• Title/Summary/Keyword: $SO_4^{2-}$

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A Study on Dyeing Effects of Onion′s Outer Shell under the Different Dyeing Conditions (염색조건에 따른 양파껍질의 염색효과에 관한 연구)

  • 정나영;이전숙;최경은
    • Korean Journal of Human Ecology
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    • v.3 no.1
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    • pp.51-63
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    • 2000
  • The purpose of this study was to identify the best dyeing conditions using onion's outer shell. and to apply to the method in practical daily life. To do this. we extracted quercetin from onion's outer shell and dyed several natural fabrics such as cotton, slack mercerized cotton, ramie. and silk. under the different conditions. Dyed fabrics were Investigated in the aspect of dyeability and colorfastness. The effective conditions for the light-fastness and washing-fastness also have been studied. The results of the experiment were varied with such conditions as temperature. time. pH degree. and treatment and types of mordants. The results are as follows ; 1. Fabrics dyed with onion's outer shell showed excellent dyeability even though there were no mordants, and the silk fabric dyed better than both cotton and ramie fabric. Furthermore, in the cases of repeated dyeing and treatment of mordants using AIK(SO$_4$)$_2$.12$H_2O$ and CuSO$_4$,.5$H_2O$ dyeability of specimen had been improved 2. Cellulose fabrics such as cotton, mercerized cotton and ramie showed the best dyeability under relatively low temperature in the range of 20~4$0^{\circ}C$. On the contrary to cellulose fabric, silk fabric showed the best dyeability under higher dyeing temperature. All fabrics had the higest K/S value at pH 3 regardless of the kind of fiber 3. Dyeing colors varied with the kind of mordants. Colors were turned into yellow in AIK(SO$_4$)$_2$.12$H_2O$ into Yellow-red in CuSO$_4$,.5$H_2O$ , and into green-Yellow in FeSO$_4$.7$H_2O$. As mordants, AIK(SO$_4$)$_2$.12$H_2O$, CuSO$_4$,. 5$H_2O$. FeSO$_4$.7$H_2O$. gallic acid and tartaric acid were used and especially AIK(SO$_4$)$_2$.12$H_2O$ showed the best dyeability and colorfastness in repeated dyeing. Mordants such as AIK(SO$_4$)$_2$.12$H_2O$ made fabrics have better chroma and washing-fastness though the light-fastness was poorer than non mordanting. 4. Repeated dyeing brought us deep color. When fresh dyebath was used each time, the dyeability was increased as the experiment was repeated more. When dyed with used dyebath several times, improved dyeability could not be expected. The optimal using times of the used dyebath was twice.

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Statistical Optimization of Medium Components for the Production of Biosurfactant by Bacillus licheniformis K51

  • Joshi Joshi;Sanket Sanket;Yadav Sanjay;Nerurkar Anuradha;Desai Anjana J.
    • Journal of Microbiology and Biotechnology
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    • v.17 no.2
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    • pp.313-319
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    • 2007
  • The nutritional medium requirement for biosurfactant production by Bacillus licheniformis K51 was optimized. The important medium components, identified by the initial screening method of Plackett-Burman, were $H_3PO_4,\;CaCl_2,H_3BO_3$, and Na-EDTA. Box-Behnken response surface methodology was applied to further optimize biosurfactant production. The optimal concentrations for higher production of biosurfactants were (g/l): glucose, $1.1;NaNO_3,\;4.4;MgSO_4{\cdot}7H_2O,\;0.8;KCl,\;0.4;CaCl_2,\;0.27;H_3PO_4,\;1.0ml/l;\;and\;trace elements\;(mg/l):H_3BO_3,\;0.25;CuSO_4,\;0.6;MnSO_4,\;2.2;Na_{2}MoO_4,\;0.5;ZnSO_4,\;6.0;FeSO_4,\;8.0;CoCL_2,\;1.0;$ and Na-EDTA, 30.0. Using this statistical optimization method, the relative biosurfactant yield as critical micelle dilution (CMD) was increased from $10{\times}\;to\;105{\times}$, which is ten times higher than the non-optimized rich medium.

