• 제목/요약/키워드: [ph]

검색결과 1,898건 처리시간 0.029초

Stability Analysis and Design of a Nonlinear Neuromuscular Control System of a Myoelectric Prosthetic Hand

  • Pak, Pyong-Sik;Okuno, Ryuhei;Akazawa, Kenzo
    • 제어로봇시스템학회:학술대회논문집
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    • 제어로봇시스템학회 2003년도 ICCAS
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    • pp.1489-1494
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    • 2003
  • A neuromuscular control system of a myoelectric prosthetic hand (PH) constitutes a nonlinear system with a dead zone whose magnitude is equal to its joint angle when the PH just grasps an object. This is because the neuromuscular control system remains an open-loop system until the PH grasps the object but it constitutes a feedback control system after the PH griped the object in which a torque induced in the fingers of the PH is fed back. To improve the transient performance of the control system, it is desirable to make the feed-forward gain as large as possible, so long as the stability of the system is not impaired. It is also desired that the control system remains stable even when the PH lifts a heavy or rigid object, because this makes the closed loop gain large and leads to the closed system unstable. According to the theory of stability analysis of nonlinear systems, we can only know the sufficient conditions that the system should be stable. Thus the nonlinear theory on stability is insufficient to be used to design the neuromuscular control system for improving its transient responses. This paper shows that the nonlinear system with a dead zone can be approximated to a linear feedback system and that well-known methods of analysis and design on linear control systems can be applicable. It is also shown through various simulation results that errors induced by approximation are practically negligible and thus the design methods are quite accurate.

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PBF와 DED 공정으로 제조된 17-4PH 스테인리스 강의 미세조직 및 기계적 특성 평가 (Evaluation of Microstructure and Mechanical Properties in 17-4PH Stainless Steels Fabricated by PBF and DED Processes)

  • 윤종천;이민규;최창영;김동혁;정명식;최용진;김다혜
    • 한국기계가공학회지
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    • 제17권2호
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    • pp.83-88
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    • 2018
  • Additive manufacturing (AM) technologies have attracted wide attention as key technologies for the next industrial revolution. Among AM technologies using various materials, powder bed fusion (PBF) processes and direct energy deposition (DED) are representative of the metal 3-D printing process. Both of these processes have a common feature that the laser is used as a heat source to fabricate the 3-D shape through melting of the metal powder and solidification. However, the material properties of the deposited metals differ when produced by different process conditions and methods. 17-4 precipitation-hardening stainless steel (17-4PH SS) is widely used in the field of aircraft, chemical, and nuclear industries because of its good mechanical properties and excellent corrosion resistance. In this study, we investigated the differences in microstructure and mechanical properties of deposited 17-4PH SS by PBF and DED processes, including the heat treatment effect.

Substituents Effect on Aziridine Chemistry: N-Inversion Energy, Reactivity and Regioselectivity of Nucleophilic Ring-opening

  • Park, Gyoo-Soon;Kim, Seok-Chan;Kang, Han-Young
    • Bulletin of the Korean Chemical Society
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    • 제26권9호
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    • pp.1339-1343
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    • 2005
  • The N-inversion energies and nucleophilic ring-opening reactions of N-substituted aziridine compounds are investigated using B3LYP/6-31+$G^*$ methods, where substituents (R) on the nitrogen atom has been H (1), Me (2), Ph (3), Bn (4), CHMePh (5), $CO_2Me$ (6), COPh (7) and $SO_2Ph$ (8). The N-inversion energy with X group are decreased as the following order: R = CHMePh (17.06 kcal/mol) $\gt$ Me (16.97) $\gt$ Bn (16.70) $\gt$ H (16.64) $\gt$ $SO_2Ph$ (12.18) $\gt$ Ph (8.91) $\gt$ COPh (5.75) $\gt$ $CO_2Me$ (5.48). For reactivity of the ring opening toward cyanide ion, the aziridine 6 (R=$CO_2Me$) is shown to be the most reactive one. During the ring opening of aziridine 6 by CN$^{\ominus}$, the torsional OCNC angle becomes near to $180^{\circ}$, where the geometry allows for the effective incorporation of electrons of the nitrogen atom to the C=O bond. It would be a possible driving force for nucleophilic ring opening reaction as well as decreasing the N-inversion energy barrier. Regarding to the regioselectivity, the orientation of nucleophile in ring opening reaction appears to be different in the case of 9 and 10. The results are discussed in terms of steric/electronic effect of the $C_2$-substituents.

