• Title/Summary/Keyword: $SmI_2$

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Studies on Spinel Ferrites (I) Effects of Addition of Rare-Earth Oxides on the Magnetic Properties of Mn-Zn Ferrites (Spinel Ferrite에 관한 연구 (I) Mn-Zn계 Ferrite의 자기특성에 대한 희토류산화물의 첨가효과)

  • 김태옥
    • Journal of the Korean Ceramic Society
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    • v.14 no.2
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    • pp.78-81
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    • 1977
  • The effects of variation in composition and the addition of small amount of the rare-earth oxides La2O3, CeO2 and Sm2O3 on the magnetic properties of Mn-Zn system ferrites, 0.5MnO.0.5ZnO.(1+0.1X) Fe2O3(X=-1, 0, 1, 2), were investigated in the range of frequencies of 0.1~100 kHz. It was shown that the magnetic permeability of the specimens with the composition Mn 0.5 Zn 0.5 Fe2O4 was maximum in the Mn-Zn system ferrites, and that the addition of a small amount of the rare-earth oxides to the composition 0.5 MnO.0.5ZnO.0.9 Fe2O3 caused the sharp increase of magnetic permeability and the decrease of the loss factors.

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Characteristics of $K_2NiF_4$-Type Oxides $(Sr,Sm)_2FeO_{~4}$

  • 요철현;이은석
    • Bulletin of the Korean Chemical Society
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    • v.17 no.4
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    • pp.321-324
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    • 1996
  • Sr1+xSm1-xFeO4-y solid solutions with a composition range 0.00 ≤x≤1.00 have been prepared at 1200 ℃ in air under normal atmospheric pressure. All the solutions exhibit the K2NiF4-type structure of tetragonal system. Mohr salt analysis shows that the mole ratio of Fe4+ ion to Fe3+ ion or the τ value increases with the x value. Nonstoichiometric chemical formulas have been formulated from the x, τ, and y values. Electrical conductivity was measured in the temperature range of 173-373 K under atmospheric air pressure. The conductivities of each sample are varied within the semiconductivity range. The conductivity at constant temperature increases steadily with x value and activation energies are varied from 0.14 to 0.32 eV. The conduction mechanism of the ferrite system may be proposed as a hopping model of conduction electrons between the mixed valence states. The Mossbauer spectrum for the composition of x=0.00 shows a six line pattern by which the existence of Fe3+(I.S.=0.32 mm/sec) can only be identified. The spectra for the compositions of x=0.50 and 1.00 presents broad single line patterns showing a mixed valence state.

Electrochemical Behavior of Light Lanthanide Ions in Nonaqueous Solution, Flow Injection Determination and Photochemical Characterization of Eight Coordinated Chelates of Heavy Metal Ions (Part I) Electrochemical Behavior of Light Lanthanide Ions in Nonaqueous Solution (물아닌용매에서 가벼운 란탄족 이온의 전기화학적 거동, 흐름주입에 의한 정량 및 중금속이온의 킬레이트형 8-배위 착물의 광화학적 특성 (제 1 보) 물아닌용매에서 가벼운 란탄족이온의 전기화학적 거동)

  • Kang, Sam-Woo;Pak, Chong-Min;Do, Lee-Mi;Song, Myoung-Kyu;Kim, Il-Kwang
    • Analytical Science and Technology
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    • v.7 no.3
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    • pp.361-369
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    • 1994
  • Voltammetric behavior of some light lanthanide ions($La^{3+}$, $Pr^{3+}$, $Nd^{3+}$, $Sm^{3+}$ and $Eu^{3+}$) in acetonitrile(AN) and dimethylformamide(DMF) has been investigated by direct current, differential pulse polarography and cyclic voltammetry. The reduction of $La^{3+}$, $Pr^{3+}$ and $Nd^{3+}$ in 0.1M TEAP proceeded directly to the metallic state through three-electron charge transfer of irreversible process where as $Sm^{3+}$ and $Eu^{3+}$ proceeded by charge transfer of two steps. As the results of the cyclic voltammetric investigation, the first step reduction of $Sm^{3+}$ and $Eu^{3+}$ were a quasireversible reaction, the second step reductions were an irreversible reaction. The cathodic peak currents of the differential pulse polarogram showed adsorptive properties at lower sweep rates and high concentrations of these metal ions. The peak potenital was shifted to a negative petential and the peak current decreased with the increase of percentage of water in AN. On the other hand, the peak potential was shifted to a positive potential and the peak current decreased with an increased percentage of water in DMF.

