• Title/Summary/Keyword: $T_2$-phase

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Formation of Phases and Mechanical Properties of YSZ-Based Thermal Barrier Coating Materials Doped with Rare Earth Oxides (희토류 산화물이 첨가된 YSZ 기반의 열차폐 코팅용 소재의 상 형성 및 기계적 특성)

  • Yong Seok Choi;Gye Won Lee;Sahn Nahm;Yoon suk Oh
    • Journal of Powder Materials
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    • v.30 no.5
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    • pp.402-408
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    • 2023
  • This study focused on improving the phase stability and mechanical properties of yttria-stabilized zirconia (YSZ), commonly utilized in gas turbine engine thermal barrier coatings, by incorporating Gd2O3, Er2O3, and TiO2. The addition of 3-valent rare earth elements to YSZ can reduce thermal conductivity and enhance phase stability while adding the 4-valent element TiO2 can improve phase stability and mechanical properties. Sintered specimens were prepared with hot-press equipment. Phase analysis was conducted with X-ray diffraction (XRD), and mechanical properties were assessed with Vickers hardness equipment. The research results revealed that, except for Z10YGE10T, most compositions predominantly exhibited the t-phase. Increasing the content of 3-valent rare earth oxides resulted in a decrease in the monoclinic phase and an increase in the tetragonal phase. In addition, the t(400) angle decreased while the t(004) angle increased. The addition of 10 mol% of 3-valent rare-earth oxides discarded the t-phase and led to the complete development of the c-phase. Adding 10 mol% TiO2 increased hardness than YSZ.

A Low-loss Phase Shifter with Harmonics Suppression Using Compact Hybrid Coupler (소형 하이브리드 커플러를 이용한 고조파가 억압된 저손실 위상 변위기)

  • Yoon, Ki-Cheol;Ji, Seung-Han;Lee, Jong-Chul
    • The Journal of The Korea Institute of Intelligent Transport Systems
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    • v.14 no.6
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    • pp.110-116
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    • 2015
  • In this paper, a compact low-loss reflector-type phase shifter with harmonic suppression using meander T-shaped branch-line coupler is suggested. The compact coupler for the phase shifter has a size of $22.2{\times}14.9mm^2$ while a conventional branch coupler has a size of $32.6{\times}27.8mm^2$. The phase shifter shows insertion losses of 0.19-0.28 dB at the center frequency of 2.1 GHz, and a measured maximum phase shift of $137^{\circ}$.

Investigation on structural symmetry of CsCoCl3·2H2O crystals by magic-angle spinning 1H and static 133Cs nuclear magnetic resonance

  • Park, Sang Hyeon;Jang, Du Chang;Jeon, Hara;Gyeong, Oh Yi;Lim, Ae Ran
    • Journal of the Korean Magnetic Resonance Society
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    • v.26 no.1
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    • pp.10-16
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    • 2022
  • The phase transition temperatures of CsCoCl3·2H2O crystals are investigated via differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA). Three endothermic peaks at temperatures of 370 K (=TC1), 390 K (=TC2), and 416 K (=TC3) were observed for phase transitions from CsCoCl3·2H2O to CsCoCl3·1.5H2O, to CsCoCl3·H2O, and then to CsCoCl3·0.5H2O, respectively. In addition, the spin-lattice relaxation time T in the rotating frame and T1 in the laboratory frame as well as changes in chemical shifts for 1H and 133Cs near TC1 were found to be temperature dependent. Our analyses results indicated that the changes of chemical shifts, T, and T1 are associated with structural phase transitions near temperature TC1. The changes of chemical shifts, T, and T1 near TC1 were associated with structural phase transitions, owing to the changes in the symmetry of the structure formed of H2O and Cs+ ions. Consequently, the structural symmetry in CsCoCl3·2H2O crystals based on temperature is discussed by the environments of their H and Cs nuclei.

