• Journal of environmental and Sanitary engineering
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• v.20 no.3 s.57
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• pp.27-35
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• 2005

The ion exchange resins have been synthesized from chlormethyl styrene - 1,4 -divinyl-benzene(DVB) with $1\%,\;4\%,\;and\;10\%$-crosslinking and macrocyclic ligand of cryptand type by copolymerization method and the adsorption characteristics of uranium(VI), calcium(II) and lutetium(III) metallic ions have been investigated in various experimental conditions. The synthesis of these resins was confirmed by content of chlorine, element analysis, and IR-spectrum. The effects of pH, time, dielectric constant of solvent and crosslink on adsorption of metallic ions were investigated. The uranium ion was showed fast adsorption on the resins above pH 3. The optimum equilibrium time for adsorption of metallic ions was about two hours. The adsorption selectivity determined in ethanol was in increasing order uranium $(UO_2^{2+})>calcium(Ca^{2+})>lutetium(Lu^{3+})$ ion. The adsorption was order of $1\%,\;4\%,\;and\;10\%$ crosslink resin and adsorption of resin decreased in proportion to order of dielectric constant of solvents.

• Nuclear Engineering and Technology
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• v.53 no.6
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• pp.1931-1938
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• 2021

Uranium ingot is produced by metallothermic reduction of uranium tetrafluoride using magnesium or calcium as reductant. Presence of oxygen containing compounds viz. uranyl fluoride and uranium oxide in the starting uranium fluoride has a significant effect on the firing time, final temperature of the charge, slag-metal separation and hence the metal recovery. As reported in the literature, the maximum tolerable limit for uranyl fluoride in the UF₄ is 2.5 wt% and limit for uranium oxide content is in the range 2-3 wt%. No theoretical or experimental basis is available till date for these limits. Analyses have been carried out in this study to understand the effect of UO₂F₂ concentration in the starting fluoride on the final temperature of the products and thus the reduction characteristics. UF₄ having uranyl fluoride concentration, less than as well as more than 2.5 wt%, have been investigated. Thermodynamic calculations have been carried out to arrive at a general expression for the final temperature attained by the products during calciothermic reduction of UF₄. Finally, an upper limit for the oxygen containing impurities has been estimated using the CaO-CaF₂ phase diagram.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.7 no.3
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• pp.161-165
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• 2009

To evaluate the efficiency of the decontamination plant for the removal of uranium compounds deposited on the internal surface of $UF_6$ cylinder for its reuse, two demonstration tests of the plant with different ratio of ${Na_2}{CO_3}$ and ${H_2}{O_2}$ were carried out, and each test had 5 steps. The main chemical form removed by the tests was to be identified as ${Na_4}{UO_2}(CO_3)_3$. More than 50% of uranium was removed by water of the first step, and at the following steps the removal amounts were exponentially decreased. On the other hand, the result shows that the injected amount of ${Na_2}{CO_3}$, compared with that of the removed uranium, was stoichiometrically excessed. This suggests that the injected amounts of ${Na_2}{CO_3}$, the generation rate of decontaminated waste, and the decontamination steps could be reduced by a process optimization of the plant.

• Journal of the Korean Chemical Society
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• v.58 no.2
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• pp.169-178
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• 2014

A new series of metal complexes of V(IV), Pd(II), Pt(IV), Ce(IV) and U(VI) with 3-[(3-chlorophenyl)-hydrazono]-pentane-2,4-dione (Cphpd) were synthesized and characterized by elemental analysis, molar conductivity, magnetic moment measurements, UV-vis, FT-IR and $^1H$ NMR as well as TG-DTG techniques. The data indicated that the Cphpd acts as a bidentate ligand through the hydrazono nitrogen and one keto oxygen. The kinetic parameters have been evaluated by using Coats Redfern (CR) and Horowitz-Metzeger (HM) methods. The thermodynamic data reflected the thermal stability for all complexes. The calculated bond length and the bond stretching force constant, F(U=O), values for $UO_2$ bond are $0.775{\AA}$ and $286.95Nm^{-1}$. The bond lengths, bond angles, dipole moment and the lowest energy model structure of the complexes have been determined with DFT calculations. The antimicrobial activity of the synthesized ligand and its complexes were screened.

• Journal of Institute of Convergence Technology
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• v.4 no.2
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• pp.47-50
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• 2014

Voloxidation is a process for converting $UO_2$ into $U_3O_8$ while removing some volatile products in spent fuels (SF). Various oxidative gas conditions including air and mixture of Ar and $O_2$ could be adopted for the process. The gas flows into a reactor under high temperature ($>500^{\circ}C$) and components of SF are reacted with the gas. SF is composed of various components such as actinides, lanthanides, and alkali metals. Therefore, it is of significance to understand their behavior during the reactions for process development. However, due to the limit of available experiments, phase diagram analysis should be preceded. TPP diagram is constructed with respect to temperature-pressure-pressure. It shows a stable phase depending on partial pressures of gas components as well as temperature. In this work, we investigated TPP diagrams for actinides, lanthanides and other oxides to determine stable oxide forms under different gas conditions. The results would be used to set up a material balance under a pyroprocessing scheme of SF and compare the gas conditions for the optimization of fission products removal.

