• Title/Summary/Keyword: $SO_4^{2-}$

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Magnesium-induced Relaxation in Rat Aorta (Magnesium에 의한 흰쥐 대동맥 이완)

  • Oh, Sung-suck;Lee, Sang-woo;Kang, Hyung-sub;Kim, Jin-shang
    • Korean Journal of Veterinary Research
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    • v.43 no.3
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    • pp.373-382
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    • 2003
  • Magnesium ion ($Mg^{2+}$) is a vasodilator, but little is known about its mechanism of action on vascular system. In vitro, extracellular magnesium sulfate ($MgSO_4$) produced relaxation in phenylephrine (PE) or high KCl-precontracted isolated rat thorocic aorta with (+E) or without (-E) endothelium in a concentration-dependent manner. The $MgSO_4$-induced relaxations were not affected by removal of the endothelium. Pretreatment of +E or -E aortic rings with nitric oxide synthase (NOS) inhibitors ($20{\mu}M$ L-NNA, $100{\mu}M$ L-NAME, $1{\mu}M$ dexamethasone and $400{\mu}M$ aminoguanidine), cyclooxygenase inhibitor ($10{\mu}M$ indomethacin), guanylate cyclase inhibitors ($10{\mu}M$ ODQ and $30{\mu}M$ methylene blue) and $Ca^{2+}$ transport blocker ($10{\mu}M$ ryanodine) did not affect the relaxant effects of $MgSO_4$. $Ca^{2+}$ channel blockers ($0.3{\mu}M$ nifedipine and $0.5{\mu}M$ veropamil) completely decreased the relaxant effects of $MgSO_4$ in +E and -E aortic rings. However, in $Ca^{2+}$-free medium, $MgSO_4$-induced vasorelaxation was potentiated and this response was inhibited by nifedipine. Protein kinase C (PKC) inhibitors ($1.0{\mu}M$ staurosporine, $0.5{\mu}M$ tamoxifen and $0.1{\mu}M$ H7) or PLC inhibitor ($100{\mu}M$ NCDC) markedly decreased the relaxant effects of $MgSO_4$ in +E and -E aortic rings. In vivo, infusion of $MgSO_4$ elicited significant decreases in arterial blood pressure. After intravenous injection of nifedipine ($150{\mu}g/kg$) and NCDC (3 mg/kg), infusion of $MgSO_4$ inhibited the $MgSO_4$-lowered blood pressure markedly. However, after introvenous injection of saponin (15 mg/kg), L-NNA (3 mg/kg), L-NAME (5 mg/kg), indomethacin (2 mg/kg), methylene blue (15 mg/kg) and aminoguanidine (10 mg/kg) failed to inhibit it. These results suggest that endothelial NQ-cGMP or prostaglandin pathway is not involved in vasorelaxant or hypotensive action of $Mg^{2+}$ and that these effects are due to the inhibitory action of $Mg^{2+}$ on the $Ca^{2+}$ channel or PLC-PKC pathway, and are due to the competitive influx of $Mg^{2+}$ and $Ca^{2+}$ through the $Ca^{2+}$ channel.

Effective Chrome Removal Process from Shaving Dust (피혁분의 효율적인 탈 크롬 방법에 관한 연구)

  • Yun, Sun-Gyu;Park, Sung-Ha;Lee, Sang-Seob;Na, Jung-Won;Ko, Myung-Han
    • Applied Chemistry for Engineering
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    • v.10 no.8
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    • pp.1104-1108
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    • 1999
  • In this study it was focused that if the chrome could be removed in the shaving dust, the reusable protein resource could be recycled from the shaving dust. As the chrome forms a Cr-collagenate by cross linking of collagen in the shaving dust, the dust was steeped for swelling and plumping by $Ca(OH)_2$ solution and then chromium in dust was resolved out by $H_2SO_4$ solution in the first stage process. In the second stage one, dust was swelled and plumped by NaOH solution and then the chromium in dust was oxygenated to a hexavalent chrome, which has high solubility in $H_2O_2$ solution. And then the chromium was removed byt he steeping of $H_2SO_4$ solution as the last process. The first stage process was consisted of the sequential steeping of 3%-$Ca(OH)_2$ and $0.8%-H_2SO_4$. In the second stage the total chrome was effectively removed by the sequential steeping of 0.1%-NaOH, $3%-H_2O_2$ and $1%-H_2SO_4$. In the completely dechromated dust, the humidity was measured as 10.68% and the crude protein was contained by 79.81%. Steeping solutions were reused 3 times for chrome removal process, the chrome was entirely removed in shaving dust.

