• Title/Summary/Keyword: $Y_2O_3$ additive

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Machinability and Strength of AlN-BN Ceramics (AlN-BN계 세라믹스의 기계가공성과 강도)

  • 감직상;하정수;정덕수;한경섭
    • Journal of the Korean Ceramic Society
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    • v.31 no.2
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    • pp.177-184
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    • 1994
  • AlN-BN ceramics with BN contents in the range of 10 to 40 wt% were prepared by hot pressing using no additive, or 3 wt%, Y2O3 or CaO, which are common densification aids for AlN. And their machinability, bend strength, and microstructures were investigated. Both the main and radial cutting forces decreased with increasing BN content in all three kinds of samples. For the BN contents of 30 wt% or above, the cutting forces were lower than that of a mild steel tested at a same condition. Especially in the case of main forces, the values were less than a quarter of that of a mild steel, indicating excellent machinability. Bend strength (when the tensile surfaces of specimens were perpendicular to the hot pressing direction) also decreased with BN content mainly due to the much lower Young's modulus of BN compared to AlN. With the composition of 30 wt% BN at which the AlN-BN ceramics started to show better machinability than a mild steel, the bend strength was 150 to 160 MPa, which is greater than that of machinable glass-ceramics of a mica system. With tensile surfaces parallel to the hot pressing direction, however, the bend strength obtained for the samples processed with the sintering acids showed low values (about 40 MPa), since most BN particles had such orientation that their cleavage planes (i.e., basal planes) were perpendicular to the pressing direction.

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A Study on the Effects of CNC Addition on Electrochemical Properties of Lead-acid Battery (CNC 첨가에 따른 납축전지의 전기화학적 특성연구)

  • Kim, Jee-Hoon;Mun, Jun-Ho;Moon, Seong-Yong;Ku, Bon-Keun;Kim, Ki-Won
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.21 no.3
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    • pp.279-285
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    • 2008
  • CNC (Carbon Nano Colloid) was used as an additive to the positive electrode to improve the discharge performance of sealed lead-acid batteries, The cathode active material ($PbO_2$) has a relatively low utility of less than 60 % compared with other kind of batteries, such as Ni-MH and Lithium ion, In this study, to overcome the above-mentioned problem we investigated the effects of CNC addition on the enhancement of electrical connection with not-utilized $PbO_2$ and resultantly electrical conductivity of electrode, We examined low rate discharge capacities, high rate discharge capacities and internal resistances of the batteries containing various amounts of CNC. From these results, we found out that the addition of CNC into the positive electrode made a significant improvement in high rate discharge capacity, We also suggested the optimum content of CNC material in positive electrode.

A Study of Efficient Removal of 2-Methylisoborneol and Geosmin by Pulsed Ultraviolet and Ultrasound (효율적인 2-Methylisoborneol, Geosmin의 제거를 위한 Pulsed UV 공정과 Ultrasound 공정의 비교 연구)

  • Han, Jonghun;Hur, Jiyong;Kim, Kangwook;Lee, Junyoung;Park, Wonseok;Lee, Jongyeol;Her, Namguk
    • Journal of Soil and Groundwater Environment
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    • v.20 no.4
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    • pp.1-7
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    • 2015
  • The degradation of off-flavors which is 2-Methylisoborneol (2-MIB) and geosmin by means of ultrasound (US) and pulsed ultraviolet (PUV) irradiation and its combination with catalyst (wire mesh, wire mesh coated TiO2, and TiO2) and additive (H2O2) were investigated via water system. A combination treatment of TiO2 and H2O2 heterogeneity with US (24 kHz) and PUV (6000 W) has shown improved results in destroying 2-MIB and geosmin, which may be attributed to chain reactions by the enhanced formation of hydroxyl radicals (·OH) through H2O2 dissociation and reactive oxide ions of TiO2 addition. Rapid degradation of off-flavors occurred within 2 min under PUV process with H2O2 100 mg/L (81.5% for 2- MIB; 79.3% for geosmin) and TiO2 100 mg/L (83.7% for 2-MIB; 79.8% for geosmin), while compared with H2O2 100 mg/L (58.4% for 2-MIB; 58.0% for geosmin) and TiO2 100 mg/L (59.2% for 2-MIB; 38.5% for geosmin) within 5 min under US process. Surprisingly, the emphasis was given on the comparison with the same injected energies between PUV and US on degradation efficiency. Based on the injected energy comparison, the US provided better degradation performance under equal input power of 200 kJ with H2O2 100 mg/L, while compared with H2O2 100 mg/L under PUV process. Our findings suggest that US can be more effective compared to PUV for the degradation of off-flavors in aspect of energy consumptions.

