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A catalog of infrared supernova remnants in the Large Magellanic Cloud

  • Seok, Ji-Yeon;Koo, Bon-Chul
    • The Bulletin of The Korean Astronomical Society
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    • v.36 no.2
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    • pp.104.1-104.1
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    • 2011
  • We present a catalog of infrared supernova remnants (SNRs) in the Large Magellanic Cloud (LMC). We have searched the Spitzer archival data for infrared counterparts to all 45 known SNRs in the LMC, and identified 21 which is 47% of the known SNRs. Seven of them are newly detected: SNR 0450-70.9, SNR in N4, N103B, DEM L241, DEM L249, DEM L316A, and DEM L316B. All newly discovered SNRs show emission at several IRAC 3.4, 4.5, 5.8, and 8.0 micron bands and/or MIPS 24 and 70 micron bands. Most SNRs show shell structures. We derive infrared fluxes of these newly detected SNRs. The catalog contains general information of each SNR such as location, age, and SN type together with AKARI and/or Spitzer fluxes. For the entire SNR sample, we examine their infrared colors and the possible correlation of the infrared fluxes with the fluxes at other wavelengths. For the newly detected SNRs except the SNR in N4, we also performed follow-up imaging observations of [Fe II] 1.644 micron line using IRIS2 mounted on the Anglo Australian Telescope. Three out of six SNRs show [Fe II] emission corresponding to their infrared shells. [Fe II] knots are also detected in N103B which show good spatial correlation to infrared emission seen at Spitzer images as well as knotty $H{\alpha}$ emission. We investigate the characteristics and origin of the infrared emission in individual SNRs, and discuss the environmental and evolutionary effects.

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Sulfuric Acid Leaching of Valuable Metals from Spent Petrochemical Catalyst using Hydrogen Peroxide as a Reducing Agent (石油化學 廢觸媒로부터 過酸化水素를 還元劑로이용한 有價金屬의 황산침출)

  • 박경호;손정수;김종석
    • Resources Recycling
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    • v.10 no.2
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    • pp.20-26
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    • 2001
  • Sulfuric acid leaching of Mn, Co and Fe from spent petrochemical catalyst was performed using hydrogen peroxide as a reducing agent. Low extraction of Mn, Co and Fe was obtained by only sulfuric acid. When hydrogen peroxide were added as a reducing agent, the high extraction of these metals could be obtained. Different from ordinary leaching, the extraction per-centages of metal components decreased with elevating leaching temperature in this process. Under the optimum condition, the extraction percentages of Mn, Co and Fe were 93.0% , 87.0% and 100% respectively.

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Luminescence properties of novel Sr-Y-Si-Oxynitride yellow phosphor for LED applications (LED용 Sr-Y-Si-계 산질화물 황색 형광체의 발광 특성)

  • Jeong, Ok Geun;Park, Jong Cheon;Ryu, Jeong Ho;Cho, Hyun
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.23 no.4
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    • pp.195-200
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    • 2013
  • Novel Sr-Y-Si-Oxynitride yellow phosphors were synthesized and the effect of calcination temperature, reduction temperature and $Eu^{2+}$ concentration on their luminescence properties were studied. Optimal temperature conditions were found to be $1400^{\circ}C$ and $1300^{\circ}C$ for solid-state reaction and reduction, respectively. The synthesized $Ba_9Y_{2+y}Si_6O_{24-3y}N_{3y}:Eu^{2+}$ phosphors showed a single intense broadband emission in the range of 571~587 nm for 450 nm excitation light source. The highest luminescence intensity was obtained with Eu concentration of 3 mol% and concentration quenching was observed beyond 5 mol%. FE-SEM and PSA showed that the synthesized phosphors consists of particles with an average size of ${\sim}8.2{\mu}m$.

Effect of SiO2 Buffer Layer Thickness on the Device Reliability of the Amorphous InGaZnO Pseudo-MOS Field Effect Transistor (SiO2 완충층 두께에 따른 비정질 InGaZnO Pseudo-MOS Field Effect Transistor의 신뢰성 평가)

  • Lee, Se-Won;Hwang, Yeong-Hyeon;Cho, Won-Ju
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.25 no.1
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    • pp.24-28
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    • 2012
  • In this study, we fabricated an amorphous InGaZnO pseudo-MOS transistor (a-IGZO ${\Psi}$-MOSFET) with a stacked $Si_3N_4/SiO_2$ (NO) gate dielectric and evaluated reliability of the devices with various thicknesses of a $SiO_2$ buffer layer. The roles of a $SiO_2$ buffer layer are improving the interface states and preventing degradation caused by the injection of photo-created holes because of a small valance band offset of amorphous IGZO and $Si_3N_4$. Meanwhile, excellent electrical properties were obtained for a device with 10-nm-thick $SiO_2$ buffer layer of a NO stacked dielectric. The threshold voltage shift of a device, however, was drastically increased because of its thin $SiO_2$ buffer layer which highlighted bias and light-induced hole trapping into the $Si_3N_4$ layer. As a results, the pseudo-MOS transistor with a 20-nm-thick $SiO_2$ buffer layer exhibited improved electrical characteristics and device reliability; field effective mobility(${\mu}_{FE}$) of 12.3 $cm^2/V{\cdot}s$, subthreshold slope (SS) of 148 mV/dec, trap density ($N_t$) of $4.52{\times}1011\;cm^{-2}$, negative bias illumination stress (NBIS) ${\Delta}V_{th}$ of 1.23 V, and negative bias temperature illumination stress (NBTIS) ${\Delta}V_{th}$ of 2.06 V.

