• Title/Summary/Keyword: (110) silicon

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Availability of Silicate Fertilizer and its Effect on Soil pH in Upland Soils (밭토양에 처리된 규산질 비료의 유효화와 토양반응 교정효과)

  • Cho, Hyun-Jong;Choi, Hee-Youl;Lee, Yong-Woo;Lee, Yoon-Jung;Chung, Jong-Bae
    • Korean Journal of Environmental Agriculture
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    • v.23 no.2
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    • pp.104-110
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    • 2004
  • Although silicon (Si) has been Down to be an essential element fer rice growth, the optimum soil level of Si for upland crops remains unestablished. This study was conducted to estimate the availability of Si fertilizer in upland soils, and also effect of the Si fertilizer on soil pH was examined. Different application rates of Si fertilizer were tested using faur soils of different available Si levels and pHs in a series of laboratory incubation study. The treatments included Si fertilizer levels of 100, 200, and 300 kg/10a. Also to examine the effects of compost and lime on the availability of Si fertilizer in upland soil, treatment of silicate fertilizer 200 kg/10a + compost 1,000 kg/10a and lime alone treatment were included. Changes of Si availability in the soils during the incubation period were measured by 1 N NaOAc extraction procedure. Availability of Si fertilizer was different among the tested soils, and about $9.1{\sim}19.2%$ of the applied Si fertilizer was extracted after 60 days laboratory incubation. Application rate could not influence the availability of Si fertilizer. Application of compost with Si fertilizer could not increase Si availability in upland soils, but lime treatment could increase Si availability. Soil pH increased by application of Si fertilizer, but the effect of Si fertilizer on soil pH was minimal. When Si fertilizer is applied on the purpose of Si nutrition in acid upland soils, lime treatment should be coupled with the Si fertilizer for remediation of soil acidity.

Fabrication of Nanopatterned Oxide Layer on GaAs Substrate by using Block Copolymer and Reactive Ion Etching (블록 공중합체와 반응성 이온식각을 이용한 GaAs 기판상의 나노패터닝된 산화막 형성)

  • Kang, Gil-Bum;Kwon, Soon-Mook;Kim, Seoung-Il;Kim, Yong-Tae;Park, Jung-Ho
    • Journal of the Microelectronics and Packaging Society
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    • v.16 no.4
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    • pp.29-32
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    • 2009
  • Dense and periodic arrays of nano-sized holes were patterned in oxide thin film on GaAs substrate. To obtain the nano-size patterns, self-assembling diblock copolymer was used to produce thin film of uniformly distributed parallel cylinders of polymethylmethacrylate (PMMA) in polystyrene (PS) matrix. The PMMA cylinders were removed with UV expose and acetic acid rinse to produce PS nanotemplate. By reactive ion etching, pattern of the PS template was transferred to under laid silicon oxide layer. Transferred patterns were reached to the GaAs substrate by controlling the dry etching time. We confirmed the achievement of etching through the removing oxide layer and observation of GaAs substrate surface. Optimized etching time was 90 to 100 sec. Pore sizes of the nanopattern in the silicon oxide layer were 20~22 nm.

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High Efficiency Solar Cell(I)-Fabrication and Characteristics of $N^+PP^+$ Cells (고효율 태양전지(I)-$N^+PP^+$ 전지의 제조 및 특성)