Thermodynamic and Physical Properties of (NH4)2MnCl4·2H2O by Nuclear Magnetic Resonance Relaxation Times

  • Kim, Yoo Young
    • Journal of the Korean Magnetic Resonance Society
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    • v.23 no.2
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    • pp.40-45
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    • 2019
  • The phase transition temperatures and thermodynamic properties of $(NH_4)_2MnCl_4{\cdot}2H_2O$ grown by the slow evaporation method were studied using differential scanning calorimetry and thermogravimetric analysis. A structural phase transition occurred at temperature $T_{C1}$ (=264 K), whereas the changes at $T_{C2}$ (=460 K) and $T_{C3}$ (=475 K) seemed to be chemical changes caused by thermal decomposition. In addition, the chemical shift and the spin-lattice relaxation time $T_{1{\rho}}$ were investigated using $^1H$ magic-angle spinning nuclear magnetic resonance (MAS NMR), in order to understand the role of $NH_4{^+}$ and $H_2O$. The rise in $T_{1{\rho}}$ with temperature was related to variations in the symmetry of the surrounding $H_2O$ and $NH_4{^+}$.

A Study on the Drive Characteristics of SRM by 2-Phase Excitation Method (2상 여자방식에 의한 SRM의 운전특성에 관한 연구)

  • 문재원;오석규;안진우;이일천;황영문
    • The Transactions of the Korean Institute of Power Electronics
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    • v.3 no.4
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    • pp.412-417
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    • 1998
  • This paper suggests the drive characteristics of a Switched Reluctance Motor(SRM) by 2-phase excitation method. T This scheme excites 2 phases simultaneously, which is similar to 2-phase excitation method of a step motor. In this s scheme. the torque is produced by mutual inductances as well as self inductances. The abrupt change of a phase e excitation produces mechanical stresses and it results in vibration and noise. The acoustic noise is reduced remarkably t through the sequential phase excitation in the 2-phase excitation. Operational principle and characteristic comp없1son t to that of the conventional SRM show that this excitation scheme has some advantages including torque ripple and n noise reduction.

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Preparation of Seleinzed CuInSeS12T Thin Films P-type Conductivity (P형 전기전도도 특성을 갖는 $Selenized CuInse_2$ 박막의 제조)

  • 박성;김선재
    • The Transactions of the Korean Institute of Electrical Engineers
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    • v.43 no.2
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    • pp.296-302
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    • 1994
  • Polycrystalline CuInSeS12T thin were prepared by depositing Cu/In layer, which was sequentially sputtered varying the Cu/(Cu+In) mole ratio, on glass substrate and selenizing with selenium metal vapor in a nitrogen atmosphere. Compositional and structural, characterization was carried out by X-ray diffraction (XRD), wavelength-dispersive spectroscopy(WDS), and scanning electron microscope(SEM). Electrical characterization was carried out by the measurements of Hall effect, electrical resistivity. Large indium loss occurs in early stage of the selenization process. The selenized films which had mole ratios larger than 0.28 have chalcopyrite CuInSeS12T phase and these that had less mole ratios have sphalerite phase. The selenized films containing CuS1xTSe phase have Cu-rich CuInSeS12T phase and these that did not contain CuS1xTSe have In-rich CuInSeS12T phase. By optimizing the sputtering conditions,it is possible to fabricate CuInSeS12T thin films which have little secondary phases and an appropriate hole concentration (10S015T ~ 10S016TcmS0-3T) for solar cells.

Development of Advanced Wastewater Treatment System using Phototrophic Purple Non-sulfur Bacteria. (광합성 박테리아를 이용한 폐수의 고도처리시스템개발)

  • Lee, Sang-Sub;Joo, Hyun-Jong;Lee, Seok-Chan;Jang, Man;Lee, Taek-Gyeon;Sim, Ho-Jae;Shin, Eung-Bae
    • Microbiology and Biotechnology Letters
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    • v.30 no.2
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    • pp.189-197
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    • 2002
  • Twenty nine strains of photosynthetic purple nonsulfur bacteria were isolated from Kyonggi area in Korea. The isolated strains were identified as Rhodopseudomonas blastica, Rhodocyclus gelatinosus, Rhodocyclus tenuis, and Rhodopseudomonas rutila. The enhanced nutrients removal system for wastewater using phototrophic purple non-sulfur bacteria was developed. Experiments were performed into two Phases and the results were compared: the synthetic wastewater was tested for the removal efficiency of nutrients and organics during Phase 1 and the real wastewater during Phase2. Results showed that 97∼99% of organics were removed during Phase 1 and 96∼99% during Phase 2. Nutrients (nitrogen and phosphorus) were also removed efficiently: 85∼91% removal of T-N and 78∼92% removal of T-P were achieved for Phase 1, and 76∼89% removal of T-N and 73∼88% removal of T-P for Phase 2.

