• 대한전기학회:학술대회논문집
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• 대한전기학회 2005년도 제36회 하계학술대회 논문집 C
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• pp.1890-1892
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• 2005

Recently, high luminance and high efficiency were realized in OLEDs with multilayer structure including emitting materials such as metal-chelate complexes. New luminescent materials, [2- (2-hydroxyphenyl)-quinoline] (Zn(HPB)q), [(1,10-phenanthroline)- (8-hydroxyquinoline)] Zn(Phen)q was synthesized. Zn-Complexes have low molecular compound and thermal stability. The ionization potential(IP) and electron affinity(EA) of Zn-complexes were measured by cyclic-voltammetry(CV). The fundamental structure of the OLEDs was $ITO/{\alpha}$-NPD/Zn-Complex/Al and then we made device structure rightly in energy band gap. We using Zn(Phen)q as emitting layer and Zn(HPB)q as electron transport layer. We measured current density-voltage, luminance-voltage characteristics.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2007년도 제33회 하계학술대회 초록집
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• pp.241-241
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• 2007

• 한국환경농학회지
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• 제34권2호
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• pp.69-76
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• 2015

국내 주요 국가산업단지인 여수국가산업단지, 울산국가산업단지 및 시화 반월산업단지 주변 토양에 대해서 2006년부터 2008년까지 3년 동안 상반기와 하반기로 각각 나누어 시료를 채취한 다음 중금속 농도와 분포특성을 파악하고, 부화지수를 이용한 토양 중금속 오염도를 평가하였다. 여수국가산업단지의 토양 중 Cd, Hg, Pb, Zn 및 Ni 농도가 다른 두 국가산업단지에서의 농도보다 더 높게 나타났으며, 시화 반월산업단지의 토양에서는 Cu, As 및 Cr의 농도가 높게 나타났으나 토양오염우려기준은 초과하지 않았다. 대체적으로 여수국가산업단지의 토양 중 중금속 오염이 다른 두 국가산업단지지역에 비하여 더 높게 나타난 것은 종합석유화학공업기지인 여수국가산업단지에는 입주해있는 석유화학공장들에서 발생하는 오염물질과 또한 이들을 수송하는 자동차 등의 비점오염원의 영향을 더 많이 받았기 때문인 것으로 판단되었다. 연구대상 지역별로 각각 구분하여 토양 중금속 결과를 이용한 주성분 분석결과 세 지역 모두 고유치가 1 이상인 주성분 2개를 각각 추출할 수 있었다. 여수 및 시화 반월국가산업단지에서는 Cd, Cu, Pb, Cr, Zn 및 Ni이 요인 1로, 그리고 As 및 Hg이 요인 2로 설명되었으며, 이는 두 지역 모두 석유화학과 기계, 철강, 전기전자 등의 배출원 영향을 받는 것으로 판단되었다. 울산국가산업단지은 Cd, Pb, Cr 및 Ni이 요인 1로, 그리고 Cu, As, Hg 및 Zn이 요인 2로 설명되었으며, 이는 기계, 석유화학, 운송장비, 비제조 등의 배출원 영향을 받는 것으로 판단되었다. 부화지수(EF)에 의한 오염도 평가 결과 3개 지역 모두 Cd, Pb 및 Zn의 EF값이 1 이상으로 나타나 이들 항목들의 오염개연성이 타 항목들에 비하여 높은 것으로 판단되었다. Cr은 시화 반월국가산업단지에서 1을 초과한 것으로 나타났으며, 3개 지역 모두 Zn의 부화지수가 상당히 높게 나타났다. 이상의 결과를 미루어 볼 때, 국가산업단지 토양의 중금속 오염은 토양환경 및 주변 농업환경에 악영향을 미칠 수 있으므로 다양한 중금속 배출원을 파악하여 각 배출원별로 철저한 관리가 필요할 것으로 판단된다.

