• Bulletin of the Korean Chemical Society
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• v.27 no.10
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• pp.1708-1711
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• 2006

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2002.07b
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• pp.1148-1151
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• 2002

Dielectric ceramics with nominal composition of $(Ba_{0.93}Sr_{0.07}O)-0.5Sm_2O_3-4.5TiO_2$ was prepared using the conventional mixed oxide process-derived powder. Effect of $SiO_2$, $MnO_2$ and $Al_2O_3$ impurity addition on the microwave properties was examined in some detail. Measured relative permittivity $(\varepsilon_r)$ values were in the range of 53 to 59 and showed little dependence on impurity addition. In contrast, quality factor $(Q{\cdot}f)$ and temperature coefficient of resonant frequency $(\tau_f)$ values were greatly influenced by the type and the amount of impurities. It was found that 0.1~0.2wt% addition of $Al_2O_3$ was most effective for improving the properties, where ${\varepsilon}_r$, $Q{\cdot}f$ and $\tau_f$ values were 57.7, 10000, and +7ppm/$^{\circ}C$, respectively.

• 한국정보디스플레이학회:학술대회논문집
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• 2008.10a
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• pp.1343-1346
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• 2008

$KSrPO_4$ and $Sr_3(Al_2O_5)Cl_2$ phosphors doped with $Eu^{2+}$ emit a blue and orange-yellow luminescence under ultraviolet (UV) excitation at ~ 400 nm, respectivel, which can be used for making white light emitting diodes.

• Journal of the Korean Ceramic Society
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• v.47 no.1
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• pp.19-25
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• 2010

Traditional Kr$\ddot{o}$ger-Vink (K-V) notation defines sites in ionic crystals as interstitial or belonging to host ions. It enables description and calculations of combinations of native and foreign defects, including dopants and substituents. However, some materials exhibit inherently disordered partial occupancy of ions and vacancies, or partial occupancy of two types of ions. For instance, the high temperature disordered phases of $Bi_2O_3$, $Ba_2In_2O_5$, $La_2Mo_2O_9$, mayenite $Ca_{12}Al_{14}O_{33}$, AgI, and $CsHSO_4$ are all good ionic conductors and thus obviously contain charged point defects. But traditional K-V notation cannot account for a charge compensating defect in each case, without resorting to terms like "100% substitution" or "Frenkel disorder". the former arbitrary and awkward and the latter inappropriate. Instead, a K-V compatible nomenclature in which the partially occupied site is defined as the perfect site, has been proposed. I here introduce it thoroughly and provide a number of examples.

• Journal of the Korean Ceramic Society
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• v.39 no.1
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• pp.33-37
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• 2002

The phosphorescence powder, $SrA1_2O_4:Eu^{2+}$, synthesized by a Polymerized Complex Method(PCM), has been compared with that by a Solid-State Reaction(SSR), and their luminescence characteristics have been studied. The PCM powders were synthesized at $900^{\circ}C$ and the SSR powders at $1200^{\circ}C$. The size of PCM powders was about $0.1{\mu}m$ and one tenth of that of the SSR powders, which was due to the lower synthesized temperature. On the other hand, residual carbon in the PCM powders decreased with an increase in the crystallinity of host lattice, which was responsible for the non-white color of the powders. Both powders showed the maximum luminescence peaks around 520nm in the wave length at room temperature. However, the peak position for the PCM powders was shifted to a slightly lower wavelength and the value of half-width of the peak was broad comparing to that of the SSR powders, and the peak intensity decreased significantly. Such a change in the luminescence characteristics was due to the large difference in size for two types of powders and partly the residual carbon in the PCM powders.

• Journal of the Korean Physical Society
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• v.73 no.11
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• pp.1679-1683
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• 2018

Polycrystalline $BaSrCo_2(Fe_{1-x}Al_x)_{12}O_{22}$ (x = 0.00, 0.01, 0.05, and 0.10) samples were synthesized by polymerizable complex method. Based on the Rietveld refinement, crystal structures of the samples were found to be single-phased and determined to be rhombohedral with space group of R-3m. The hysteresis curves of the samples were measured under 15 kOe at various temperatures ranging from 4.2 and 295 K. It shows that they were not saturated with increasing Al ion contents due to the reduction of magnetic anisotropy. $M_{15kOe}$ was decreased with increasing Al ions contents. We expect that non-magnetic Al ions preferentially occupy the up-spin site of $18h_{VI}$, $3b_{VI}$, and $3a_{VI}$. The $M{\ddot{o}}ssbauer$ spectra of the samples were obtained at 295 K, and analyzed with sixsextets for Fe sites corresponding to the Y-type hexaferrite crystallography sites. The <$E_Q$> shows abrupt changes, and the <$H_{hf}$> shows abrupt decreases around x = 0.05 due to the coexistence of magnetic secondary phases.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.8 no.4
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• pp.626-633
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• 1998

