• Title/Summary/Keyword: $SO_X$

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The removing characteristic of harmful exhaust from a motorcycle using non-thermal plasma (플라즈마를 이용한 이륜자동차 배출가스저감 특성)

  • Kim, Young-Ju;Park, Hong-Jae;Jung, Jang-Gun;Lee, Jae-Dong;Park, Jae-Yoon;Koh, Hee-Seog
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.07b
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    • pp.1127-1130
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    • 2003
  • In the last several centuries, humankind have been experienced the material abundance with a development of technical civilization and being industrialized quickly. During the process of this, environmental pollutant have occurred naturally so that humankind have more interests for environment pollutant. Air pollution caused by exhaust from a car is very harmful for human. Most of exhaust from a gasoline engine are $CO_x(CO+CO_2),\;NO_x(NO+NO_2)$, and THC(Total Hydrocarbon). The method to remove these kinds of noxious gases are so many thing such as the three catalysts, $NO_x$ catalysts, Filter and so on. However, although air pollution caused by exhaust from motorcycle have also occurred very much, there is no regulation for motorcycle. In this paper, we studied to remove $CO_x(CO+CO_2),\;NO_x(NO+NO_2)$, THC exhaust from a motorcycle using non-thermal plasma In the result, $NO_x(NO+NO_2)$ concentration was decreased approximately 70% and THC(Total Hydrocarbon) was removed about 40%.

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Simultaneous Removal of $SO_2$ and NOx Using Ozone Generator and Absorption- Reduction Technique (오존발생장치와 흡수환원법을 이용한 배기가스 동시 탈황 탈질 공정)

  • Mok, Young-Sun;Lee, Joo-Hyuck;Shin, Dong-Nam;Koh, Dong-Jun;Kim, Kyong-Tae
    • Journal of Korean Society of Environmental Engineers
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    • v.28 no.2
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    • pp.191-196
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    • 2006
  • The injection of ozone, produced by dielectric barrier discharge, into the exhaust gas gives rise to a rapid oxidation of NO that is the main component of nitrogen oxides($NO_x$) in most practical exhaust gases. Once NO is converted into $NO_2$, it on readily be reduced to $N_2$ in the next step by a reducing agent such as sodium sulfide and sodium sulfite. The reducing agents used ca also remove $SO_2$ effectively, which makes it possible to treat $NO_x\;and\;SO_2$ simultaneously. The present two-step process made up of an ozonizing chamber and an absorber containing a reducing agent solution was able to remove about 95% of the $NO_x$ and 100% of the $SO_2$, initially contained in the simulated exhaust gas. The formation of $H_2S$ from sodium sulfide was prevented by using a strong basic reagent(NaOH) together with the reducing agent. The removal of $NO_x$\;and\;SO_2$ was more effective for $Na_2S$ than $Na_2SO_3$.

Thermal Behavior of the Layered Structure in Metal-dodecanesulfonate intercalation compounds, [M($H_2O$)$_6$](C$_12$H$_25$SO$_3$)$_2$.x$H_2O$ (M=Co, Cu) (도데칸술폰이 삽입된 금속 화합물, [M($H_2O$)$_6$(C$_12$H$_25$SO$_3$)$_2$.x$H_2O$ (M=Co, Cu)의 층상 구조의 열적 성질)

  • 허영덕;박성훈;전태현
    • Journal of the Korean institute of surface engineering
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    • v.33 no.1
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    • pp.25-33
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    • 2000
  • The synthesis and characterization of intercalated compound of dodecanesulfornate into hydrated metal, [M($H_2$O)\ulcorner](C\ulcornerH\ulcorner$SO_3$)$_2$.$xH_2$O (M=Co, Cu) was presented. The compounds shows a layered structure which was determined by powder X-ray diffraction. Thermal behavior of the layered structure was investigated using thermal analysis, and FT-IR spectroscopy by varying the temperature. The increase in layer spacing of the products by increasing the temperature is also checked by X-ray diffraction. We can suggest three kinds of layered structure by varying the temperature, which is accompanied by changing the intercalated dodecanesulfonate from the monolayer to the bilayer structure or changing the tilt angle.

