• 한국세라믹학회지
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• 제47권6호
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• pp.485-490
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• 2010

In our previous studies, continuous SiC fiber-reinforced SiC-matrix composites ($SiC_f$/SiC) had been fabricated by two different slurry infiltration methods: vacuum infiltration and electrophoretic deposition (EPD). 12 wt% of $Al_2O_3-Y_2O_3$-MgO with respect to SiC powder was used as additives for liquid-phase assisted sintering. After hot pressing at $1750^{\circ}C$ under 20 MPa for 2 h in Ar atmosphere, a high composite density could be achieved for both cases, whereas the problems such as large grain size and non-uniform distribution of liquid phase were observed, which was resulted in the relatively poor mechanical properties of composites. Therefore, efforts have been made to reduce the grain growth during the sintering, including the optimization for hot pressing condition and utilization of spark plasma sintering using a SiC monolith. Based on the results, spark plasma sintering was found to be effective method in decreasing the amount of sintering additive, time and grain growth, which will be explained in comparison to the results of hot pressing in this paper.

• 한국세라믹학회지
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• 제20권4호
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• pp.324-332
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• 1983

In this studies resistivity thermal expansion and microstructure of the Forsterite Porcelain as a high frequency insulator were investigated. The body containing Zn-glass shows higher resistivity than any other body. The bodies containing K, Ba, Cd-glass respectively consist of fine crystals of mosaic type. The bodies containing Bi, Zn, Zr-glass repectively included more large crystals because of the grain growth and coherence of fine particles In the 4 series Forsterite containing excess MgO 0-6% the thermal coefficients of the bodies increased with the increasing of excess MgO and the bodies have conspicuously high thermal expansion coefficients when 15% excess $BaCO_3$ was added to. The resistivities of additive bodies of $BaCO_3$ 0, 5, 10% in Forsterite containg excess MgO 2% are higher than any other that of composition. Bacause the growing of Forsterite crystals was restrained with the increasing of excess MgO $BaCO_3$ their grain size became fine and their grain boundaries were decomposed and also the glass phase having high refractive inder was increased. The higher the firing temperature increased the more the process of crystal growing was progressed.

• 한국재료학회지
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• 제20권3호
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• pp.142-147
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• 2010

Nano-sized $BaNd_2Ti_5O_{14}$ powders were prepared by the spray pyrolysis process. Sucrose used as the organic additive enabled the formation of nano-sized $BaNd_2Ti_5O_{14}$ powders. The powders prepared from the spray solution without sucrose had a spherical shape, dense structure and micron size before and after calcination. However, the precursor powders prepared from the spray solution with sucrose had a large size, and hollow and porous morphology. The precursor powders had an amorphous crystal structure because of the short residence time of the powders inside the hot wall reactor. The complete decomposition of sucrose did not occur inside the hot wall reactor. Therefore, the precursor powders obtained from the spray solution with sucrose of 0.5M had a carbon content of 39.2wt.%. The powders obtained from the spray solution with sucrose of 0.5M had a slightly aggregated structure of nano-sized primary powders of $BaNd_2Ti_5O_{14}$ crystalline phase after calcination at $1000^{\circ}C$. The calcined powders turned into nano-sized $BaNd_2Ti_5O_{14}$ powders after milling. The mean size of the $BaNd_2Ti_5O_{14}$ powders was 125 nm.

• 한국재료학회지
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• 제25권8호
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• pp.423-428
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• 2015

Impedancemetric $NO_x$ (NO and $NO_2$) gas sensors were designed with a stacked-layer structure and fabricated using $LaCr_xCo_{1-x}O_3$ (x = 0, 0.2, 0.5, 0.8 and 1) as the receptor material and $Li_{1.3}Al_{0.3}Ti_{1.7}(PO_4)_3$ plates as the solid-electrolyte transducer material. The $LaCr_xCo_{1-x}O_3$ layers were prepared with a polymeric precursor method that used ethylene glycol as the solvent, acetyl acetone as the chelating agent, and polyvinylpyrrolidone as the polymer additive. The effects of the Co concentration on the structural, morphological, and $NO_x$ sensing properties of the $LaCr_xCo_{1-x}O_3$ powders were investigated with powder X-ray diffraction, field emission scanning electron microscopy, and its response to 20~250 ppm of $NO_x$ at $400^{\circ}C$ (for 1 kHz and 0.5 V), respectively. When the as-prepared precursors were calcined at $700^{\circ}C$, only a single phase was detected, which corresponded to a perovskite-type structure. The XRD results showed that as the Co concentration of the $LaCr_xCo_{1-x}O_3$powders increased, the crystal structure was transformed from an orthorhombic phase to a rhombohedral phase. Moreover, the $LaCr_xCo_{1-x}O_3$ powders with $0{\leq}x<0.8$ had a rhombohedral symmetry. The size of the particles in the $LaCr_xCo_{1-x}O_3$powders increased from 0.1 to $0.5{\mu}m$ as the Co concentration increased. The sensing performance of the stack-structured $LaCr_xCo_{1-x}O_3/Li_{1.3}Al_{0.3}Ti_{1.7}(PO_4)_3$ sensors was found to divide the impedance component between the resistance and capacitance. The response of these sensors to NO gas was more sensitive than that to $NO_2$ gas. Compared to other impedancemetric sensors, the $LaCr_{0.8}Co_{0.2}O_3/Li_{1.3}Al_{0.3}Ti_{1.7}(PO_4)_3$ sensor exhibited good reversibility and reliable sensingresponse properties for $NO_x$ gases.