  • 강진영;안병태
    • Journal of the Korean Institute of Telematics and Electronics
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    • v.18 no.3
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    • pp.42-51
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    • 1981
  • Boron was predeposited into p (100) Si wafer at 94$0^{\circ}C$ for 60minutes to make the back surface field. High tempreature diffusion process at 1145$^{\circ}C$ for 3 hours was immediately followed without removing boron glass to obtain high surface concentration Back boron was annealed at 110$0^{\circ}C$ for 40minutes after boron glass was removed. N+ layer was formed by predepositing with POCI3 source at 90$0^{\circ}C$ for 7~15 minutes and annealed at 80$0^{\circ}C$ for 60min1es under dry Of ambient. The triple metal layers were made by evaporating Ti, Pd, Ag in that order onto front and back of diffused wafer to form the front grid and back electrode respectively. Silver was electroplated on front and back to increase the metal thickness form 1~2$\mu$m to 3~4$\mu$m and the metal electrodes are alloyed in N2 /H2 ambient at 55$0^{\circ}C$ and followed by silicon nitride antireflection film deposition process. Under artificial illumination of 100mW/$\textrm{cm}^2$ fabricated N+PP+ cells showed typically the open circuit voltage of 0.59V and short circuit current of 103 mA with fill factor of 0.80 from the whole cell area of 3.36$\textrm{cm}^2$. These numbers can be used to get the actual total area(active area) conversion efficiency of 14.4%(16.2%) which has been improved from the provious N+P cell with 11% total area efficiency by adding P+ back.

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BS/channeling studies on the heteroepitaxially grown $Y_2O_3$ films on Si substrates by UHV-ICB deposition (실리콘 기판 위에 UHV-ICB 증착법으로 적층 성장된 $Y_2O_3$박막의 BS/channeling 연구)

  • 김효배;조만호;황보상우;최성창;최원국;오정아;송종한;황정남
    • Journal of the Korean Vacuum Society
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    • v.6 no.3
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    • pp.235-241
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    • 1997
  • The crystallinity and the structure of heteroepitaxially grown $Y_2O_3$ films on the silicon substrates deposited by Ultra High Vacuum Ionized Cluster Beam(UHV-ICB) were investigated by Back-scattering Spectroscopy(BS)/channeling. The channeling minimum values, $X_{min}$, of the $Y_2O_3$ films deposited by other methods were 0.8~0.95 up to the present, which indicates amorphous or highly polycrystalline nature of the $Y_2O_3$ films. On the contrary, the channeling minimum value of heteroepitaxially grown $Y_2O_3$ films on Si(100) and Si(111) deposited by UHV-ICB are 0.28 and 0.25 respectively. These results point out fairly good crystalline quality. It is also observed that the top region of $Y_2O_3$ films have less crystalline defects than the bottom region regardless of the crystal direction of the Si substrates. The axis of $Y_2O_3$<111> epitaxially grown on Si(111) is tilt by $0.1^{\circ}$ with respect to Si<111>. That of $Y_2O_3$<110> on Si(100) is parallel to the Si<001>. The $Y_2O_3$ film on Si(100) grew with single domain structure and that on Si(111) grew with double domain structure. From the result of oxygen resonance BS/channeling, the oxygen atoms in heteroepitaxially grown $Y_2O_3$ film on Si(111) substrate have the crystallinity, but that on Si(100) shows almost channeling amorphous state.

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The Distributions of Nutrients, Chlorophyll-a, and Primary Productivity in the South Pacific Ocean (남태평양의 영양염, 엽록소, 일차생산성 분포)

  • Kim, Dong-Yup;Shim, Jung-Hee;Song, Hwan-Seok;Kang, Young-Chul;Kim, Dong-Seon
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.6 no.1
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    • pp.40-48
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    • 2001
  • The vertical distributions of temperature, salinity, dissolved oxygen, nutrients, chlorophyll, and primary production were investigated within the top 200m water depth in the south Pacific Ocean in February,2000. The study area ($24^{\circ}-41^{\circ}S,\;81^{\circ}-168^{\circ}W$) can be hydrologically divided into two regions. Upwelling was actively occurring in the eastern region of the $110^{\circ}S$ line, meanwhile it was not active in the western region. Accordingly, chemical properties in the surface waters were different between the two regions; nitrate+nitrite and phosphate concentrations were much higher in the eastern region than in the western region due to the active upwelling, but silicate concentration was higher in the western region. Among the nutrients, the major element influencing primary production was also different between the two regions; silicon would be a major element influencing primary production in the eastern region, but nitrogen may act as a major element for primary production in the western region. Primary production showed similar values in the two regions in spite of the large differences of nutrient concentrations in the surface waters, but the total chlorophyll integrated within the 200 m water depth was almost twice as much as in the western region than that in the eastern legion.

