• 제목/요약/키워드: [O]/[$N_2$] ratio

검색결과 1,313건 처리시간 0.036초

Fouling analysis and biomass distribution on a membrane bioreactor under low ratio COD/N

  • Gasmi, Aicha;Heran, Marc;Hannachi, Ahmed;Grasmick, Alain
    • Membrane and Water Treatment
    • /
    • 제6권4호
    • /
    • pp.263-276
    • /
    • 2015
  • This paper deals with the influence of chemical oxygen demand to nitrogen ratio ((COD/N) ratio) on the performance of an membrane bioreactor. We aim at establishing relations between COD/N ratio, organisms' distribution and sludge properties (specific resistance to filtration (SRF) and membrane fouling). It is also essential to define new criteria to characterize the autotrophic microorganisms, as the measurements of apparent removal rates of ammonium seem irrelevant to characterize their specific activity. Two experiments (A and B) have been carried on a 30 L lab scale membrane bioreactor with low COD/N ratio (2.3 and 1.5). The obtained results clearly indicate the role of the COD/N ratio on the biomass distribution and performance of the membrane bioreactor. New specific criteria for characterising the autotrophic microorganisms activity, is also defined as the ratio of maximum ammonium rate to the specific oxygen uptake rate in the endogenous state for autotrophic bacteria which seem to be constant whatever the operating conditions are. They are about 24.5 to 23.8 $gN-NH_4{^+}/gO_2$, for run A and B, respectively. Moreover, the filterability of the biological suspension appear significantly lower, specific resistance to filtration and membrane fouling rate are less than $10^{14}m^{-2}$ and $0.07\;10^{12}m^{-1}.d^{-1}$ respectively, than in conventional MBR confirming the adv < antage of the membrane bioreactor functioning under low COD/N ratio.

Deposition and Luminescent Characterization of $Y_3Al_5O_{12}$:Ce Thin Film Phosphor

  • Kim, Joo-Won;Han, Sang-Hyuk;Kim, Young-Jin;Chung, Sung-Mook
    • 한국정보디스플레이학회:학술대회논문집
    • /
    • 한국정보디스플레이학회 2004년도 Asia Display / IMID 04
    • /
    • pp.657-659
    • /
    • 2004
  • Trivalent cerium ($Ce^{3+}$) activated yttrium aluminum garnet ($Y_3Al_5O_{12}$, YAG) phosphor thin films were deposited on quartz glass substrates by rf magnetron sputtering. The effects of sputtering parameters and annealing condition on the luminescent properties were investigated. The sputtering parameters were $O_2$/Ar gas ratio, rf power, and deposition time. The films were annealed at 1200 $^{\circ}C$ for 5 hours in $N_2+$vacuum atmosphere. Polycrystalline YAG:Ce thin film phosphor could be obtained with a gas ratio of $O_2$/(Ar+$O_2$)=0.5 after post-annealing. PL spectra excited at 450 nm showed a yellow single band at 550 nm.

  • PDF

Dependences on Heating Conditions and Applicabilities as an Additive for ECIA of Sr1-xBaxFe3+1-ΤFe4+ ΤO3-y Ferrite System

  • Lee, Eun-Seok
    • Bulletin of the Korean Chemical Society
    • /
    • 제25권6호
    • /
    • pp.859-864
    • /
    • 2004
  • The solid solutions of the $Sr_{1-x}Ba_xFeO_{3-y)$ system (x = 0.0, 0.1, 0.2 and 0.3) having a perovskite structure were prepared in air at 1423 K and then heat-treated in air (A), $O_2(O)\;and\;N_2(N)$ to examine possibility of controlling the nonstoichiometry and applicability as an additive for electrical conducting inorganic adhesives (ECIA). In the samples heated in $N_2$ stream, there existed almost no $Fe^{4+}$ ions, and at constant temperature their electrical conductivities were considerably lower than those of the samples heat-treated in air or $O_2.\; Sr_{0.8}Ba_{0.2}Fe^{3+}_{0.49}Fe^{4+}_{0.51}O_{2.76}$ (SB2-A) whose $Fe^{3+}/Fe^{4+}$ ratio was nearly 1 (0.96) and whose conductivity values (1.04 $ohm^{-1}cm^{-1}$ at 283 K and 1.88 $ohm^{-1}cm^{-1}$ at 673 K) were higher than any other samples, was found to be the best additive for ECIA.

