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Chemical Poisoning of Ni/MgO Catalyst by Alkali Carbonate Vapor in the Steam Reforming Reaction of DIR-MCFC

  • 문형대;임태훈;이호인
    • Bulletin of the Korean Chemical Society
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    • v.20 no.12
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    • pp.1413-1417
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    • 1999
  • Chemical poisoning of Ni/MgO catalyst was induced by hot alkali carbonate vapor in molten carbonate fuel cell (MCFC), and the poisoned (or contaminated) catalyst was characterized by TPR/TPO, FTIR, and XRD analysis. Carbonate electrolytes such as K and Li were transferred to the catalyst during DIR-MCFC operation at 650 ℃. The deposition of alkali species on the catalyst consequently led to physical blocking on catalytic active sites and structural deformation by chemical poisoning. TPR/TPO analysis indicated that K species enhanced the reducibility of NiO thin film over Ni as co-catalyst, and Li species lessened the reducibility of metallic Ni by chemical reaction with MgO. FTIR analysis of the poisoned catalyst did not exhibit the characteristic ${\vector}_1$$(D_{3h})$ peaks (1055 $cm^{-1},\;1085\;cm{-1})$ for pure crystalline carbonates, instead a new peak (1120 $cm^{-1})$ was observed proportionally with deformed alkali carbonates. From XRD analysis, the oxidation of metallic Ni into $Ni_xMg_{1-x}O$ was confirmed by the peak shift of MgO with shrinking of Ni particles. Conclusively, hot alkali species induced both chemical poisoning and physical deposition on Ni/MgO catalyst in DIR-MCFC at 650 ℃.

A Study on the Disk Vibration Control by Disk Damper For 100kTPI Hard Disk Drive Design (100KTPI급 HDD 구현을 위한 DISK DAMPER에 관한 연구)

  • Han, Y.S.;Kang, S.W.;Oh, D.H.;Hwang, T.Y.;Tran, Greg
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2002.11b
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    • pp.363-368
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    • 2002
  • A practical implementation method of squeeze-film aeroelastic disk vibration damping and its practical design performance are presented to provide a solution method to meet the tight TMR(Track Mis-Registration) design budget of high-TPI HDDs. Most previous research results are mainly based on the component-level study in the 'open-cover state' which is far from the realistic operation HDD condition. In this study, the squeeze-film disk damping effect is widely investigated under the realistic drive-level condition of 'enclosed-cover state.' It is found that the proper aeroelastic gap(s) between disk(s) and adjacent surface(s) to give significant vibration reduction in the enclosed HDD operating conditions can be achieved not only by classical well-known squeeze-film damping gaps such as very small 0.0x-millimeter level gaps which are not practically implementable in mass-production HDDs, but also by a few 0.x millimeter which is possible for designing realistic HDD design. The various experimental results including drive-level PES are also presented to prove feasibility of the optimal disk damper design for 93kTPI HDDs.

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The effect of thickness and operation temperature on Ga doped ZnO thin film NOx gas sensor

  • Hwang, Hyeon-Seok;Yeo, Dong-Hun;Kim, Jong-Hui;Song, Jun-Tae;Kim, Jeong-Ho
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.06a
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    • pp.365-365
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    • 2008
  • In this work, Ga-doped ZnO (GZO) thin films for NOx gas sensor application were deposited on low temperature co-fired ceramics (LTCC) substrates, by RF magnetron sputtering method. The LTCC substrate is one of promising materials for this application since it has many advantages (e.g., low cost production, high manufacturing yields and easy realizing 3D structure etc.). The LTCC substrates with thickness of 400 pm were fabricated by laminating 12 green tapes which consist of alumina and glass particle in an organic binder. The structural properties of the fabricated GZO thin films with different thickness are analyzed by X-ray diffraction method (XRD) and field emission scanning electron microscope (FESEM). The GZO gas sensors are tested by gas measurement system under varing operation temperature and show good performance to the NOx gas in sensitivity and response time.

