• Title/Summary/Keyword: $SO_2$ Oxidation

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Antioxidative activity of flavonoid rich extract of Oenothers odorate Jacquin on oxidation of low density lipoprotein (LDL 산화에 대한 달맞이꽃의 플라보노이드 추출물의 항산화 활성)

  • Ryu, Beung-Ho;Kim, Hee-Sook;Cho, Kyung-Ja
    • Journal of Life Science
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    • v.12 no.3
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    • pp.325-331
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    • 2002
  • There is growing interest ill understanding the role and mechanisms of flavonoid as antioxidant on LDL. The antioxidative activity of flavonoid typically present in Oenothers odorate Jacquin was investigated in vitro using a human LDL oxidation assay. In present work, LDL was incubated with increasing concentrations of extracts of extracts of Oenothers odorate Jacquin and LDL oxidation was started by adding CuSO$_4$to the media. Substances in leaves extracts of Oenothers odorate Jacquin are capable of inhibiting the initiation and the propagation of LDL oxidation. They inhibit LDL oxidation, monitored by thiobarbituric acid-reactive substances(TBARS), as well as modification as shown through direct measurement of electrophoretic mobility, diene conjugates. Inhibition is a dose dependent effect that becomes already apparent at concentration of extracts as low as 40$\mu\textrm{g}$/mL. Inhibition is almost complete at 80$\mu\textrm{g}$/mL. Extracts of Oenothers odorate Jacquin were more potent antioxidative activity than either ascorbic acid and dl-a -tocopherol.

Effect of Re-oxidation on the Electrical Properties of Mutilayered PTC Thermistors (적층 PTC 써미스터의 전기적 특성에 대한 재산화의 영향)

  • Chun, Myoung-Pyo
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.26 no.2
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    • pp.98-103
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    • 2013
  • The alumina substrates that Ni electrode was printed on and the multi-layered PTCR thermistors of which composition is $(Ba_{0.998}Ce_{0.002})TiO_3+0.001MnCO_3+0.05BN$ were fabricated by a thick film process, and the effect of re-oxidation temperature on their resistivities and resistance jumps were investigated, respectively. Ni electroded alumina substrate and the multi-layered PTC thermistor were sintered at $1150^{\circ}C$ for 2 h under $PO_2=10^{-6}$ Pa and then re-oxidized at $600{\sim}850^{\circ}C$ for 20 min. With increasing the re-oxidation temperature, the room temperature resistivity increased and the resistance jump ($LogR_{290}/R_{25}$) decreased, which seems to be related to the oxidation of Ni electrode. The small sized chip PTC thermistor such as 2012 and 3216 exhibits a nonlinear and rectifying behavior in I-V curve but the large sized chip PTC thermistor such as 4532 and 6532 shows a linear and ohmic behavior. Also, the small sized chip PTC thermistor such as 2012 and 3216 is more dependent on the re-oxidation temperature and easy to be oxidized in comparison with the large sized chip PTC thermistor such as 4532 and 6532. So, the re-oxidation conditions of chip PTC thermistor may be determined by considering the chip size.

Oxide Layer Growth in High-Pressure Steam Oxidation (고압 수증기 내에서 산화막 형성에 관한 연구)

  • 박경희;안순의;구경완;왕진석
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.07a
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    • pp.735-738
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    • 2000
  • This paper shows experimentally that oxide layer on the p-type Si-substrate can grow at low temperature(500$^{\circ}C$∼600$^{\circ}C$) using high pressure water vapor system. As the result of experiment, oxide layer growth rate is about 0.19${\AA}$/min at 500$^{\circ}C$, 0.43${\AA}$/min at 550$^{\circ}C$, 1.2${\AA}$/min at 600$^{\circ}C$ respectively. So, we know oxide layer growth follows reaction-controlled mechanism in given temperature range. Consequently, granting that oxide layer growth rate increases linearly to temperature over 600$^{\circ}C$, we can expect oxide growth rate is 5.2${\AA}$/min at 1000$^{\circ}C$. High pressure oxidation of silicon is particularly attractive for the thick oxidation of power MOSFET, because thermal oxide layers can grow at relatively low temperature in run times comparable to typical high-temperature, 1 atm conditions. For higher-temperature, high-pressure oxidation, the oxidation time is reduced significantly

