• The Korean Journal of Malacology
• /
• v.26 no.1
• /
• pp.1-18
• /
• 2010

Biological organisms produce organic-inorganic nanocomposite composites that are hierarchically organized in composition and microstructure, containing both inorganic and organic components in complicated mixtures. The process related to the generation and regeneration of organic-inorganic complex in nature is called biomineralization process. Understanding how the process operates in a biological environment is a valuable guide to the synthesis of novel advanced material and developing important industrial processes. Like the mechanism of organisms, mollusks were also synthesized from interaction between organic matrices and minerals and their morphology was designed through biomineralization. In this study, shell formation has been studied as a bio-model and the application of biomimetics based on biomineralization is focused.

• Economic and Environmental Geology
• /
• v.51 no.3
• /
• pp.223-232
• /
• 2018

The viscous force of fluids and the capillary force acting on the pore network of the porous media are important factors determining the immiscible displacement during geological $CO_2$ sequestration, these were directly affected by geological formation conditions and injection conditions. This study aimed to observe the migration and distribution of injected fluid and pore water, and quantitatively investigate displacement efficiency on various injection temperatures. This study aimed to perform micromodel experiments by applying n-hexane used as a proxy fluid for supercritical $CO_2$. In this study, immiscible displacement process from beginning of n-hexane injection to equilibrium of the distribution of the n-hexane and pore water was observed. The images from experiment were used to observe the displacement pattern and estimate the areal displacment efficiency of the n-hexane. For investigate the affects of the injection temperatures on the migration in macroscopic, migration of n-hexane in single pore was analyzed. The measurement revealed that the displacement efficiency at equilibrium state decreases as the temperature increases. The result from experiments indicate that the temperatures can affect the displacement pattern by changing the viscous forces and the capillary forces. The experimental results could provide important fundamental information on reservoir conditions and fluid injection conditions during geological $CO_2$ sequestration.

• Proceedings of the Korea Water Resources Association Conference
• /
• 2015.05a
• /
• pp.257-257
• /
• 2015

Carbon Capture and Storage with ocean sequestration is being considered as one of the most effective option for reducing the $CO_2$ net flux from atmosphere nowadays. But it is still possible for $CO_2$ substance to leaks out from transport pipeline or from the under seabed storage sites and causing damage to ambient environment. The behavior of liquid $CO_2$ under droplet shape would be strongly affected by the presence of other contaminants such as $SO_2$ comes from processing processes. This presentation shows the behavior in the sea water of pure liquid $CO_2$ droplets as well as droplets that consist of $SO_2$ substances. The study uses computational fluid dynamic models in comparison with experimental data from other previous researchers. Droplet of liquid $CO_2$ is assumed to be released at several depths in deep ocean, with other environmental conditions are set up respectively. All calculations are conducted with many different ratio of contaminant $SO_2$ to provide fundamental data of those particles rising characteristics. The effect of contaminants on the behavior of $CO_2$ droplets would be clearly shown through the results of particle deformation, terminal rising velocity happen due to buoyancy force driving from the difference in density of $CO_2$ substance and ocean water around.

• Journal of Forest and Environmental Science
• /
• v.30 no.1
• /
• pp.1-14
• /
• 2014

Timber harvest in natural forests and its implications on carbon sequestration were investigated in the Southwestern Nigeria. Data on timber harvest from forest estates for a 3-year period were collected from the official record of States' Forestry Department. The data registered the species, volume and number of timbers exploited during the study period. The data were analyzed accordingly for rate of timber harvest and carbon value of the exploited timbers using existing biomass functions. Values were compared for significant differences among states using one way analysis of variance. The results showed that the most exploited logs, in terms of volume and number of trees, have the highest amount of carbon removal. There was a variation in type of timber species being exploited from each state. The total number of harvested trees from Oyo, Ondo, Ogun, Ekiti and Osun were estimated at 100,205; 111,789; 753; 15,884 and 18,153 respectively. Total quantity of carbon removed for the 3-year period stood at 2.3 million metric tons, and this translated to 8.4 million metric tons of $CO_2$. The annual carbon and $CO_2$ removal therefore were estimated at 760,120.73 tons and 2.8 million tons/ year respectively. There were significant differences (p<0.05) in the amount of $CO_2$ removed from the five states. Based on our result, we inferred that there is increasing pressure on economic tree species and it is plausible that they are becoming scarce from the forests in Southwestern Nigeria.. If the present rate of log removal is not controlled, forests could become carbon source rather than carbon sink and the on biological conservation, wood availability and climate change may turn out grave. For the forest to perform its environmental role as carbon sink, urgent conservation measures and logging policies are needed to be put in place.