A Study on Fine Particle Removal of ESP according to $(NH_4)_2SO_4$ Injection Rate (황산암모늄 주입에 따른 전기집진기(ESP)에서의 미세분진 제거)

  • 서정민
    • Journal of Environmental Science International
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    • v.7 no.4
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    • pp.505-510
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    • 1998
  • This study has been carried out to investigate Electrostatic Precipitator's(ESP) performance enhancement and removal efficiency of fine particle according to (NH4)2SO4injection rate. The following conclusions are derived from the these test results : 1) For plant condition cases, according to the variation of concentration agent [(NH4)2SO4]-10ppm, when inlet dust loading was 2g/m2. And when Inlet dust loading was 3g/m", that was increased to 98 19% 99.16% 99.23%, 99.58%, 2) It Is seen from thins experiments that the increasing 30ppm concentration of (NH4)2SO4 increase the collection efficiency and fine particle omission control.

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Surface Charge Density and Acidic Characteristics of $SO_4^{2-}/Al_2O_3$ ($SO_4^{2-}/Al_2O_3$의 표면전하밀도와 산적특성)

  • 함영민;홍영호;장윤호
    • Journal of the Korean Ceramic Society
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    • v.30 no.11
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    • pp.933-940
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    • 1993
  • SO42-/Al2O3 powder was prepared by the coprecipitation method from the Al(NO3)3.9H2O and NH4OH and followed by being treated with various concentrations of sulfuric acid. The characterization of these powders was performed with XRD, BET and FT-IR. The surface charge density at alumina/KCl(aq) interface was measured by potentiometric titration method. From the experimental data it was shown that acid strength, specfic surface area, and structure of surface treated alumina were independent on the amount of exchanged SO42-. However, the acid amounts of alumina were increased with the amounts of SO42- formed on alumina surface. The relation between the acid amount of SO42- ion exchanged alumina surface and the surface charge density for SO42-/Al2O3/KCl(aq) interface was investigated.

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Synthesis of High Purity Al2O3 from Low Grade Bauxite Ore(I) -Extraction of Al Component by the Decomposition of Bauxite Ore with Ammonium Sulfate- (저품위 Bauxite로부터 고순도 Al2O3의 합성(I) -Bauxite의 황산암모늄분해에 의한 Al 성분의 추출-)

  • Kwon, Kung-Taek;Song, Yon-Ho;Lee, Chul-Tae
    • Applied Chemistry for Engineering
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    • v.5 no.4
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    • pp.588-596
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    • 1994
  • A decomposition reaction of bauxite ore with $(NH_4)_2SO_4$ was investigated to prepare Al component pregnant solution for the direct product of high purity $Al_2O_3$ from low grade bauxite ore. Al component in the bauxite was sulfatized to $NH_4Al(SO_4)_2$ or $Al_2(SO_4)_3$ in this decomposition. The optimum conditions of the decomposition for bauxite ore were reaction temperature of $425^{\circ}C$, reaction time of 40min, $(NH_4)_2SO_4$ weight ratio to bauxite of 7.0 and particle size of bauxite ore of -200mesh. The optimum leaching conditions of sulfated bauxite ore were leaching temperature of $100^{\circ}C$, leaching time of 1hr and pulp density of 200ml $H_2O$ to sulfated ore of 1.0g bauxite. Under the above mentioned decomposition and leaching conditions, 94% of Al component in the bauxite ore was extracted.

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Purification and Properties of Alkaline Pretense from Xanthomonas sp. YL-37 (Xanthomonas sp. YL-37 균주가 생산하는 Alkali성 단백질분해효소의 정제 및 성질)

  • 장형수;권태종
    • Microbiology and Biotechnology Letters
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    • v.26 no.5
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    • pp.427-434
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    • 1998
  • An alkaline protease was 4-fold purified, yielding 2.3% of recovery by ammonium sulfate precipitation, CM-cellulose column chromatography and Sephadex G-100 column chromatography. The purified enzyme was estimated to be monomeric with molecular weight of about 62,000 from polyacrylamide gel eletrophoresis (PAGE) and sodiumdodecylsulfate polyacrylamide gel electrophoresis (SDS-FAGE). The optimal pH and temperature of the alkaline pretense activity were 11.0 and 50$^{\circ}C$, respectively, exhibiting high stability at pH value from 6.0 to 11.0 at 50$^{\circ}C$ for 30 minute. The alkaline pretense was activated by MnSO$_4$, CaCl$_2$, and was inhibited by CuSO$_4$, ZnSO$_4$, HgCl$_2$, EDTA and EGTA. Also, the enzyme was found to be a metaloenzyme requiring Mn$\^$2+/ as cofactor. The NH$_2$-terminal amino acid of alkaline protease was alanine. The Km and Vmax values of this enzyme for casein was 4.0 mg/$m\ell$ and 5,500 unit/$m\ell$, respectively.

