• Title/Summary/Keyword: $Y-BaCeO_3$

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Effect of $CeO_2$-addition and Particle Size of Doping Material on Characteristic of High-$T_c$ Superconducting Thick Film Using Diffusion Process ($CeO_2$첨가와 도포물질의 입자크기가 화산공정을 이용한 고온초전도 후막의 특성에 미치는 영향)

  • 임성훈;강형곤;홍세은;윤기웅;황종선;한병성
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.14 no.2
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    • pp.152-157
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    • 2001
  • For the fabrication of YBa$_2$Cu$_3$O$_{x}$ thick film using diffusion process between $Y_3$BaCuO$_{5}$ and BaO+CuO, each material was selected as substrate and doping material. In this paper, we investigated the characteristic of YBa$_2$Cu$_3$O$_{x}$ thick film due to both addition of CeO$_2$into substrate and initial particle size of doping material. Through X-ray diffraction patterns and SEM photographs, the variation of composition and thickness of the formed phase was observed. It was from the experiment obtained that the addition of CeO$_2$into $Y_2$BaCuO$_{5}$ substrate and the initial particle size of doping material play important part in promoting the reaction between substrate and doping material.aterial.

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Two-wave mixing in Ce:$BaTIO_3$, Mgo:$LiNbO_3$ and :$LiNbO_3$ crystals (Ce:$BaTIO_3$, Mgo:$LiNbO_3$와 Fe:$LiNbO_3$ 결정에서의 이광파혼합 실험)

  • 주원제;박주형;곽장만;오차환;송석호;한양규;김필수
    • Korean Journal of Optics and Photonics
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    • v.9 no.6
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    • pp.423-427
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    • 1998
  • Two wave mixing experiments in $LiNbO_3$, $BaTiO_3$ are carried out, and the characteristics as optical information processing device are investigated. Examined crystals are commonly used ones, such as 0.03% mol Ce-doped $BaTiO_3$, 0.03% mol Fe-doped $LiNbO_3$, and 6% mol MgO-doped $LiNbO_3$. $Ar^+$ ion laser is used as the writing beam, and He-Ne Laser is used as the reading beam. The recording-decay and erasing characteristics of diffraction gratings, the time constants, and also the angular selectivities are measured for each crystals and compared.

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Crystal growth and pinning enhancement of directionally melt-textured$(Y_{0.5}Nd_{0.25}Sm_{0.25})Ba_2Cu_3O_y$ oxides in air

  • Kim So-Jung
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.15 no.5
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    • pp.188-192
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    • 2005
  • High $T_c(Y_{0.5}Nd_{0.25}Sm_{0.25})Ba_2Cu_3O_y[(YNS)-123]$ superconductors with/without $CeO_2$ additive were systematically investigated by the zone melt growth process in air. Cylindrical green rods of (YNS)-123 oxides were fabricated by cold isostatic pressing (CIP) method using rubber mould. A sample prepared by this method showed well-textured microstructure, and $(Y_{0.5}Nd_{0.25}Sm_{0.25})_2BaCuO_5[(YNS)211]$ nonsuperconducting inclusions were uniformly dispersed in large $(Y_{0.5}Nd_{0.25}Sm_{0.25})Ba_2Cu_3O_y$[(YNS)123] superconducting matrix. In this study, optimum melting temperature and growth rate were $1100^{\circ}C$ and 3 mm/hr, respectively. The directionally melt-textured (YNS)-123 sample with $CeO_2$ additive showed an onset critical temperature $(T_c)\;T_c{\geq}93K$ and sharp superconducting transition.

The effect of Attrition milling and calcining temperature on the microstructure and electrical properties of non-reduction PTCR-$BaTiO_3$ Ceramics (내환원 $BaTiO_3$ 세라믹스의 PTCR특성 및 미세구조에 대한 Attrition milling과 하소온도가 미치는 영향)