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A Study on the Efficiency of a Load Sensing Main Control Valve Using SimulationX (SimulationX를 이용한 부하 감지형 메인 컨트롤밸브의 효율에 관한 연구)

  • Kim, Dong Myoung;Lee, Jung Min;Jung, Won Jee;Jang, Joo Sup
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.40 no.1
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    • pp.87-95
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    • 2016
  • In this study, we develop a model of an open center and load-sensing system and for a main control valve to analyze system characteristics and efficiency using SimulationX. In order to analyze the operating characteristics of the pressure and flow of the main control valve of an open center system, a test was performed at each port. The reliability of the model was confirmed by comparing the similarity of the analysis results with the test results before analyzing the operating characteristics of the system. Development of the load sensing main control valve was performed by adding a flow sharing valve and a notched shape to the open center system based on it's the proven reliability. The authors performed the simulation under the same load conditions in order to compare the efficiency of the systems. Additionally, the combined operation performance was investigated by means of analyzing the characteristics of flow distribution under different load conditions.

Design and Implementation on Frequency Synthesizer Qualification Model Level for SAR payload (위성 레이다용 QM급 주파수합성기 설계 및 제작)

  • Kim, Dongsik;Kim, Hyunchul;Heo, John;Kim, Wansik
    • The Journal of the Institute of Internet, Broadcasting and Communication
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    • v.20 no.3
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    • pp.9-14
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    • 2020
  • In this paper, Qualification Model of frequency synthesizer is designed for X-band SAR system and performed electrical and environment test. Designed frequency synthesizer generate 13.65 GHz with very low phase noise performance. The integrated phase noise from 10Hz to 1MHz is -37.91 dBc. IRF performances are analyzed according to phase noise and jitter. Also, thermal and structure analysis are achieved for stable operation in space environment. Designed frequency synthesizer is consist of 2 modules of 6U size and generate L-band, C-band, Ku-band. The result of this study would enhance the design ability of RF module and help the frequency synthesizer design for SAR payload system.

Design of Square Root and Inverse Square Root Arithmetic Units for Mobile 3D Graphic Processing (모바일 3차원 그래픽 연산을 위한 제곱근 및 역제곱근 연산기 구조 및 설계)

  • Lee, Chan-Ho
    • Journal of the Institute of Electronics Engineers of Korea SD
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    • v.46 no.3
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    • pp.20-25
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    • 2009
  • We propose hardware architecture of floating-point square root and inverse square root arithmetic units using lookup tables. They are used for lighting engines and shader processor for 3D graphic processing. The architecture is based on Taylor series expansion and consists of lookup tables and correction units so that the size of look-up tables are reduced. It can be applied to 32 bit floating point formats of IEEE-754 and reduced 24 bit floating point formats. The square root and inverse square root arithmetic units for 32 bit and 24 bit floating format number are designed as the proposed architecture. They can operation in a single cycle, and satisfy the precision of $10^{-5}$ required by OpenGL 1.x ES. They are designed using Verilog-HDL and the RTL codes are verified using an FPGA.

An Integrated Mach-Zehnder Interferometric Sensor based on Rib Waveguides (Rib 도파로 기반 집적 마흐젠더 간섭계 센서)

  • Choo, Sung-Joong;Park, Jung-Ho;Shin, Hyun-Joon
    • Journal of the Institute of Electronics Engineers of Korea SD
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    • v.47 no.4
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    • pp.20-25
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    • 2010
  • An integrated Mach-Zehnder interferometric sensor operating at 632.8 nm was designed and fabricated by the technology of planar rib waveguides. Rib waveguide based on silica system ($SiO_2-SiO_xN_y-SiO_2$) was geometrically designed to have single mode operation and high sensitivity. It was structured by semiconductor fabrication processes such as thin film deposition, photolithography, and RIE (Reactive Ion Etching). With the power observation, propagation loss measurement by cut-back method showed about 4.82 dB/cm for rib waveguides. Additionally the chromium mask process for an etch stop was employed to solve the core damaging problem in patterning the sensing zone on the chip. Refractive index measurement of water/ethanol mixture with this device finally showed a sensitivity of about $\pi$/($4.04{\times}10^{-3}$).