• Proceedings of the KWS Conference
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• 2003.11a
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• pp.18-20
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• 2003

Optimal processing and system to produce the laser welded tube for one body formed bumper beam are studied. The calculated size of tube is a thickness of 1.4mm, diameter of 105.4mm and length of 2000mm. The tube is shaped from cool rolled high strength steel sheet(tensile strength: 60kgf/$\textrm{mm}^2$ grade). Two roll bending method is the optimal tube shaping process compared to UO-bending, bending on press brake, multi-step continuous roll forming and 3 roll bending methods. Weld quality monitoring and seam tracking along the butt-joint lengthwise to the tube axis are also studied. The longitudinal butt-joint is welded by the $CO_2$ laser welding system equipped with a seam tracker and plasma sensor. The constructed $CO_2$ laser tube welding system can be used for the precision seam tracking and the real-time monitoring of weld quality. Finally, the obtained laser welded tube can be used for one-body formed automobile bumper beam.

• Korean Journal of Veterinary Research
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• v.38 no.3
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• pp.652-658
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• 1998

The efficiency of nuclear transfer using donor embryos originated from ovum pickup(OPU) and activated recipient cytoplasts were examined for induction of twinning in Korean native cattle(KNC). After aspiration of follicle by OPU, regardless of the vacuum applied, we obtained same result in proportions of recovered cumulus-oocyte complex (COCs) with compact cumulus. Under electric stimulation(1.0kV/cm DC for $40{\mu}s$), most of activated oocytes proceed to anaphase II/telophase II within 3h(84.7%). In the treatment of oocyte activation, the preactivation which was performed before fusion had significant effect on the developmental rates to morula/blastocyst stage(9.4 vs 4.0%). In embryo transfer of nuclear transferred embryos, we obtained 2 twins from KNC recipients and 1 twin from a Holstein recipient. Our results showed that it is possible to obtain twins using nuclear transfer technique in KNC.

• International Journal of Automotive Technology
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• v.7 no.2
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• pp.209-216
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• 2006

A study has been conducted for an optimal processing and an apparatus for manufacturing a laser welded tube for one-body formed bumper beam. The tube dimensions used in calculation were the thickness of 1.4 mm, the diameter of 105.4 mm and the length of 2000 mm. The tube was formed of a cold rolled high strength steel plate(tensile strength of 600 MPa). The two-roll bending method was the optimal tube forming process in comparison with the UO-bending method, the bending method on the press brake, the multi-step continuous roll-forming method and the 3-roll bending method. Monitoring of the welding quality was conducted and the seam tracking along the butt-joint lengthwise to the tube axis was also examined. The longitudinal butt-joint was welded by using a $CO_2$ laser welding machine equipped with a seam tracker and a plasma sensor. The $CO_2$ laser tube welding machine could be used for precise seam tracking and real-time monitoring of the welding quality. As a result, the developed laser welded tube could be used for a one-body formed automobile bumper beam.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.4 no.1
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• pp.48-56
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• 1992

The purpose of this study was to investigate the enhancement of heat transfer without additional external power in the case of rectangular air jet impinging vertically on the flat heating surface. In an attempt to enhance the heat transfer rate in two-dimensional impinging jet, the technique used in the present study was placement of square rod bundles as a turbluence promoter in front of the heat transfer surface. The effects of the clearance between the flat plate and square rod, and the nozzle exit velocity on the heat transfer characteristics have been investigated experimentally. The results obtained through this study were summerized as follows. High heat transfer enhancement was achived by means of flow acceleration and thinning of boundary layer by inserting rods in front of the heating flat plate. The smaller the clearance between rod and heating plate was, the larger heat transfer effect became. Average Nusselt number reached maximum at $Re=5.76{\times}10^4$ and C＝1㎜ and the enhancement rate of heat transfer became maxium at this condition with the enhancement ratio as high as about 1.427 when normalized by the flat plate value. The correlating equation of average Nusselt number and Reynolds number was obtained, which is $\bar{N}uo=1.324{\cdot}Re^{0.459}{\cdot}(C/A)^{-0.034}$.

• Smart Structures and Systems
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• v.4 no.6
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• pp.795-807
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• 2008

A challenging problem in structural damage detection based on vibration data is the requirement of a large number of sensors and the numerical difficulty in obtaining reasonably accurate results when the system is large. To address this issue, the substructure identification approach may be used. Due to practical limitations, the response data are not available at all degrees of freedom of the structure and the external excitations may not be measured (or available). In this paper, an adaptive damage tracking technique, referred to as the sequential nonlinear least-square estimation with unknown inputs and unknown outputs (SNLSE-UI-UO) and the sub-structure approach are used to identify damages at critical locations (hot spots) of the complex structure. In our approach, only a limited number of response data are needed and the external excitations may not be measured, thus significantly reducing the number of sensors required and the corresponding computational efforts. The accuracy of the proposed approach is illustrated using a long-span truss with finite-element formulation and an 8-story nonlinear base-isolated building. Simulation results demonstrate that the proposed approach is capable of tracking the local structural damages without the global information of the entire structure, and it is suitable for local structural health monitoring.