A Study on Frequency and the Physical Properties of Ni-Cu-Zn Ferrites with the Variation of Ni Addition and Temperature Prepared by Co-Precipitation Method (공침법으로 제조한 Ni-Cu-Zn Ferrite의 Ni 첨가량과 온도에 따른 주파수 및 물리적 특성 연구)

  • Kim, Moon-Suk;Koh, Jae-Gui
    • Journal of the Korean Magnetics Society
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    • v.15 no.5
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    • pp.282-286
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    • 2005
  • Ni-Cu-Zn ferrites were prepared by the co-precipitation and ferrite microwave absorbers on low temperature sintering were investigated in this work. The properties of its microwave absorbing and physical were analyzed into variations of Ni addition, calcination temperature, sintering temperature. From the analysis of X-ray diffraction patterns, we can see that all the particles have only a single phase spinel structure. In addition, the powders particle size distribution obtained the nano size. By increasing the Ni additive, the permeability of the powders was decreased and the loss factor increased at sintering temperature $1100^{\circ}C$. Also, we considered that it can used high frequency rage. We found that the $(Ni_{0.7}Cu_{0.2}Zn_{0.1}O)_{1.02}(Fe_{2}O_3)_{0.98}$ appeared microwave absorbing properties better than other composition.

Effect of Ni addition on anodically deposited $MnO_2$ film (Anodic deposition된 $MnO_2$ 막에 있어서 Ni 첨가 영향)

  • Kim, Bong-Seo;Lee, Dong-Yoon;Lee, Hee-Woong;Chung, Won-Sub
    • Proceedings of the KIEE Conference
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    • 2003.07c
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    • pp.1535-1537
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    • 2003
  • Manganese oxide electrode was designed to improve electrical conductivity for dimensionally stable anode(DSA) using discreet variation (DV)-X${\alpha}$ method. It was calculated in DV-X${\alpha}$ method that the addition of nickel to manganese oxide reduce the energy band gap of manganese oxide electrode. Therefore, it is estimated that nickel in 3 additive elements of Ti, Ni and Sn is the best candidate to improve the electrical conductivity of manganese oxide. The anodically deposited manganese oxide which was produced in 0.2M $MnSO_4$ and 0.2M (Mn,Ni)$SO_4$ solution had $MnSO_4$ structure which was identified by XRD. The $MnSO_4$ films produced in both solutions over than 50mA/$cm^2$ of current density and long deposition time of 600sec showed low adhesion with Ti substrate.

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Electrochemical Behavior of Lithium-Iron Oxide Electrode and Measurement of Chemical Diffusion Coefficient of Lithium (리튬-철계 산화물 전극의 전기화학 거동 및 리튬의 화학확산 계수 측정)

  • Lee Joung-Jun;Chong Won-Jung;Ju Jeh-Beck;Sohn Tai-Won;Cho Won-Il;Cho Byung-Won;Kim Hyung-Sun
    • Journal of the Korean Electrochemical Society
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    • v.4 no.4
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    • pp.139-145
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    • 2001
  • Various compositions of iron oxide based materials as a cathode of lithium secondary battery have been fabricated and tested with electrochemical method. A layered form of $LiFeO_2$ was synthesized by mixing and heating the initial materials of $FeCl_3\;6H_2O,\;LiOH$ and NaOH at low temperature. The effect of changing the precursors composition was investigated. As a result, when increasing the additive amount of NaOH, the capacity of the electrode is decreased but the performance and declining rate of capacity became smaller. $LiFeO_2$ synthesized with the weight ratio of $NaOH/FeCl_3/LiOH,\;2/1/7$ showed the largest capacity, but the discharging efficiency was sharply decreased after 30 cycles. Charge-discharge tests of lithium cells with $LiFeO_2$ cathode having the layer structure were performed. This cell showed the reversibility in the range of 1.5-4.5V of cell voltage. By using CPR method, chemical diffusion coefficients were measured in 1M $LiPF_6/EC/DEC$ solution. The value of chemical diffusion coefficient decreased with increasing the lithium content x, In 0.5$10^{-11}^cm^2/s$.

