• 제목/요약/키워드: (111) orientation

검색결과 353건 처리시간 0.034초

Application of Inverse Pole Figure to Rietveld Refinement: I. Rietveld Refinement of Copper Sheet using X-ray Diffraction Data

  • Kim, Yong-Il;Jung, Maeug-Joon;Kim, Kwang-Ho
    • The Korean Journal of Ceramics
    • /
    • 제6권3호
    • /
    • pp.236-239
    • /
    • 2000
  • Both the X-ray diffraction data of the normal direction in the sample orientation and the pole figure data of three reflections, (111), (200) and (220), were used to do the Rietveld refinement for the copper sheet prepared by a cold rolling process. The agreement between calculated and observed patterns was not satisfactory, which was attributed to the preferred orientation effect of the copper sheet. The Rietveld refinement for the copper sheet could be done successfully by applying the pole density of each reflection obtained from the corresponding inverse pole figure to the X-ray diffraction data of the normal direction. The R-weighted pattern, $R_{wp}$ was 12.99% and the goodness-of-fit indicator, S, was 3.68.

  • PDF

라우에 배면반사법을 이용한 PMN-PT 단결정 성장 방향 분석 (An Analysis of the Growing Orientation of PMN-PT Single Crystal Using the Laue Back-Reflection Method)

  • 조치영;서희선;권병진;이원옥;이상구;김민찬
    • 한국전기전자재료학회논문지
    • /
    • 제28권12호
    • /
    • pp.787-791
    • /
    • 2015
  • In this paper, the growing orientation of PMN-PT single crystal is analyzed using the Laue-Back Reflection Method. Two kinds of PMN-PT single crystals are grown using the Bridgman growing method in the [001] and [111] directions and their the Laue photographs are simulated assuming cubic crystal systems. From the comparison between simulation and test results, it can be concluded that the single crystals are grown in the desired crystal orientations.

UHV-ICB 방법으로 Si(111) 기판위에 성장된 $Y_2O_3$ 박막의 구조적 특성에 관한 연구 (Structural Characteristics of $Y_2O_3$ Films Grown on Differently Surface-treated Si(111) by Ultrahigh Vacuum Ionized Cluster Beam)

  • 이동훈;성태연;조만호;황정남
    • 한국재료학회지
    • /
    • 제9권5호
    • /
    • pp.528-532
    • /
    • 1999
  • Y$_2$O$_3$films were grown on SiO$_2$-covered Si(111), and hydrogen-terminated Si(111), and hydrogen-terminated Si(111) substrates at 50$0^{\circ}C$ by ultrahigh vacuum ionized cluster beam deposition (UHV-ICB). The microstructures and growth behavior of these films have been investigated by transmission electron diffraction (TED) and high-resolution transmission electron microscopy(HREM). The TED results show that the $Y_2$O$_3$grown on the SiO$_2$-Si has the epitaxial relationship of (11-1)Y$_2$O$_3$∥(111)Si and [-110]Y$_2$O$_3$∥[-110]Si. The film on the H-Si substrate contains YS\ulcorner and amorphous YSi\ulcornerO\ulcorner layers at the interface, having the orientation relationship each other. For the YSi\ulcorner and the Si substrate, the relationship is (0001)YSi\ulcorner∥(111)Si and [1-210]YSi\ulcorner∥∥[-110]Si. For the $Y_2$O$_3$and the YSi\ulcorner ; the relationship is as follows: (11-1)Y$_2$O$_3$∥(0001)YSi\ulcorner and [-110]Y$_2$O$_3$∥[1-210]YSi\ulcorner(111)Y$_2$O$_3$∥(0001)YSi\ulcorner and [-110]Y$_2$O$_3$∥[1-210]YSi\ulcorner. Explanation is given to describe the formation mechanisms of the interfacial phases of SiO\ulcorner, YSi\ulcornerO\ulcorner and YSi\ulcorner. It is shown that the crystallinity of the $Y_2$O$_3$film on the SiO$_2$-Si(111) is better than that of $Y_2$O$_3$on H-Si(111).

  • PDF

Electronic structure and magnetism of catalytic material Pt3Ni surfaces: Density-functional study

  • Sharma, Bharat Kumar;Kwon, Oryong;Odkhuu, Dorj;Hong, Soon Cheol
    • 한국자기학회:학술대회 개요집
    • /
    • 한국자기학회 2012년도 자성 및 자성재료 국제학술대회
    • /
    • pp.172-172
    • /
    • 2012
  • A Pt-skin $Pt_3Ni$(111) surface was reported to show high catalytic activity. In this study, we investigated the magnetic properties and electronic structures of the various oriented surfaces of bulk-terminated and Pt-segregated $Pt_3Ni$ by using a first-principles calculation method. The magnetic moments of Pt and Ni are appreciably enhanced at the bulk-terminated surfaces compared to the corresponding bulk values, whereas the magnetic moment of Pt on the Pt-segregated $Pt_3Ni$(111) surface is just slightly enhanced because of the reduced number of Ni neighboring atoms. Spin-decomposed density of states shows that the dz2 orbital plays a dominant role in determining the magnetic moments of Pt atoms in the different orientations. The lowering of the d-band center energy (-2.22 eV to -2.46 eV to -2.51 eV to -2.65 eV) in the sequence of bulk-terminated (100), (110), (111), and Pt-segregated (111) may explain the observed dependence of catalytic activity on surface orientation. Our d-band center calculation suggests that an observed enhanced catalytic activity of a $Pt_3Ni$(111) surface originates from the Pt-segregation.