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A Study on the Influence of Atmospheres in Frictional Machining(Part II) (摩찰加工 에 있어서의 零圍氣 영향 에 관한 硏究 제2보)

  • 손명환
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.6 no.2
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    • pp.113-120
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    • 1982
  • In the previously reported Part I, the experimental results in frictional machining that finished medium carbon steel SM 50 C under 6 kinds of liquid atmospheres by using ceramic tip as a frictional tool was described. The present study reports the experimental results that all the machining conditions are same in the Part I except tool material changed ceramics into tungsten carbide. The ceramic tool material is a stable oxide and a non-metallic material, but the tungsten carbide has the metallic characteristics that adhere to carbon steel at about 750.deg.C. The present study shows th comparison of the experimental results for the above 2 kinds of frictional tool material.

A Study on the Behavior of Heavy Metal Ions and Hydration of Clinker Utilizing Municipal Solid Waste Incineration Ash (생활폐기물 소각재를 이용하여 합성한 클링커의 중금속 및 수화반응 거동에 관한 연구)

  • Ahn Ji Whan;Han Gi Chun;Han Ki Suk
    • Resources Recycling
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    • v.13 no.4
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    • pp.3-10
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    • 2004
  • The intension of this study is to produce ordinary portland cement using ash, both bottom ash and fly ash, obtained from municipal solid waste incineration ash (MSWI). We used limestone, waste molding sand, shale, slag from converting furnaces and fly ash as main raw materials and mixed them, setting the lime saturation factor (LSF) within 91.0, the silica modulus (SM) within 2.40, and iron modulus (IM) within 1.80. We conducted tests adding bottom ash alone 1, 2 and 3% by weight, respectively, and a mixture of bottom ash 0.9% and fly ash 0.1 % by weight. The result of analysis on clinker shows that the more ash is added, the lower the burnability index (B.I.) falls, lowering the mineral evolution of calcium silicate accordingly. From the measurement of compressive strength we have learned that the more ash is used, the lower the strength becomes.

Heritabilities and Genetic Correlations on Egg Compositions in Layers (난용계의 난구함분에 관한 유전력 및 유전상관)

  • 상병찬;한성욱;정선부
    • Korean Journal of Poultry Science
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    • v.16 no.2
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    • pp.83-89
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    • 1989
  • This study was conducted to estimate heritabilities, genetic and phenotypic correlations on egg compositions in layers. The data analysis were a total of 6,097 eggs in S. C. W. Leghorn and R. I. Red from March 1, 1980 to July 31, 1981. The results obtained are summarized as follows; 1. The average albumen weight at first egg, 300 and 500 days of age were 28.67, 36.25 and 37.51g in the S. C. W. Leghorn, and 28.95, 36.01 and 36.85g in the R. I. Red, respectively. The yolk weigh at first egg ,300 and 500 days were 9.21, 15.94 and17.86g in the S. C. W. Leghorn,9.46, 16.43 and 18.54g in the R. I. Red, respectively. The shell weight at first egg, 300 and 500 days were 4.04, 5.39 and 5.40g in the S. C. W. Leghorn, and 3.66, 5.13 and 5.28g, respectively. 2. The heritability estimates based on the variance of sire and dam components were 0.631-0.164 and 0.412-0.496 in the S. C. W. Leghorn,0.234-0.563 and 0.477-0.610 in the R. I. Red for albumen weight; 0.213-0.530 and 0.343-0.613 in the S. C. W. Leghorn, 0.253-0.437 and 0.389-0.477 in the R. I. Red for yolk weight; 0.427-0.602 and 0.336-0.409 in the S. C. W. Leghorn, 0.141-0.281 in the R. I. Red for shell weight, respectively. 3. The genetic correlation coefficients of egg compositions were as follows; In the S. C. W. Leghorn and R. I. Red, the coefficients between albumen weight and yolk weight, 0.082-0.339 and 0.142-0.465; between albumen weight and shell weight, 0.674-0.952 and 0.216-0.546; between yolk weight and shell weight,0.173-0.171 and 0.121-0.749, respectively.

