• Title/Summary/Keyword: $T_m-shift$

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A Study on the Growth Rate and Surface Shape of Single Crystalline Diamond According to HFCVD Deposition Temperature (HFCVD 증착 온도 변화에 따른 단결정 다이아몬드 표면 형상 및 성장률 변화)

  • Gwon, J.U.;Kim, M.S.;Jang, T.H.;Bae, M.K.;Kim, S.W.;Kim, T.G.
    • Journal of the Korean Society for Heat Treatment
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    • v.34 no.5
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    • pp.239-244
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    • 2021
  • Following Silicon Carbide, single crystal diamond continues to attract attention as a next-generation semiconductor substrate material. In addition to excellent physical properties, large area and productivity are very important for semiconductor substrate materials. Research on the increase in area and productivity of single crystal diamonds has been carried out using various devices such as HPHT (High Pressure High Temperature) and MPECVD (Microwave Plasma Enhanced Chemical Vapor Deposition). We hit the limits of growth rate and internal defects. However, HFCVD (Hot Filament Chemical Vapor Deposition) can be replaced due to the previous problem. In this study, HFCVD confirmed the distance between the substrate and the filament, the accompanying growth rate, the surface shape, and the Raman shift of the substrate after vapor deposition according to the vapor deposition temperature change. As a result, it was confirmed that the difference in the growth rate of the single crystal substrate due to the change in the vapor deposition temperature was gained up to 5 times, and that as the vapor deposition temperature increased, a large amount of polycrystalline diamond tended to be generated on the surface.

Studies of Crystallographic and Magnetic Properties in Fe0.9Zn0.1Cr2S4 (Fe0.9Zn0.1Cr2S4의 결정학적 및 자기적 성질에 관한 연구)

  • Bae, Sung-Hwan;Kim, Sam-Jin;Kim, Chul-Sung
    • Journal of the Korean Magnetics Society
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    • v.17 no.1
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    • pp.34-37
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    • 2007
  • The crystallographic and magnetic properties of $Fe_{0.9}Zn_{0.1}Cr_2S_4$ have been studied by X-ray diffractometer(XRD), vibrating sample magnetometer(VSM) and $M\"{o}ssbauer$ spectroscopy measurement. The crystal structure was determined by the normal cubic spinel of space group Fd3m and the lattice constant was $a_0=9.9967\;{\AA}$. The specific phenomenon which looks like cusp pattern at 77 K was observed in magnetization corves(ZFC : Zero Field Cooling) under 100 Oe applied field. $N\acute{e}el$ temperature($T_N$) was determined to be 153 K by VSM and $M\"{o}ssbauer$ spectra. The asymmetric 8-line profile has been observed at 4.2 K, which was attributed by the colossal electric quadupole interaction(${\Delta}E_Q$), ${\Delta}E_Q$ has 2.22 mm/s at 4.2 K. The ${\Delta}E_Q$ abruptly decreases around 77 K and then it disappears above 77 K with diminishing of 8-line pattern. The isomer shift $\delta$ at room temperature is 0.48 mm/s relative to Fe metal, which means that the charge state of Fe ions is ferrous in character.

$^{11}B$ NMR study of $M_gB_2$ superconductor

  • Lee, Moon-Hee;Halperin, W.P.;Cho, B.-K.
    • Journal of the Korean Magnetic Resonance Society
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    • v.9 no.1
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    • pp.21-28
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    • 2005
  • $^{11}B$ nuclear magnetic resonance (NMR) measurements have been performed to investigate electronic structures and vortex states of $M_gB_2$ superconductor. The central transition shows a narrow peak down to 25 K at 3.15 T. Below 25 K, an extra line starts to show up and dominates. The extra line is broad and asymmetric with a long tail in the high frequency side, which confirms that this originates from vortex pinning below the irreversibility temperature. From temperature evolution of the fraction and linewidth of the broad portion, temperature dependence of coherence length and penetration depth are extracted.

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Mössbauer Study of Two Discernable Fe Sites in CaFe2O4

  • Yoon, Sung-Hyun
    • Journal of Magnetics
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    • v.14 no.2
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    • pp.86-89
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    • 2009
  • Structural and magnetic properties of polycrystalline $CaFe_2O_4$ prepared by the solid state reaction method were studied using powder X-ray diffraction (XRD) and $M{\ddot{o}}ssbauer$ spectroscopy. The structure of $CaFe_2O_4$ belongs to an orthorhombic system (space group: Pnma) with the lattice parameters $a=9.2373\;{\AA}$, $b=3.0237\;{\AA}$, and $c=10.7124\;{\AA}$. Results of structural refinement indicate, however, that there are two slightly different iron sites in the sample. The $M{\ddot{o}}ssbauer$ spectrum at 4.2 K shows a hyperfine sextet with a hyperfine magnetic field and an isomer shift of 47.3 T and 0.36 mm/s, respectively. An examination of the spectrum revealed that the line widths of the spectral lines were not uniform. The degree of asymmetric line broadening decreases with increasing temperature, suggesting that the difference in the degree of crystalline distortions between two $FeO_6$ octahedra is eliminated as the temperature rises.

