton with increased strength and affinity for dyes with additional properties such as fabric touch or luster. In this study, cotton fabric specimens were mercerized to investigate the changes in physical and mechanical properties pertaining to the hand or touch of fabrics. Physical properties were measured using the KES(Kawabata Evaluation System).

Semi-Industrial Scale Data (NF분리막에 의한 머어서폐수에서의 알칼리 회수 및 국내 실용화 방안 연구)

  • 손은종;최은경;김진우
    • Proceedings of the Korean Fiber Society Conference
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    • 1998.04a
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    • pp.354-359
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    • 1998
  • 본 연구에서는 분획분자량이 RO막과 UF막 사이에 있는 NF막(Nanofiltration Membrane) 의 특성을 이용하여 앞서의 기초연구$^{1)}$ 를 바탕으로 현장적용을 위한 소현장규모의 실험을 수회 진행하여 실제로 NF막 공정기술의 현장실용화를 위해 검토되어야 할 사항 및 운전시간에 따른 막투과량 거동의 변화 및 온도의존성 등을 검토하였고, 이와 병행하여 염색공장, 염색공단조합, 폐알칼리 수거회사와의 면담을 통하여 머어서 공정 및 머어서 폐수 관련 현황을 조사하여 이를 토대로 분리막 공정의 경제성에 주요 역할을 하는 고농도 가성소다 폐수 수집을 위한 수세방법을 소개하였고 본 기술의 국내 실용화를 위한 문제점 파악 및 현 상황에서의 실용화 최적 방안을 제안하여 보았다.(중략)

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Development of NaOH Concentration Control System for a Liquor-Flow Polyester Hydrolysis Machine (액류감량기 가성소다 농도 제어 시스템의 개발)

  • 박정우;변희운;노근필;구자길;황백순;김덕리
    • Textile Coloration and Finishing
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    • v.12 no.4
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    • pp.233-238
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    • 2000
  • In this study, the control system of sodium hydroxide was demonstrated to systemize hydrolysis process in polyester dyeing. We mainly focused on the application method of acid-alkali titration for the polyester hydrolysis machine of liquor-flow type. Industrial pH meter with electrode type was used for identifying equivalence point. Three units which were analogue-to-digital card, microprocessor and digital output card were used to control NaOH concentration in the control part of the system. The yielded data are translated to the microprocessor through analogue-digital interfacing card. After calculating, NaOH concentration in NaOH storage tank was controlled through the digital output card and solenoid valves.

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BALLOON DILATATION OF ESOPHAGEAL STRICTURE (Balloon 확장술에 의한 식도협착증의 치료)

  • 윤성철;나인국;김형종;노영수;임현준;이길우
    • Proceedings of the KOR-BRONCHOESO Conference
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    • 1991.06a
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    • pp.33-33
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    • 1991
  • 부식성 식도염에서 속발한 식도협착의 비외과적 치료법으로 사용되었던 종래의 각종 소식자를 이용한 확장술은 그 효과가 일시적이며 소아에서 시행시 많은 문제점이 있다. 근래들어 관상동맥, 요관, 대장 등의 협착에 사용되어온 balloon Catheter를 이용한 식도 확장술은 비교적 안전하고 효과적이어서 소아나 정도가 심한 식도협착의 치료에 큰 도움을 줄 수 있다. 본 교실에서는 최근 2년간 부식성 식도염 후 속발한 식도협착 6 례를 Balloon catheter 확장법으로 치료하여 아래와 같은 결과를 얻었기에 보고하는 바이다. 1) 전체 6명 중 남자가 4명 여자가 2명으로 평균 연령은 45.7세였다. 2) 부식제의 종류는 가성소다가 5명 초산이 1명이였다. 3) 협착부위는 1례가 경부식도이며 5례가 흉부식도였고 이중 1례는 다발성 협착이 였다. 4) 확장 전 식도조영사진 상 협착부위의 평균 내경은 4.3mm였다. 5) 확장술을 시행한 횟수는 2회에서 5회( 평균 3.5회 )로 확장술이 끝난 후의 평균 내경은 13.5mm였다. 5) 확장술시 3례에서 식도파열이 발생하였으나 보존적 치료법으로 치유되었다.