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Study on the Annealing Effect and Magnetic Properties of a Zn0.7Mn0.3O Film (열처리 효과에 따른 Zn0.7Mn0.3O박막의 자기 특성 연구)

  • Kim, Y.M.;Kim, Y.;Yoon, M.;Park, C.S.;Lee, Y.S.;Jeon, M.S.;Park, I.W.;Park, Y.J.;Lyou, Jong H.;Kim, S.S.
    • Journal of the Korean Magnetics Society
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    • v.13 no.4
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    • pp.155-159
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    • 2003
  • We report on the annealing effect and ferromagnetic characteristics of Zn$_{0.7}$Mn$_{0.3}$O film prepared by sol-gel method on the silicon (100) substrate using field emission-scanning electron microscopy (FE-SEM), energy dispersive spectroscopy (EDS), X-ray diffractometry (XRD) and superconducting quantum interference device (SQUID) magnetometry. Magnetic measurements show thatZn$_{0.7}$Mn$_{0.3}$O films exhibit ferromagnetism at 5 K revealing the coercive field of ∼110 Oe for as grown sample and 360, 1035 Oe for samples annealed at 700, 800 $^{\circ}C$, respectively. Our experimental evidence suggests that ferromagnetic precipitates of a manganese oxide may be responsible for the observed ferromagnetic behaviors of the film.he film.

In Situ X-ray Photoemission Spectroscopy Study of Atomic Layer Deposition of $TiO_2$ on Silicon Substrate

  • Lee, Seung-Youb;Jeon, Cheol-ho;Kim, Yoo-Seok;Kim, Seok-Hwan;An, Ki-Seok;Park, Chong-Yun
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.08a
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    • pp.222-222
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    • 2011
  • Titanium dioxide (TiO2) has a number of applications in optics and electronics due to its superior properties, such as physical and chemical stability, high refractive index, good transmission in vis and NIR regions, and high dielectric constant. Atomic layer deposition (ALD), also called atomic layer epitaxy, can be regarded as a special modification of the chemical vapor deposition method. ALD is a pulsed method in which the reactant vapors are alternately supplied onto the substrate. During each pulse, the precursors chemisorb or react with the surface groups. When the process conditions are suitably chosen, the film growth proceeds by alternate saturative surface reactions and is thus self-limiting. This makes it possible to cover even complex shaped objects with a uniform film. It is also possible to control the film thickness accurately simply by controlling the number of pulsing cycles repeated. We have investigated the ALD of TiO2 at 100$^{\circ}C$ using precursors titanium tetra-isopropoxide (TTIP) and H2O on -O, -OH terminated Si surface by in situ X-ray photoemission spectroscopy. ALD reactions with TTIP were performed on the H2O-dosed Si substrate at 100$^{\circ}C$, where one cycle was completed. The number of ALD cycles was increased by repeated deposition of H2O and TTIP at 100$^{\circ}C$. After precursor exposure, the samples were transferred under vacuum from the reaction chamber to the UHV chamber at room temperature for in situ XPS analysis. The XPS instrument included a hemispherical analyzer (ALPHA 110) and a monochromatic X-ray source generated by exciting Al K${\alpha}$ radiation (h${\nu}$=1486.6 eV).