Fiber Fabry-Perot type Optical Current Transducer with Frequency Ramped Signal Processing Scheme

  • Park, Youn-Gil;Seo, Wan-Seok;Lee, Chung-E.;Taylor, Henry-F.
    • Journal of the Optical Society of Korea
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    • v.2 no.2
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    • pp.74-79
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    • 1998
  • The use of a fiber Fabry-Perot interferometer (FFPI) as an optical current transducer is demonstrated. A conventional inductive pickup coil converts the time-varying current I(t) being measured to a voltage waveform V(t) applied across a piezeolectric strip to which the FFPI is bonded. The strip experiences a longitudinal expansion and contraction, resulting in an optical phase shift ${\phi}(t)$ in the fiber proportional to V(t). This phase shift is measured using a frequency-modulated semiconductor light source, photodiodes to monitor the reflected light from the FFPI and the laser power, and a digital signal processor. Calibration routines compute V(t) and I(t) from the measured phase shift at a l KHz rate. Response to 60 Hz ac over the design range 0-1300A rms is characterized Transient response of the FFPI transducer is also measured.

Effect of Temperature on Mitotic Cycle of Rice Root Meristem Cells (벼 뿌리세포의 유사분열주기에 대한 배양온도의 영향)

  • 김재철;이승준;권성환;곽성희
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.35 no.1
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    • pp.65-72
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    • 1990
  • The mitotic cycle duration and component plase periods of rice (Oryza sativa L. 'Sumjinbyeo and Seokwangbyeo') root merisem cells at 15, 20, and 30$^{\circ}C$ were determined the use of tritiated thymidine, In this work, the time interval between the maxima of sequential mitotic appearances of marked cells was used to estimate the mitotic cycle duration (MCD) of rice, The MCD of rice of the cultivar 'Sumjinbyeo' and 'Seokwangbyeo' at 20. and 30$^{\circ}C$ was 12. and 20hr, respectively. But the MCD of 'Sumjinbyeo' and 'Seokwangbyeo' was 18 and 20hr, at 15$^{\circ}C$. respectively. The MCD decreased with increasing temperature, The duration of component phase of rice cultivar 'Seokwangbyeo' were essentially the same ratio at 20$^{\circ}C$ and 30$^{\circ}C$. but in 'Sumjinbyeo' cultivar the ratio of $G_1$ period was almost doubled while those of $G_2$ and M were decreased by almost two times at 20$^{\circ}C$ and 30$^{\circ}C$. Deoxyribonucleic acid (DNA). Ribonucleic acid (RNA), and protein synthesis were reduced with increasing temperature from 15$^{\circ}C$ to 30$^{\circ}C$ while the MCD was decreased, This result suggest that DNA, RNA and protein synthesis may not affect the MCD from 15$^{\circ}C$ to 30$^{\circ}C$ in rice.

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Frequency Responses of Ambulatory ECG Systems and Their Correction by a Compensation Circuit

  • Iwao, K.;Yokoi, A.;Suzuki, S.;Goto, T.;Doniwa, K.;Okajima, M.
    • Journal of Biomedical Engineering Research
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    • v.11 no.1
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    • pp.13-18
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    • 1990
  • Frequency responses of ambulatory electrocardiogram systems were measured. Phase shift was assessed by our improved Wagner's method. The characteristics of the systems were found much worse than that of ordinary ECG equipment both in gain and phase responses. The decay of -3dB in amplitude observed in 0.2Hz and the lead of 45 dog in phase was observed in 0.6Hz. In order to investigate which of these 2 responses play major role in generating false S -T deviation, mathe- matical filters were Composed in a computer and actual ECGs were fed. The false S-T deviation were found to be caused mostly by enormous lead in phase, and then, the compensation circuit to diminish the lead in phase was inserted in the commercial systemes. The compensated systems showed no false deviation in S-T segment.

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