• 제목/요약/키워드: %24LaInO_3%24

검색결과 81건 처리시간 0.025초

(Pr, Co, Cr, La)-doped ZnO 바리스터의 전기적 특성에 미치는 소결온도효과 (Effects Sintering Temperature on Electrical Properties of (Pr, Co, Cr, La)-doped ZnO Varistors)

  • 남춘우
    • 한국전기전자재료학회논문지
    • /
    • 제19권12호
    • /
    • pp.1085-1091
    • /
    • 2006
  • The microstructure, electrical properties, and its stability of (Pr, Co, Cr, La)-doped ZnO varistors were investigated at different sintering temperatures in the range of $1230{\sim}1300^{\circ}C$. As the sintering temperature increased, the sintered density increased from 5.50 to $5.77g/cm^3$, the varistor voltage decreased from 777.9 to 108.0 V/mm, the nonlinear coefficient decreased from 77.0 to 7.1, and the leakage current increased from $0.4{\mu}A\;to\;50.6{\mu}A$. On the other hand, the donor concentration increased from $0.90{\times}10^{18}\;to\;2.59{\times}10^{18}/cm^3$ and the barrier height decreased from 1.89 to 0.69 eV with increasing temperature. The stability of nonlinear electrical properties was obtained from sintering temperature of $1260^{\circ}C$. The varistors sintered at $1260^{\circ}C$ marked the high electrical stability, with $%{\Delta}V_{1mA}=+1.9%,\;%{\Delta}a=10.6%,\;and\;%{\Delta}I_L=+20%$ for DC accelerated aging stress state of $0.95V_{1mA}/150^{\circ}C/24h$.

Piezoelectric Characteristics and Temperature Stability of Resonant Frequency of PbTiO3 System Ceramics for High Frequency Resonator using Srd Overtone Thickness Vibration Mode

  • Yoo, Juhyun ;Min, Sukkyu ;Hwang, Sangmo ;Park, Changyub;Yoon, Hyunsang
    • 한국전기전자재료학회논문지
    • /
    • 제15권4호
    • /
    • pp.338-343
    • /
    • 2002
  • In this study, $Pb_{0.88}(La_{\alpha}Nd_{1-\alpha})_{0.08}(Mn_{1/3}Sb_{2/3})_{0.02}Ti_{0.98}O_3$ system ceramics with La molar ratio $\alpha$ variation were manufactured for 24 MHz class resonator application. Electromechanical coupling factor, mechanical quality factor and dynamic range of $3^{rd}$ overtone thickness vibration mode were measured as the variations of La and Nd molar ratio. Mechanical quality factor and dynamic range at $\alpha$ = 0.6 composition ceramics showed the highest value of 2691 and 52.37 dB, respectively. The temperature coefficient of resonant frequency measured from $-20^{\circ} to 80^{\circ}$ showed an excellent value of $5ppm/^{\circ}C$ at $\alpha$=1 composition ceramics.

충남탄전, 대동누층군의 셰일과 탄질암에 관한 암석화학 및 환경지구화학적 특성 (Petrochemistry and Environmental Geochemistry of Shale and Coal from the Daedong Supergroup, Chungnam Coal Field, Korea)