산성이온수 농도제어를 위한 Microprocessor를 이용한 PWM 제어 (The PWM Control Which used Microprocessor for Intensity Control of Acid Ion Water)

  • 권윤중;남상엽
    • 전자공학회논문지
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    • 제50권7호
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    • pp.269-274
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    • 2013
  • 전해 산성이온수는 알칼리성 이온수에 비해 응용분야가 음용을 목적으로 하는 알칼리이온수와 많이 다르게 이용되고 있으며 ph 농도에 따라 강산성인 경우 잔류염소에 의한 살균 목적의 소독제로 사용되고, 중산성인 경우 세척과 세안으로 사용하고, 약산성인 경우 식재료와 혼합하여 요리에 널리 사용할 수 있다. 이런 산성이온수를 생성하기 위해서는 물을 전기분해 하여 사용하는데 전기분해 하는 과정에서 염소가스와 수산화나트륨 등의 물질로 살균력을 가지며, 전기분해시 +전극 쪽으로 -이온을 띤 염소, 인, 유황 등의 유기물이 모여져 산성이온수를 만든다. 또한 산성수와 알칼리수를 분리하기 위해서 격막을 사용했다. ph 농도변화의 구현방법은 Microprocessor를 이용하여 강산성에서 약산성 사이의 ph 농도를 PWM(pulse width modulation) 제어로 3종류의 PWM 전압을 전해조 전극에 인가하여 PWM제어에 의한 연속적으로 농도가 조절된 산성수가 생성되게 구현하였다.

Cloning and Characterization of a PI-like MADS-Box Gene in Phalaenopsis Orchid

  • Guo, Bin;Hexige, Saiyin;Zhang, Tian;Pittman, Jon K.;Chen, Donghong;Ming, Feng
    • BMB Reports
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    • 제40권6호
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    • pp.845-852
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    • 2007
  • The highly evolved flowers of orchids have colorful sepals and fused columns that offer an opportunity to discover new genes involved in floral development in monocotyledon species. In this investigation, we cloned and characterized the homologous PISTALLATA-like (PI-like) gene PhPI15 ($\underline{Ph}alaenopsis$ $\underline{PI}$ STILLATA # $\underline{15}$), from the Phalaenopsis hybrid cultivar. The protein sequence encoded by PhPI15 contains a typical PI-motif. Its sequence also formed a subclade with other monocot PI-type genes in phylogenetic analysis. Southern analysis showed that PhPI15 was present in the Phalaenopsis orchid genome as a single copy. Furthermore, it was expressed in all the whorls of the Phalaenopsis flower, while no expression was detected in vegetative organs. The flowers of transgenic tobacco plants ectopically expressing PhPI15 showed male-sterile phenotypes. Thus, as a Class-B MADS-box gene, PhPI15 specifies floral organ identity in orchids.

시호(柴胡)와 산장(酸漿) 복합제가 LPS로 유도된 우울증에 미치는 효과 (Effect of Mixture extracted from Bupleuri Radix and Physalidis Herba on the LPS-induced depression in Rats)

  • 이원행;김도훈;이태희
    • 대한본초학회지
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    • 제30권3호
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    • pp.69-76
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    • 2015
  • Objectives : The effect of mixture extracted from Bupleuri Radix and Physalidis Herba(BR+RH) on the LPS-induced Depression in rats was investigated. Methods : Rats were administered intragastrically BR+PH after injectio of LPS to induce deprssion. Immobility was examined using Tail Suspension Test(TST), Forced Swimming Test(FST). The level of plasma corticosterone was measured by an Enzyme-Linked Immunosorbent Assay(ELISA) method. The expressions of c-Fos, Corticotropin Releasing Factor(CRF), NADPH-d in the Paraventricular nucleus(PVN) and TH in the Locus coeruleus(LC) were measured by immunohistochemical method. Results : In the effect of BR + PH on TST, immobility was significantly decreased comparing with the LPS group. In FST, immobility was shown decrease tendency in the BR+PH group. The expression of c-Fos in the PVN was significantly decreased at BR + PH400 group, comparing with the LPS group. The expression of CRF in PVN was shown dto have the decrease tendency in the BR+PH group, comparing with the LPS group. The expression of NADPH-d in PVN was not significantly decreased at BR+PH groups, comparing with the LPS group. The expression of TH in the LC was shown to have the decrease tendency at BR + RH groups, but not significantly, comparing with the LPS group. Conclusions : Anti-depressant effect of mixture after extracted from Bupleuri Radix and Physalidis Herba was through the anti-inflammatory effect via inhibition of HPA axis. NO and catecholamine system is not involved.

