• Title/Summary/Keyword: $VO_2$ film

Search Result 65, Processing Time 0.024 seconds

A Study of Friction Characteristics according to the Morphology of Solid Transfer Film (고체윤활막 형상에 따른 마찰특성의 변화에 관한 연구)

  • Lim, Hyun-Woo;Jang, Ho
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
    • /
    • 2000.11a
    • /
    • pp.310-317
    • /
    • 2000
  • Tribological properties of friction materials containing different volume ratios of solid lubricants (graphite and MoS$_2$) were studied using a pad-on-disk type friction tester. Morphology and thickness of the friction film were carefully examined to correlate the friction performance with the property of the friction film. Results showed that the friction materials containing 16vo1. % of graphite and 5 vol. % of MoS$_2$exhibited best friction stability among others. In particular, the thickness of the friction film decreased as the amount of MoS$_2$increased and severe friction oscillation was observed when the friction material contained MoS$_2$only (21 vol. %). Microscopic observations and friction tests suggested that the coherent thick transfer film improved the friction stability.

  • PDF

Characteristics of VOx Thin Film, NiOx Thin Film, and CuIx Thin Film for Carrier Selective Contacts Solar Cells (전하선택접촉 태양전지 적용을 위한 VOx 박막, NiOx 박막, CuIx 박막의 특성 연구)

  • Kiseok Jeon;Minseob Kim;Eunbi Lee;Jinho Shin;Sangwoo Lim;Chaehwan Jeong
    • Current Photovoltaic Research
    • /
    • v.11 no.2
    • /
    • pp.39-43
    • /
    • 2023
  • Carrier-selective contacts (CSCs) solar cells are considerably attractive on highly efficient crystalline silicon heterojunction (SHJ) solar cells due to their advantages of high thermal tolerance and the simple fabrication process. CSCs solar cells require a hole selective contact (HSC) layer that selectively collects only holes. In order to selectively collect holes, it must have a work function characteristic of 5.0 eV or more when contacted with n-type Si. The VOx, NiOx, and CuIx thin films were fabricated and analyzed respectively to confirm their potential usage as a hole-selective contact (HSC) layer. All thin films showed characteristics of band-gap engergy > 3.0 eV, work function > 5.0 eV and minority carrier lifetime > 1.5 ms.

The Properties of RF Sputtered Zinc Tin Oxide Thin Film Transistors at Different Sputtering Pressure (스퍼터 증착된 Zinc Tin Oxide 박막 트랜지스터의 공정 압력에 따른 특성 연구)

  • Lee, Hong Woo;Yang, Bong Seob;Oh, Seungha;Kim, Yoon Jang;Kim, Hyeong Joon
    • Journal of the Semiconductor & Display Technology
    • /
    • v.13 no.1
    • /
    • pp.43-49
    • /
    • 2014
  • Zinc-tin oxides (ZTO) thin film transistors have been fabricated at different process pressure via re sputtering technique. TFT properties were improved by depositing channel layers at lower pressure. From the analysis of TFTs comprised of multi layer channel, deposited consecutively at different sputtering pressure, it was suggested that the electrical characteristics of TFTs were mainly affected by interfacial layer due to their high conductance, however, the stability under the NBIS condition was influenced by whole bulk layer due to low concentration of positive charges, which might be generated by the oxygen vacancy transition, from Vo0 to $Vo^{2+}$. Those improvements were attributed to increasing sputtered target atoms and decreasing harmful effects of oxygen molecules by adopting low sputtering pressure condition.

Hydrothermal Synthesis of Vanadium (IV) Dioxide and its Thermochromic Property (바나듐(IV) 이산화물의 수열합성 및 이의 열변색 특성)

  • Lee, Hun Dong;Son, Dae Hee;Lee, Won Ki;Jin, Young Eup;Lee, Gun-Dae;Park, Seong Soo
    • Applied Chemistry for Engineering
    • /
    • v.26 no.4
    • /
    • pp.427-431
    • /
    • 2015
  • In this study, vanadium dioxide ($VO_2$) powder well known as a thermochromic material was prepared from $V_2O_5$ powder and oxalic acid dihydrate by hydrothermal and calcination process at various conditions. The chemical bonding and crystal structures in addition to thermal property of samples were determined using FE-SEM, XRD, XPS, and DSC. Also, spectroscopic and thermochromic properties of film samples were analyzed by UV-Vis-NIR spectroscopy after the thin film was prepared from the sol dispersed with the size of below 50 nm by the ball-milling of powder sample. With increasing the calcination temperature, the phase transition temperature of samples increased from $40^{\circ}C$ to $70^{\circ}C$ due to the increase of particle size.

