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http://dx.doi.org/10.14478/ace.2015.1047

Hydrothermal Synthesis of Vanadium (IV) Dioxide and its Thermochromic Property  

Lee, Hun Dong (R&D Center, CFC Teramate Co.)
Son, Dae Hee (R&D Center, CFC Teramate Co.)
Lee, Won Ki (Department of Polymer Engineering, Pukyong National University)
Jin, Young Eup (Department of Industrial Chemistry, Pukyong National University)
Lee, Gun-Dae (Department of Industrial Chemistry, Pukyong National University)
Park, Seong Soo (Department of Industrial Chemistry, Pukyong National University)
Publication Information
Applied Chemistry for Engineering / v.26, no.4, 2015 , pp. 427-431 More about this Journal
Abstract
In this study, vanadium dioxide ($VO_2$) powder well known as a thermochromic material was prepared from $V_2O_5$ powder and oxalic acid dihydrate by hydrothermal and calcination process at various conditions. The chemical bonding and crystal structures in addition to thermal property of samples were determined using FE-SEM, XRD, XPS, and DSC. Also, spectroscopic and thermochromic properties of film samples were analyzed by UV-Vis-NIR spectroscopy after the thin film was prepared from the sol dispersed with the size of below 50 nm by the ball-milling of powder sample. With increasing the calcination temperature, the phase transition temperature of samples increased from $40^{\circ}C$ to $70^{\circ}C$ due to the increase of particle size.
Keywords
vanadium dioxide; thermochromic; phase transition; hydrothermal; monoclinic;
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