• Title/Summary/Keyword: $TiO_2$ Coating

Search Result 692, Processing Time 0.03 seconds

Preparing and Ferroelectric Properties of the Pb($Zr_{0.52}$$Ti_{0.48}$)$O_3$ Thin Film by Sol-Gel Method. (Sol-Gel법에 의한 Pb($Zr_{0.52}$$Ti_{0.48}$)$O_3$박막의 제조 및 강유전 특성)

  • 이영준;정장호;이성갑;이영희
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 1994.11a
    • /
    • pp.168-170
    • /
    • 1994
  • Pb($Zr_{0.52}$$Ti_{0.48}$)$O_3$ ceramic thin films were fabricated from an alkoxide-based solution by Sol-Gel method. Pb($Zr_{0.52}$$Ti_{0.48}$)$O_3$ ceramic thin films were formed by spin coating method on Pt/$SiO_2$Si substrate at 4000ppm for 30 seconds. The coating process was repeated 6 times and then heat-treated at temperature between 500∼800[$^{\circ}C$] for 1 hour. The final thickness of the thin films were about 4800[A]. The ferroelectric perovskite phases precipitated under the heat-treated at 700[$^{\circ}C$] for 1 hour. Pb($Zr_{0.52}$$Ti_{0.48}$)$O_3$ thin films heat-treated at 700[$^{\circ}C$] for 1 hour showed good dielectric and ferroclectric properties.

Dielectric Properties of the $Pb(Zr_{0.52}Ti_{0.48})O_3$ Thin Film by Sol-Gel Method. (Sol-Gel 법으로 제조한 $Pb(Zr_{0.52}Ti_{0.48})O_3$ 박막의 유전 특성)

  • Chung, Jang-Ho;Lee, Young-Jun;Lee, Sung-Gap;Lee, Young-Hie
    • Proceedings of the KIEE Conference
    • /
    • 1994.07b
    • /
    • pp.1454-1456
    • /
    • 1994
  • $Pb(Zr_{0.52}Ti_{0.48})O_3$ ceramic thin films were fabricated from an alkoxide-based solution by Sol-Gel method. $Pb(Zr_{0.52}Ti_{0.48})O_3$ ceramic thin films were formed by spin coating method on $Pt/SiO_2/Si$ substrate at 3000rpm for 30 seconds. The coating process was repeated 6 times and then heat-treated at temperature between 500 - $800[^{\circ}C]$ for 1 hour. The final thickness of the thin films were about 4800[A]. The 100% ferroelectric perovskite phases precipitated under the heat treated at $700[^{\circ}C]$ for 1 hour. $Pb(Zr_{0.52}Ti_{0.48})O_3$ thin films heat-treated at $700[^{\circ}C]$ for 1 hour showed good dielectric constant (812) property.

  • PDF

Effects of Catalyst Coating Methods on NO Removal Characteristics of Functional Fabric Filters (촉매 코팅방법에 따른 기능성여과포의 NO 제거 반응 특성)

  • Kang, Min Pil;Song, Yun-Seob;Lee, Hyo Song;Kim, Sang Do;Park, Young Ok;Hwang, Taek-Sung;Rhee, Young-Woo
    • Korean Chemical Engineering Research
    • /
    • v.40 no.6
    • /
    • pp.725-728
    • /
    • 2002
  • A series of fabric filters including P-84, Nomex and PTFE were coated with a commercial $V_2O_5/TiO_2$ catalyst as an effort to develop a functional fabric filter of simultaneous removal of dust and NOx. The coating methods employed are sol-gel coating method, spray coating method and dip coating method, and the effects of coating method on NOx removal performance of functional fabric filter were investigated. Experimental conditions are as follows: the temperatures of $100-250^{\circ}C$ which are the normal operating temperature range of fabric filters, the space velocity of $5,000hr^{-1}$, the oxygen concentration of 6%, and the $NH_3/NO$ ratio of 1.0. Results showed that the sol-gel coating method gave the best NOx removal performance mainly due to its ability in controlling the amount of catalyst and uniform coating.