Temperature Dependence of Nanoscale Friction and Conductivity on Vanadium Dioxide Thin Film During Metal-Insulator Transition

  • Kim, Jong Hun;Fu, Deyi;Kwon, Sangku;Wu, Junqiao;Park, Jeong Young
    • Proceedings of the Korean Vacuum Society Conference
    • /
    • 2013.08a
    • /
    • pp.143.2-143.2
    • /
    • 2013
  • Nanomechanical and electrical properties of vanadium dioxide (VO2) thin films across thermal-driven phase transition are investigated with ultra-high vacuum atomic force microscopy. VO2 thin films have been deposited on the n-type heavily doped silicon wafer by pulsed laser deposition. X-ray diffraction reveals that it is textured polycrystalline with preferential orientation of (100) and (120) planes in monoclinic phase. As the temperature increases, the friction decreased at the temperature below the transition temperature, and then the friction increased as increasing temperature above the transition temperature. We attribute this observation to the combined effect of the thermal lubricity and electronic contribution in friction. Furthermore, the dependence of nanoscale conductance on the local pressure was indicated at the various temperatures, and the result was discussed in the view of pressure-induced metal-insulator transition.

  • PDF

Understanding the Electrical Property of Si-doped β-Ga2O3 via Thermal Annealing Process (열처리 공정을 이용한 Si-doped β-Ga2O3 박막의 전기적 특성의 이해)

  • Lee, Gyeongryul;Park, Ryubin;Chung, Roy Byung Kyu
    • Journal of the Microelectronics and Packaging Society
    • /
    • v.27 no.4
    • /
    • pp.19-24
    • /
    • 2020
  • In this work, the electrical property of Si-doped β-Ga2O3 was investigated via a post-growth annealing process. The Ga2O3 samples were annealed under air (O-rich) or N2 (O-deficient) ambient at 800~1,200℃ for 30 mins. There was no correlation between the crystalline quality and the electrical conductivity of the films within the experimental conditions explored in this work. However, it was observed the air ambient led to severe degradation of the film's electrical conductivity while N2-annealed samples exhibited improvement in both the carrier concentration and Hall mobility measured at room temperature. Interestingly, the x-ray photoemission spectroscopy (XPS) revealed that both annealing conditions resulted in higher concentration of oxygen vacancy (VO). Although it was a slight increase for the air-annealed sample, high resistivity of the film strongly suggests that VO cannot be a shallow donor in β-Ga2O3. Therefore, the enhancement of the electrical conductivity of N2-annealed samples must be originated from something other than VO. One possibility is the activation of Si. The XPS analysis of N2-annealed samples showed increasing relative peak area of Si 2p associated with SiOx with increasing annealing temperature from 800 to 1,200℃. However, it was unclear whether or not this SiOx was responsible for the improvement as the electrical conductivity quickly degraded above 1,000℃ even under N2 ambient. Furthermore, XPS suggested the concentration of Si actually increased near the surface as opposed to the shift of the binding energy of Si from its initial chemical state to SiOx state. This study illustrates the electrical changes induced by a post-growth thermal annealing process can be utilized to probe the chemical and electrical states of vacancies and dopants for better understanding of the electrical property of Si-doped β-Ga2O3.