For the fabrication of low temperature cofirable glass/ceramic with high dielectric constant, crystallizing glass [$SiO_2-TiO_2-RO (RO:BaO, CaO:SrO)$] was formed. The glass/ceramic composites were made by mixing this glass and alumina ceramic as filler, and its characteristics was investigated. With this glass compositon, it was possible to fabricate the glass which could be crystallized under $900^{\circ}C$. And it was found that the crystallizing temperature was changed in accordance with the composition of RO in glass. By adding $Bi_2O_3$ as flux, using $Al_2O_3$ as filler and sintering at $860^{\circ}C$, low temperature cofirable glass/ceramic with high dielectric constant was fabricated. The density of that composites was 3.96 g/$\textrm{cm}^3$, dielectric constant was 17 and Q. f was 600.

• Journal of the Korean Ceramic Society
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• v.24 no.4
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• pp.321-328
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• 1987

The chemical durability of six alumino fluorophosphate glass samples studied. The composition of glass varied with MgF2 content from 0 to 12.5wt% in 30AlF3-2MgF2-(50-x)MF2-10P2O5(M; Sr, Ba). Samples were maintained in distilled water at 95$^{\circ}C$ from 1 to 100hrs. Weight loss, pH change and leached elements of the solution, and IR transmittance of samples were measured and also their surfaces were observed by SEM. Chemical durabilities of these samples were increased with increasing MgF2 contents. The following various properties were increased rapidly up to 10 hours after that changed slowly. The sample after leached at 95$^{\circ}C$ during 100 hrs showed 0.5mg/$\textrm{cm}^2$ in weight loss. The pH of leached solution is 6.2 and concentration of Mg, Sr, and Ba element of that leached solution were 24,115 and 125 ppm, respectively. The infrared transmittance of leached sample decreased 7% compare to unleached one. And also SEM photomicrograph and EDS analysis showed that the corrosion of samples were decreased with respect to increasing MgF2 content.

• Journal of the Korean Chemical Society
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• v.44 no.4
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• pp.350-355
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• 2000

The compounds, CaAl$_2$(BO$_3$)$_2$O, SrAl$_2$(BO$_3$)$_2$O and BaAl$_2$(BO$_3$)$_2$O, are good host lattices for highly efficient $Eu^{2+}$ luminescence. The europium emission peaks at 450 nm in $Eu^{2+}$:CaAl$_2$(B0$_3$)$_2$O, 411 nm in $Eu^{2+}$: SrAl$_2$(BO$_3$)$_2$O and 375 nm in $Eu^{2+}$: BaAl$_2$(BO$_3$)$_2$O. The $Eu^{2+}$: CaAl$_2$(BO$_3$)$_2$O Phosphor shows a high output and should be a good maintenance in VUV Xe lamps. It is ideally suited for use in PDP phosphors. The $Eu^{2+}$ ion is interesting because the Stokes shift emission is a strong host dependent. The difference in the Stokes shift is oneimportant factor leadingto a difference in wavelength. If the 5d level of $Eu^{2+}$ ion is lower in energy,according to a decrease in the doping lattice size, then the emission wavelength will be longer and the Stokes shift will be smaller. Therefore, a knowledge of the relationship between the crystal lattice size and the Stokes shift. (orthe energy of the 5d level),is essential for beingable to predict $Eu^{2+}$ emission properties.

• Proceedings of the Korean Nuclear Society Conference
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• 1996.05c
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• pp.385-390
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• 1996

Cs는 AW500 에서 높은 분배계수 값(K$_{Cs}$>$10^3$$m\ell$/g)을 얻었으며 , Sr은 13X, 평형 용액의 pH=10의 조건에서 최대의 분배계수값(K$_{Sr}$~$10^4$$m\ell$/g)을 보였고, 평형용액의 pH 증가에 따라서 급격히 증가하는 경향을 보였다. 또한 AW500-Cs와 13X-Sr계는 고액비, 즉 V/m=40, 및 초기용액의 pH가 3 이상에서 최대의 분배계수 값을 얻었으며, 혼합제올라이트의 비(AW500/13X)가 1.5인 조건에서 Cs과 Sr을 효과적으로 동시에 분리할 수 있음 보았다. 그리고 1,10$0^{\circ}C$에서 배소한 AW500-Cs는 CsAlSi$_2$O$_{6}$로 재결정되며 , 13X-Sr은 SrAI$_2$Si$_2$O$_{8}$ 및 SiO$_2$상(phase)으로 재결정한다.