  • PDF

홈파기를 이용한 새로운 실리콘 직접접합 기술 (A Novel Silicon Direct Bonding Technology using Groove Matrix)

  • 김은동;김남균;김상철;박종문;이승환
    • 한국전기전자재료학회:학술대회논문집
    • /
    • 한국전기전자재료학회 1995년도 추계학술대회 논문집
    • /
    • pp.81-84
    • /
    • 1995
  • A reliable bonding between two silicon wafers, regularly grooved and non-grooved, was done by the direct boning technology, It is Presented that high structural duality was realized not only at the bended interface but in the bulk, commensurate with the filling of artificial grooves, which would be attributed to the dislocation-gettering capability of groove free-surfaces during annealing. The groove filling would be explained with mass-transport phenomena assisted by the dislocation movement from initial contact boundaries toward groove surfaces. Intrinsic voids can be easily removed by aid of the grooves. The proposed method yielded also an intimate bonding not only between {111} wafers strongly misoriented and slightly inclined to {111} basal plane but even between {111} and {100} orientation wafers.

  • PDF

냉간압연된 인코넬 690에서 미세조직과 집합조직의 발달 (Development of Microstructure and Texture in Cold Rolled INCONEL690)

  • 안재평;표은종;허무영
    • 소성∙가공
    • /
    • 제3권4호
    • /
    • pp.392-400
    • /
    • 1994
  • The formation of preferred orientations in the cold rolling texture of the Inconel 690 sheets was studied by the x-ray texture measurements and TEM observations. The increasing {220} pole intensity in the plane normal at the higher reductions was related to the {110}<112> texture component. The rolling texture of the Inconel 690 was the pure metal type which could be described by {112}<111>, {123}<634> and {110}<112> orientations. The dislocation cells were found in the near {110}<112> oriented grains. The onset of deformation twins in the {112}<111> oriented grains caused the weakening of {112}<111> and the development of {552}<115> in the rolling texture.

  • PDF

Highly (111)-oriented SiC Films on Glassy Carbon Prepared by Laser Chemical Vapor Deposition

  • Li, Ying;Katsui, Hirokazu;Goto, Takashi
    • 한국세라믹학회지
    • /
    • 제53권6호
    • /
    • pp.647-651
    • /
    • 2016
  • SiC films were prepared on glassy carbon substrates by laser chemical vapor deposition under a high pressure of $10^4Pa$ using a diode laser (wavelength = 808 nm) and a polysilaethylene precursor. (111)-oriented SiC films were formed at a deposition temperature ($T_{dep}$) range of 1150 - 1422 K. At $T_{dep}=1262K$, the SiC film with a high Lotgering factor of above 0.96 showed an exhibited pyramid-like surface morphology and flower-like grains. The highest deposition rate ($R_{dep}$) was $220{\mu}m\;h^{-1}$ at $T_{dep}=1262K$.

X-ray Microdiffraction 을 이용한 구리 Interconnect의 Texture 분석 (Texture Analysis of Cu Interconnects Using X-ray Microdiffraction)

  • 정진석
    • 한국결정학회지
    • /
    • 제12권4호
    • /
    • pp.233-238
    • /
    • 2001
  • 1㎛ 이하로 집속된 방사광원으로부터의 x-선을 이용하여 새로운 분석법인 x-선 미세회절(x-ray microdiffraction)을 사용하면 다결정시료 내 grain들의 방위나 strain의 국지적 분포를 정밀하게 측정할 수 있다. 포항가속기연구소 방사광원의 x-ray microbeam 실험 장치를 사용하여 찍은 Laue 사진을 측별히 쓰여진 분석 software를 이용하여 분석함으로써 고집적회로에 쓰이는것과 같은 방법으로 제작된 Si wafer 상의 다른 선폭의 구리 도선들이 가지는 texture 를 밝혀내었다. 실험시 x-ray빔의 크기는 2×3㎛²정도이었으며, 분석 결과에의하면 선폭 1㎛도선에서는 grain들이 방위가 특정한 방향성이 없는 반면, 선폭 20㎛도선의 중앙부분에서는 〈111〉fiber texture 가 관측되었다. Grain들의 크기는 선폭 1㎛의도선에서 2∼5㎛, 선폭 20㎛의도선에서는 6∼8㎛로 측정되었다.

  • PDF

레이저 어블레이션에 의한 $(Pb,La)TiO_3$ 박막의 제작 (Fabrication of $(Pb,La)TiO_3$ Thin Films by Pulsed Laser Ablation)

  • 박정흠;김준한;이상렬;박종우;박창엽
    • 한국전기전자재료학회논문지
    • /
    • 제11권2호
    • /
    • pp.133-137
    • /
    • 1998
  • $(Pb_{0.72}La_{0.28})Ti_{0.93}O_3(PLT(28))$ thin films were fabricated by pulsed laser deposition. PLT films deposited on $Pt/Ti/SiO_2/Si$ at $600^{\circ}C$ had a preferred orientation in (111) plane and at $550^{\circ}C$ had a (100) preferred orientation. We found that (111) preferred oriented films had well grown normal to substrate surface. This PLT(28) thin films of $1{\mu}m$ thickness had dielectric properties of ${\varepsilon}_r$=1300, dielectric $loss{\fallingdotseq}0.03 $. and had charge storage density of 10 [${\mu}C/cm^2$] and leakage current density of less than $10^{-6}[A/cm^2]$ at 100[kV/cm]. These results indicated that the PLT(28) thin films fabricated by pulsed laser deposition are suitable for DRAM capacitor application.

  • PDF