  • Lee, Jeong-Cheol;Myoung, Seong-Jae;Chun, Myoung-Pyo;Cho, Jeong-Ho;Kim, Byung-Ik;Sin, Dong-Wook
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.06a
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    • pp.288-288
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    • 2007
  • 본 연구에서 내환원성 $BaTiO_3$의 PTCR(Positive Temperation Coefficient Resistance) 특성 및 미세구조에 대한 분쇄 및 출발 원료들의 하소 조건의 영향을 연구하였다. $BaCO_3$, $TiO_2$, $CeO_2$를 Attrition milling 하여 1차 혼합 및 분쇄한 후 건조하여 혼합분말을 얻었으며, $(Ba_{1-x}Ce_x)TiO_3$를 합성하기 위하여 $1000^{\circ}C{\sim}1200^{\circ}C$ 공기중에서 하소하였다. 각 하소온도에서 제조한 $(Ba_{1-x}Ce_x)TiO_3$에 첨가제를 2차 혼합하고 초미분쇄하여 분말을 제조하였다. 직경 5mm 의 시편을 제조하여 환원 및 재산화 분위기에서 소결을 한 후 상온저항값 및 R-T특성을 측정하였고 SEM 을 통해 미세구조를 관찰하였다. 또한 하소 후 온도에 따른 상분석을 XRD를 통하여 분석하였다. 그 결과 하소온도가 증가함에 따라 상온저항값은 감소하는 경황을 보였으며 PTC특성은 감소하다가 증가하는 경향을 보였다. 초미분쇄에 따른 입자크기는 $1{\mu}m$이하로 작아졌으며 미립화가 됨에 따라 하소/소결온도에 앙향을 줄 것으로 사료된다.

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Investigation on the Preparation and Electrical Conductivity of $CeO_2$-System Solid Electrolytes ($CeO_2$계 복합산화물 고체 전해질 제조와 전기전도 특성에 관한 연구)

  • ;dladydan
    • Journal of the Korean Ceramic Society
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    • v.32 no.2
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    • pp.155-162
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    • 1995
  • Solid oxide electrolytes of the MCe1-xGdxO3-x/2 (M: Ba, Mg. x=0.0-0.20) system were prepared using powders synthesized by the "liquid mix" method and calcined from the cross-linked polyacrylic polymer. The specimens were analyzed using XRD and SEM with EDX, and the sintering behavior of the electrolytes and their electrical conductivity were also studied. Although Mg-cerate is relatively inferior to Ba-cerate in the sinterability and chemical homogenity(EDX analysis data), both the Ba- and the Mg-cerate electrolytes at 80$0^{\circ}C$ show their maximum conductivities at x=0.10 and their values are in the same order of magnitude, i.e., 3.5$\pm$0.17.10-2(ohm.cm)-1.ohm.cm)-1.

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Highly Efficient Mutually Pumped Phase Conjugators Using BaTiO3:Ce

  • Shin, Seung-Ho;Dou, Shuo-Xing
    • Journal of the Optical Society of Korea
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    • v.8 no.2
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    • pp.79-82
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    • 2004
  • High-efficiency mutually pumped phase conjugation (MPPC) has been realized in a BaTiO$_3$:Ce crystal in the bridge geometry. The laser source is a dye laser operating from 580 to 650 nm. We have observed that, with a beam ratio of 1, self-pumped phase conjugation (SPPC) appears and competes with MPPC at short wavelengths while it disappears at long wavelengths. When the beam ratio is slightly higher than 1, SPPC no longer occurs. Phase conjugate reflectivity near 500% has been obtained at a beam ratio of 70. Our experiments demonstrate that Ce-doped BaTiO$_3$crystals, which have already been found efficient in SPPC experiments, are also efficient for the generation of MPPC.

The Influence of the Dielectric Properties BaO-Nd$_2$O$_3$-TiO$_2$Ceramics for the Additions of CeO$_2$ (산화세륨의 첨가가 BaO-Nd$_2$O$_3$-TiO$_2$계 세라믹 유전체의 유전특성에 미치는 영향)

  • 이석진;이창화;이상석;최태구
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1992.05a
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    • pp.137-139
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    • 1992
  • By addition of 1~5mol% CeO$_2$to powders with composition in the BaO-Nd$_2$O$_3$-TiO$_2$, temperature coefficient of permittivity of sintered ceramics may be decreased from approximately-140ppm/$^{\circ}C$~-65ppm/$^{\circ}C$. Dense, fine grained ceramics were prepared with permitivity within the range of 78~92 and Q above 1000.

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