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Flexural Strength of HSB Steel Girders Due to Inelastic Lateral-Torsional Buckling - Sections with Slender Web (HSB 강거더의 비탄성 횡비틂좌굴에 의한 휨강도 - 세장 복부판 단면)

  • Cho, Eun-Young;Shin, Dong-Ku
    • Journal of Korean Society of Steel Construction
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    • v.24 no.2
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    • pp.217-231
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    • 2012
  • The flexural behavior of HSB I-girder with a non-slender web attributed to inelastic lateral-torsional buckling under uniform bending was investigated using nonlinear finite element analysis of ABAQUS. The girder was assumed to have a compact or noncompact web in order to prevent premature bend-buckling of the web. The unbraced length of the girder was selected so that inelastic lateral-torsional buckling governs the ultimate flexural strength. The compression flange was also assumed to be either compact or noncompact to prevent local buckling of the elastic flange. Both homogeneous sections fabricated from HSB600 or HSB800 steel and hybrid sections with HSB800 flanges and SM570-TMC web were considered. In the FE analysis, the flanges and web of I-girder were modeled as thin shell elements. Initial imperfections and residual stresses were imposed on the FE model. An elasto-plastic strain hardening material was assumed for steel. After establishing the validity of the present FE analysis by comparing FE results with test results in existing literature, the effects of initial imperfection and residual stress on the inelastic lateral-torsional buckling behavior were analyzed. Finite element analysis results for 96 sections demonstrated that the current inelastic strength equations for the compression flange in AASHTO LTFD can be applied to predict the inelastic lateral torsional buckling strength of homogeneous and hybrid HSB I-girders with a non-slender web.

Fatty Acid Profiles and Sensory Properties of Longissimus dorsi, Triceps brachii, and Semimembranosus Muscles from Korean Hanwoo and Australian Angus Beef

  • Cho, Soohyun;Park, B.Y.;Kim, J.H.;Hwang, I.H.;Kim, J.H.;Lee, J.M.
    • Asian-Australasian Journal of Animal Sciences
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    • v.18 no.12
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    • pp.1786-1793
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    • 2005
  • The study compared the fatty acid profiles of 3 muscles (Longissimus dorsi, LD, Triceps brachii, TB and Semimembranosus, SM) obtained from Korean Hanwoo (18 steers, 24 months old) and Australian Angus beef (18 steers, 24 months old) and assessed their role in sensory perception. The samples of each carcass were prepared in the same manner, and cooked both as traditional grilled steaks and Korean BBQ style. A total of 720 Korean sensory panelists evaluated the beef samples for tenderness, juiciness, flavor, and overall liking. Oleic acid (18:1) was significantly (p<0.05) higher in TB than that in LD and SM. The essential linoleic acid (C18:2) was significantly (p<0.05) higher in TB and SM than that in LD. For LD muscle, the proportion of saturated fatty acids was significantly (p<0.05) highest, while that of polyunsaturated fatty acids was lowest among the three muscles. Australian Angus beef had significantly (p<0.05) higher n-3 PUFA than that of the Korean Hanwoo for the three muscles, while the latter contained significantly (p<0.05) higher n-6 PUFA than that of the former. The clustering analysis showed that there a was significant difference in fatty acids such as C16:0, C16:1n7, C18:0, C18:2n6, C18:3n3, C20:3n6, C20:4n6, C22:4n6, and C22:5n3 for sensory perception (tenderness, juiciness, flavor and overall likeness) of the beef from two origins (p<0.05) among three clusters. Especially, C14:0 had a significant effect on sensory perception only for Korean Hanwoo beef; while C20:5n3 had a significant (p<0.05) effect only for Australian Angus beef based on clustering with the sensory variables.