  • 이찬희;이현구;김경웅
    • 자원환경지질
    • /
    • 제30권5호
    • /
    • pp.417-431
    • /
    • 1997
  • Characteristics of sedimentary rocks and enrichment of toxic elements in shale and coal from the Chungnam coal field were investigated based upon geochemistry of major, trace and rare earth elements. Shale and coal of the area are interbedded along the Traissic to the Jurassic Daedong Supergroup, which can be subdivided into grey shale, black shale and coal. The coal had been mined, however all the mines are abandonded due to the economic problems. The shale and coal are characterized by relatively low contents of $SiO_2$, and $Al_2O_3$ and high levels of loss-on-ignition (LOI), CaO and $Na_2O$ in comparison with the North American Shale Composite (NASC). Light rare earth elements (La, Ce, Yb and Lu) are highly enriched with the coal. Ratios of $Al_2O_3/Na_2O$ and $K_2O/Na_2O$ in shale and coal range from 30.0 to 351.8 and from 4.2 to 106.8, which have partly negative correlations against $SiO_2/Al_2O_3$ (1.24 to 6.06), respectively. Those are suggested that controls of mineral compositions in shale and coal can be due to substitution and migration of those elements by diagenesis and metamorphism. Shale and coal of the area may be deposited in terrestrial basin deduced from high C/S (39 to 895) and variable composition of organic carbon (0.39 to 18.40 wt.%) and low contents of reduced sulfur (0.01 to 0.05 wt.%). These shale and coal were originated from the high grade metamorphic and/or igneous rocks, and the rare earth elements of those rocks are slightly influenced with diagenesis and metamorphism on the basis of $Al_2O_3$ versus La, La against Ce, Zr versus Yb, the ratios of La/Ce (0.38 to 0.85) and Th/U (3.6 to 14.6). Characteristics of trace and rare earth elements as Co/Th (0.07 to 0.86), La/Sc (0.31 to 11.05), Se/Th (0.28 to 1.06), V/Ni (1.14 to 3.97), Cr/V (1.4 to 28.3), Ni/Co (2.12 to 8.00) and Zr/Hf (22.6~45.1) in the shale and coal argue for inefficient mixing of the simple source lithologies during sedimentation. These rocks also show much variation in $La_N/Yb_N$ (1.36 to 21.68), Th/Yb (3.5 to 20.0) and La/Th (0.31 to 7.89), and their origin is explained by derivation from a mixture of mainly acidic igneous and metamorphic rocks. Average concentrations in the shale and coal are As=7.2 and 7.5, Ba=913 and 974, Cr=500 and 145, Cu=20 and 26, Ni=38 and 35, Pb=30 and 36, and Zn=77 and 92 ppm, respectively, which are similar to those in the NASC. Average enrichment indices for major elements in the shale (0.79) and coal (0.77) are lower than those in the NASC. In addition, average enrichment index for rare earth elements in coal (2.39) is enriched rather than the shale (1.55). On the basis of the NASC, concentrations of minor and/or environmental toxic elements in the shale and coal were depleted of all the elements examined, excepting Cr, Pb, Rb and Th. Average enrichment indices of trace and/or potentially toxic elements (As, Cr, Cu, Ni, Pb, U and Zn) are 1.23 to 1.24 for shale and 1.06 to 1.22 for coal, respectively.

  • PDF

Relationship between transition temperature and magnetic entropy changes in manganite materials

  • Phan, Manh-Huong;Yu, Seong-Cho;A.N. Ulyanov
    • 한국자기학회:학술대회 개요집
    • /
    • 한국자기학회 2002년도 동계연구발표회 논문개요집
    • /
    • pp.121-121
    • /
    • 2002
  • A theoretical consideration for entropy changes in a magnetic solid is given in a general manner and has been taken into account for such La$\sub$0.7/Ca$\sub$0.3-x/Ba$\sub$x/MnO$_3$(x = 0.12, 0.24, 0.3) compounds. The total entropy changes, in which the total entropy is decomposed into the magnetic, lattice, and electron entropies, are discussed in detail. (omitted)

  • PDF

나노구조 제어를 위한 EB-PVD법에 의반 세라믹스 코팅 (Ceramic Coating by Electron Beam PVD for Nanos-Tructure Control)

  • 마쯔바라 히데아기
    • 세라미스트
    • /
    • 제9권6호
    • /
    • pp.24-29
    • /
    • 2006
  • Electron beam physical vapor deposition (EB-PVD) process has currently been applied to thermal barrier coatings (TBCs) for aircraft engines. Due to unique columnar structure, EB-PVD TBCs have advantages in resistances to thermal shock and thermal cycle for their applications, compared to films prepared by plasma spray By the EB-PVD equipment, we successfully obtained yttria-stabilized zirconia (YSZ) layer which has columnar and feather like structure including a large amount of nano size pores and gaps. The EB-PVD technique has been developed for coating functional perovskite type oxides such as (La, Sr)MnO3. Electrode properties have been improved by interface and structural control.