Optical Characteristics of Er and Yb co-doped YCa4B3O10 (Er과 Yb이 동시 도핑된 YCa4B3O10의 광 특성)

  • Jang, Won-Kweon;Yu, Young-Moon
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.20 no.12
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    • pp.1082-1086
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    • 2007
  • Optical characteristics of $YCOB(YCa_4B_3O_{10})$, known as a crystal of self frequency doubling, was investigated when Yb and Er ions were co-doped 20 % and 2 %, respectively. The absorption cross section of Er,Yb:YCOB crystal at $1.0\;{\mu}m$ was larger than that of Yb:YCOB, which means that the former was profitable for more energy absorption than the latter. The fluorescent lifetime at $1.5\;{\mu}m$ was measured to be 1.27 ms at room temperature, and lengthened to 1.54 ms and 1.62 ms at low temperatures of 77 K and 6 K, respectively. The line widths of fluorescent spectrum at $1.5\;{\mu}m$ were getting narrower as lowering temperature. However, we didn't observe a temperature dependent peak wavelength shift.

Parellel Computation of the Shift Table of a Hashing-Based Algorithm for the Order-Preserving Multiple Pattern Matching (순위다중패턴매칭을 위한 해싱기반 알고리즘의 이동테이블 병렬계산)

  • Park, Jeonghoon;Kim, Youngho;Kwan, Sanghoon;Sim, Jeong Seop
    • Proceedings of the Korea Information Processing Society Conference
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    • 2017.04a
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    • pp.36-39
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    • 2017
  • 길이가 같은 두 문자열의 같은 위치에 있는 문자의 순위가 모두 일치할 때, 두 문자열은 순위동형이라 한다. 순위다중패턴매칭문제는 텍스트 T와 k개의 패턴들의 집합 $P^{\prime}=\{P_1,P_2{\ldots},P_k\}$이 주어졌을 때, P'의 패턴들과 순위동형인 T의 모든 부분문자열의 위치를 찾는 문제이다. 최근 전처리단계에서 P'에 대한 이동테이블을 O(kmqlogq) 시간에 계산하여 순위다중패턴매칭문제를 해결하는 해싱기반 알고리즘이 제시되었다. 이때 P'에서 가장 짧은 패턴의 길이를 m, q-그램의 길이를 q라고 한다. 본 논문에서는 P'이 주어졌을 때, 이동테이블을 O(mqlogq) 시간에 계산하는 병렬알고리즘을 제시한다. 실험결과, 본 논문에서 제시하는 병렬알고리즘은 k개의 스레드를 이용하여 m=100, q=5에 대해 k=100일때와 k=1,000일 때 순차알고리즘보다 각각 약 12.9배, 약 215배 빠른 수행시간을 보였다.

HTS high gradient magnetic separator prototype

  • Diev, D.N.;Lepehin, V.M.;Makarenko, M.N.;Polyakov, A.V.;Shcherbakov, V.I.;Shutova, D.I.;Surin, M.I.;Tagunov, E. Ya.
    • Progress in Superconductivity and Cryogenics
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    • v.20 no.4
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    • pp.1-5
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    • 2018
  • A high gradient magnetic (HGM) separator prototype with the $2^{nd}$ generation high temperature superconducting (2G HTS) magnetic system operated in sub-cooled nitrogen is presently under development at NRC "Kurchatov Institute" (Moscow, Russia). The main goal of the project is an attempt to shift away from the complicated liquid helium cryostats towards simple cryocooler-based nitrogen cryogenics as much more convenient for HGM separators industrial applications. Using of commercial HTS tapes allows to get a sufficient level of magnetic fields and extraction forces with low energy consumption. The expected operational parameters of the device are 1.2-1.5 T in the empty operational gap and up to 3 T on the ferromagnetic filters. In this paper we briefly describe the design of the HTS rotary separator prototype with the horizontally oriented rotor axis and propose different types of ferromagnetic filters intended for weakly magnetic ores enrichment.