• The Korean Journal of Ecology
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• 제19권3호
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• pp.261-270
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• 1996

To investigate the degree of contamination from Korean coastal region, the concentrations of Cu, Pb, Zn and Cd in sediments, seawater and oyster (Crassostrea gigas) at Masan Bay, Onsan Bay, Daesan industrial complex and their control areas were analysed. Values for sediments, seawater and oyster in the industrial complex coastal region were higher than those in the control area except for seawater in Daesan. The values for dissolved phasc of Cu, Pb, Zn and Cd in seawater showed 0.3~1.75 ${\mu}g/l$, 0.013~0.12 ${\mu}g/l$, 0.20~6.14 ${\mu}g/l$ and 0.007~0.021 ${\mu}g/l$, respectively. The concentrations of Cu, Pb, Zn and Cd in sediments werd 12.0~47.8 ${\mu}g/g$, 6.16~59.5 ${\mu}g/g$, 43.0~230 ${\mu}g/g$ and 0.52~11.2 ${\mu}g/g$, respectively. The concentrations of Cu, Pb, Zn and Cd in oyster showed 12.1~85.6 ${\mu}g/g$, 0.267~1.48 ${\mu}g/g$, 1, 070~3, 250 ${\mu}g/g$ and 3.23~7.71 ${\mu}g/g$, respectively. The contents of heavy metals in oysters at industrial complex coastal region showed that they were not seriously contaminated compared with those of Mussel Watch (1992).

• 한국환경과학회지
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• 제16권12호
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• pp.1355-1367
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• 2007

This study summarizes the relations among $PM_{2.5}$ concentration, water-soluble ions concentration, metallic element Components characteristics and SPSS in negative ion and metallic element of $PM_{2.5}$ particle in Miryang.(By the urban area, the industrial complex area and the suburban area according to the season) $PM_{2.5}$ concentration of total 72 samples collected from 3 sites turned out to range from 3.47 to 34.7 ${\mu}g/m^3$, and the average concentration was the suburban area-the kin nup(16.00 ${\mu}g/m^3$) > the urban area-the roof of the old Miryang university(10.32 ${\mu}g/m^3$) > the industrial complex-Sapo industrial complex(10.29 ${\mu}g/m^3$). In particular, the suburban area had $PM_{2.5}$ concentration 1.5 times those of urban area, industrial complex. It was thought although the site was suburban and farm-side without pollutants around, it had a higher concentration value influenced by external factors including the brickyard, small-scale incinerator, driving range construction, construction on the Daegu-Busan express and the widening of the four-lane road between Miryang-Anyang nearby. As for water-soluble ions among $PM_{2.5}$ particle collected in Miryang area, $SO4_{2^-}$ accounted for 60% and $NO_{3^-}$, was 30% in spring and summer. And $NO_{3^-}$ accounted for 50% and $SO4_{2^-}$ was 35% in fall and winter. The AI value of metallic Components among $PM_{2.5}$ particle collected in Miryang area had a high value influenced by the apartment complex construction and the extension work of road. The industrial complex area had Zn concentration 3 times, and Fe concentration 2 times those of urban area and suburb area. When it comes to the relation with metallic elements in urban area, the highest coefficient of correlation was between Cr-Fe with 0.85, and Pb-Cd turned out in the reverse correlation. Among metallic elements, the coefficients of correlation between Zn and Cr, Mn, Fe, NI were high in industrial complex area. The highest coefficient of correlation was between Mn-Zn with 0.88, meanwhile Ni and Cu, Cd turned out in the reverse correlation in the suburb area. These coefficients of correlation are attributed to the difference in pollutant sources, rather than difference in pollutant and non-pollutant.