  • PDF

금강하구 표층퇴적물의 지화학적 특성에 관한 연구 (Geochemical Characteristics of Surface Sediments in the Keum River Estuary Adjacent to Coastal Area)

  • 서만석;박영석
    • 수산해양교육연구
    • /
    • 제19권1호
    • /
    • pp.1-7
    • /
    • 2007
  • The purpose of this study was to investigate geochemical characteristics of surface sediments in the Keum river estuary adjacent to coastal area. For this study we collected the 21 surface sediments samples. Mean size of surface samples was $3.24{\sim}6.65{\phi}$ on inner estuary and was $2.15{\sim}3.42{\phi}$ on outside estuary. Surface samples were composed of silt on inner estuary and were composed of sand which was more larger than $4{\phi}$ on outside estuary. Most major elements except CaO, $Na_2O$ showed good relationships between variation of contents and grain size. Contents of $Al_2O_3$, $Fe_2O_3$, MgO, $K_2O$, $TiO_2$, $P_2O_5$ and $M_nO$ were increased predominately owing to the variation of mean size of surface samples. Contents of Co, Cr, Cu, Li, Sr, Zn, La, Ce, Pb, Rb, Nd have a good relationships with grain size but Ba, Th, Sm have not. All of major and minor elements contents except $K_2O$ and Ba were less than world mean contents of shallow surface sediments but apprehend a high pollution possibility on silt sediments in the estuaries.

산소 용해수 발생 장치를 이용한 소형 연못의 산소 거동 연구 (A Study on Kinetics of Oxygen in Small Size Pond using Oxygen Solubilization Device System)

  • 김영택;배윤선;노은경;박철휘
    • 한국물환경학회지
    • /
    • 제22권3호
    • /
    • pp.475-481
    • /
    • 2006
  • The major problem in closing water like lakes and ponds in Korea is that because they are exposed to surrounding, so easily polluted. The pollution in closing water can be caused by not only artificial factor like sewage but also natural factor like elution from sediment. For insurance of safe and satisfied water source, lots of studies and projects are now going on. In this study, we examined the behavior and effect of microbubble ($3{\sim}10{\mu}m$) produced by device called O.S.D (Oxygen Solubillization Device) in small size pond. The value of oxygen transfer coefficient ($K_La$) was 0.68/min independently of air flow rate, 6.5 times higher than commercial aeration stone and the variation of nitrogen concentration was $0.008NO_3/O_2$, DO concentration was potentially saturated for 24 hr. From the results of pilot plant, SOD of experiment (O.S.D) and control were $12.18gO_2{\cdot}m^{-2}{\cdot}d^{-1}$ and $47.95gO_2{\cdot}m^{-2}{\cdot}d^{-1}$ respectively. In conclusion, because O.S.D has extraordinary physico-chemical characteristics, it can contribute to improvement of both the waterbody and the sediment environment.

이진트리의 최소선형배열 알고리즘 (Algorithm for Minimum Linear Arrangement(MinLA) of Binary Tree)

  • 이상운
    • 한국인터넷방송통신학회논문지
    • /
    • 제24권2호
    • /
    • pp.99-104
    • /
    • 2024
  • 이진트리의 최소 선형 배열(MinLA) 문제의 해는 선형 복잡도 O(n)의 근사 알고리즘으로 구하고 있으며, k = 10에 대해 다양한 근사 알고리즘 수행 결과가 제시되어 있고, 단지 2개 알고리즘만이 최적 해 3,696을 얻었다. 본 논문은 이진트리의 정확한 해를 O(n) 복잡도로 구하는 알고리즘을 제안하였다. 제안된 알고리즘은 먼저, n = 2k - 1개 노드들에 중위 탐색(in-order search) 방법으로 번호를 부여하고, 2 ≤ 𝑙 ≤ k-2, (k = 5)와 2 ≤ 𝑙 ≤ k-3, (k = 6) 레벨에 존재하는 노드들에 대해 단 노드 자식들까지의 범위를 대상으로 번호를 재배열하는 방법을 적용하였다. 제안된 알고리즘을 k=5,6,7에 적용한 결과 Chung[14]의 S(k)min=2k-1+4+S(k-1)min+2S(k-2)min 이론을 증명하였으며, S(5)min에 대해서는 Chung[14]의 60보다 좋은 58을 얻었다. 또한, 기존의 근사 알고리즘들은 배열 결과를 제시하지 않고 있는데 비해 제안된 알고리즘은 정확한 배열 방법도 제시하는 장점을 갖고 있다. 따라서 제안된 알고리즘은 k > 10인 이진트리에 대해서도 항상 빠르게 최적의 해를 얻을 수 있기 때문에 기존의 근사 알고리즘을 적용하지 않아도 된다.