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High Quality Ultrathin Gate Oxides Grown by Low-Temperature Radical Induced Oxidation for High Performance SiGe Heterostructure CMOS Applications (저온 래디컬 산화법에 의한 고품질 초박막 게이트 산화막의 성장과 이를 이용한 고성능 실리콘-게르마늄 이종구조 CMOS의 제작)

  • 송영주;김상훈;이내응;강진영;심규환
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.16 no.9
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    • pp.765-770
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    • 2003
  • We have developed a low-temperature, and low-pressure radical induced oxidation (RIO) technology, so that high-quality ultrathin silicon dioxide layers have been effectively produced with a high reproducibility, and successfully employed to realize high performace SiGe heterostructure complementary MOSFETs (HCMOS) lot the first time. The obtained oxide layer showed comparable leakage and breakdown properties to conventional furnace gate oxides, and no hysteresis was observed during high-frequency capacitance-voltage characterization. Strained SiGe HCMOS transistors with a 2.5 nm-thick gate oxide layer grown by this method exhibited excellent device properties. These suggest that the present technique is particularly suitable for HCMOS devices requiring a fast and high-precision gate oxidation process with a low thermal budget.

Developing Hollow Carbon Balls by Oxidation of Carbon Blacks

  • Kang, Dong-Su;Kim, Beom-Jun;Lee, Kwang-Ju;Kim, Suk-Hwan;Lee, Sang-Woo;Roh, Jae-Seung
    • Carbon letters
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    • v.14 no.1
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    • pp.55-57
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    • 2013
  • The development of hollow carbon balls by $CO_2$ oxidation of two types of carbon blacks was studied. Super P (SP) and Denka Black (DB) were used for this study. Specific surface area (SSA), structural parameters, and microstructures were examined using Brunauer, Emmett and Teller apparatus, X-ray diffraction spectroscopy, and transmission electron microscope (TEM), respectively. The SSAs of both oxidized carbon blacks increased after oxidation. The SSAs of raw DB and SP were 73 $m^2/g$ and 60 $m^2/g$, respectively. Maximum SSAs of oxidized DB and SP were 152 $m^2/g$ and 253 $m^2/g$, respectively. The $d_{002}$ of DB and SP showed almost no change after oxidation. The Lc of raw DB ($38{\AA}$) and SP ($19{\AA}$) increased with increasing weight loss. The $L_c$ of SP increased up to $254{\AA}$ at 96% weight loss. The SSA increased about twice in DB (148 $m^2/g$) and about four times in SP (254 $m^2/g$) after 3 h oxidation compared with the original carbon blacks. Through TEM observation the outer parts of the oxidized carbon blacks showed a rigid shell structure and the inner parts looked empty. Generally it looked like an angular soccer ball, so we named it 'hollow carbon ball'. It is expected that the hollow carbon ball can be used as catalyst supports.

A Study on the Characteristics of PM1.0 Chemical Components Using a Real-time Aerosol Mass Spectrometer (실시간 에어로졸 질량분석기를 이용한 PM1.0의 화학적성분의 특성에 관한 연구)

  • Park, Jinsoo;Choi, Jinsoo;Kim, Hyunjae;Oh, Jun;Sung, Minyoung;Ahn, Joonyoung;Lee, Sangbo;Kim, Jeongho
    • Journal of the Korean Society of Urban Environment
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    • v.18 no.4
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    • pp.485-494
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    • 2018
  • This study aims to identify the characteristics of oxidation and chemical composition of PM in winter season, 2017 at Incheon area. The mean concentration of air pollutants were $46{\pm}22{\mu}g/m^3-PM_{10}$, $29{\pm}18{\mu}g/m^3/-PM_{2.5}$, $5{\pm}3ppb-SO_2$, $0.56{\pm}0.24ppm-CO$, $21{\pm}13ppb-O_3$ and $28{\pm}17ppb-NO_2$, respectively. The dominant ion of the $PM_{1.0}$ chemical component were organic with $3.2{\mu}g/m^3$ and nitrate with $1.9{\mu}g/m^3$. The day and night variation of the $PM_{1.0}$ chemical components was higher in nighttime than those of daytime. The averaged nitrate oxidation rate (SOR) was 0.06 and sulfate oxidation rate was 0.11 during the field campaign. In the high mass loading period, nitrate oxidation rate (NOR) was up to 0.6 and also the nitrate in $PM_{1.0}$ was increased. The averaged ratio of $NO_x/SO_2$ was 8.7 and nitrate/sulfate was 3.1, respectively. In this results, the nitrate component in $PM_{1.0}$ was influenced by NOx from the stationary source as power plant and the mobile source around the measurement site.

