• The Bulletin of The Korean Astronomical Society
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• v.35 no.1
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• pp.51.1-51.1
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• 2010

We present the interim results of simultaneous observations of SiO and H2O masers toward 401 known stellar SiO and/or H2O maser sources (166 both SiO and H2O maser sources, 83 only SiO maser sources, and 152 only H2O maser sources) using KVN_Yonsei telescope. The results of 166 known SiO/H2O maser sources will be presented by Kim et al. and the results of 83 only SiO maser sources and 152 only H2O maser sources presented here. Both SiO and H2O maser emission were detected from 30 sources giving a detection rate of 36 % toward known 83 only SiO maser sources, while they were detected from 66 sources giving a detection rate of 43 % toward known 152 only H2O maser sources at one epoch observation. Only SiO masers were detected from 42 sources toward 83 only SiO sources, while they were detected from 28 sources toward 152 only H2O sources. Characteristics of these observed sources in the IRAS two-color diagram is investigated including mutual relations between SiO and H2O maser emission. In addition, these results will be useful for statistical study of late-type stars and future VLBI observations.

• Journal of the Korean Chemical Society
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• v.39 no.3
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• pp.163-175
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• 1995

Metal free phthalocyanine($H_2Pc$) partially doped with iodine, $H_2Pc(I)x$, has been made to improve photosensitizing efficiency of ZnO/$H_2Pc$. The content of iodine dopant level(x) for $H_2Pc(I)x$ upon $H_2Pc$ polymorphs was characterized as ${\chi}-H_2Pc(I)_{0.92}$ and ${\beta}-H_2Pc(I)_{0.96}$ by elemental analysis. Characterization of iodine-oxidized $H_2Pc$ were investigated by TGA (thermogravimetric analysis), UV-Vis, FT-IR, Raman and ESR (electron spin resonance) spectrum, and the adsorption properties of $H_2Pc(I)x$ on ZnO were characterized by means of Raman and ESR studies. TGA for $H_2Pc(I)x$ showed a complete loss of iodine at approximately 265$^{\circ}C$ and the Raman spectrum of $H_2Pc(I)x$ and ZnO/$H_2Pc(I)x$ at 514.5 nm showed characteristic $I_3^-$ patterns in the frequency region 90∼550 $cm^{-1}$. ZnO/$H_2Pc(I)x$ exhibited a very intense and narrow ESR signal at $g=2.0025{\pm}0.0005$ compared to $H_2Pc$/ZnO. Iodine doped ZnO/$H_2Pc(I)x$ showed a better photosensitivity compared to iodine undoped ZnO/$H_2Pc$. That is, the surface photovoltage of ${\chi}-H_2Pc(I)_{0.92}$/ZnO was approximately 31 times greater than that of ZnO/${\chi}-H_2Pc$ and ZnO/${\beta}-H_2Pc(I)_{0.96}$ was 5 times more efficient than ZnO/${\beta}-H_2Pc$ at 670 nm. And the dependence of photosensitizing effect upon $H_2Pc$ polymorphs was exhibited that the surface photovoltage of ZnO/${\chi}-H_2Pc(I)_{0.92}$ was approximately 5 times greater than ZnO/${\beta}-H_2Pc(I)_{0.96}$ at 670 nm. Therefore Iodine doping of H_2Pc$ resulted in increase in photoconductivity of $H_2Pc$ and photovoltaic effect of ZnO/$H_2Pc$ in the visible region.