내피세포성 이완인자에 대한 세포외 $Ca^{2+}$$Ca^{2+}$-길항제의 작용기전 (Acting Mechanisms of Extracellular$Ca^{2+}$ and $Ca^{2+}$ - antagonists on Endothelium - Derived Relaxing Factor in Rabbit Aorta.)

  • 진성훈
    • Journal of Chest Surgery
    • /
    • 제24권3호
    • /
    • pp.229-244
    • /
    • 1991
  • A bioassay technique and organ bath study were performed to analyze the effects of extracellular $Ca^{2+}$ and $Ca^{2+}$-antagonists on endothelium-derived relaxing factor[s][EDRF] released from the endothelial cells of rabbit aorta. Transverse strips with intact endothelium or damaged endothelium were used for the mechanical contraction experiment using organ bath. Long segment including thoracic and abdominal aorta with endothelium [EDRF donor aorta] was perfused with Tyrode solution which was aerated with 95% $O_2-5%$ $CO_2$ mixed gas and kept at 35oC. The perfusate was bioassayed with a transverse strip of thoracic aorta with damaged endothelium. The test strip was contracted with nor-epinephrine and acetylcholine was used to stimulate the release of EDRF from endothelial cells. The results obtained were as follows; 1] The endothelium-dependent relaxation[EDR] induced by acetylcholine was biphasic; an initial rapid relaxation followed by a slow relaxation. 2] EDR induced by acetylcholine was reduced gradually with the decrease in the concentration of extracellular $Ca^{2+}$. The effect of extracellular $Ca^{2+}$ on EDR was more prominent in the late slow relaxation phase. 3] EDR to acetylcholine was not altered by acute exposure to organic $Ca^{2+}$-antagonists. Pretreatment with verapamil to the EDRF donor aortic segment did not alter the magnitude of EDR. 4] Among the inorganic $Ca^{2+}$-antagonists $Mn^{2+}$ and $Cd^{2+}$ did not inhibit EDR, whereas $Co^{2+}$ and $La^{3+}$ inhibited EDR. 5] The inhibitory response of $Co^{2+}$ to EDR developed when infused directly on the test strip. That of $La^{3+}$, however, was evoked when added to solution perfusing the donor aortic segment. The above results suggest that $Ca^{2+}$-antagonists do not affect EDR and the inhibitory effect of $Ca^{2+}$ results from influencing the action of EDRF on vascular smooth muscle, whereas that of $La^{3+}$ results from its action on the release of EDRF from endothelial cells.

  • PDF

Temporal and Spatial Variability of Precipitation and Evaporation over the Tropical Ocean

  • Yoo, Jung-Moon;Lee, Hyun-A
    • 한국지구과학회지
    • /
    • 제24권1호
    • /
    • pp.22-29
    • /
    • 2003
  • Temporal and spatial variability of precipitation (P), evaporation (E), and moisture balance (P-E; precipitation minus evaporation) has been investigated over the tropical ocean during the period from January 1998 to July 2001. Our data were analyzed by the EOF method using the satellite P and E observations made by the Tropical Rainfall Measuring Mission (TRMM) Precipitation Radar (PR) and the Special Sensor Microwave/Imager (SSM/I). This analysis has been performed for two three-year periods as follow; The first period which includes the El Ni${\tilde{n}}$o in early 1998 ranges from January 1998 to December 2000, and the second period which includes the La Ni${\tilde{n}}$o events in the early 1999 and 2000 (without El Ni${\tilde{n}}$o) ranges from August 1998 to July 2001. The areas of maxima and high variability in the precipitation and in the P-E were displaced from the tropical western Pacific and the ITCZ during the La Ni${\tilde{n}}$o to the tropical middle Pacific during the El Ni${\tilde{n}}$o, consistent with those in previous P studies. Their variations near the Korean Peninsula seem to exhibit a weakly positive correlation with that in the tropical Pacific during the El Ni${\tilde{n}}$o. The evaporation, out of phase with the precipitation, was reduced in the tropical western Pacific due to humid condition in boreal summer, but intensified in the Kuroshio and Gulf currents due to windy condition in winter. The P-E variability was determined mainly by the precipitation of which the variability was more localized but higher by 2-3 times than that of evaporation. Except for the ITCZ (0-10$^{\circ}$N), evaporation was found to dominate precipitation by ${\sim}$2 mm/day over the tropical Pacific. Annual and seasonal variations of P, E, and P-E were discussed.