Electrical Properties of Sol-Gel Derived Ferroelectric Bi3.35Sm0.65Ti3O12 Thin Films

  • Kang, Dong-Kyun;Cho, Tae-Jin;Kim, Byong-Ho
    • Journal of the Korean Ceramic Society
    • /
    • v.42 no.3 s.274
    • /
    • pp.150-154
    • /
    • 2005
  • Ferroelectric $Bi_{3.35}Sm_{0.65}Ti_{3}O_{12}(BSmT)$ thin films were synthesized by sol-gel process. In this experiments, $Bi(TMHD)_{3},\;Sm_{5}(O^{i}Pr)_{13},\;Ti(O^{i}Pr)_4$ were used as precursors, which were dissolved in 2-methoxyethanol. The BSmT thin films were deposited on the Pt/TiO/SiO/Si substrates by spin-coating. Thereafter, the thin films with the thickness of 240 nm were annealed from 600 to $720^{\circ}C$ in oxygen atmosphere for 1 h, and post-annealed in oxygen atmosphere for 1 h after deposition of Pt electrode to enhance the electrical properties. To investigate the effects of Sm-substitution in the BTO thin films, the BTO and BSmT thin films were prepared, respectively. The remanent polarization and coercive voltage of the BSmT thin films annealed at $720^{\circ}C$ were $19.48{\mu}C/cm^2$ and 3.40 V, respectively.

The Characteristics of 〈112〉-preferred Orientation for Photocatalytic TiO2 Fabricated by CVD (CVD법에 의해 제작된 광촉매 TiO2 〈112〉 우선배향의 특성)

  • Kang, Kyoung-tae;Jhin, Jung-geun;Kang, Pil-kyu;Ro, Dae-ho;Byun, Dong-jin
    • Korean Journal of Materials Research
    • /
    • v.13 no.7
    • /
    • pp.436-441
    • /
    • 2003
  • The characteristics of <112> orientation were studied for the $TiO_2$thin films, which were prepared on the glass by CVD (chemical vapor deposition) at various substrate temperatures. It was confirmed that $TiO_2$ films exhibited <112>-preferred orientation in a specific temperature range. Although $TiO_2$polycrystalline film grown deposited at relatively low temperature showed the growth of random directions, the <112>-preferred orientation was gradually developed with increasing deposition temperature. According to exhibit higher degree of <112>-preferred orientation, $TiO_2$thin film showed porous surface morphology, well-developed columnar structure, and deeper voids resulted from non-aggregation of columns were observed. In addition, transmittance was enhanced. Therefore, the growth of $TiO_2$with <112>-preferred orientation is suitable for glass coating because of predominance of photocatalytic efficiency and transmittance.

Optical Property of Au-doped $TIO_2/SiO_2$ thin film (금 나노미립자가 함침된 $TiO_2/SiO_2$ 박막의 광학적 성질)

  • Jung, Mie-Won;Kim, Ji-Eun;Lee, Kyung-Chul
    • Journal of the Korean Chemical Society
    • /
    • v.44 no.1
    • /
    • pp.60-67
    • /
    • 2000
  • The wavelength of the surface plasmon absorption depends on the dielectric matrix. $TiO_2/SiO_2$ complex oxide films doped with Au nanoclusters were prepared by sol-gel spin-coating method using $Ti(OPr^i)_4$, $Si(OEt)_4$, and $HAuCl_4{\cdot}7H_2O$. The wavelength of the maximum absorption of Au nanoehrsters in the $TiO_2/SiO_2$ thin films was obtained with lineality from 540 nm to 615 nm depending on the molar ratio of $TiO_2$. The particle sizes and structures of these nanoclusters have been identified through a TEM and X-ray diffraction patterns. The dielectric constants of $TiO_2/SiO_2$ thin films were calculated from the experimental results.

  • PDF

Preparation and Electrochemical Characterization of ZrO2/Ti Electrode by ESD Coating Method (ESD 코팅법에 의한 ZrO2/Ti 전극의 제조 및 전기화학적 특성)

  • Kim, Han-Joo;Hong, Kyeong-Mi;Sung, Bo-Kyung;Park, Soo-Gil
    • Journal of the Korean Electrochemical Society
    • /
    • v.11 no.2
    • /
    • pp.95-99
    • /
    • 2008
  • This study has made the electrode that is coated zirconium oxide on the titanium by ESD(Electrostatic spray deposition) coating methode. It has investigated the effects of the etching method of a Ti substrate as the preparation, making of zirconium oxide film and electrochemical characteristics of the electrode that is etched on the titanium. The HCl etching develops a fine and homogeneous roughness on the Ti substrate. Fabrication and material properties of the metal oxide electrode, which is known to be so effective to generate ozone and hypochlorous acid (HOCl) as power oxidant, were studied. A proper metal oxide material is focus zirconium oxide through reference. A coating method to enhance the fabrication reproducibility of the zirconium oxide electrode was used ESD coating method by zirconium oxychloride. Zirconium oxide films on the Ti substrate were tested using SEM, XRD, Cyclic voltammetry.