Effect of Oyster Shell, Fly Ash and Gypsum Application on Rice Yield and Quality (패각, 석탄회 및 석고 시용이 벼 수량과 미질에 미치는 영향)

  • Lee, Young-Han;Kim, Jong-Gyun;Lee, Han-Saeng;Cho, Ju-Sik;Ha, Ho-Seoung
    • Korean Journal of Soil Science and Fertilizer
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    • v.30 no.3
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    • pp.242-247
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    • 1997
  • This study was conducted to investigate the combined effects of oyster shell, fly ash and gypsum on rice yield and quality. The four treatments of soil amelioration were oyster shell 4, fly ash 80, fly ash 56 + gypsum 24 and oyster shell 0.8 + fly ash 40 + gypsum 24 ton/ha. Rice yield were in the order of oyster shell, fly ash and control plats. The pH, EC values and OM, Ca, $SO_4$, moisture contents of the top-soil after rice harvesting in soil amelioration treatments were increased, while Mg, Na, Fe, Zn and Al were decreased than those of control. Rice quality was the best in the fly ash plat due to lower T-N and higher Mg/K ratio.

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Effects of Fly Ash,Gypsum,and Shell on the Chemical Properties of Soil and Growth of Chinese Cabbage in Plastic Film Housed Paddy (시설재배논에 석탄회,석고,패각시용이 토양화학성과 배추의 생육에 미치는 영향)

  • Ha, Ho-Sung;Kang, Ui-Gum;Lee, Hyub;Lee, Yong-Bok
    • Korean Journal of Environmental Agriculture
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    • v.17 no.1
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    • pp.65-69
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    • 1998
  • In order to evaluate the utility of bituminous coal fly ash, gypsum, oyster shell as soil amendments, aadic clayloam paddy soils with low calaum content were amended in the upper 15㎝ with amendments, and then Chinese cabbage was cultivated under plastic film house. Amendments treated were, in metric tons per hectare, i) none(Check) ; ii) 80 fly ash(FA) ; iii) 4 shell(SH) ; iv) 56 fly ash+24 gypsum (FG) ; v) 40 fly ash+24 gypsum+0.8 shell(FGS). On the whole, soil chemical properties were improved by amendments treatments. Amongst treatments, FA prominently neutralized soil pH and increased contents of Av. $P_2O_5$, Ex. K, and Av. B in soils. Besides, it showed the highest ratio in bacteria/fungi and (bacteria+actinomycetes)/fungi. FGS also affected the neutralization of soil pH and the increment of Ex. Mg. Amendments plants appeared alkaline damages only at early growing stage, but showed positive responses in fresh weight yields : 23% for FGS : 21% for FG : 19 18% for SH. At harvesting, leaves both of FA and FGS plants had higher values in contents of N, P, K, Ca, Mg, Fe, Mn, Zn, B, reduang-sugar, and vitamin-C than of others. In especial, Check plants appeared the heart rot symptoms owing to calaum defiaency differently from amendments plants. Taken together, FGS was an effective combination enable to maximize the utility of fly ash, gypsum, shell as soil amendments, espeaally in cabbage yield and quality.

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The Change of Sagittal Alignment of the Lumbar Spine after Dynesys Stabilization and Proposal of a Refinement

  • Park, Won Man;Kim, Chi Heon;Kim, Yoon Hyuk;Chung, Chun Kee;Jahng, Tae-Ahn
    • Journal of Korean Neurosurgical Society
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    • v.58 no.1
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    • pp.43-49
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    • 2015
  • Objective : $Dynesys^{(R)}$ is one of the pedicle-based dynamic lumbar stabilization systems and good clinical outcome has been reported. However, the cylindrical spacer between the heads of the screws undergoes deformation during assembly of the system. The pre-strain probably change the angle of instrumented spine with time and oblique-shaped spacer may reduce the pre-strain. We analyzed patients with single-level stabilization with $Dynesys^{(R)}$ and simulated oblique-shaped spacer with finite element (FE) model analysis. Methods : Consecutive 14 patients, who underwent surgery for single-level lumbar spinal stenosis and were followed-up more than 24 months (M : F=6 : 8; age, $58.7{\pm}8.0$ years), were analyzed. Lumbar lordosis and segmental angle at the index level were compared between preoperation and postoperative month 24. The von Mises stresses on the obliquely-cut spacer ($5^{\circ}$, $10^{\circ}$, $15^{\circ}$, $20^{\circ}$, $25^{\circ}$, and $30^{\circ}$) were calculated under the compressive force of 400 N and 10 Nm of moment with validated FE model of the L4-5 spinal motion segment with segmental angle of $16^{\circ}$. Results : Lumbar lordosis was not changed, while segmental angle was changed significantly from $-8.1{\pm}7.2^{\circ}$ to $-5.9{\pm}6.7^{\circ}$ (p<0.01) at postoperative month 24. The maximum von Mises stresses were markedly decreased with increased angle of the spacer up to $20^{\circ}$. The stress on the spacer was uneven with cylindrical spacer but it became even with the $15^{\circ}$ oblique spacer. Conclusion : The decreased segmental lordosis may be partially related to the pre-strain of Dynesys. Further clinical and biomechanical studies are required for relevant use of the system.