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Shipboard Verification Test of Onboard Carbon Dioxide Capture System (OCCS) Using Sodium Hydroxide(NaOH) Solution (가성소다(NaOH) 용액을 이용한 선상 이산화탄소 포집 장치의 선박 검증시험)

  • Gwang Hyun Lee;Hyung Ju Roh;Min woo Lee;Won Kyeong Son;Jae Yeoul Jeong;Tae-Hong Kim;Byung-Tak NAM;Jae-Ik Kim
    • Journal of the Society of Naval Architects of Korea
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    • v.61 no.1
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    • pp.51-60
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    • 2024
  • Hi Air Korea and Hanwha ocean are currently developing an Onboard Carbon dioxide Capture System (OCCS) to absorb CO2 emitted from ship's engine using a sodium hydroxide(NaOH) solution, and converting the resulting salt into a solid form through a chemical reaction with calcium oxide (CaO). The system process involves the following steps; 1)The reaction of CO2 gas absorption in water, 2)The reaction between carbonic acid (H2CO3) and NaOH solution to produce carbonate or bicarbonate, and 3)The reaction between carbonate or bicarbonate and CaO to form calcium carbonate (CaCO3). And ultimately, the solid material, CaCO3, is separated and discharged using a separator. The OCCS has been installed on an ship and the test results have confirmed significant reduction effects of CO2 in the ship's exhaust gas. A portion of the exhaust gas emitted from the engine was transferred to the OCCS using a blower. The flow rate of the transferred gas ranged from 800 to 1384 m3/hr, and the CO2 concentration in the exhaust gas was 5.1 vol% for VLSFO, 3.7 vol% for LNG and a 12 wt% NaOH solution was used. The results showed a CO2 capture efficiency of approximately 42.5 to 64.1 vol% and the CO2 capture rate approximately 48.4 to 52.2kg/hr. Additionally, to assess the impact of the discharged CaCO3on the marine ecosystem, we conducted "marine ecotoxicity test" and performed Computational Fluid Dynamics (CFD) analysis to evaluate the dispersion and dilution of the discharged effluent.

Sintering of $\alpha{\;}-{\;}Al_2O_3$ with NaOH (가성소다를 이용한 $\alpha{\;}-{\;}Al_2O_3$의 소결반응)

  • 김재용;이진수;서완주;박수길;엄명헌
    • Journal of environmental and Sanitary engineering
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    • v.15 no.1
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    • pp.95-101
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    • 2000
  • This study was investigated to the reaction of alumina sintering with alkaline. The soluble $NaAlO_2$ was made after the commercial ${\alpha}-Al_2O_3$ was calcinated with NaOH. The reaction of alumina was carried out to be based on the effects of calcination temperature, time, and the mixing ratio of ${\alpha}-Al_2O_3/NaOH$. The alumina was calcined over $500^{\circ}C$ with NaOH powder after it was sieved with 170/270 mesh. The calcined alumina with NaOH powder was dissolved into $25^{\circ}C$ distilled water and filtrated, and HCI was added to adapt pH 6.5~7.5. The residue was separated with vacuum pump for filtration after it was adapted to proper pH, and aluminum compound was precipitated with $Al(OH)_3$. The investigation was carried out with the variables; the calcination temperature($500-900^{\circ}C$), the calcination time (30~90 min), and the concentration of HCI when leaching(0.5~3.0N) respectively. In this investigation, the main product of ${\alpha}-Al_2O_3$ and NaOH was $NaAlO_2$ and the maximum conversion ratio was 91.4% under the optimum conditions as followed ; the ratio of NaOH/${\alpha}-Al_2O_3$ was 1.5 and the calcination conditions were $800^{\circ}C$ and 90 min.

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Chlor-alkali Membrane Process and its Prospects (클로알칼리 멤브레인법과 전망)

  • Park, In Kee;Lee, Chang Hyun
    • Membrane Journal
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    • v.25 no.3
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    • pp.203-215
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    • 2015
  • Chlor-alkali (CA) membrane process is based on salined water electrolysis employing cation condutive polymer electrolytes, which has been used for the conventional production of both sodium hydroxide and chlorine gas. The CA membrane process has advantages such as relatively low environmental impacts and fairly reduced energy consumption, when compared with diaphragm and mercury process. In this review articles, basic concepts, fundamental characteristics, key technologies of CA membrane process are dealt with in detail. In addition, advanced technologies associated with CA membrane process are described. They include zerogap and oxygen depolarized cathode technologies to improve energy efficiency during the electrolysis. Carbon dioxide mineralization technology will also be introduced as an example of hybridization with different technologies. Finally, current market trend in CA membrane process will be presented.