알콕사이드로부터 AlN분말의 합성 및 분말 특성 (Preparation of Aluminum Nitride from an Alkoxide and its Properties)

  • 이홍림;박세민;조덕호
    • 한국세라믹학회지
    • /
    • 제26권1호
    • /
    • pp.100-108
    • /
    • 1989
  • Aluminum hydroxides were prepared by the alkoxide hydrolysis method using Al-isopropoxide as a starting material and NH4OH as a catalytic agent. When Al-isopropoxide was hydrolyzed in a H2O-NH3 system, only Al(OH)3 was obtained over all pH values. However, AlOOH was formed besides Al(OH)3 when Al-isopropoxide was hydrolyzed in a H2O-NH3-isopropyl alcohol system. The AlOOH/Al(OH)3 ratio was increased as the isopropyl alcohol content was increased. The hydroxides, Al(OH)3 and AlOOH, obtained in this study and the commerical products, $\alpha$-Al2O3 and AlOOH were subjected to the carbothermal reduction and nitridation reaction to product AlN powder, using carbon black as a reducing agent under N2 atmosphere at various temperatures. AlN was synthesized from the obtained Al(OH)3 and the commercial AlOOH at 145$0^{\circ}C$, however, synthesized from the obtained AlOOH and the commercial alpha-alumina at 135$0^{\circ}C$. The temperature difference is assumed to be attributed to the reactivity of those powders. AlN powder prepared from the Al-isopropoxide was observed to have the narrower particle size distribution than that prepared from the commercial $\alpha$-Al2O3 or AlOOH.

  • PDF

Canonical Correlation of 3D Visual Fatigue between Subjective and Physiological Measures

  • Won, Myeung Ju;Park, Sang In;Whang, Mincheol
    • 대한인간공학회지
    • /
    • 제31권6호
    • /
    • pp.785-791
    • /
    • 2012
  • Objective: The aim of this study was to investigate the correlation between 3D visual fatigue and physiological measures by canonical correlation analysis enabling to categorical correlation. Background: Few studies have been conducted to investigate the physiological mechanism underlying the visual fatigue caused by processing 3D information which may make the cognitive mechanism overloaded. However, even the previous studies lack validation in terms of the correlation between physiological variables and the visual fatigue. Method: 9 Female and 6 male subjects with a mean age of $22.53{\pm}2.55$ voluntarily participated in this experiment. All participants were asked to report how they felt about their health sate at after viewing 3D. In addition, Low & Hybrid measurement test(Event Related Potential, Steady-state Visual Evoked Potential) and for evaluating cognitive fatigue before and after viewing 3D were performed. The physiological signal were measured with subjective fatigue evaluation before and after in watching the 3D content. For this study suggesting categorical correlation, all measures were categorized into three sets such as included Visual Fatigue set(response time, subjective evaluation), Autonomic Nervous System set(PPG frequency, PPG amplitude, HF/LF ratio), Central Nervous System set(ERP amplitude P4, O1, O2, ERP latency P4, O1, O2, SSVEP S/N ratio P4, O1, O2). Then the correlation of three variables sets, canonical correlation analysis was conducted. Results: The results showed a significant correlation between visual fatigue and physiological measures. However, different variables of visual fatigue were highly correlated to respective HF/LF ratio and to ERP latency(O2). Conclusion: Response time was highly correlated to ERP latency(O2) while the subjective evaluation was to HF/LF ratio. Application: This study may provide the most significant variables for the quantitative evaluation of visual fatigue using HF/LF ratio and ERP latency based human performance and subjective fatigue.

봄철 건조기 용기형 벽면녹화에서 식재지반 조성에 따른 황금줄사철의 적응성 (Growth Response on the Euonymus fortunei 'Emelad' n 'Gold' as affected by Artificial Plantings Soil Properties during Dry Spring Season)

  • 주진희;김혜란;박헌;윤용한
    • 한국환경과학회지
    • /
    • 제23권7호
    • /
    • pp.1299-1305
    • /
    • 2014
  • For evaluating the effect of various artificial planting soil properties on the Euonymus fortunei 'Emelad'n Gold' growth, a container green wall system experiment was conducted in a wall of greenhouse at Konkuk University, Glocal campus. The experimental artificial planting grounds were prepared with different organic soil conditioner ratios (Control, $A_4O_1$, $A_2O_1$ and $A_1O_1$) and with drought tolerance and an ornamental value Euonymus fortunei 'Emelad'n Gold' was planted. The soil and plant characteristics were investigated from April to Jun 2010. The volumetric soil moisture contents were significantly increasing order as the amount of organic soil conditioner level increased in order to $A_1O_1$ > $A_2O_1$ > $A_4O_1$ > Control. At 4 treatment, soil chemical properties were inversely related to organic soil container ratios increase. The differences of root collar caliper, number of branch, and survival rate between the organic soil conditioner ratio were not significantly affected by organic soil conditioner. But, plant height, internode length, leaf length and leaf width were significantly shorter on plants planted $A_1O_1$ than plants planted other treatments. Therefore, Euonymus fortunei 'Emelad'n Gold' had good growth response regardless of organic soil conditioner ratio and the plant is expected to be a highly valuable shrub for the green wall system if it should be considered in integration with stormwater retention or as a soil conditioner for increasing soil water contents in artificial planting soil.