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The development of a ceramic filter with dust $/SO_x/NO_x$ removal ability (II) (먼지$/SO_x/NO_x$ 동시처리용 세라믹 필터 개발에 관한 연구)

  • 신현규;김영배;엄우식;이희수;김영길
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 1999.10a
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    • pp.461-462
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    • 1999
  • 고온고압의 연소 분위기를 생성시키는 석탄이용 발전 시스템 및 소각로, 유리공장 등에서 발생되는 먼지 및 유해가스 제거 기술은 세계적으로 문제시되고 있는 환경오염 차원에서 필수적으로 요구되어지는 기술이라 할 수 있다. 이러한 고온고압의 시스템에서 사용될 수 있는 필터로 현재 세라믹이 가장 적절한 재질로 평가되고 있는데 이는 세라믹 자체가 지닌 열적 안정성 때문이라고 할 수 있다.(중략)

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Efficient Desulfurization and Denitrification by Low Temperature Plasma Process (저온 플라즈마 공정에 의한 효율적인 탈황 및 탈질)

  • Kim, Sung-Min;Kim, Dong-Joo;Kim, Kyo-Seon
    • Korean Chemical Engineering Research
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    • v.43 no.1
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    • pp.129-135
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    • 2005
  • In this study, we have analyzed the removal efficiencies of $SO_2$ and $SO_2/NO$ by the pulsed corona discharge process and investigated the effects of several process variables on those removal efficiencies systematically. The effects of process variables such as applied voltage, pulse frequency, residence time, and initial concentrations of reactants (NO, $SO_2$, $NH_3$, $H_2O$, and $O_2$) on the removal efficiency were analyzed. As the applied voltage, the pulse frequency or the residence time increases or as the $O_2$ or the $H_2O$ or the $NH_3$ concentration in the inlet feed gas stream increases, the $SO_2$ removal efficiencies and the simultaneous removal efficiencies of $SO_2/NO$ also increase. These experimental results can be used as a basis to design the pulsed corona discharge process to remove $NO_x$ and $SO_x$.

Pollutants Behavior in Oxy-CFBC by Application of In-Furnace deSOx/deNOx Method (순산소 순환유동층에서 로내 탈황 및 탈질법 적용에 따른 오염물질 거동특성)

  • Choi, Gyung-Goo;Na, Geon-Soo;Shin, Ji-Hoon;Keel, Sang-In;Lee, Jung-Kyu;Heo, Pil-Woo;Yun, Jin-Han
    • Clean Technology
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    • v.24 no.3
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    • pp.212-220
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    • 2018
  • Oxy-fuel combustion is considered as a promising greenhouse gas reduction technology in power plant. In this study, the behaviors of NO and $SO_2$ were investigated under the condition that in-furnace $deNO_x$ and $deSO_x$ methods are applied in oxy-fuel circulating fluidized bed combustion condition. In addition, the generation trends of $SO_3$, $NH_3$ and $N_2O$ were observed. For the purpose, limestone and urea solution were directly injected into the circulating fluidized bed combustor. The in-furnace $deSO_x$ method using limestone could reduce the $SO_2$ concentration in exhaust gas from ~403 to ~41 ppm. At the same experimental condition, the $SO_3$ concentration in exhaust gas was also reduced from ~3.9 to ~1.4 ppm. This trend is mainly due to the reduction of $SO_2$. The $SO_2$ is the main source of the formation of $SO_3$. The negative effect of $CaCO_3$ in limestone, however, was also appeared that it promotes the NO generation. The NO concentration in exhaust gas reduced to ~26 - 34 ppm by appling selective non-catalytic reduction method using urea solution. The $NH_3$ concentration in exhaust gas was appeared up to ~1.8 ppm during injection of urea solution. At the same time, the $N_2O$ generation also increased with increase of urea solution injection. It seems that the HNCO generated from pyrolysis of urea converted into $N_2O$ in combustion atmosphere. From the results in this study, the generation of other pollutants should be checked as the in-furnace $deNO_x$ and $deSO_x$ methods are applied.

Empirical Analysis on Determinants of Air Pollution in China (중국의 대기오염 배출 결정요인에 대한 경험적 분석)

  • Li, Dmitriy D.;Wang, Wen;Bae, Jeong Hwan
    • Environmental and Resource Economics Review
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    • v.29 no.1
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    • pp.23-45
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    • 2020
  • The rapid economic growth has brought tremendous pressure on the environment and caused severe air pollution in China. This study empirically examines causes of air pollution in China. Panel-corrected standard errors procedure (PCSE) was used to analyze major determinants of increasing or reducing emissions of sulfur dioxide (SO2) and nitrogen oxides (NOX) in 30 Chinese provinces. The estimation results show that SO2 emission is mitigated as per capita regional GDP increases, but the relation between emission of NOX and per capita regional GDP is found to have an inverse N-shaped curve, which implies that emission of NOX is ultimately expected to decline with economic growth. As for increasing factors of air pollutants, electricity consumption is a significant common source of SO2 and NOX emissions. Moreover, the results show that increment of coal consumption significantly affects emission of SO2 while increase of natural gas consumption reduce emission of SO2. On the other side, investment in energy industry, and investment on treatment of waste gases are determinants of mitigating emissions of SO2, but have no impact on NOX. Consumption of diesel, truck ratio and number of vehicles increase emission of NOX. Meanwhile, higher precipitation rate is a common determinant of mitigating emissions of SO2 and NOX. Policy implications are suggested in the conclusion.