• 한국산학기술학회논문지
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• 제13권8호
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• pp.3800-3805
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• 2012

본 논문에서는 도심 열섬현상 방지 및 에너지 효율을 높이기 위하여 적외선 반사율이 30%이상인 건물 내 외장재용 흑색 차열안료 및 도료에 대한 연구를 하였다. 안료는 $Fe_2O_3$과 $Cr_2O_3$의 혼합원료를 $900{\sim}1,200^{\circ}C$에서 소성하여 합성하였으며, 도료는 합성한 안료에 아크릴수지와 기타첨가제를 사용하여 제조하였다. 연구결과, Cr과 Fe을 1:0.9 몰비로 혼합하여 $1,000^{\circ}C$에서 소성한 안료의 발색도가 가장 우수하였고, 차열안료 20%에 분산제 1.5%를 첨가하여 제조한 차열도료로 $125{\mu}m$ 두께의 도막을 형성시켰을 때 적외선 반사가 가장 우수하였다. 차열도료와 일반도료의 표면온도 차이는 $36.5^{\circ}C$로 나타났으며 700~2,500nm 파장대의 적외선 반사율(TSR)은 39.3%로 측정되었다. 또한, 500시간의 내후성 평가에서 색상변화는 거의 나타나지 않았다.

• 한국전기전자재료학회논문지
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• 제13권3호
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• pp.188-192
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• 2000

In this study PZT etching was performed using planar inductively coupled Ar/Cl$_2$/BCI$_3$ plasma. The etch rate of PZT film was 2450 $\AA$/min at Ar(20)/BCl$_3$(80) gas mixing ratio and substrate temperature of 8$0^{\circ}C$. X-ray photoelectron spectroscopy(XPS) analysis for films composition of etched PZT surface was utilized. The chemical bond of PbO is broken by ion bombardment and Cl radical, and the peak of metal Pb in a Pb 4f narrow scan begins to appear upon etching. As increasing additive BCl$_3$content the relative content of oxygen decreases rapidly in contrast with etch rate of PZT thin film. So we though that the etch rate of PZT thin film increased because abundant B and BCl radicals made volatile oxy-compound such as B$_{x}$/O$_{y}$ and/or BClO$_{x}$ bond. We achieved etch profile of about 80$^{\circ}$ at Ar(20)/BCl$_3$(80) gas mixing condition and substrate temperature of 8$0^{\circ}C$TEX>X>.

• 에너지공학
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• 제7권1호
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• pp.24-34
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• 1998

본 연구에서는 ZnO 및 TiO2의 혼합소결시에 접합제 및 첨가제의 종류 및 구성비가 아연계 흡수제의 탈황 및 재생반응 특성에 미치는 영향을 분석하였다. 접합제로 bentomite와 kaolinite를, 첨가제로는 Mo계, Ni계, Cu계를 선정하여 함량을 변화시켰다. 흡수제에 대한 탈황-재생-탈황반응의 반복실험을 위해 연천칭분석기(TGA)계를 조립하여 각 흡수제에 대해 탈황-재생반응의 2사이클 반복실험특성을 조사하였다. XRD분석결과 접합제 및 첨가제의 종류 및 함량에 관계없이 대부분 Zn2 TiO4 와 Zn2 TiO8가 형성됨을 확인하였다. Kaolinite를 접합제로 사용한 탈황제의 표면적이 더 컸으며 접합제의 함량이 증가할수록 표면적과 세공부피는 증가하였다. 탈황반응은 68$0^{\circ}C$, 재생반응은 73$0^{\circ}C$가 적합하였으며 3 mol%의 CuO를 첨가제로 사용한 경우 탈황과 재생반응이 모두 우수하였다. NiO를 첨가제로 사용한 경우 재생성이 우수하였으며 MoO3를 첨가제로 사용한 경우 성능이 우수하지 못하였다. 3 mol%의 CuO를 첨가제로 사용한 흡수제에 대해 고정층에서 연속반복반응실험을 한 결과 반응성이 높게 유지되었다.