• 한국세라믹학회지
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• 제32권3호
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• pp.313-320
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• 1995

We investigated the preferred orientation, electrical and magnetic properties of the Mn-Zn ferrite thin films deposited on SiO2/Si(100) by ion beam sputtering. The Cu-added Mn-Zn ferrite thin films had a preferred orientation of (111) with a weak orientation, (311). While the Zn-added one had a strong (111) preferred orientation. The saturation magnetization of the Cu- or Zn-doped Mn-Zn ferrite films increased with increasing substrate temperature (Ts) due to the increase of grain size and the enhancement of crystallinity. For the same reason the coercivity of Cu- or Zn-doped Mn-Zn ferrite films deposited at low Ts increased with increasing Ts, but those of the films deposited at high Ts slightly decreased not only because the defect density of the films decreases but because more grains have multi-domains with increasing Ts. The resistivity of Cu- or Zn-added Mn-Zn ferrite thin fims measured by complex impedance method decreased with increasing Ts due to the ehhancement of crystallinity as well as due to the increase of grain size.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2000년도 춘계학술대회 논문집 전자세라믹스 센서 및 박막재료 반도체재료 일렉트렛트 및 응용기술
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• pp.76-79
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• 2000

The $Ba(Zn_{1/3}Ta_{2/3})O_3$ ceramics were prepared by conventional mixed oxide method. The structural properties of the BZT ceramics with the sintering temperature were investigated by XRD, SEM. The BZT ceramics have a complex-perovskite structure. The BZT ceramics sintered at $1550^{\circ}C$ had a superstructure plane of BZT(100). Increasing the sintering temperature, the bulk density and ordering were increased. The bulk density of the BZT ceramics sintered at $1550^{\circ}C$ was $7.50[g/cm^3]$. Increasing the sintering temperature, the average grain size were increased and pore were decreased.

• 한국항해항만학회지
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• 제31권8호
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• pp.671-674
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• 2007

본 논문에서는 ETC 시스템에서 다중반사로 인한 오신호 또는 시스템간의 간섭을 방지하기 위하여 사용될 전파흡수체를 설계 및 제작하였다. 자성손실 재료인 MnZn-ferrite, 도전손실 재료인 Carbon과 지지재인 CPE를 사용하여 조성비별로 전파흡수체 샘플을 제작하고, 측정된 샘플의 데이터로부터 최적의 조성비가 MnZn-ferrite : Carbon : CPE = 40 : 15 : 45 wt% 임이 확인되었다. 확인된 샘플로부터 재료정수 복소비유전율과 복소비투자율을 계산하여 시뮬레이션 하였으며, 이 결과를 토대로 전파흡수체를 실제 제작하여 전파흡수능을 분석한 결과 시뮬레이션과 실제측정 값이 거의 일치하는 것을 볼 수 있었다. 결과적으로 전파흡수체의 조성비 MnZn-ferrite : Carbon : CPE = 40 : 15 : 45 wt% 로 두께 3.38 mm, 주파수 5.8 GHz대에서 전파흡수능 20 dB 이상의 전파흡수체를 개발하였다.

• 대한화학회지
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• 제32권1호
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• pp.30-36
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• 1988

에틸렌디아민, 프로필렌디아민 및 디에틸렌트리아민의 구리(II), 카드뮴(II) 및 아연(II) 착이온의 安定度에 미치는 壓力의 影響을 폴라로그래피로 조사하였다. 支持電解質로서는 0.10M의 KN$O_3$ 용액을 쓰고, 킬레이트제의 농도는 0.01M에서 0.1M까지 변화시켰다. 압력이 1기압에서 1,500기압으로 증가함에 따라 금속착이온의 解離常數는 증가하였으며, 단위압력당 증가율은 $Cu(dien)_2^{2+}$의 1.1 ${\times} 10^{-3}$ %에서 Zn(en)$_2^{2+}$의 5.0${\times} 10^{-3}$ % 까지의 값으로 나타났다.

• 한국전기전자재료학회논문지
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• 제31권3호
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• pp.177-181
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• 2018

We prepared ZnS thin films via chemical bath deposition (CBD) in an aqueous solution of ammonia ($NH_3$) and hydrazine ($N_2H_4$). The composition ratio of hydrazine used was 0%, 17%, 22%, 29%, or 50%. We investigated the effects of hydrazine and ammonia on the growth, and the structural and optical properties of ZnS in terms of surface uniformity, voids, and grain size. We found that during the growth of ZnS films, hydrazine was very effective for improving the surface morphology and layer uniformity with fast layer formation, while it had no effect on the bandgap energy, $E_g$.