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The relative contribution of SO$_2$-to-sulfate conversion processes over the metropolitan Seoul Area (수도권에서 아황산가스의 황산염으로 전환시 각 과정의 상대적 기여도)

  • 배수야;김용표
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 2003.05b
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    • pp.353-354
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    • 2003
  • 대기 중에서 여러 과정을 통해 아황산가스 (SO$_2$)가 황산 (H$_2$SO$_4$)으로 산화된다. 황산은 증기압이 낮아 대기 중에서는 대부분 황산염 (SO$_4$$^{2-}$ ) 에어로졸로 존재한다. 황산염 에어로졸은 직간접적으로 지구복사평형에 관여하여 기후와 기상에 영향을 미친다. 이 연구의 목적은 수도권에서의 아황산가스가 황산염으로 전환되는 각각의 경로의 상대적 기여도를 예측해보고자 하였으며 아황산가스에 의해 황산염이 얼마나 형성되는지를 알아보고자 하였다. (중략)

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Transport Properties of PEBAX Blended Membranes with PEG and Glutaraldehyde for SO2 and Other Gases (SO2와 다른 기체에 대한 PEG와 Glutaraldehyde가 혼합된 PEBAX 막의 투과 특성)

  • Cho, Eun Hye;Kim, Kwang Bae;Rhim, Ji Won
    • Polymer(Korea)
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    • v.38 no.6
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    • pp.687-693
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    • 2014
  • Poly(ether-block-amide) 1657 (PEBAX 1657) blended membranes with molecular weight 400 poly(ethylene glycol) (PEG 400) were prepared and their permeability was tested for the gases $N_2$, $O_2$, $CH_4$, $CO_2$, and $SO_2$ by the time-lag method. The permeation characteristics were investigated in terms of diffusivity and solubility, which are dominant factors for gas transport. With the addition of PEG 400, the permeability of all the gases increased and also the ideal selectivity for several pair gases was enhanced. In particular, selectivity for $CO_2/N_2$ ranged from 53.2 (pristine PEBAX 1657 membrane) to 84.1 (50% PEG 400 added), for $SO_2/CO_2$ from 38.9 to 50.7, and for $CO_2/CH_4$ from 17.7 to 31.4. The increase of both permeability and selectivity is mainly because of the increase of solubility of the gases, especially $CO_2$ and $SO_2$. To obtain durability against water vapor, glutaraldehyde (GA) was added to the PEBAX 1657/PEG 400 blended membranes. As a result, permeability decreased owing to a reduction of the free volume and ether oxide units, which are the main factors in elevating the permeability for the blended membranes, and selectivity decrease however; we believe that the durability of the resulting membranes would be increased.

Development of Technology for Recovering Valuable Metals in Detoxified Waste Asbestos-Containing Waste (무해화된 폐석면에 함유된 유가금속 회수 기술 개발)

  • Kim, Dong Nyeon;Yang, Dong Hyeon;Kim, Seok Chan
    • Applied Chemistry for Engineering
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    • v.31 no.4
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    • pp.438-442
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    • 2020
  • Studies on the recovery conditions and optimization process for valuable metal recovery through chemical treatment from detoxified asbestos-containing waste composed of calcium silicate, larnite, merwinite, and akermanite were conducted. The main components, Si, Ca, and Mg, of detoxified asbestos-containing waste (DACW) were separated and recovered in the form of SiO2, CaSO4, and Mg(OH)2 compounds, respectively. Each separated component was confirmed through X-ray diffraction (XRD) and inductively coupled plasma spectrometer (ICP) analysis. The recovery conditions for each component were first treating them with an acid to separate SiO2 and subsequently with H2SO4 to recover Ca in the form of sulfate, CaSO4. The remaining Mg was recovered by precipitation with Mg(OH)2 under strong basic conditions. This study suggested that it is possible to convert existing treatment process of asbestos waste by landfill through recovering the components into a resource-recycling green technology.