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Effect of DC Bias on the Growth of Nanocrystalline Diamond Films by Microwave Plasma CVD (마이크로웨이브 플라즈마 CVD에 의한 나노결정질 다이아몬드 박막 성장 시 DC 바이어스 효과)

  • Kim, In-Sup;Kang, Chan Hyoung
    • Journal of the Korean institute of surface engineering
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    • v.46 no.1
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    • pp.29-35
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    • 2013
  • The effect of DC bias on the growth of nanocrystalline diamond films on silicon substrate by microwave plasma chemical vapor deposition has been studied varying the substrate temperature (400, 500, 600, and $700^{\circ}C$), deposition time (0.5, 1, and 2h), and bias voltage (-50, -100, -150, and -200 V) at the microwave power of 1.2 kW, working pressure of 110 torr, and gas ratio of Ar/1%$CH_4$. In the case of low negative bias voltages (-50 and -100 V), the diamond particles were observed to grow to thin film slower than the case without bias. Applying the moderate DC bias is believed to induce the bombardment of energetic carbon and argon ions on the substrate to result in etching the surfaces of growing diamond particles or film. In the case of higher negative voltages (-150 and -200 V), the growth rate of diamond film increased with the increasing DC bias. Applying the higher DC bias increased the number of nucleation sites, and, subsequently, enhanced the film growth rate. Under the -150 V bias, the height (h) of diamond films exhibited an $h=k{\sqrt{t}}$ relationship with deposition time (t), where the growth rate constant (k) showed an Arrhenius relationship with the activation energy of 7.19 kcal/mol. The rate determining step is believed to be the surface diffusion of activated carbon species, but the more subtle theoretical treatment is required for the more precise interpretation.

A temperature sensor using single phase-vanadium dioxide thin films (single phase-vanadium dioxide 박막을 이용한 온도센서에 관한 연구)

  • Kim, Ji-Hong;Hong, Sung-Min;Kwak, Yeon-Hwa;Park, Soon-Seob;Hwang, Hak-In;Moon, Byung-Moo
    • Proceedings of the KIEE Conference
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    • 2006.10a
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    • pp.109-110
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    • 2006
  • In bio applications, high temperature coefficient of resistance (TCR) at $30^{\circ}C{\sim}40^{\circ}C$ is especially important for a temperature sensor. In this work, single phase-vanadium dioxide ($VO_2$) thin films for temperature sensor were fabricated by reactive DC magnetron sputtering and post-annealing method. VOx thin films deposited by reactive sputtering in a controlled $Ar/O_2$ atmosphere can be transformed into single phase-$VO_2$ films by post-annealing in $N_2$ atmosphere. The grown $VO_2$ thin films have a moderate resistance at room temperature and very high TCR at room temperature and transition temperature, respectively 2.88%/K and 15.8%/K. A detailed structural characterization is performed by SEM, XRD and RBS. SEM morphology image indicates that grains of fabricated $VO_2$films are homogeneous and ball-like in shape. A fact that the films contain only single phase-$VO_2$ is obtained by XRD and RBS analysis. After deposition, the sensors were fabricated by micromachining technology. Silicon nitride membrane and black nickel were used for a thermal isolation structure and absorption layer. In the vicinity of room temperature, the TCR of sensors was enough high to apply for bio sensors.

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Performance-aware Dynamic Thermal Management by Adaptive Vertical Throttling in 3D Network-on-Chip (3D NoC 구조에서 성능을 고려한 어댑티브 수직 스로틀링 기반 동적 열관리 기법)

  • Hwang, Junsun;Han, Tae Hee
    • Journal of the Institute of Electronics and Information Engineers
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    • v.51 no.7
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    • pp.103-110
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    • 2014
  • Recent TSV based 3D Integrated Circuit (IC) technology needs more powerful thermal management techniques. However, because cooling cost and form factor are restricted, thermal management are emphasis on software based techniques. But in case of throttling thermal management which one of the most candidate technique, increasing bus occupation induce total performance decrease. To solve communication bottleneck issue in TSV based 3D SoC, we proposed adaptive throttling technique Experimental results show that the proposed method can improve throughput by about 72% compare with minimal path routing.