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Understanding the Viscoelastic Properties and Surface Characterization of woodflour-Polypropylene Composites (목분-폴리프로필렌 복합재의 점탄성적 성질과 표면특성)

  • Son, Jungil;Gardner, Douglas J.
    • Journal of Adhesion and Interface
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    • v.3 no.4
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    • pp.1-9
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    • 2002
  • The main goal of this study was to analyze the effect of process additives, i.e. maleated polypropylene (MAPP), and nucleating agent on the viscoelastic properties of different types of extruded polypropylene-wood plastic composites manufactured from either PP homopolymer, high crystallinity PP or PP impact copolymer using dynamic mechanical thermal analysis. And also, the esterification reaction between wood flour and maleated polypropylene, and its role in determining the mechanical properties of wood flour-polypropylene composites was investigated. The wood plastic composites were manufactured using 60% pine wood flour and 40% polypropylene on a Davis-Standard $Woodtruder^{TM}$. Dynamic mechanical thermal properties, polymer damping peaks(than ${\delta}$), storage modulus (E') and loss modulus (E") were measured using a dynamic mechanical thermal analyzer. XPS (X-ray Photoelectron Spectroscopy), also known as ESCA (Electron Spectroscopy for Chemical Analysis) study of wood flour treated with MAPP was performed to obtain information on the chemical nature of wood fiber before and after treatment. To analyze the effect of frequency on the dynamic mechanical properties of the various composites, DMA tests were performed over a temperature range of -20 to $100^{\circ}C$, at four different frequencies (1, 5, 10 and 25 Hz), and at a heating rate of $5^{\circ}C/min$. From these results, the activation energy of the various composite was measured using an Arrhenius relationship to investigate the effect of maleated PP and nucleating agent on the measurement of the interphase between the wood and plastic of the extruded polypropylene wood plastic composites.

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Curing Properties of UV-LED Curable Color Coating (UV-LED 경화형 칼라 코팅의 경화특성 연구)

  • Ho, Shin-Chan;Kim, Jong-Gu;Hong, Jin-Who;Ahn, Tae-Jung;Kim, Hyun-Kyoung
    • Journal of Adhesion and Interface
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    • v.13 no.1
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    • pp.31-37
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    • 2012
  • In this study, we investigated the curing properties of UV-LED curable color coating. Specially, the effects of UV-LED wavelength (365, 395, and 405 nm), inert gas, the concentration of photosensitizer, and dual curing on the curing behavior of UV-LED coating systems were studied. The photopolymerization behaviors and the unreacted acrylate groups at Film-air (FA) interface and Film-substrate (FS) interface were investigated by photo differential scanning calorimetry (Photo-DSC) and Fourier-transform infrared spectroscopy with attenuated total reflection (FT-IR/ATR), respectively. Photo-DSC results showed that the heat flow and the ultimate conversion for coating system cured by 405 nm UV-LED were higher than the corresponding values for coating systems cured by 395 and 365 nm UV-LED. FT-IR/ATR results showed that the UV-LED curing systems improved interior and through curing of the coating film, but significantly are affected by oxygen inhibition at FA-interface. The inert environment such as nitrogen purging and the dual curing improved the surface and interior curing of the coating films.

Preparation of Fragrant Microcapsule for Reducing Stress (긴장완화를 위한 향기나는 마이크로캡슐의 제조)

  • Kim, Yoon A;Kim, So Hyun;Park, Ji Su;Lee, Da Som;Kim, Jin Gon;Shin, Jae Sup
    • Journal of Adhesion and Interface
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    • v.13 no.1
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    • pp.17-23
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    • 2012
  • A fragrant microcapsule was prepared for use by students to reduce the stress of taking examinations. Rosmarinic acid was used as a fragrant oil which had the effect of relaxing stress, polycaprolactone (PCL) was used as a capsule wall material, and poly(vinyl alcohol) (PVA) as a stabilizer. The solvent evaporation method was used to form the microcapsule. The microcapsules were prepared by changing the stirring rate, the concentration of the stabilizer, and the molecular weight of PCL. The shape of the microcapsule was characterized by scanning electron microscopy (SEM). The size of the microcapsule was reduced by increasing the stirring speed. The release rate of rosmarinic acid was decreased when the higher molecular weight PCL was used. When the prepared microcapsule was tested in an aromatherapy class, the microencapsulated fragrant oil had a longer release time than the original fragrant oil. The study data showed that this fragrant oil was effective for increasing concentration ability, reducing stress, increasing digestive power, and increasing memory for the students.

