• 제목/요약/키워드: $V_2O_5$

검색결과 3,778건 처리시간 0.032초

리튬 이차전지의 정극 물질로서 $Li_2O-P_2O-V_2O_5$ 유리의 충방전 특성 (Charge/discharge Properties of $Li_2O-P_2O-V_2O_5$ Glasses as a Cathode Material for Lithium Rechargeable Battery)

  • 송희웅;구할본;손명모;이헌수
    • 한국전기전자재료학회:학술대회논문집
    • /
    • 한국전기전자재료학회 1999년도 추계학술대회 논문집
    • /
    • pp.383-386
    • /
    • 1999
  • The importance of rechargeable lithium cells has been emphasized. So a large variety of materials has been discovered and evaluated for use as reversible cathodes and electroyltes. This paper examines the charge/discharge properties and the charge/discharge cycling life of Li$_2$O-P$_2$O-V$_2$O$_{5}$Li cells. In audition, DTA tests were carried out on Li$_2$O-P$_2$O-V$_2$O$_{5}$ glass. As a result the best performance was achieved when 0.3Li$_2$O-0.1P$_2$O$_{5}$-0.6V$_2$O$_{5}$Li cells was mixed with SP270. that is discharge capacity of 240mAh/g have been achieved. In addition this battery exhibited good cycling performance. Considering these results we expected utilization of the Li$_2$O-P$_2$O-V$_2$O$_{5}$ glass as a cathode material in a secondary battery.y battery.

  • PDF

고정원에서 배출되는 $NO_x/SO_x$의 동시제거를 위한 SCR 촉매의 제조법에 관한 연구: I. $V_2O_5-MoO_3/TiO_2$ 촉매들의 표면특성과 반응성 (Studies on the Preparation for the Simultaneous Removal of NO and $SO_2$ from Stationary Sources I.Surface properties and reactivity of $V_2O_5-MoO_3/TiO_2$ catalysts)

  • 구미화;정석진
    • 한국대기환경학회지
    • /
    • 제8권1호
    • /
    • pp.58-67
    • /
    • 1992
  • For removing $NO_x$ and $SO_x$ from the flue gases emitted from stationary sources, $V_2O_5-MoO_3/TiO_2$ catalysts were prepared by the conventional impregnation method (aqueous solution) and a sort of surface fixation method(nonaqueous solution) as reported excellent reproducibility catalysts. And these catalysts observed their catalytic activities as well as their surface properties. V-Mo-O oxide, prepared from nonaqueous solution of $VOCl_3$ and $Mo(CO)_6$ and aqeous solution method, was supported as amorphous state by XRD and SEM measurements. The infrared spectra of fresh and used catalysts showed that in used catalysts, V=O bands decreased and new bands of vanadium oxysulfate bands were very sensitive. So the catalysts prepared from nonaqueous solution may bring about the high activity. Results from catalytic activity measurements at 350$^\circ$C, in the presence of $SO_2, NO$ conversion was more increased than in absence of $SO_2$. As the $MoO_3$ was added to $V_2O_5/TiO_2 system, SO_2$ conversion increased. It found that from the results, $V_2O-5-MoO_3/TiO_2$ catalysts prepared from an nonaqueous solution may bring about the high activity for both the reaction of NO and $SO_2$ removal.

  • PDF

Flux가 Lithium Ferrite의 미세구조 및 메모리코어 특성에 미치는 영향 (The Effects of Flux on the Microstructure and Memory Core Characteristics of Lithium Ferrites)

  • 임호빈
    • 한국세라믹학회지
    • /
    • 제16권1호
    • /
    • pp.26-30
    • /
    • 1979
  • The microstructures and memory core characteristics of substituted lithium ferrites with addition of $Bi_2O_3$, $V_2O_5$, $Nb_2O_3$, and $P_2O_5$ were investigated. The effects of composite flux on the sintering of the substituted lithium ferrites were also studied. The results show that the addition of $Bi_2O_3$, $V_2O_5$, and $Nb_2O_5$ enhances sintering whereas $Sb_2O_3$ and $P_2O_5$ inhibits it, and that the addition of $Nb_2O_5$ results in uniform grain size while the addition of $Bi_2O_3$ or $V_2O_5$ results in non-uniformity in grain size. When $P_2O_5$ was added with $V_2O_5$ or $Bi_2O_3$, however, it results in uniform grain size and improved memory core properties.