• 한국환경보건학회지
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• 제26권2호
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• pp.80-90
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• 2000

To determine the effect of air pollutants in Taejon City, we used medical insurance claim data for asthma and the data monitored from telemetry system of Ministry of Environment for air pollutants and meteorological factors. From November 1st, 1997 to October 31th, 1998, 95,629 asthma patients were covered by medical insurance at Taejon City. Subjects were composed of 49,563 males (51.8%) and 46.336 females(48.2%), and among the subjects, the proportion under 15 years old was 62.8% of the total. During the study period, daily mean concentrations of each air pollutants-So2, No2, CO, O3 and TSP-were 9.8 ppb, 17.6 ppm, 1.414 pp, 17.3 ppb and 60.6 $\mu\textrm{g}$/㎥, respectively, which were lower than each of the environmental recommended exposure levels, Through the simple correlation analysis between each air pollutants and meteorological factors, O3 was positively correlated with temperature, but negatively with relative humidity. TSP, SO2, NO2, CO were negatively correlated with meteorological factors, and these air pollutants except O3 were positively correlated with each other, O3 was correlated with TSP positively but the others negatively. Estimating relative risks of each air pollutant with the baseline general additive model, daily mean concentrations of TSP(Lag 0, 1, 4, 5day) were significantly associated with the increase of the asthma admission. Two age subgroups, under 15 and 15~54 have shown various association of all air pollutants concentration with the asthma admission. However, in case of over 54 age subgroup, only TSP(Lag 0 day) among all air pollutants was associated with the asthma admission. Each of ambient outdoor pollutant concentrations in Taejon City are significantly associated with the admission of asthma patients even though all concentrations in Taejon City are significantly associated with the admission of asthma patients even though all concentrations were much lower than the environmental recommended exposure levels. Therefore, continuous effort lowering air pollutant concentration and introducing an active environmental conservation policy should be implanted for preventing hazardous health effects. Considering major proportion of asthma admissions, high susceptibility and less confounding factors among the age subgroup under 15 will be a useful target population for assessing such health effect monitoring.

• 공업화학
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• 제21권4호
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• pp.417-423
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• 2010

파라자일렌(p-xylene) 분리용 흡착제로서 효과적인 그래뉼 형태의 바인더리스 ZSM-5 성형체를 제조하는 방법을 검토하였다. $SiO_2/Al_2O_3$ = 50인 ZSM-5 결정분말에 무기 바인더인 colloidal silica sol 30 wt% 용액과 유기첨가물인 microcrystalline cellulose를 첨가하여 구형화한 후, 소성, 바인더리스 처리, ${NH_4}^+$ 이온교환, 활성화 등의 과정을 거쳐 충분한 강도(0.721 kgf) 및 높은 결정화도(94.6%)와 넓은 BET 비표면적($379.2m^2$/g)을 갖는 흡착제를 제조하였다. 제조된 성형체의 흡착특성을 평가하기 위해 자일렌 3가지 이성질체를 1 : 1 : 1의 무게비로 혼합하여 $100^{\circ}C$에서 회분식 흡착실험을 수행한 결과 제조된 바인더리스 ZSM-5 성형체는 상용흡착제보다 파라자일렌에 대해 높은 선택적 흡착성능을 나타냈다.

• 한국추진공학회지
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• 제19권6호
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• pp.42-53
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• 2015

고체추진제에 첨가되는 알루미늄 입자의 크기에 따른 탄소 복합재 노즐의 기계적 삭마특성 변화를 예측하는 연구를 수행하였다. 추진제에 첨가되는 알루미늄 입자의 초기 크기에 따라 연소생성물 응집체($Al(l)/Al_2O_3(l)$)의 크기와 분포를 예측할 수 있는 모델을 개발하여 사용하였으며, 모델 예측 결과로 얻어지는 응집체의 크기를 초기조건으로 하여 상용 수치해석 프로그램(STAR CCM+)을 이용한 복합재 노즐에서의 기계적 삭마특성 해석을 수행하였다. 본 연구를 통해 초기 알루미늄 첨가제의 크기가 작을수록 응집체의 크기가 작아지고, 기계적 삭마가 감소하는 특성을 확인하였으며, 특히 나노입자를 사용할 때 기계적 삭마가 확연히 개선됨을 확인하였다.