Spinnability and Rheological Properties of Sols Derived from Si(OC2H5)4 and Zr(O-nC3H7)4 Solutions

  • 한상목
    • 산업기술연구
    • /
    • 제20권A호
    • /
    • pp.29-36
    • /
    • 2000
  • The shape of the polymers in the mixed alkoxide solutions of Si(OC2H5)4 and Zr(n-OC3H7)4 with various water contents (1, 2, 4, and 8 in molar ratio to alkoxide, r) and catalysts was examined by rheological measurements, and its relation with fiber drawing behavior of the solutions was described. It was found that fibers could be drawn in the viscosity range 1~100 P from the acid-catalyzed solutions with lower water contents of the molar ratio H2O/alkoxide, $r{\leq}2$. On the other hand, no fiber could be drawn from the acid-catalyzed solutions including a large amount of water($r{\geq}4$) and the base-catalyzed solutions. The relation between the intrinsic viscosity [${\eta}$] and number average molecular weight ${\bar{M}}n$, namely $[{\eta}]=K{\bar{M}}n{\alpha}$, has shown that the acid-catalyzed spinnable solution (r = 1 and 2) had linear polymers where the exponent a's were about 0.56 and 0.81, whereas non-spinnable solutions (r = 4 and 8) had three dimensional network polymers or spherical particles where the exponent a's were 0.41-0.51 and 0.35.

  • PDF

Y2O3-AlN 세라믹스의 생성상 및 물성에 미치는 WO3 및 Ga2O3의 첨가효과 (Effect of WO3 or Ga2O3 Addition on the Phase Evolution and Properties of Y2O3-Doped AlN Ceramics)

  • 신현호;윤상옥;김신;황인준
    • 한국세라믹학회지
    • /
    • 제50권3호
    • /
    • pp.206-211
    • /
    • 2013
  • The effect of a $WO_3$ or $Ga_2O_3$ addition on the densification, phase evolution, optical reflectance, and elastic and dielectric properties of $Y_2O_3$-doped AlN ceramics sintered at $1800^{\circ}C$ for 3 h is investigated. The investigated compositions of the additives are 4.5 wt% $Y_2O_3$ (YA), 3.5 wt% $Y_2O_3$-1.0 wt% $Ga_2O_3$ (YGA), and 3.5 wt% $Y_2O_3$-1.0 wt% $WO_3$ (YWA). $YAlO_3$ and $Y_4Al_2O_9$ form as the secondary phases in all of the investigated compositions, whereas $W_2B$ appears additionally in the YWA. In the YGA, Ga is detected in the AlN grains, indicating that the dissolution of $Ga_2O_3$ into the AlN lattice occurs. The addition of $WO_3$ blackens the specimen more significantly than that of $Ga_2O_3$ does. In all of the investigated specimens, the linear shrinkage and the apparent density are above 20 percent and in the range of 3.34-3.37 $g/cm^3$, respectively. The elastic modulus, Poisson's ratio, the dielectric constant, and the dielectric loss are in the ranges of 335-368 GPa, 0.146-0.237, 8.60-8.63, $2.65-3.95{\times}10^{-3}$, respectively. The sinterability and the properties of $Y_2O_3$-doped AlN ceramics are not much altered by the addition of $WO_3$ or $Ga_2O_3$.

에어로졸 데포지션으로 제조된 4H-SiC 위 Al2O3 게이트 산화막의 후열처리 공정에 따른 전기적 특성 (Electrical Properties of Al2O3 Gate Oxide on 4H-SiC with Post Annealing Fabricated by Aerosol Deposition)

  • 김홍기;김성준;강민재;조명연;오종민;구상모;이남석;신훈규
    • 전기전자학회논문지
    • /
    • 제22권4호
    • /
    • pp.1230-1233
    • /
    • 2018
  • 에어로졸 데포지션 (aerosol deposition)공정을 통해 $Al_2O_3$막을 4H-SiC 상에 50 nm 두께로 제조하였고, 후열처리 공정에 따른 전기적 특성을 분석하였다. 그 결과 $N_2$분위기 열처리 시 $Al_2O_3$와 SiC 계면의 고정전하량이 감소하였으나 산소공공 생성에 의한 누설전류의 증가를 확인하였다. 본 결과로부터 계면특성 향상과 누설전류의 감소를 위해서는 적절한 $N_2$$O_2$가스의 혼합이 중요함을 확인하였다.

저온연소조건에서 급속압축기를 이용한 n-heptane/n-butanol 혼합연료의 착화지연에 관한 연구 (The investigation on the Ignition Delay of n-heptane/n-butanol Blend Fuel using a Rapid Compression Machine at Low Temperature Combustion Regime)

  • 송재혁;강기중;;;최경민;김덕줄
    • 한국연소학회:학술대회논문집
    • /
    • 한국연소학회 2013년도 제46회 KOSCO SYMPOSIUM 초록집
    • /
    • pp.25-28
    • /
    • 2013
  • This study presents both experimental and numerical investigation of ignition characteristics of n-heptane and n-butanol mixture. The $O_2$ concentration was fixed to 9-10% to make high exhaust gas recirculation(EGR) rate condition. Experiments were performed using a rapid compression machine. In addition, a numerical study of the ignition delay time was performed using CHEMKIN codes to validate experimental results and predict chemical species after combustion process. The results showed that the ignition delay time increased with increasing n-butanol ratio and the reactivity decreased by low $O_2$ concentration.

  • PDF