Effects of the Rheological Properties of UV Cured Acrylic Pressure Sensitive Adhesive with Nano-particles on the Silk Screen Printing and Adhesion (실크 스크린 인쇄 및 점착력에 나노 입자가 포함된 UV 경화형 아크릴계 감압 점착제의 유변학적 특성)

  • Cho, Min-Jeong;Kang, Ho-Jong;Kim, Dong-Bok
    • Journal of Adhesion and Interface
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    • v.18 no.1
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    • pp.25-32
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    • 2017
  • For application to display module junction process, the silk screen printing based on UV curable acrylic pressure sensitive adhesive(PSA) with silica nano-particles and the rheological properties were studied to investigate the effect on printability and adhesion. The monomers for PSA were based on 2-ethylhexyl acrylate(2-EHA) and acrylic acid(AA) 93:7, butyl acylate(BA), 2-hydroxyethyl acrylate(2-HEA) and tetrahydrofurfuryl acrylate(THFA) were added. Additionally, hydrophobic and hydrophilic nano-particles AEROSIL R974 and AEROSIL 200 were added, respectively. When the ratio of nano-particle was used above 4 or 7 phr, G' and ${\eta}^*$ were increased significantly. When the ratio of AEROSIL 200 was used above 7 phr, the penetration property was decreased during the silk screen printing. We found that the adhesion was decreased with increasing the nano-particle content, and it was decreased in the case of the hydrophilic nano-particle AEROSIL 200.

Preparation and Characterization of Cellulose Nano-Whiskers Extracted from Microcrystalline Cellulose by Acid Hydrolysis (산 가수분해를 이용하여 microcrystalline cellulose로부터 추출 된 cellulose nano-whisker의 특성분석)

  • Jeong, Hae-Deuk;Yoon, Chang-Rok;Lee, Jong-Hyeok;Bang, Dae-Suk
    • Elastomers and Composites
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    • v.45 no.1
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    • pp.51-57
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    • 2010
  • Cellulose nanowhiskers (CNW) gamered increasing interest for their remarkable reinforcement of polymer composites. In this work, we were to produce cellulose whiskers from commercially available microcrystalline cellulose (MCC) by acid hydrolysis with sulfuric and hydrochloric acids. Electron microscopy found that each acid produced sililar cellulose crystals of diameters ranging from 20 to 30 nm and lengths ranging from 200 to 300 nm. Moreover, all samples showed remarkable flow birefringence through crossed polarization filters. Conductometric titration of CNW suspensions revealed that the sulfuric acid treated sample had a surface charge of between 140.00 mmol/kg and 197.78 mmol/kg due to sulfate groups, while that of the hydrochloric acid treated sample was undetectable. Thermogravimetric analysis showed that the thermal decomposition temperature and apparent activation energy (evaluated by Broido's method at different stages of thermal decomposition.) of H1-CNW - prepared by hydrolysis with hydrochloric acid - was higher than those of S1-CNW and S2-CNW - prepared by hydrolyzing MCC with sulfuric acid.

Multi-copter Wind-tunnel Test (멀티콥터 풍동시험)

  • Hwang, SeungJae;Cho, TaeHwan;Kim, YangWon;Chung, JinDeog
    • Journal of Aerospace System Engineering
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    • v.11 no.6
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    • pp.10-16
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    • 2017
  • In order to improve the safety of the multi-copter, Korea Aerospace Research Institute (KARI) performed a wind-tunnel test using an octocopter with the maximum takeoff weight (MTOW) of 28 kg. The wind-tunnel test was performed with three different RPM ranges, 3,500, 4,500 and 5,500 rpm, and three different wind speeds, 3.5, 5 and 7 m/sec. The tested range of the angle of attacks was $-40^{\circ}$ to $20^{\circ}degree$ and ${\pm}90^{\circ}degree$. Vortex ring state (VRS) of the tested multi-copter was located around the vertical descending speed of 6 m/sec and the decrement of thrust was about 13 % at the time of testing. Compared with the single propeller wind-tunnel test result, the propeller efficiency of the octocopter dropped to 10 to 15% depending on the propeller RPM. It is hypothesized that the obtained aerodynamic characteristics by the wind-tunnel test will be used to improve the performance and wind resistance of the multi-copter.