  • PDF

우레아 및 포름산을 이용한 바나듐 산화물 나노소재의 합성 및 전기화학적 특성 (Vanadium Oxide Nanomaterials Prepared Using Urea and Formic Acid as Cathodes for Lithium Batteries)

  • 박수진;이만호;박희구
    • 공업화학
    • /
    • 제21권2호
    • /
    • pp.211-216
    • /
    • 2010
  • 우레아와 포름산을 이용한 균일침전법으로 $(NH_4)_{0.3}V_2O_5$$V_2O_5$ 나노소재를 합성한 후 TGA, SEM, FT-IR, XRD, 선형 전압전류법 등을 이용하여 물성과 전기화학적 특성을 조사하였다. 평균 층간 거리는 우레아 첨가 유무에 따라 $10.7{\AA}$, $14.2{\AA}$로 각각 나타났다. 또한 표면구조는 합성 시 우레아가 첨가된 소재는 나노로드, 포름산만 첨가된 시료는 나노쉬트 모양의 단위체가 형성되었다. $95^{\circ}C$에서 우레아를 첨가하여 제조한 $(NH_4)_{0.3}V_2O_5$ 나노소재의 전지용량은 평균 280 mAh/g 이상이었다.

Supercapacitor용 $V_{2}O_{5}$ Composite의 전압영역에 따른 충방전 특성 (Charge/discharge Properties of $V_{2}O_{5}$ Composite with different Voltage range for Supercapacitor)

  • 김명산;김종욱;구할본;박복기
    • 한국전기전자재료학회:학술대회논문집
    • /
    • 한국전기전자재료학회 2000년도 하계학술대회 논문집
    • /
    • pp.507-510
    • /
    • 2000
  • The purpose of this study is to research and developV$_2$O$_{5}$-SP270 composite electrode for supercapacitor. Property of an electrical double layer capacitor depend both on the technique used to prepare the electrode and on the current collector structure. The study is to research that V$_2$O$_{5}$-carbon composite electrode for supercapacitor with different voltage range. Suprcapacitor cell of V$_2$O$_{5}$-SP270 composite electrode with 25PVDFLiC1O$_4$PC$_{10}$ polymer electrolyte bring out good capacitor performance below 3V. The discharge capacitance of SP270 in 1st cycles was 13F/g at 0.1mA/cm$^2$, 3V. We performed cycle voltammogram, charge/discharge property.y.rty.y.

  • PDF

V2O5 기반의 금속 산화물 투명 광전소자 (V2O5 Embedded All Transparent Metal Oxide Photoelectric Device)

  • 김상윤;최유림;이경남;김준동
    • 전기학회논문지
    • /
    • 제67권6호
    • /
    • pp.789-793
    • /
    • 2018
  • All transparent metal oxide photoelectric device based on $V_2O_5$ was fabricated with structure of $V_2O_5/ZnO/ITO$ by magnetron sputtering system. $V_2O_5$ was deposited by reactive sputtering system with 4 inch vanadium target (purity 99.99%). In order to achieve p-n junction, p-type $V_2O_5$ was deposited onto the n-type ZnO layer. The ITO (indium tin oxide) was applied as the electron transporting layer for effective collection of the photo-induced electrons. Electrical and optical properties were analyzed. The Mott-Schottky analysis was applied to investigate the energy band diagram through the metal oxide layers. The $V_2O_5/ZnO/ITO$ photoelectric device has a rectifying ratio of 99.25 and photoresponse ratios of 1.6, 4.88 and 2.68 under different wavelength light illumination of 455 nm, 560 nm and 740 nm. Superior optical properties were realized with the high transmittance of average 70 % for visible light range. Transparent $V_2O_5$ layer absorbs the short wavelength light efficiently while passing the visible light. This research may provide a route for all-transparent photoelectric devices based on the adoption of the emerging p-type $V_2O_5$ metal oxide layer.