Establishment of Waste Collection and Transportation System for Composting I. Estimation of Unit Garbage Generation (퇴비화촉진을 위한 쓰레기 수거체계의 확립 I. 음식물찌꺼기 원단위 발생량의 산정)

  • Shin, H.S.;Hwang, E.J.;Kang, H.;Lee, S.J.;Jang, W.
    • Journal of the Korea Organic Resources Recycling Association
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    • v.3 no.2
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    • pp.25-36
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    • 1995
  • It is important to separate the compostables from waste for successful operation of composting plant, since various compositions are mixed in it. For the separation of compostables, it is necessary to estimate total amounts of compostables from several sources. Based on it, required capacity and number of composting plant as well as proper waste collection and transportation system can be determined. So, amounts of garbage, major target material for composting. were estimated in this study. In survey of unit garbage generation(UGG). different estimation results would be obtained depending on the basis of its measurement. However, previous researches did not consider it. In this paper, the correlations between area and the number of user of garbage source were analyzed to find the related equations which were apllyed to estimation of total generation. Obtained results are as the following. Relative variations of measured UGG based on area and custumer are 62.5 and 52.8, respectively. In linear regression, related equation between area and custumer was Y=0.244X+59.0 (X=area, Y=custumer). The correlation factor r is 0.904. Equation Y=616.5X/(X+1215.4) was also obtained from linear regression using Monod equation (r=0.720). From the first order equation and measured data of UGG based on custumer, amounts of garbage generation from restaurant in Seoul and the whole country were calculated to 2043.9 ton/d and 9014.0 ton/d, respectively. But, the values calculated from measured data of UGG based on area were as low as 821.3 ton/d Cin Seoul) and 3821.0 ton/d(in the whole country). Consequently, the measurement of unit garbage generation based on the number of custumer was more favorable to lessen the points of survey and to guarantee the representative values. Especially, it would fit well on restaurant having statistics of area.

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An Experience of Management of Homeless Neurosurgical Patients

  • Kim, Dae-Ki;Jwa, Cheol-Su;Kim, Gang-Hyeon;Kang, Jae-Kyu
    • Journal of Korean Neurosurgical Society
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    • v.42 no.3
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    • pp.191-194
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    • 2007
  • Objective : Homeless patients probably have epidemiologic features that are different from those of general population. However, there have been no published articles about clinical characteristics of neurosurgical homeless patients. The authors tried to assess the clinical characteristics and treatment outcome of homeless neurosurgical patients. Methods : We retrospectively reviewed the medical records and radiological films of 76 homeless patients and 72 non-homeless patients following head trauma who were admitted to our neurosurgical department between June 2001 and June 2005. We compared two groups of the patients with the demographics, the clinical and laboratory characteristics. Also, 3D-day mortality was determined according to Glasgow Coma Scale (GCS) score. Results : Age of homeless patients was younger than that of non-homeless patients. Homeless patients had previous craniotomy evidences in skull x-rays more frequently (10.5% vs. 1.4%). Acute subdural hematoma was the most common type of head injury in the two groups. Moderate and severe head injury, based on GCS score on admission was more frequent in homeless patients (64% vs. 39%). Fifty percent of homeless patients underwent operation for traumatic head injury. However, 3D-day mortality according to GCS score was not significantly higher in homeless patients. Conclusion : Most homeless neurological patients were relatively young men. Also, moderate or severe brain injuries were observed more frequently. However, mortality rate of homeless patients in neurosurgical field is not significantly higher in the present study.

An Experimental Study on Droplet Size Characteristics of Liquid Jets in Subsonic Crossflow (아음속 수직분사제트에서 액적크기 특성에 대한 실험적 연구)

  • Kim, Min-Ki;Song, Jin-Kwan;Kim, Jin-Ki;Hwang, Yong-Seok;Yoon, Young-Bin
    • Journal of ILASS-Korea
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    • v.12 no.2
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    • pp.115-122
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    • 2007
  • The spray characteristics and drop size measurements have been experimentally studied in liquid jets injected into subsonic crossflow. With water as fuel injection velocity, injection angle and atomize. internal flows were varied to provide of jet operation conditions. The injector internal flow was classified as three modes such as a non-cavitation flow, cavitation, and hydraulic flip flows. Pulsed Shadowgraph Photography measurement was used to determine the spatial distribution of the spray droplet diameter in a subsonic crossflow of air. And this study also obtains the SMD (Sauter Mean Diameters) distribution by using Planar Liquid Laser Induced Fluorescence technique. The objectives of this research are get a droplet distributions and drop size measurements of each condition and compare with the other flow effects. As the result, This research has been showned that droplet size were spatially dependent on air-stream velocity, fuel injection velocity, injection angle effects, and normalized distance from the injector exit length(x/d, y/d). There are also different droplet size characteristics between cavitation, hydraulic flip and the non-cavitation flows.

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