• Bulletin of the Korean Chemical Society
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• v.31 no.4
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• pp.1077-1080
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• 2010

• Korean Journal of Environmental Biology
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• v.18 no.1
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• pp.33-39
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• 2000

Gordona sp. MS6, desulfurizing petroleum, can convert dibenzothiophene (DBT) to 2-hydroxybiphenyl (2-HBP) and sulfate. In this study, the effect of DBT degradation product on DBT desulfurization activity was investigated. When $Na_2$SO$_4$ and DBT were simultaneously added in the medium sulfur sources, specific growth rate of strain MS6 was doubled compared to not adding $Na_2$SO$_4$. But, sulfate inhibited DBT desulfurization rate, furthermore, when 0.05 g/L $Na_2$SO$_4$ was supplied DBT desulfurization rate decreased down to 40%. When 2-HBP and its derivative, 2, 2'-dihydroxybiphenyl (DHBP) were not added, DBT desulfurization rate was 5.0 $\mu$mol L$^{-1}$ㆍh$^{-1}$. With the increase of 2-HBP and DHBP concentration, DBT desulfurization rate was decreased. No DBT desulfurization activity of Gordona sp. MS6 was observed when initial concentration was over 0.15 mM 2-HBP and 0.8 mM DHBP [Gordona sp., Desulfurization, Dibenzothiophene, 2-Hydroxybiphenyl, Sulfate].

• Journal of radiological science and technology
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• v.16 no.2
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• pp.51-60
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• 1993

The $CaSO_4$ : Tm-PTFE TLDs have been prepared and their energy dependences of TL intensity to X-rays have been investigated. The dose dependence of the prepared $CaSO_4$ : Tm-PTFE TLDs is linear within the range of $100{\mu}Gy-10Gy$ for X-rays and gamma rays. The spectral peaks of TL emission spectrum are at about 350nm and 475nm. The fading rate of the main peak has been found to be about 2% for 30days when $CaSO_4$ : Tm-PTFE TLDs stored in the dark room at room temperature. The energy dependence of $CaSO_4$ : Tm-PTFE TLD has been compensated by combining the TL responses of one bare TLD and five TLDs filtered with 1.0mm Al, 0.2mm Cu, 0.5mm Cu, 1.5mm Cu, 2.0mm Pb respectively. The determined correction coefficients for filter combination are $a_0=0.078,\;a_1=-0.009,\;a_2=-0.235,\;a_3=0.588,\;a_4=0.568\;and\;a_5=0.180$ respectively. From the results of these studies, the prepared TLD badge of six dosimeter combination may be useful as a radiation dosimeter for personal and environmental monitoring.

• Journal of Environmental Health Sciences
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• v.16 no.2
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• pp.11-20
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• 1990

To investigate ionic characteristics of acid rain by the succeeding rainfall. bulk precipitation was collected every each 5mm rainfall from march to october 1990 at Dae Jeon area. pH, sulfate nitrate, chloride, ammonium ion was measured and analyzed. The result was as follows: 1. The weighted average pH of rain was 5.1$\pm$ 0.72(4.15~7.6) and rain pH less than 5.5 was appeared 51.3% 2. Average ion concentrations of sulfate, nitrate, chloride and ammonium ion was 125.12 $\mu$eq/l, 62.38 $\mu$eq/l, 31.95 $\mu$eq/l, 66.6 $\mu$eq/l and rates of each anions was 57%, 28.4%, 14.6% and rate of sulfate by nitrate was 2 times. 3. There is no correlations time interval of rainfall and Ion concentration change. 4. From initial to 15mm rainfall, each ion concentrations were decreased. and average concentration of pH, SO$^{-2}_{4}$, Cl ion concentration was increased in the succeeding rainfall 5. Only sulfate ion was correlated by the simple regression analysis with pH except NO$^{-}_{3}$, Cl$^{-}$ and NH$_{4}^{+}$ Cl$^{-}$ correlation coefficient was very high at the multiple regression analysis with pH. 6. Simple & multiple correlation coefficient among anions and NH$^{+}_{4}$ was very high especially N$^{+}_{4}$ and SO$^{2-}_{4}$ at simple regression analysis and SO$^{-2}_{4}$ and NO$_{3}^{-}$, Cl$^{-}$, NH$_{4}^{-}$ at multiple regression analysis.

• Proceedings of the Korea Air Pollution Research Association Conference
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• 2000.11a
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• pp.247-248
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• 2000

산업규모의 급속한 팽창과 더불어 에너지원의 확보에 석탄이 차지하는 비중이 커지고, 산업경제의 부산물인 쓰레기의 처리가 매립에서 소각방식으로 바뀌어가고 있는 시점에서 산업연료사용량과 난방부분의 에너지 사용량이 급속히 증가하고 있다. 이러한 인간의 생산활동으로 인해 대기 중으로 배출되는 가스는 크게 연소가스와 소각가스로 분리할 수 있는데 대표적인 연소가스로써는 SO$_2$가 있으며, 소각가스로는 HCl이 있다. (중략)

• Analytical Science and Technology
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• v.27 no.4
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• pp.213-222
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• 2014

The atmospheric aerosols of $PM_{10}$ and $PM_{2.5}$ were collected at Gosan site of Jeju Island during 2012- 2013. Their ionic and elemental species were analyzed in order to examine the composition variation of the haze aerosols in accordance with the pathway of air mass. The concentrations of $nss-SO_4{^{2-}}$, $NO_3{^-}$, and $NH_4{^+}$ increased 2.1~3.7 times in coarse particle and 3.1~6.5 times in fine particle modes, respectively, showing especially high $NO_3{^-}$ concentrations in fine particles during the haze days. The concentrations of S, Zn, Pb and K increased 3.0~5.6 times in coarse particles and 3.2~7.7 times in fine particles during the haze days, on the other hand Al, Fe, and Ca concentrations were high only in coarse particles. Due to the back trajectory analysis, the concentrations of $nss-SO_4{^{2-}}$ and $NO_3{^-}$ for haze days were high when the inflow pathway of air mass was from China, especially a high increase of $NO_3{^-}$ as through the south of China. The $NO_3{^-}/nss-SO_4{^{2-}}$ concentration ratio was relatively high in coarse mode as air mass inflow from China, but in fine mode it was high as air mass passing through the Korean peninsula.