• 한국신재생에너지학회:학술대회논문집
• /
• 2011.05a
• /
• pp.220.1-220.1
• /
• 2011

In recent years, the importance of Carbon Capture and Storage (hereafter CCS) is growing bigger and bigger. The development and commercialization of CCS technology are concerned for reducing carbon dioxide($CO_2$) emissions. For the most studies, the technology of $CO_2$ storage is known as the geological storage, ocean sequestration, mineral carbonation, industrial utilization, and so on. The geological storage is adjudged the most reasonable technology from economic and environmental aspects. Generally, the $CO_2$ geological storage is comprised of compression - transportation - drilling/injection - storage/management process. The critical problem is a leakage of $CO_2$ in all process. For resolving a leakage problem, it is necessary to predict and build a monitoring system. Those systems are proved safety of a leakage and received positive social perceptions of $CO_2$ geological storage. For those reasons, a risk assessment of $CO_2$ geological storage is required. A risk assessment is an estimated process of the possible effects when spilling $CO_2$. Although numerous studies of risk assessment have studied, it is incomplete to evaluate a risk and disaster quantitatively. The risk assessment will be developed for domestic application and safe $CO_2$ geological storage considering characteristics of Korea.

• Geophysics and Geophysical Exploration
• /
• v.7 no.1
• /
• pp.25-32
• /
• 2004

We have carried out laboratory measurements of P-wave velocity and deformation strain during $CO_2$ injection into a porous sandstone sample, in dry and water-saturated conditions. The rock sample was cylindrical, with the axis normal to the bedding plane, and fluid injection was performed from one end. Using a piezoelectric transducer array system, we mapped fluid movement during injection of distilled water into dry sandstone, and of gaseous, liquid, and supercritical $CO_2$ into a water-saturated sample. The velocity changes caused by water injection ranged from $5.61\;to\;7.52\%$. The velocity changes caused by $CO_2$ injection are typically about $-6\%$, and about $-10\%$ for injection of supercritical $CO_2$, Such changes in velocity show that the seismic method may be useful in mapping $CO_2$ movement in the subsurface. Strain normal to the bedding plane was greater than strain parallel to the bedding plane during $CO_2$ injection; injection of supercritical $CO_2$ showed a particularly strong effect. Strain changes suggest the possibility of monitoring rock mass deformation by using borehole tiltmeters at geological sequestration sites. We also found differences associated with $CO_2$ phases in velocity and strain changes during injection.

• BMB Reports
• /
• v.56 no.12
• /
• pp.669-674
• /
• 2023

Severe acute respiratory syndrome coronavirus 2 (SARS-CoV-2) infection leads to various clinical symptoms including anemia. Lipocalin-2 has various biological functions, including defense against bacterial infections through iron sequestration, and it serves as a biomarker for kidney injury. In a human protein array, we observed increased lipocalin-2 expression due to parental SARS-CoV-2 infection in the Calu-3 human lung cancer cell line. The secretion of lipocalin-2 was also elevated in response to parental SARS-CoV-2 infection, and the SARS-CoV-2 Alpha, Beta, and Delta variants similarly induced this phenomenon. In a Calu-3 implanted mouse xenograft model, parental SARSCoV-2 and Delta variant induced lipocalin-2 expression and secretion. Additionally, the iron concentration increased in the Calu-3 tumor tissues and decreased in the serum due to infection. In conclusion, SARS-CoV-2 infection induces the production and secretion of lipocalin-2, potentially resulting in a decrease in iron concentration in serum. Because the concentration of iron ions in the blood is associated with anemia, this phenomenon could contribute to developing anemia in COVID-19 patients.