• Applied Chemistry for Engineering
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• v.31 no.6
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• pp.674-678
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• 2020

In this study, a Pd/TiO2 catalyst which oxidized H2 at room temperature without an additional energy source was prepared. And a specific surface area of TiO2 as a support was not proportional to H2 oxidation reaction performance of Pd/TiO2 catalyst. In addition La2O3 was added to Pd/TiO2 catalyst in order to evaluate the performance effect due to the change of catalysts physical properties. A Pd/La2O3-TiO2 was prepared by adding different amounts of La2O3 to TiO2 and CO chemisorption analysis was performed. Compared to the conversion rate (14% at 0.5% H2) of the Pd/TiO2(G) catalyst, the Pd/La2O3-TiO2 catalyst showed 74% which was improved by more than five times. It was found that the larger the metal dispersion of Pd as an active metal is, the more favorable to H2 oxidation reaction is. However, when the added La2O3 amount exceeded 10%, the catalyst performance decreased again. Finally, it was concluded that the physical properties of the Pd/La2O3-TiO2 catalyst have a dominant influence on the catalytic activity until 0.3~0.5% of injected H2 concentrations and the catalyst reaction rate was controlled by substance transfer from 1% or more concentrations of H2.

• Journal of the Korean Chemical Society
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• v.52 no.3
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• pp.322-327
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• 2008

The geometrical structure, binding energy and vibrational frequencies of HOOCl-H2O cluster were investigated with MP2/6-311G(d,p) and MP2/6-311G(2d,2p) methods. The most stable conformer is skew HOOCl-H2O cluster and the binding energy was 46~48kJ/mol. The trans HOOCl-H2O cluster is less stable than skew form, but the binding energy is big enough to stablize the complex. The vibrational frequencies of skew and trans HOOCl-H2O cluster were calculated and compared with the spectrum of HOOCl.

• The Bulletin of The Korean Astronomical Society
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• v.35 no.1
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• pp.51.2-51.2
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• 2010

We have carried out an extensive statistical analysis based on the results of simultaneous observations of SiO and $H_2O$ masers toward 166 known SiO and $H_2O$ maser sources using KVN_Yonsei radio telescope (Kim et al.2010, ApJS submitted). We investigate the distributions of the mean velocities and the intensity ratios between SiO and $H_2O$ maser emission including those between SiO v=1 and v=2,J=1-0 transitions according to type of evolved stars. We also investigate mutual relations between SiO and $H_2O$ maser properties(total flux densities and velocity structures etc.) according to stellar pulsation phases. Most of SiO masers appear around the stellar velocity (80 % within ${\pm}5km\;s^{-1}$), while $H_2O$ masers show a different characteristic compared with SiO masers (69% within ${\pm}5km\;s^{-1}$). In addition, we investigate a correlation between $SiO/H_2O$ maser emission and AKARIFIS flux density as well as the AKARI color characteristics of SiO and $H_2O$ observational results in the AKARIFIS two-color diagram.

• Journal of the Korean Chemical Society
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• v.61 no.6
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• pp.328-338
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• 2017

The density functional theory(DFT) and ab initio calculations have been applied to investigate hydrogen interaction of $H_2O_3(H_2O)_n$ clusters(n=1-5). The structures, IR spectra, and H-bonding energies are calculated at various levels of theory. The $trans-H_2O_3$ monomer is predicted to be thermodynamically more stable than cis form at the CCSD(T)/cc-pVTZ level of theory. For clusters, the geometries are optimized at the MP2/cc-pVTZ level of theory. The binding energy of $H_2O_3-H_2O$ cluster is predicted to be -6.39 kcal/mol at the CCSD(T)//MP2/cc-pVTZ level of theory after zero-point vibrational energy (ZPVE) and basis set superposition error (BSSE) correction. This result implies that $H_2O_3$ is a stronger proton donor(acid) than either $H_2O$ or $H_2O_2$. The average binding energies per $H_2O$ are predicted to be 8.25 kcal/mol for n=2, 7.22 kcal/mol for n=3, 8.50 kcal/mol for n=4, and 8.16 kcal/mol for n=5.