Synthesis of Two Nitro Analogs of Tranylcypromine: Relations of Aromatic Substitution of Nitro Groups to MAO-Inhibitory Activity

  • Kang, Gun-Il;Hong, Suk-Kil
    • Archives of Pharmacal Research
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    • v.11 no.1
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    • pp.33-40
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    • 1988
  • Two new nitro analogs of tranylcypromine, (E)-2-(p-nitrophenyl)cyclopropylamine ((E)-p-NTCP) and (E)-2-(m-nitrophenyl)cyclopropylamine ((E)-m-NTCP) were synthesized in order to examine the effect of aromatic nitro substitution on the MAO-inhibitory activity of 2-phenylcyclopropylamines. The compounds were obtained by treating t-butyl (E)-2-(p-nitrophenyl) cyclopropanecarbamate and t-butyl (E)-2-(m-nitrophenyl)cyclopropanecarbamate with p-toluenesulfonic acid in $CH_3$CN. Inhibitions of rat brain mitochondrial MAO-A and B by the compounds were examined using serotonin and benzylamine as the substrate at both in vitro and ex vivo levels. It was found from in vitro measurements that (E)-p-NTCP at $6.0{\times}10^{-5}M$ elicited merely 22.5% inhibition against MAO-B without any effect on MAO-A. In contrast, (E)-m-NTCP showed fair degrees of inhibitions of MAO-A and B with $IC_{50}$ values, $2.5{\times}10^{-7}M\;and\;1.4{\times}10^{-6}M$, respectively. It was also noted from (E)-m-NTCP that m-nitro substitution caused a shift of selectivity of the inhibition toward MAO-A. According to ex vivo measurements at 1.5, 3, 6, and 12 hr following the administration of a dose of 0.015 mmol/kg, i.p. to the rats, the inhibition percents of MAO-A by (E)-m-NTCP were 58.6, 63.7 63.6, and 46.6%, slightly lower than those observed by tranylcypromine. Whereas, (E)-m-NTCP at the same dose level did not show significant inhibitions against both MAO-A and MAO-B. Possible reasons for the difference in potencies between (E)-m-NTCP and (E)-p-NTCP were sought in relation to differing electron withdrawing effects of m- and p-substituents which will influence electron density of the side chain amino functions and the partitions.

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Analysis of the Apoptotic Mechanisms of Snake Venom Toxin on Inflammation-induced HaCaT Cell-line

  • Chun, Youl Woong;Song, Ho Sueb
    • Journal of Acupuncture Research
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    • v.34 no.1
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    • pp.23-30
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    • 2017
  • Objectives : In this study, the roles of Interleukin (IL)-4 and Signal transducer and activator of transcription 6 (STAT6), which have been reported to play a role in the pathogenesis of inflammation and cancer, were evaluated in snake venom toxin (SVT)-induced apoptosis. Methods : Inflammation was induced in human HaCaT kerationocytes, by lipopolysaccharide (LPS; $1{\mu}g/mL$) or tumor necrosis factor-${\alpha}$ (TNF-${\alpha}$), followed by treatment with SVT (0, 1, or $2{\mu}g/mL$). Cell viability was assessed by MTT assays after 24 h, and the expression of levels of IL-4, STAT6, and the apoptosis-related proteins p53, Bax, and Bcl-2 were evaluated by western blotting. Electro mobility shift assays (EMSAs) were performed to evaluate the DNA binding capacity of STAT6. Results : MTT assays showed that inflammation-induced growth of HaCaT cells following LPS or TNF-${\alpha}$ stimulation was inhibited by SVT. Western blot analysis showed that p53 and Bax, which promote apoptosis, were increased, whereas that of Bcl-2, an anti-apoptotic protein, was decreased in a concentration-dependent manner in LPS- or TNF-${\alpha}$-induced HaCaT cells following treatment with SVT. Moreover, following treatment of HaCaT cells with LPS, IL-4 concentrations were increased, and treatment with SVT further increased IL-4 expression in a concentration-dependent manner. Western blotting and EMSAs showed that the phosphorylated form of STAT6 was increased in HaCaT cells in the context of LPS- or TNF-${\alpha}$-induced inflammation in a concentration-dependent manner, concomitant with an increase in the DNA binding activity of STAT6. Conclusion : SVT can effectively promote apoptosis in HaCaT cells in the presence of inflammation through a pathway involving IL-4 and STAT6.

Design and Performance Evaluation of Load-Modulation MIMO System Using High-Order Modulation (고차 변조를 사용하는 Load-Modulation MIMO 시스템 설계와 성능 평가)

  • Lee, Dong-Hyung;An, Changyoung;Ryu, Heung-Gyoon
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.40 no.11
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    • pp.2121-2130
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    • 2015
  • In this paper, we analyze LM-MIMO (load-modulation multiple-input multiple-output) system with single RF chain. And then, we confirm that load modulation technique can support generation of high-order m-PSK modulation and m-QAM modulation in LM-MIMO system. Finally we evaluate performance of LM-MIMO system with load modulation. Conventional MIMO system requires a number of RF chains for expansion of MIMO dimension. A number of RF chains can cause various problems. On the other hand, although LM-MIMO system is expanded, LM-MIMO system requires single RF chain only. Therefore, LM-MIMO system has low-complexity and low power consumption. As results, we can confirm that load modulation of T-model can modulate high-order m-PSK and m-QAM singal. Also, we can confirm that $4{\times}4$ LM-MIMO system using load modulation has a similar performance to conventional $4{\times}4$ MIMO system.