Correlation between Skin Translucency and Scattering Reflection using Miniaturized New Optical Device (피부 투명감 측정 기기의 소형화 및 피부의 확산 반사광과 투명감 사이의 연구)

  • Lee, Myeong-Ryeol;Jeong, Choon-Bok;Junng, Yu-Chul;Kim, Han-Kon;Nam, Gae-Won
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.37 no.2
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    • pp.121-127
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    • 2011
  • Skin darkness is the source of trouble to many women. Skin darkness is the state that while skin redness and brightness are reduced, skin yellowness is increased. Skin translucency which is measured by skin color, especially brightness is an another expression of skin darkness. Skin brightness is usually expressed by L value of $L^{*} \;a^{*}\; b^{*}$ (CIELAB color space system). However, it is hard to find the relationship between L value and perceptive efficacy such as translucency because the L value is just a factor of evaluation of skin darkness. The skin with high translucency has high scattering reflective light value than low value. In this study, we measured the skin translucency of 20 ~ 30 ages men and women face by both our designed previous device which use polarized light to detect surface and scatter reflective light independently and $Lumiscan^{TM}$ which is improved designed to confirm our new device working ability by calculation of relationship between trnaslucency and scattering reflective light value. The result of this study indicate that there is a high correlation (R = 0.732, p < 0.01) between translucency and scattering reflective light value, and suggest that $Lumiscan^{TM}$ is portable and easy measuring device more that previous device.

Stability of Nano-emulsions prepared upon Change of Composition (조성변화에 따라 제조된 나노에멀젼의 안정성)

  • Cho, Wan Goo;Kim, Eun Hee;Jeon, Bong-Ju;Cha, Young-Kweon;Park, Seon-Ki
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.39 no.1
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    • pp.55-63
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    • 2013
  • Applications of nano-emulsion for cosmetics as a means of promoting dermal absorption have been the subject of interest. In this study, the stability of nano-emulsions prepared by low-energy emulsification method and varying the composition of raw materials was investigated. By measuring the particle size of the nano-emulsion against time, the stability of nano-emulsions prepared by adding polyol to water phase was increased significantly compared with the nano-emulsions prepared by adding polyol to ethanol phase. The speed of adding ethanol phase to water phase did not have a significant impact on the particle size and stability. Depending on the type of oil, stability was not affected. However, there would be a correlation between the initial size of the nano-emulsion droplets and the molecular weight and polarity of the oil. Stability and the initial particle size according to the type of polyols showed a similar trend except 1,2 hexanediol. The initial droplet size was affected by the concentration of surfactant and oil. However, the initial droplet size did not change against time. Concentration of ethanol was observed to have a significant impact on the initial particle size and stability.

Anti-melanogenesis Activities for the Terpenes from the Acantophanax koreanum Stems (섬오갈피나무 줄기 유래 테르펜 화합물의 멜라닌 생성 저해 활성)

  • Mun, Seung Ri;Hyun, Ju Mi;Jo, Yeon Jeong;Jung, Eun Yeong;Lee, Nam Ho
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.43 no.4
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    • pp.289-295
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    • 2017
  • A. koreanum was investigated to identify the constituents possessing whitening effects. As anti-melanogenesis activities were screened for the ethanol extract and solvent fractions, n-hexane (Hex) and ethyl acetate (EtOAc) fractions showed the most potent activities. Three constituents were isolated from the n-Hex fraction of A. koreanum; kaurenoic acid (1), $16{\alpha}$-hydro-17-isovaleroyloxy-ent-kauran-19-oicacid (2), $16{\alpha}$-hydroxy-17-isovaleroyl-oxy-ent-kauran-19-oic acid (3). The chemical structures of the isolated compounds were elucidated based on the spectroscopic data including $^1H$ and $^{13}C$ NMR spectra, as well as comparison of the data to the literature values. Whitening effects were studied for the isolated compounds. Upon the anti-melanogenesis test using ${\alpha}-MSH$ stimulated B16F10 melanoma cells, the compounds 1, 2 and 3 inhibited the cellular melanogenesis and intracellular tyrosinase activities effectively. Based on these results, A. koreanum stems extract could be potentially applicable as whitening ingredients in cosmetic formulations.

Application of SP Survey and Numerical Modeling to the Leakage Problem of Irrigation facilities (수리시설물 누수탐지에 대한 자연전위법 적용 및 수치 해석)

  • Song Sung-Ho;Kwon Byung-Doo;Yang Jun-Mo;Chung Seung-Hwan
    • Geophysics and Geophysical Exploration
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    • v.5 no.4
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    • pp.257-261
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    • 2002
  • We have carried out integrated research including field survey and numerical modeling to appraise the applicability of SP method to the leakage problems of irrigation facilities. The leakage pattern of the dike studied here can be classified into the three categories: leakage through the abutment, leakage by piping through dike, and leakage due to the composite effects of landslide and distortion of the dike structure. for the numerical modeling to interpret quantitatively SP survey results acquired at dike, we have modified the computer code proposed by Sill (1983) to apply to the leakage problems. The numerical studies match the characteristic patterns of SP anomalies according to the leakage types and appear to be very useful to interpret the leakage zone and path. The SP monitoring results were also well coincided with tidal variations observed at every embankment so we found the SP method is quite effective not only to detect the leakage zone but also to determine the leakage trend. The numerical modeling results also reproduced the SP anomalies due to seawater leakage in the embankment.