A Study on the Efficient Applicability of Fenton Oxidation for the Wastewater Containing Non-biodegradable Organics (생물난분해성 유기물질 함유 폐수처리를 위한 Fenton 산화법의 효율적 적용방안에 관한 연구)

  • Jun, Se Jin;Kim, Mi Jeong
    • Journal of Korean Society of Water and Wastewater
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    • v.14 no.1
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    • pp.76-83
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    • 2000
  • This research is about wastewater containing non-biodegradable TDI(Toluene Diisocyanate) that is treated by the activated carbon adsorption method. In the case of the Fenton oxidation process being applied to the existing process, optimal pH, reaction time, chemical dosing amount, removal rate, and cost were investigated. A pilot plant test was applied after finding optimal conditions with lab experiments. The optimal conditions were pH 3~5(COD removal rate 84~88%) and reaction time 30min~1hr. In higher $H_2O_2$ dosing amount, COD removal rate was a little higher. But there was little difference in the removal rate according to $FeSO_4{\cdot}7H_2O$ dosing amount. Treatment cost was economical in the case of the Fenton oxidation process being operated earlier than activated carbon adsorption system. But chemical dosing point, chemical mixing effect, chemical dosing amount, removal rate, and the cost of facility and others must be considered in practical process.

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Charactristice of a colored Galvanized Coating using Ti-Zn Alloy System (Zn-Ti계용융아연 도금강판의 착색화 특성)

  • 전선호
    • Journal of Surface Science and Engineering
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    • v.30 no.5
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    • pp.320-332
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    • 1997
  • The development of colored surface on zinc coating by the oxidation of a melten alloy of zinc with a minor amount of oxygen-avid additive such as tianium has been studied. Using a galvanizing Zinc alloy containing 0.1 to 0.3wt%Ti, gold, purple or blue color was developed clearly and stably, depending upon the extent of oxidation, by air cooling after hot dipping in a bath at temperature of $550^{\circ}C$ to $600^{\circ}C$. The source of the color is light interference with surface oxide layer. THe final color depends on the thickness of the color depends on the thickness of $TiO_2$, played So compositing, temperature and time at elevated temperature after are all controlling variables. Since oxidation film such as $TiO_2$ played role of passivation film, the corrosion resistance in a colored galvanized steel sheet. It is also thought that surface oxide layer of $TiO_2$ inhibited dissolution of the coating layer.

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Studies on Preparation of Transparent Iron Oxide (투명산화철의 製造에 관한 硏究)

  • Baek, Moo-Hyun;Lim, Jong-Ho;Kim, Tae-Kyung;Lee, Seoung-Won
    • Resources Recycling
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    • v.13 no.6
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    • pp.9-15
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    • 2004
  • The optimum conditions were studied for the preparation of transparent iron oxide with the air oxidation of FeOOH. The FeOOH obtained by mixing NaOH and FeSO$_4$ solution in various conditions such as R(=2NaOH/FeSO$_4$), FeSO$_4$ concentration. reaction temperature and air flow rate. When the FeSO$_4$ increased gradually, the concentration of iron ion in the solution became high. So, particle size increased precipitating Fe$_3O_4$. Goethite dehydrate at about 200$^{\circ}C$ and ended the reaction at about 320$^{\circ}C$ forming hematite. The lower the reaction temperature was, the shorter the particle length of goethite and particle size decreased. When the flow rate of air as an oxidant increased, the amount of dissolved oxygen in the solution increased, which made oxidation rate increased. And then particle size of goethite decreased.