• Journal of Environmental Health Sciences
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• v.26 no.2
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• pp.41-48
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• 2000

This study has been carried out to determine the seasonal characteristics of concentration of various ionic (CI-, NO3-, SO42-, Na+, NH+, K+, Ca2+) and heavy metallic (Pb, Mn, Cu, Ni) species in Pusan from August 1997 to April 1998. The concentrations of CI-, Na+, K+ were higher during summer with 2.98 ${\mu}{\textrm}{m}$/㎥. Seasonal variation of total concentration of but the concentration of NH4+ was higher during winter with 2.46${\mu}{\textrm}{m}$/㎥. Seasonal variation of total concentration of heavy metals(Pb, Cu, Mn, Ni) were 186.0 ng/㎥ in summer, 222.6 ng/㎥ in autumn, and 135.83 ng/㎥ in winter. Over the seasons inspected, the concentration of Mn was higher in coarse particles than fine particles and concentration of Ni was higher in fine particles than coarse particles. during yellow sand period, the concentration of TSP was increased about two times than that of other period. SO42-, Ca2+ concentrations were higher than other ionic components because of soil particles. The concentration of Ni showed 94.62ng/㎥ was increased about 4~5 times than other period. Principal component of the yellow sand, SO42-, Ca2+ could be discreased by rainfall and washout effect of atmospheric aerosol was higher in coarse particles than fine particles. Results from PCA(principal component analysis) showed that major pollutant was NaCl by seasalt particulate and (NH4)2SO4.

• Journal of the Mineralogical Society of Korea
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• v.27 no.1
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• pp.53-62
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• 2014

In order to remove Fe impurity from low-grade pyrophyllite ore, the effect of certain variables such as particle size, concentration of sulfuric acid, amount of ammonium sulfate, added hydrogen peroxide, and temperature were studied. The euhedral cubic pyrites were observed in the low-grade pyrophyllite ore by reflected light microscopy, and quartz and dickite were identified in the sample by XRD analysis. The results of the Fe removal experiments showed that the best Fe removal parameters were when the particle size was at -325 mesh, the addition of $H_2SO_4$, $(NH_4)_2SO_4$ and $H_2O_2$ was at a 2.0 M, 10.0 g/l, and 3.0 M concentration, respectively, and at a $70^{\circ}C$ leaching temperature. In the dissolution kinetics analysis, the dissolution of Fe from the pyrite surface was a controlled chemical reaction, and the Fe dissolution reaction was proportioned to 0.066/R, $[H_2SO_4]^{1.156}$, $[(NH_4)_2SO_4]^{0.745}$, $[H_2O_2]^{0.428}$.

• The Journal of Korean Medicine
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• v.17 no.2 s.32
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• pp.178-190
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• 1996

This experiment was performed in order to study the effects of Haepyoyijintang on the pulmonary injury caused by $SO_2$. Healthy adult male rats weighting about 250g were divided into 4 groups- the Normal group, the Control group, the group of Haepyoyijintang administration for 5 days after $SO_2$ gas exposure (Sample I ), and the group of Haepyoyijintang administration for 10 days before and for 5 days after $SO_2$ gas exposure (SampleⅡ). The results were obtained as follows; 1. In the total number of leucocyte, Sample I and Sample II decreased significantly compared with Control group. 2. In the erythrocyte sedimentation rate, Sample I and Sample Ⅱ decreased significantly compared with Control group. 3. In the lung weight, Sample I and Sample II decreased significantly compared with Control group. 4. In the lung TBA level, only Sample II decreased significantly compared with Control group. 5. In the tracheal glycoprotein level, Sample I and Sample II decreased significantly compared with Control group. According to the above results, Haepyoyijintang has significant effects on the pulmonary injury caused by $SO_2$ in rats.

• Journal of Korean Society for Atmospheric Environment
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• v.5 no.1
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• pp.22-32
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• 1989

In order to assess the level of atmospheric pollution and to contribute the health improve ment of residents in Pusan, the authors measured the $CO, SO_2, NO_2, TSP, Noise, Pb, Cd, Cr and V$ level at 3 place by time from Jan. 1988 to Feb. 1988. THe places were Kukje, Daehyeon, Pujeon underground commercial floor. The results were as follows; 1. The range of concentration of air pollutants (1) CO : 0.5 - 3.0 ppm (2) $SO_2$ : 0.012 - 0.360 ppm (3) $NO_2$ : 0.018 - 0.089 ppm (4) TSP : 30 - 330 $\mug/m^3$ (5) Pb : 0.219 - 3.116 $\mug/m^3$ (6) Cd : 0.000 - 0.070 $\mug/m^3$ (7) Cr : 0.378 - 4.098 $\mug/m^3$ (8) V : 0.000 - 1.010 $\mug/m^3$ (9) Noise : 47 - 77 dB(A) 2. The level of all air pollutants were higher in the afternoon or night than in the morning. 3. The mean concentration of $SO_2$ in all places exceede the ambient air quality standard of $SO_2$,.