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Effects of a Chelated Copper as Growth Promoter on Performance and Carcass Traits in Pigs

  • Zhao, J.;Allee, G.;Gerlemann, G.;Ma, L.;Gracia, M.I.;Parker, D.;Vazquez-Anon, M.;Harrel, R.J.
    • Asian-Australasian Journal of Animal Sciences
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    • v.27 no.7
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    • pp.965-973
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    • 2014
  • Three studies were conducted to investigate whether a chelated Cu can replace $CuSO_4$ as a growth promoter in pigs. In Exp. 1, a total of 240 piglets (Large White${\times}$Landrace, $7.36{\pm}0.10kg$) were randomly allocated to 1 of 3 treatments with 8 replicates and 10 piglets per pen. Treatments included a NRC control ($CuSO_4$, 6 mg/kg), two Cu supplementations from either $CuSO_4$ or $Cu(HMTBa)_2$ at 170 mg/kg. Pigs fed $Cu(HMTBa)_2$ were 6.0% heavier than pigs fed either the NRC control or 170 mg/kg $CuSO_4$ (p = 0.03) at the end of the experiment. During the 42 days of experimental period, pigs fed $Cu(HMTBa)_2$ gained 9.0% more (p = 0.01), tended to eat more feed (p = 0.09), and had better feed efficiency (p = 0.06) than those fed $CuSO_4$. Compared with the 6 mg/kg $CuSO_4$ NRC control, liver Cu was increased 2.7 times with 170 mg/kg $CuSO_4$ supplementation, and was further increased with $Cu(HMTBa)_2$ (4.5 times, p<0.05). In Exp. 2, a total of 616 crossbred piglets (PIC, $5.01{\pm}0.25kg$) were randomly allocated to 1 of 4 treatments with 7 replicates and 22 piglets per pen. Treatments included a NRC control (from $CuSO_4$), and three pharmaceutical levels of Cu (150 mg/kg) supplemented either from C$CuSO_4$, tri-basic copper chloride ($Cu_2[OH]_3C1$), or $Cu(HMTBa)_2$. Pigs fed $CuSO_4$ or $Cu(HMTBa)_2$ had better feed efficiency (p = 0.01) and tended to gain more (p = 0.08) compared with those fed the NRC control. Pigs fed $Cu_2[OH]_2C1$ were intermediate. Pigs fed $Cu(HMTBa)_2$ had the highest liver Cu, which was significantly higher than those fed ($Cu_2[OH]_3C1$) or the negative control (p = 0.01). In Exp. 3, a total of 1,048 pigs (PIC, $32.36{\pm}0.29kg$) were allotted to 6 treatments with 8 replicates per treatment and 20 to 22 pigs per pen. The treatments included a NRC control with 4 mg/kg Cu from $CuSO_4$, a positive control with 160 mg/kg Cu from $CuSO_4$, and incremental levels of $Cu(HMTBa)_2$ at 20, 40, 80, and 160 mg/kg. During the overall experimental period of 100 days, no benefit from 160 mg/kg $CuSO_4$ was observed. Pigs fed $Cu(HMTBa)_2$ had increased ADG (linear and quadratic, $p{\leq}0.05$) and feed efficiency (linear and quadratic, $p{\leq}0.05$) up to 80 mg/kg and no further improvement was observed at 160 mg/kg for the whole experimental period. Pigs fed 80 mg/kg $Cu(HMTBa)_2$ weighed 1.8 kg more (p = 0.07) and were 2.3 kg heavier in carcass (p<0.01) compared with pigs fed 160 mg/kg $CuSO_4$. In addition, loin depth was increased with increased $Cu(HMTBa)_2$ supplementation with pigs fed 80 mg/kg $Cu(HMTBa)_2$ had the greatest loin depth (p<0.05). In summary, $Cu(HMTBa)_2$ can be used to replace high $CuSO_4$ as a growth promoter in nursery and grower-finisher pigs.