• Economic and Environmental Geology
• /
• v.54 no.1
• /
• pp.105-115
• /
• 2021

The geological CO2 sequestration in underground geological formation such as deep saline aquifers and depleted hydrocarbon reservoirs is one of the most promising options for reducing the atmospheric CO2 emissions. The process in geological CO2 sequestration involves injection of supercritical CO2 (scCO2) into porous media saturated with pore water and initiates CO2 flooding with immiscible displacement. The CO2 migration and distribution, and, consequently, the displacement efficiency is governed by the interaction of fluids. Especially, the viscous force and capillary force are controlled by geological formation conditions and injection conditions. This study aimed to estimate the effects of surfactant on interfacial tension between the immiscible fluids, scCO2 and porewater, under high pressure and high temperature conditions by using a pair of proxy fluids under standard conditions through pendant drop method. It also aimed to observe migration and distribution patterns of the immiscible fluids and estimate the effects of surfactant concentrations on the displacement efficiency of scCO2. Micromodel experiments were conducted by applying n-hexane and deionized water as proxy fluids for scCO2 and porewater. In order to quantitatively analyze the immiscible displacement phenomena by n-hexane injection in pore network, the images of migration and distribution pattern of the two fluids are acquired through a imaging system. The experimental results revealed that the addition of surfactants sharply reduces the interfacial tension between hexane and deionized water at low concentrations and approaches a constant value as the concentration increases. Also it was found that, by directly affecting the flow path of the flooding fluid at the pore scale in the porous medium, the surfactant showed the identical effect on the displacement efficiency of n-hexane at equilibrium state. The experimental observation results could provide important fundamental information on immiscible displacement of fluids in porous media and suggest the potential to improve the displacement efficiency of scCO2 by using surfactants.

• Economic and Environmental Geology
• /
• v.49 no.1
• /
• pp.13-22
• /
• 2016

The objectives of this study were to recover silica and iron oxides and $CO_2$ sequestration using serpentine via various acid dissolution and pH swing processes. Serpentine collected from Guhang-myeon in S. Korea were mainly composed of antigorite and magnetite consisting of $SiO_2$ (45.3 wt.%), MgO (41.3 wt.%), $Fe_2O_3$ (12.2 wt.%). Serpentine pulverized ($${\leq_-}75{\mu}m$$) and then dissolved in 3 different acids, HCl, $H_2SO_4$, $HNO_3$. Residues treated with acidic solution were recovered from the solution (step 1). And then the residual solution containing dissolved serpentine was titrated using $NH_4OH$. And pH of the solution increased up to pH=8.6 to obtain reddish precipitates (step 2). After recovery of the precipitates, the residual solution reacted with $CO_2$ and then pH increased up to pH=9.5 to precipitate white materials (step 3). The mineralogical characteristics of the original sample and harvested precipitates were examined by XRD, and TEM-EDS analyses. ICP-AES analysis was also used to investigate solution chemistry. The dissolved ions were Mg, Si, and Fe. The antigorite became noncrystralline silica after acid treatment (step 1). The precipitate at pH=8.6 was mainly amorphous iron oxide, of which size ranged from 2 to 10 nm and mainly consisting of Fe, O, and Si (step 2). At pH=9.5, nesquehonite [$Mg(HCO_3)(OH){\cdot}2(H_2O)$] and lasfordite [$MgCO_3{\cdot}H_2O$] were formed after reaction with $CO_2$ (step 3). The size of carbonated minerals was ranged from 1 to $6{\mu}m$. These results indicated that the acid treatment of serpentine and pH swing processes for the serpentine can be used for synthesis of other materials such as silica, iron oxides and magnesium carbonate. Also, This process may be useful for the precursor synthesis and $CO_2$ sequestration via mineral carbonation.

• Applied Chemistry for Engineering
• /
• v.19 no.5
• /
• pp.526-532
• /
• 2008

The proposed $CO_2$ storage technology in the present study is a one-step sequestration process that stabilizes $CO_2$ in a reactor with Serpentine. The advantage of this technology is associated with its high stability of final product so that the entire system is recognized as permanent environment-friendly $CO_2$ removal method. Since the sequestration reaction mechanisms are generally understood that carbonation reaction proceeds with very slow rate, so that pretreatment method to increases reaction rate of $CO_2$ carbonation reaction should be developed. To increase the reactivity of Serpentine with $CO_2$, two different methods of pretreatment are carried out in the present investigation. One is heat-treatment, the other is chemical pretreatment. In this study, only chemical pretreatment is considered leaching method of magnesium from Serpentine using sulfuric acid at the various reaction temperatures, times, and acid concentrations. Experimental results illustrated that pretreatment by sulfuric acid increases surface area of serpentine from $11.1209m^2/g$ to $98.7903m^2/g$ and extracts magnesium compounds. Single variable experiment demonstrated the enhancements of magnesium extraction with increased reaction temperature and time. Amount of magnesium extraction is obtained by using the data of ICP-AES as maximum extraction condition of magnesium is 2 M acid solution, $75^{\circ}C$ and 1hr. After performing chemical pretreatment, carbonation yield increased from 23.24% to 46.30% of weight.