Geometrical Characteristics and Reactivities of Tetracoordinated Pd Complexes: Mono- and Bidentate Ligands and Charged and Uncharged Ligands

  • Yoo, Jin-Seon;Ha, Dong-Su;Kim, Jae-Sang;Kim, Bong-Gon;Park, Jong-Keun
    • Bulletin of the Korean Chemical Society
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    • 제29권3호
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    • pp.627-640
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    • 2008
  • The geometrical structures, atomic charges, and relative energies of tetracoordinated Pd complexes [PdCl3Z (Z = Cl-, Br-, OH?-, H2O, NH3, PH3), PdCl2Z2 (Z = Br-, OH?-, H2O, NH3, PH3), PdZ?2X (Z = Cl-, OH?-, H2O, NH3, PH3; X = oxalate, O2-?CCO2-), and PdZ2Y (Z = Cl?-, OH?-, H2O, NH3, PH3; Y = succinate, CO2-?CHCHCO2-?)] and the ligand exchange reactions of the Pd complexes were investigated using the ab initio second order Mller-Plesset perturbation (MP2) and Density Functional Theory (DFT) methods. The geometrical characteristics of the tetracoordinated Pd(II) complexes with mono- and bidentate ligands, the effects of the atomic charges for the charged and uncharged ligands, the (dz2-p ) interactions between the dz2-orbital of Pd(II) and the p -orbital of bidentates, and the relative stabilities between the isomers of PdCl2Z2 and PdZ2Y were investigated in detail. The potential energy surfaces for the ligand exchange reactions used for the conversions of {[PdCl2(NH3)2] + H2O} to {[PdCl(NH3)2(H2O)]+ + Cl?-?} and {[PdCl2(PH3)2] + H2O} to {[PdCl(PH3)2(H2O)]+ + Cl?-?]} were investigated. The geometrical structure variations, molecular orbital variations (HOMO and LUMO), and relative stabilities for the ligand exchange processes were also examined quantitatively.

(펜타메틸시클로펜타디에닐) 비스(포스핀)루테늄의 염화물과 수소화물 유도체 (Chloro- and Hydrido Complexes of (Pentamethylcyclopentadienyl) bis(phosphine)ruthenium)

  • 이동환
    • 대한화학회지
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    • 제36권2호
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    • pp.248-254
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    • 1992
  • 에탄올 용매 중에서, 착물 $[({\eta}^5-C_5Me_5)RuCl_2]_2$ (1)에 대하여 과량의 포스핀을 반응시켜 비스(포스핀)루테늄 유도체$({\eta}^5-C_5Me_5)Ru(PR_3)_2Cl(PR_3=PMe_3,\; PMe_2Ph,\;PEt_3,\;PMePh_2$, 1/2DPPE, 1/2DPPB) (2a${\sim}$2f)를 합성하였다. 이 유도체들은 에탄올 용매 중에서 $NaBH_4$와 반응하여 상응하는 황색의 착수소화물 $({\eta}^5-C_5Me_5)Ru(PR_3)_2Hl(PR_3=PMe_3,\;PEt_3,\;PMePh_2$, 1/2 DPPE, 1/2DPPB) (3a${\sim}$3e)을 생성한다. 착염화물 (2a${\sim}$2f)와 착수소화물 (3a∼3e)는 모두 결정으로 얻어졌으며, IR, $^1H-NMR$ 그리고 원소분석으로 동정되었다.

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이기종의 모바일 IP 네트워크에서 끊김없는 프록시 기반의 핸드오프 기법 (SePH: Seamless Proxy-based Handoff Scheme in IP-based Heterogeneous Mobile Networks)

  • 이승현;신동렬;정종필
    • 정보처리학회논문지C
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    • 제19C권1호
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    • pp.71-82
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    • 2012
  • 향후의 차세대 무선 네트워크(NGWN) 환경에서는 음성을 비롯한 모든 정보들이 ALL-IP 망에서 동작하게 될 것이며, 현재는 이러한 과도기로서 IP 네트워크에서 사용자로 하여금 끊김없는 서비스를 유지하기 위한 망의 중요성 및 이기종 네트워크 간의 핸드오프에 대한 중요성이 커지고 있다. 이에 본 논문에서는 NGWN에서 여러 기법 중 핸드오프 성능을 높일 수 있는 끊김없는 PMIPv6 기반의 프록시 모델을 이용한 SePH를 제안한다. SePH의 특징으로는 핸드오프 과정 중 탐색 과정을 줄임으로서 끊김없는 IP 기반의 이동성을 효율적으로 지원할 수 있다. 제안한 SePH 기법의 성능 평가는 현재 이동성 관리 프로토콜에 비해 처리량, 핸드오프 지연시간, 패킷손실 및 시그널링 오버헤드 등의 이동성 관리 측면에서 QoS 향상을 보여준다.