The Effect of SO2-O2 Mixture Gas on Phase Separation Composition of Bunsen Reaction with HIx solution (HIx 용액을 이용한 분젠 반응에서 상 분리 조성에 미치는 SO2-O2 혼합물 기체의 영향)

  • Han, Sangjin;Kim, Hyosub;Ahn, Byungtae;Kim, Youngho;Park, Chusik;Bae, Kikwang;Lee, Jonggyu
    • Transactions of the Korean hydrogen and new energy society
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    • v.23 no.5
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    • pp.421-428
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    • 2012
  • The Sulfur-Iodine (SI) thermochemical hydrogen production process is one of the most promising thermochemical water splitting technologies. In the integrated operation of the SI process, the $O_2$ produced from a $H_2SO_4$ decomposition section could be supplied directly to the Bunsen reaction section without preliminary separation. A $HI_x$ ($I_2+HI+H_2O$) solution could be also provided as the reactants in a Bunsen reaction section, since the sole separation of $I_2$ in a $HI_x$ solution recycled from a HI decomposition section was very difficult. Therefore, the Bunsen reaction using $SO_2-O_2$ mixture gases in the presence of the $HI_x$ solution was carried out to identify the effect of $O_2$. The amount of $I_2$ unreacted under the feed of $SO_2-O_2$ mixture gases was little higher than that under the feed of $SO_2$ gas only, and the amount of HI produced was relatively decreased. The $O_2$ in $SO_2-O_2$ mixture gases also played a role to decrease the amount of a impurity in $HI_x$ phase by only striping effect, while that in $H_2SO_4$ phase was hardly affected.

GROUPOID AS A COVERING SPACE

  • Park, Jong-Suh;Lee, Keon-Hee
    • Bulletin of the Korean Mathematical Society
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    • v.21 no.2
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    • pp.67-75
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    • 1984
  • Let X be a topological space. We consider a groupoid G over X and the quotient groupoid G/N for any normal subgroupoid N of G. The concept of groupoid (topological groupoid) is a natural generalization of the group(topological group). An useful example of a groupoid over X is the foundamental groupoid .pi.X whose object group at x.mem.X is the fundamental group .pi.(X, x). It is known [5] that if X is locally simply connected, then the topology of X determines a topology on .pi.X so that is becomes a topological groupoid over X, and a covering space of the product space X*X. In this paper the concept of the locally simple connectivity of a topological space X is applied to the groupoid G over X. That concept is defined as a term '1-connected local subgroupoid' of G. Using this concept we topologize the groupoid G so that it becomes a topological groupoid over X. With this topology the connected groupoid G is a covering space of the product space X*X. Further-more, if ob(.overbar.G)=.overbar.X is a covering space of X, then the groupoid .overbar.G is also a covering space of the groupoid G. Since the fundamental groupoid .pi.X of X satisfying a certain condition has an 1-connected local subgroupoid, .pi.X can always be topologized. In this case the topology on .pi.X is the same as that of [5]. In section 4 the results on the groupoid G are generalized to the quotient groupoid G/N. For any topological groupoid G over X and normal subgroupoid N of G, the abstract quotient groupoid G/N can be given the identification topology, but with this topology G/N need not be a topological groupoid over X [4]. However the induced topology (H) on G makes G/N (with the identification topology) a topological groupoid over X. A final section is related to the covering morphism. Let G$_{1}$ and G$_{2}$ be groupoids over the sets X$_{1}$ and X$_{2}$, respectively, and .phi.:G$_{1}$.rarw.G$_{2}$ be a covering spimorphism. If X$_{2}$ is a topological space and G$_{2}$ has an 1-connected local subgroupoid, then we can topologize X$_{1}$ so that ob(.phi.):X$_{1}$.rarw.X$_{2}$ is a covering map and .phi.: G$_{1}$.rarw.G$_{2}$ is a topological covering morphism.

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