Estimation of Direct and Service Sire Genetic Parameters for Reproductive Traits in Yorkshire

  • Kim, B.W.;Kim, S.D.;Lee, I.J.;Chung, K.H.;Kwon, O.S.;Ha, J.K.;Lee, J.G.
    • Asian-Australasian Journal of Animal Sciences
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    • v.15 no.9
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    • pp.1232-1236
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    • 2002
  • Direct and service sire genetic parameters for total number of pigs born (TNB), number of pigs born alive (NBA), total pig weight at birth (TWB), and average pig birth weight (ABW) were estimated by DF-REML under a multiple trait animal model. Data on 3,078 litters of the Yorkshire from Jan, 1975 to Dec, 1998 at National Livestock Research Institute were obtained. The animal model included fixed contemporary group effects and random additive direct, service sire, and residual effects. Additive genetic relationships among animals were included. A separate relationship matrix for service sires and their sire was also included. Additive direct heritability estimates for TNB, NBA, TWB, and ABW were 0.19, 0.18, 0.25 and 0.39, respectively. Service sire heritability estimates for TNB, NBA, TWB, and ABW were 0.02, 0.01, 0.02 and 0.01, respectively. The genetic and phenotypic correlations of TNB with NBA estimated in this study were 0.81 and 0.81, respectively, and the genetic and phenotypic correlations of TNB with TWB estimated were 0.82 and 0.76, respectively. Results indicate that service sires account for 1 to 2% of the total variation for TNB, NBA, TWB, and ABW. Further investigation is needed to determine whether the service sire effect is primarily genetic or environmental.

Electrodeposition of Manganese from Ferromanganese Slag with Ammonium Sulfate (황산암모늄에 의한 훼로망간 슬랙으로부터 망간의 전착)

  • Duk Mook Kim
    • Journal of the Korean Chemical Society
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    • v.29 no.4
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    • pp.390-396
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    • 1985
  • The manganese was extracted from ferromanganese slag with 6N ammonium sulfate and purified with ammonium sulfide. The current efficiencies were substantially increased when small amounts of selenious acid is used as an additive. Stainless steel was used as cathodic electrode and lead (+1% Ag) as anodic electrode. The effects of several variables were investigated, and the optimum conditions were found to be; 40g/l Mn in electrolyte at pH 7.0 with 1$20g/l (NH_4)_2SO_4$, Cathode current density 60mA/cm$^2$, Current efficiency 90% and up at the temperature about $25^{\circ}C.$ The metal produced has been consistantly of high quality.

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Electrophoretic Deposition of YBCO powder in mixed suspension solution of iso-prophanol and iso-buthanol (이소프로판올과 이소부탄올 용매에서의 YBCO 분말 영동전착)

  • Soh, Dae-Wha;Li, Ying-Mei;Park, Jung-Cheul;N., Korobova
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.11b
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    • pp.288-291
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    • 2001
  • It is very important to select suspension solution for forming electrophoretic deposited YBCO thick mm, because it is heavily affected to its superconducting properties. In this paper, high-temperature superconductor films of $YBa_{2}Cu_{3}O_{7-x}$ were fabricated by electrophoretic deposition (EPD) from alcohol-based suspension such as iso-propanol, iso-butanol, and their mixture. For the formation of YBCO dense and adherent coating on a silver wire by EPD, 1 % PEG(1000) 2 ml, as a additive for making their surface crack-free, was used for electrophoresis. As a results, the cracks were considerably decreased and the superconducting critical current density $(J_e)$ without/with PEG was $1200A/cm^2$ and $2020A/cm^2$, which films deposited in mix iso-propanol and iso-butanol suspension.

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Electrophoretic Deposition of YBCO powder in mixed suspension solution of iso-prophanol and iso-buthanol (이소프로판올과 이소부탄을 용매에서의 YBCO 분말 영동전착)

  • ;;;Korobova N.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.11a
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    • pp.288-291
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    • 2001
  • It is very important to select suspension solution for forming electrophoretic deposited YBCO thick film, because it is heavily affected to its superconducting properties. In this paper, high-temperature superconductor films of YBa$_2$Cu$_3$$O_{7-x}$ were fabricated by electrophoretic deposition (EPD) from alcohol-based suspension such as iso-propanol, iso-butanol, and their mixture. For the formation of YBCO dense and adherent coating on a silver wire by EPD, 1% PEG(1000) 2 $m\ell$, as a additive for making their surface crack-free, was used for electrophoresis. As a results, the cracks were considerably decreased and the superconducting critical current density (J$_{c}$) without/with PEG was 1200 A/$\textrm{cm}^2$ and 2020 A/$\textrm{cm}^2$, which films deposited in mix ism-propanol and iso-butanol suspension.ion.

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