$V_2O_5-WO_3/TiO_2$ 계 SCR 촉매의 가스상 원소수은 산화 활성 (Activity of $V_2O_5-WO_3/TiO_2$-based SCR Catalyst for the Oxidation of Gas-phase Elemental Mercury)

  • 홍현조;함성원
    • 청정기술
    • /
    • 제17권4호
    • /
    • pp.370-378
    • /
    • 2011
  • 가스상 원소수은의 산화수은으로의 산화에 대한 $V_2O_5-WO_3/TiO_2$ 계 SCR 촉매의 활성이 조사되었다. 상용 SCR 촉매의 경우 원소수은 산화반응에 산화제로 작용하는 HCl의 존재 및 반응조건에 상관없이 반응 후의 모든 촉매에서 수은성분이 검출되지 않았다. 이는 $V_2O_5-WO_3/TiO_2$ 계 SCR 촉매에서 HCl에 의한 원소수은의 산화는 수은이 촉매표면에 거의 흡착되지 않는 Eley-Rideal mechanism에 의해 진행되는 것을 나타내는 결과이다. $V_2O_5$ 함량에 따라 수은 산화활성이 크게 증가되는 것으로부터 $V_2O_5$가 수은산화 반응에 주된 활성점 임을 확인할 수 있었다. 그러나 $V_2O_5$ 함량에 따라 TOF는 감소하는데 이는 촉매 표면에 존재하는 $V_2O_5$의 구조에 따라 수은산화 활성에 차이가 있다는 것을 의미한다. 동일한 반응온도와 HCl 농도에서 산화 조건에 비해 SCR 조건에서 원소수은의 산화활성은 크게 낮은 것으로 나타났다.

고체전해질용 CuO-$Nb_{2}O_{5}-V_{2}O_{5}$계 유리의 결정화와 전기적 특성 (Crystallization and Electrical Properties Of CuO-$Nb_{2}O_{5}-V_{2}O_{5}$ Glass for Solid-state electrolyte)

  • 손명모;이헌수;구할본;김윤선
    • 한국전기전자재료학회:학술대회논문집
    • /
    • 한국전기전자재료학회 2000년도 하계학술대회 논문집
    • /
    • pp.552-556
    • /
    • 2000
  • The crystallization behavior and dc Conductivities of CuO-Nb$_2$O$_{5}$ -V$_2$O$_{5}$ glasses prepared by quenching on the copper plate were investigated. The conductivities of the glasses were range from 10$^{-4}$ s.$cm^{-1}$ / at room temperature, but the conductivities of the glass-ceramics were 10$^{-3}$ s.$cm^{-1}$ / increased by 10$^1$ order. The linear relationship between In($\sigma$T) and T$^{-1}$ suggested that the electrical conduction in the present glass system would be due to a small polaron hopping mechanism. The value of activation energy of glass-ceramics heat-treated at 30$0^{\circ}C$ for 12hrs was found to be 0.leV

  • PDF

비정질과 결정질 V2O5 박막의 온도에 따른 발광특성 (Temperature-dependent photoluminescence properties of amorphous and crystalline V2O5 films)

  • 강만일;추민우;김석원
    • 한국결정성장학회지
    • /
    • 제24권5호
    • /
    • pp.202-206
    • /
    • 2014
  • $V_2O_5$ 박막에서의 PL 특성을 조사하기 위해 RF 스퍼터링법을 이용하여 비정질과 결정질 $V_2O_5$ 박막을 제작하였고, 10~300 K의 온도까지 PL 스펙트럼을 측정하였다. 상온에서 성장된 비정질 박막에서는 ~505 nm를 중심으로 하는 하나의 PL 피크만이 관찰되었고, 결정질 $V_2O_5$ 박막에서는 505 nm를 중심으로 하는 피크와 산소결함에 의한 것으로 알려진 ~695 nm를 중심으로 하는 피크가 관찰되었다. 비정질과 결정질 $V_2O_5$ 박막에서 관찰되는 505 nm에서의 PL 피크의 위치는 온도에 강한 의존성을 보였고, 그 값은 300 K에서 2.45 eV였고, 10 K에서 2.35 eV였다. 505 nm에서의 PL은 $V_2O_5$에서의 밴드 에너지 전이에 의한 것이었으며, 또한 온도의 감소에 따른 피크 위치 에너지의 감소는 전자-포논 상호작용의 감소에 의한 격자팽창효과의 감소 때문이었다.