Studies on the Hard Anodizing in Sulphuric Acid Solution (黃酸溶液에서의 硬質陽極酸化에 關한 硏究)

  • Kim, Jong-Chan;Park, Yong-Jin
    • Journal of the Korean institute of surface engineering
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    • v.13 no.1
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    • pp.8-15
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    • 1980
  • The critical voltage of hard coat range of Al alloys (K 186, 43S) at various electrolytes and the effects of voltage, temperature of electrolytes and concentration of sulfric acid were investigated, m the hope that to find the adequate voltage. Two kind of A1 alloys were anodized in three typical electrolytes and micro vickers hardness of the films were measured. With respect to the relationship between the hardness of the film and the voltage The result of this experiment are as fallows. 1. The critical voltage of hard coat rangs for the electrolytes $H_2SO_4\;10%,\;H_2SO_4\;10%\;+\;H_2C_2O_4\;2H_2O\;10g/l,\;H_2SO_4\;10%\;+\;NaHSO_4\;5%$ was 20V 22V 24V respectively. 2. $H_2SO_4\;10%\;+\;NaHSO_4$ 5% electrolyte was most adventageous among the three electrolyte in the respect of hardness. 3. The effect of concentration of sulphuric acid was not appeared.

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A Study on the Chemical Composition of Precipitation during the Period of Sandy Dust Phenomena (黃砂現象時 降水의 化學的 成分에 關한 硏究)

  • 李敏熙;韓振錫;韓義正;辛燦基
    • Journal of Korean Society for Atmospheric Environment
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    • v.5 no.2
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    • pp.1-11
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    • 1989
  • Sandy dust phenomena was observed from April 19 to 23, 1988 in Seoul. During this period it rained and the precipitation was collected to investigate the rain chemistry. This study was carried out to analyzed the chemical composition of precipitation by the measurements of conditivity, cations $(H^+, NH_4^+, K^+, Na^+, Ca^{2+}, MG^{2+})$, and anions $(SO_4^{2-}, NO_3^-, Cl^-, F^-, Br^-)$ which are believed to be the major ions playing an important role in the acidity of rain water. During the period of sandy dust phenomena the range of pH value and conductivity concentration of rainwater were 6.0-6.7, 172-254 $\mu \mho/cm$. The anions and cations concentrations increased and the orders of these concentrations were $SO_4^{2-} > Cl^- > NO_3^- > Na^+ > Ca^{2+} > NH_4^+ > Mg^{2+}$. THe principal chemical compounds of rainwater were estimated at $(NH_4)_2 SO_4, CaSO_4, NaCl, and MgCl_2$.

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On the Rapid Hardening Cement (II) (초속경시멘트 제조에 관한 연구(제2보 수화반응))

  • 한기성;최상흘;한상목;서일영
    • Journal of the Korean Ceramic Society
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    • v.12 no.4
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    • pp.3-8
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    • 1975
  • Hydration processes of the rapid hardening cement clinkers, which were synthesized from domestic alunite for major alumina source, limestone, kaolin and fluorite, were investigated by means of x-ray diffraction analysis, thermal analysis and microscopic observation etc. The clinkers were composed mainly of alite, calcium fluroaluminate (C11A7.CaF2) minerals. While the hydratio processes of the clinkers are altered by concentration of SO3 in the paste, calcium aluminate hydrates such as C4AH13, CAH10 and calcium monosulfate hydrate (C3A.CaSO4.12H2O) are formed at first and then some of them are transformed into ettringite(C3A.3CaSO4.32H2O) within 30~60 min. when the concentration of SO3 in the paste are enough. However the formed ettringite are changed slowly into calcium monosulfate hydrate as the concentration of SO3 become lowered, and the paste is hardened with these close-packed minerals. When the content of SO3 in clinker is so enough, calcium sulfoaluminate hydrates are found without any addition of anhydrite or hemi-hydrite.

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