Characterization of Surface Modified Polysulfone Membranes with Various Fluorine Chemicals

  • Lee, Choong-Sub;Rhim, Ji-Won
    • Korean Membrane Journal
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    • v.4 no.1
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    • pp.20-24
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    • 2002
  • The surface of polysulfone membranes has been modified using the fluorine chemicals, ITFE (2-iodo-1,1,1-trifluoro-ethane F.W.=209.94) and PFPI (1H,1H-pentafluoro-n-propyl iodide F.W.=259.95), and PFI (1H,1H,2H,2H-perfluorohexyl iodide, F.W.=373.99) based on Friedel-Crafts reaction mechanism with varying reaction temperatures, reaction time, and catalysis types. The resulting membranes were characterized through mainly the contact angle measurement and pure water permeability. The smaller reactant shows the larger contact angles. FeBr$_3$ catalyst is more effective than AlCl$_3$. Typically, the PS film treated with ITFE at $25^{\circ}C$ under FeBr$_3$ catalyst showed the contact angle 78.5$^{\circ}C$ which indicated 10% over the value of unreacted PS films. More than 50% of pure water flux 8.0 g/$m^2$hr, reduced at reaction time 10 min relative to the original flux, 3.49 g/$m^2$hr.

Characteristics of (Sr1-xBax)NdFe3+1-τFe4+τO4-y System Heat-treated in Air

  • Lee, Eun-Seok;Hag, Jang-Chun
    • Transactions on Electrical and Electronic Materials
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    • v.13 no.1
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    • pp.39-42
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    • 2012
  • To study the physical and chemical properties, solid solutions of $(Sr_{1-x}Ba_x)NdFe{^{3+}}_{1-\tau}Fe{^{4+}}_{\tau}O_{4-y}$ system with x=0.0(SBN-0), 0.1(SBN-1), 0.2(SBN-2) and 0.3(SBN-3) were synthesized in air at 1,473 K and annealed in air at 1,073 K for 24 h. X-ray powder diffraction assured that the four samples had tetragonal symmetries (I4/mmm). Their lattice volumes increased gradually with x values. Nonstoichiometric chemical formulas were formulated using the data such as $\tau$(amount of $Fe^{4+}$ ion) and y(oxygen deficiency) values using Mohr salt analysis. It was found out that all the four samples had excessive oxygen (4-y>4.0). All the samples started to lose some of their oxygen at around 613K(TG/DTA thermal analysis). They exhibited semiconductivities in the temperature range of around 283-1173K. All the four specimens had sufficient tensile strength to endure the force of 19.6 N (2 kg of weights) and the conductivity values of the ECIAs which were painted on pieces of glass with the area of $150mm^2$ ($10mm{\times}15mm$) and it was in the order of ECIA-0${\rightarrow}$ECIA-1${\rightarrow}$ECIA-2${\rightarrow}$ECIA-3 at a constant temperature.

Microwave-assisted Fenton degradation of methylene blue (마이크로웨이브를 이용한 메틸렌 블루의 펜톤산화)

  • Kim, Shin-Young;Ahn, Johng-Hwa
    • Journal of Industrial Technology
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    • v.37 no.1
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    • pp.21-26
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    • 2017
  • This work experimentally determined the effect of combining of microwave irradiation and the Fenton process on decolorization of methylene blue ($C_{16}H_{18}N_3SCl$, MB). As [$H_2O_2$] increased from 2.65 to 4.41 mM, the decolorization of MB increased from 22.7 to 99.1%. As [$Fe^{2+}$] increased from 0.07 to 0.18 mM, the decolorization of MB increased from 24.0 to 98.5%. MB removal efficiencies were ${\geq}95%$ at $[H_2O_2]{\geq}3.5mM$ and $3.5{\leq}[H_2O_2]/[Fe^{2+}]{\leq}17.3$, but $[H_2O_2]/[Fe^{2+}]{\geq}20$ caused a decrease in MB removal. A two-stage kinetic model matched the experimental data well.