Effects of Growth Ambient, Process Pressure, and Heat Treatments on the Properties of RF Magnetron Sputtered GaMgZnO UV-Range Transparent Conductive Films

  • Patil, Vijay;Lee, Chesin;Lee, Byung-Teak
    • Korean Journal of Materials Research
    • /
    • v.31 no.6
    • /
    • pp.320-324
    • /
    • 2021
  • Effects of growth variables and post-growth annealing on the optical, structural and electrical properties of magnetron-sputtered Ga0.04Mg0.10Zn0.86O films are characterized in detail. It is observed that films grown from pure oxygen plasma showed high resistivity, ~102 Ω·cm, whereas films grown in Ar plasma showed much lower resistivity, 2.0 × 10-2 ~ 1.0 × 10-1 Ω·cm. Post-growth annealing significantly improved the electrical resistivity, to 4.3 ~ 9.0 × 10-3 Ω·cm for the vacuum annealed samples and to 1.3 ~ 3.0 × 10-3 Ω·cm for the films annealed in Zn vapor. It is proposed that these phenomena may be attributed to the improved crystalline quality and to changes in the defect chemistry. It is suggested that growth within oxygen environments leads to suppression of oxygen vacancy (Vo) donors and formation of Zn vacancy (VZn) acceptors, resulting in highly resistive films. After annealing treatment, the activation of Ga donors is enhanced, Vo donors are annihilated, and crystalline quality is improved, increasing the electron mobility and the concentration. After annealing in Zn vapor, Zn interstitial donors are introduced, further increasing the electron concentration.

Power Enhancement of ZnO-Based Piezoelectric Nanogenerators Via Native Defects Control

  • Kim, Dohwan;Kim, Sang-Woo
    • Proceedings of the Korean Vacuum Society Conference
    • /
    • 2013.08a
    • /
    • pp.297.2-297.2
    • /
    • 2013
  • Scavenging electricity from wasteful energy resources is currently an important issue and piezoelectric nanogenerators (NGs) based on zinc oxide (ZnO) are promising energy harvesters that can be adapted to various portable, wearable, self-powered electronic devices. Although ZnO has several advantages for NGs, the piezoelectric semiconductor material ZnO generate an intrinsic piezoelectric potential of a few volts as a result of its mechanical deformation. As grown, ZnO is usually n-type, a property that was historically ascribed to native defects. Oxygen vacancies (Vo) that work as donors exist in ZnO thin film and usually screen some parts of the piezoelectric potential. Consequently, the ZnO NGs' piezoelectric power cannot reach to its theoretical value, and thus decreasing the effect from Vo is essential. In the present study, c-axis oriented insulator-like sputtered ZnO thin films were grown in various temperatures to fabricate an optimized nanogenerator (NGs). The purity and crystalinity of ZnO were investigated with photoluminescence (PL). Moreover, by introducing a p-type polymer usually used in organic solar cell, it was discussed how piezoelectric passivation effect works in ZnO thin films having different types of defects. Prepared ZnO thin films have both Zn vacancies (accepter like) and oxygen vacancies (donor like). It generates output voltage 20 time lager than n-type dominant semiconducting ZnO thin film without p-type polymer conjugating. The enhancement is due to the internal accepter like point defects, zinc vacancies (VZn). When the more VZn concentration increases, the more chances to prevent piezoelectric potential screening effects are occurred, consequently, the output voltage is enhanced. Moreover, by passivating remained effective oxygen vacancies by p-type polymers, we demonstrated further power enhancement.

  • PDF

A Study on the ZVS-CV Converter Using Thin-Film Inductor (박막 인덕터를 이용한 ZVS-CV 컨버터에 관한 연구)

  • Im, Sang-Un;Kim, Young-Jae;Kim, Hee-Jun;Kim, Hyoung-June
    • Proceedings of the KIEE Conference
    • /
    • 1999.07f
    • /
    • pp.2522-2525
    • /
    • 1999
  • Buck converter is considered to be one of the most widely used DC-DC converters due to its simple structure and high reliable performance. However, when it be combined with thin-film inductor, its own low inductance requires higher switching frequency in order to maintain optimum output ripple voltage and thus gives rise to extra switching losses. In view to overcoming such a technical in-convenience, soft switching fashion is suggested such as zero-voltage-switching of which an well known example is a Zero-Voltage-Switching clamp voltage(ZVS-CV) converter for which low inductance is imperatively required for ZVS operation. In order to support our suggestion, a 1W of ZVS-CV buck converter( Vo=3.3V, Iomax=0.3A, fs= 1.2MHz) is built by use of thin-film inductor, and then tested for comparing the measured efficiency between ours and conventional one. As the our results. the efficiency is improved about 2% at full load by the application of our concept.

  • PDF