Medium Optimization for Pediocin SA131 Production by Pediococcus pentosaceus SA131 against Bovine Mastitis Using Response Surface Methodology

  • Park, Yeo-Lang;Lee, Na-Kyoung;Park, Keun-Kyu;Park, Yong-Ho;Kim, Jong-Man;Nam, Hyang-Mi;Jung, Suk-Chan;Paik, Hyun-Dong
    • Food Science of Animal Resources
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    • v.30 no.1
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    • pp.66-72
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    • 2010
  • Pediococcus pentosaceus SA131 was isolated from jeotgal, is the bacteriocin producer against bovine mastitis pathogens, Streptococcus uberis E290, Enterococcus gallinarum E362, and Staphylococcus epidermidis ATCC 12228. The medium composition for pediocin SA131 production by P. pentosaceus SA131 was optimized using response surface methodology. Component of medium was studied as carbon source (glucose, fructose, lactose, glycerol, sucrose, maltose, and mannitol), nitrogen source (beef extract, yeast extract, peptone, malt extract, and tryptone), mineral and surfactant ($MgSO_4$, $KH_2PO_4$, $(NH_4)_2SO_4$, $MnSO_4$, NaCl, sodium acetate, and Tween 80). Through one factor-at-a-time experiment, glucose, fructose, yeast extract, malt extract, NaCl, $MgSO_4$, and Tween 80 were determined as the good ingredient. The effects of major factors for pediocin SA131 production were investigated by two-level fractional factorial designs (FFD). By a $2^4$ FFD, fructose, yeast extract, and $MnSO_4$ were found to be the important factors for the bacteriocin production. Subsequently, a $2^3$ central composite design (CCD) was adopted to derive a statistical model for optimizing the composition of the fermentation medium. The estimated optimum composition for the production of pediocin SA131 by P. pentosaceus SA131 was as follows; 0.13% fructose, 1% glucose, 1.8% yeast extract, 2.58% $MnSO_4$, 0.2% NaCl, and 0.2% Tween 80. The pediocin production under optimized medium was increased to 1,000 AU/mL, compared to the 400 AU/mL in MRS medium.

The Effects of Sonic Waves on the Oxidation Reaction of Alcohols Using $BaMnO_4\;and\;KMnO_4-CuSO_4{\cdot}5H_2O$ (유기초음파화학·초음파가 $BaMnO_4$$KMnO_4-CuSO_4{\cdot}5H_2O$를 이용한 알코올의 산화반응에 미치는 영향)

  • Eui Sang Ryoo;Dae Hyun Shin;Byung Hee Han
    • Journal of the Korean Chemical Society
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    • v.31 no.4
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    • pp.359-363
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    • 1987
  • Sonic waves (50KHz) was accelerated the oxidation reaction of primary, benzyl and secondary alcohol with $BaMnO_4\;and\;KMnO_4-CuSO_4{\cdot}5H_2O$ to give the corresponding aldehyde and ketone at $30^{\circ}C/1$ atm. in high yields compared to stirring or refluxing condition.

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A Study on Consumer Values Clothing Shopping Orientation and Clothing Satisfaction (성인여성의 가치인식과 의복쇼핑성향 및 의복만족에 관한 연구)