• Journal of environmental and Sanitary engineering
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• v.15 no.4
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• pp.27-27
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• 2000

In order to treat the dyeing wastewater, the UV/TiO₂/H₂O₂ system was investigated, and proper pretreatment methods were examined to reduce the load on the system considering economical and technical efficiency. The results of this study were as follows: 1.UV/TiO₂/H₂O₂ system with pretreatment process was adopted, the result of Chemical coagulation and pH control units was pH 11→ coagulation → pH 4 and the optimum dosage of FeCl₃ was 600㎎/ℓ 2. Proper dosage of TiO₂in the UV/TiO₂/H₂O₂ system with pretreatment process was 2g/ℓ and H₂O₂ was 1000㎎/ℓ, UV contact time was 20min to get below 200㎎/ℓ of $COD_{Cr}$

• Journal of environmental and Sanitary engineering
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• v.15 no.4
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• pp.26-34
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• 2000

In order to treat the dyeing wastewater, the $UV/TiO_2/H_2O_2$ system was investigated, and proper pretreatment methods were examined to reduce the load on the system considering economical and technical efficiency. The results of this study were as follows: 1. $UV/TiO_2/H_2O_2$ system with pretreatment process was adopted, the result of Chemical coagulation and pH control units was $pH{\;}11{\;}{\rightarrow}{\;}coagulation{\;}{\rightarrow}{\;}pH{\;}4$ and the optimum dosage of $FeCl_3$ was $600mg/{\ell}$. 2. Proper dosage of $TiO_2$ in the $UV/TiO_2/H_2O_2$ system with pretreatment process was $2g/{\ell}$ and $H_2O_2$ was $1000mg/{\ell}$, UV contact time was 20min to get $200mg/{\ell}$ of $COD_{Cr}$.

• Journal of Environmental Science International
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• v.15 no.3
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• pp.193-201
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• 2006

Advanced oxidation processes involving $O_3/H_2O_2$ and $O_3/catalyst$ were used to compare the degradability and the effect of pH on the oxidation of 1,4-dioxane, Oxidation processes were carried out in a bubble column reactor under different pH. Initial hydrogen peroxide concentration was 3.52 mM in $O_3/H_2O_2$ process and 115 g/L (0.65 wt.%) of activated carbon impregnated with palladium was packed in $O_3/catalyst$ column. 1,4-dioxane concentration was reduced steadily with reaction time in $O_3/H_2O_2$ oxidation process, however, in case of $O_3/catalyst$ process, about $50{\sim}75%$ of 1,4-dioxane was degraded only in 5 minutes after reaction. Overall reaction efficiency of $O_3/catalyst$ was also higher than that of $O_3/H_2O_2$ process. TOC and $COD_{cr}$ were analyzed in order to examine the oxidation characteristics with $O_3/H_2O_2\;and\;O_3/catalyst$ process. The results of $COD_{cr}$ removal efficiency and ${\Delta}TOC/{\Delta}ThOC$ ratio in $O_3/catalyst$ process gave that this process could more proceed the oxidation reaction than $O_3/H_2O_2$ oxidation process. Therefore, it was considered that $O_3/catalyst$ advanced oxidation process could be used as a effective oxidation process for removing non-degradable toxic organic materials.

• Journal of the Korean Ceramic Society
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• v.25 no.2
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• pp.136-142
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• 1988

β-Al2O3, which is used for solid electrolyte membrances in sodium-sulfur batteries, was prepared by sol-gel process. Sodium-n-propoxide NaOC3H7 and aluminum-isopropoxide Al(OC3H7)3 were hydrolyzated in the solution at pH 3, pH 7, pH 9 and pH 11, respectively. The sol-gel processed samples were calcined at several temperature steps, respectively and analysed by thermal analyser(DT-TGA), infrared spectrum analyser and X-ray diffraction analyser. The gelling rate of solution at pH 7 was much higher than that of the solution at pH 3. Thermal exchanging behavior of the gels at pH 3 were similar to Na2O·Al2O3·6H2O and, above pH 7, were similar to Na2O·Al2O3·3H2O. When samples' composition ratio was 9.13 : 90.87 [NaOC3H7:Al(OC3H7)3] at pH 7, β-Al2O3 was formed at 1100℃.