  • 구자명;이명희
    • Journal of the Korean Society of Clothing and Textiles
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    • v.23 no.3
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    • pp.459-470
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    • 1999
  • The objectives of this study were to investigate the difference the clothing shopping orientation and clothing satisfaction according to satisfaction·dissatisfaction group to examine how the clothing satisfaction was influenced by consumer values demographic variable clothing shopping orientation. The subject were 457 women in Seoul Korea The results of the study were as follows. 1. five factors of clothing shopping orientation (SO) derived by factor analysis : F.1. conspicious SO : F,2 search SO: F,3 recreational SO : F,4 addictive SO :F,5 independent SO . Two factors of terminal value derived by factor analysis : F,1 responsible : F.2 ambitious. 2. Satisfaction group had high levels of search SO, dissatisfaction group had high levels of addictive SO. Satisfaction group was satisfied with color style appropriateness for wearer in order dissatisfaction group was dissatisfied with care price size in order. 3. Conspicious SO were influenced bysocial stratification social recognition and happiness. Search SO were influenced by dwelling area and age. Recreational SO were influenced by social stratification social recognition and responsible value. Addictive SO influenced by responsible value social recognition and happiness. independent SO were influenced by marital status and ambitious value. 4. Clothing satisfaction was influenced by addictive conspicious SO happiness and recreational SO(R2=24.6)

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Operating Characteristics of 0.4 MW-Scale Gas Dispersion Type FGD Absorber (0.4 MW급 가스분사식 배연탈황 흡수탑의 운전 특성)

  • An, Hi-Soo;Kim, Ki-Hyoung;Park, Seung-Soo;Park, Kwang-Kyu;Kim, Young-Ho
    • Journal of Korean Society for Atmospheric Environment
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    • v.24 no.4
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    • pp.415-422
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    • 2008
  • This study was carried out to investigate the effect of operating and design conditions of gas dispersion type of absorber on $SO_2$ removal efficiency. pH difference between upper and lower part of gas dispersing plate of absorber was 0.2, which was relatively low. This was supposed that recirculation capacity of absorbing liquid between froth zone and reaction zone of absorber be increased by oxidation air injection through liquid riser which acted as liquid pump. Test results showed that $SO_2$ removal efficiency was more sensitive than absorber ${\Delta}P$. High $SO_2$ removal even at lower pH resulted from very low concentration of $HSO_3^-$ ion in absorbing liquid because of direct supply of dissolved oxygen into froth zone. 96% of $SO_2$ removal efficiency was obtained under the condition of absorber pH 5.2, flue gas flow rate of $1,530\;Nm^3/hr$, inlet $SO_2$ concentration of 800 ppm, absorber ${\Delta}P$ of 250mmAq. The following equation by a multiple linear regression was obtained to describe the relationship between $SO_2$ removal and operating variables. $$f=1-{\exp}(-1.3939+1.060pH+0.0139{\Delta}P-0.00267G-0.000064SO_2Conc.),\;R^2=0.9719$$

The Effect of Metallic Oxides on the Formation Rates and Rigidities of the Elastic Sodium Alginate-$CaSO_4{\cdot}1/2H_2O$ Gel. (Sodium Alginate-$CaSO_4{\cdot}1/2H_2O$ 彈性體의 生成速度 및 彈性에 미치는 金屬酸化物의 影響)

  • Shin, Hong-Dae;Huh, Yeonn;Kim, Uun-Sik
    • Journal of the Korean Chemical Society
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    • v.9 no.1
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    • pp.16-22
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    • 1965
  • The time-lag-effect of alkali salts on the gelation of sodium alginate-$CaSO_4{\cdot}$1/2 $H_2O$ is compared with Miyake's data, and then the formation rate of the elastics measured by the continuous method (an improved Schwedoff's method) and the change of rigidity with metallic oxides are studied as follows: (1) The gelation processes of sodium alginate and $CaSO_4{\cdot}$1/2 $H_2O$-aqueous sol are studied by measuring, continuously the increases of tensions ofsamples. (2) The time-lag-effect of $Na_3PO_4$ on the formation rate of the elastic gel is larger than that of $Na_2CO_3$, but the difference between the effects of the two alkali salts on the rate is found not so greater than predicted in Miyake's data. (3) Any regularities of the effect on the rate by metallic oxides are not observed. The increasing effects of the rates of $SiO_2$ and MgO are relatively large, and that of ZnO is relatively small. However, $Al_2O_3$, $Sb_2O_3$ and $TiO_2$show some decreasing effects. As a result it is noted that the regularities do not depend on the effect of oxide species and their amounts. (4) It is not found proportionality between the rigidity and the gelation rate. However, the increasing effect of the rigidity with the addition of metallic oxides can be observed. The rigidity increasing rate of MgO is the largest of them.

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