• Journal of Microbiology and Biotechnology
• /
• v.10 no.3
• /
• pp.419-422
• /
• 2000

A three-phase fluidized-bed bioreactor including Thiobacillus sp. IW was tested to remove H_2S and $NH_3$ simultaneously. The inlet $H_2S$ was oxidized to $SO_4^{2-}$ by Thiobacillus sp. IW, and the $NH_3$ reacted with the $SO_4^{2-}$ to form $(NH_4)_2SO_4$. The removal efficiency of $H_2S$ was 98.4-99.9% for an inlet concentration of 36-730 ppm and that of $NH_3$ was 60.2-99.2% for an inlet concentration of 45-412 ppm. The removal efficiency of $NH_3$ was reduced when the inlet loading rate of $NH_3$ was increased above 10 mg/l/h. When the bioreactor was operated for 25 days with a lower inlet concentration of $NH_3$ compared with the of $H_2S$, the bioreactor exhibited an excellent performance with a stable pH, dissolved oxygen content, and cell concentration.

• Journal of Environmental Health Sciences
• /
• v.23 no.3
• /
• pp.109-120
• /
• 1997

The purpose of this study is to evaluate the effectiveness of wastewater treatment containing surfactant. For that, comparative analysis of effectiveness of Featon Oxidation, Aluminum Sulfate, PAC (Poly Aluminum Chloride) on the treatment of the synthetic wastewater containing LAS (Linear Alkyl Sulfate), a main component of the commercial detergent was carried. Then, the optimum pH, the dosage of reagents, and the concentration of the LAS in each treatment were determined. The results of the study were summarized as following. 1. In Fenton Oxidation, optimal pH was 3 and 97.92% removal of LAS was achieved. However, the increase of the pH reduced the efficiency of LAS removal. The proper chemical dosages of FeSO$_4$ and $H_2O_2$ were 300 mg/l and the increase of dosages didn't affected the removal efficiency. Therefore, it was concluded that the economic chemical dosage was 300 mg/l of FeSO$_4$ and $H_2O_2$. 2. In case of Alum treatment, optimal pH was 11 with 61.13% removal efficiency. At other pH range, the removal efficiency was very low indicating that removal efficiency is greatly influenced by pH. The proper chemical dosage was 200 mg/l with the removal efficiency of 77.65%. The increase of chemical dosage, however, reduced the removal efficiency. 3. In case of using PAC, optimal pH was 6 with 97.99% removal efficiency. The result showed that wastewaters containing surfactant were almost completely removed at pH 6 by PAC. Removal efficiency was decreased by increasing PAC dosage higher than 400 mg/l and dosage over 700 mg/l of PAC abolished the treatment. 4. The comparative analysis of three methods revealed that the effective pH ranges were at pH 2-5 with Fenton oxidation, at pH 6-11 with PAC, and pH 11 with Alum. The removal efficiencies at these pH were 83.95-97.92%, 75.98-97.99% and 61.13%, respectively. 5. Increase in LAS concentration reduced the removal efficiencies of all three methods. In the case of PAC or Alum treatment, treatment abolished at LAS concentration higher than 700 mg/l.

• Journal of Environmental Science International
• /
• v.7 no.4
• /
• pp.505-510
• /
• 1998

This study has been carried out to investigate Electrostatic Precipitator's(ESP) performance enhancement and removal efficiency of fine particle according to (NH4)2SO4injection rate. The following conclusions are derived from the these test results : 1) For plant condition cases, according to the variation of concentration agent [(NH4)2SO4]-10ppm, when inlet dust loading was 2g/m2. And when Inlet dust loading was 3g/m", that was increased to 98 19% 99.16% 99.23%, 99.58%, 2) It Is seen from thins experiments that the increasing 30ppm concentration of (NH4)2SO4 increase the collection efficiency and fine particle omission control.

• Membrane and Water Treatment
• /
• v.10 no.3
• /
• pp.201-206
• /
• 2019

In this study, we performed an electrowinning process for effective removal of metals (Cu and Ni) in solution and their recovery as solid forms. A complete removal of Cu and Ni (1,000 mg/L) was observed during four times recycling test, indicating that our electrowinning system can ensure the efficient metal removal with high stability and durability. In addition, we investigated effect of operation parameters (i.e., concentration of boric acid only for Ni, variation of pH, concentration of electrolyte ($H_2SO_4$), and cell voltage) on the efficiency of metal removal (Cu and Ni) during the electrowinning. The addition of boric acid significantly enhanced removal efficiency of Ni as the concentration of boric acid increased up to 10 g/L. Compared to negligible pH effect (pH 1, 2, and 4) on the Cu removal, we observed the increase in removal efficiency of Ni as the pH increased from 1 to 4. The electrolyte concentration did not significantly influence the removal of Cu and Ni in this study. We also obtained great removal rates of Cu and Ni at 2.5 V and 4.0 V, which were much faster than those at lower voltages. Finally, almost 99% of each Cu and Ni (1,000 mg/L) was selectively removed from the mixture of metals by adjusting pH and addition of boric acid after the completion of Cu removal. The findings in this study can provide a fundamental knowledge about effect of important parameters on the efficiency of metal recovery during the electrowinning.

• Journal of Korean Society for Atmospheric Environment
• /
• v.6 no.1
• /
• pp.85-96
• /
• 1990

Simultaneous removal efficiencies of hydrophilic and hydrophobic gaseous pollutants are experimentally determined, and the macroscopic removal mechanism of pollutants in a dry scrubber is analyzed using the extended model of three phase equilibrium distribution of pollutant at high temperatures that can describe the different morphological conditions of adsorbent and water at varying relative humidities. For the simplicity, the inside of spray dryer is divided into three regions of ; (1) absorption, (2) three-phase equilibrium, and (3) adsorption, and the removal efficiencies of each pollutants at three regions are observed at different experimental conditions to estimate the effects of important parameters of dry scrubber. The laboratory experiments simulate the three regions of spray dryer with the temperature control and thus evaporation rate of water from the slurry particle. $SO_2$ as a hydrophilic gaseous pollutant and vinyl chloride as a hydrophobic toxic gas are selected for the future field application to soid waste incineration, and the two types of slurry are made of the two sorbents ; 10 wt.% $Ca(OH)_2$, and 10 wt.% NaOH. Result of temperature effect shows the height of absorption plus three-phase region is decreased as the operation temperature is increased, which results in the lower removal efficiency of $SO_2$ but higher removal for vinyl chloride in the adsorption region of dry scrubber. The removal efficiency of $SO_2$ is higher by NaOH slurry than by $Ca(OH)_2$ slurry due to the hygroscopic nature of NaOH, while the removal of vinyl chloride is higher in $Ca(OH)_2$ case. From the analysis of redults using three-phase equilibrium distribution model, the effective two-phase partition coefficients can be obtained, and the possible extention in the application of the three-phase equilibrium model in a dry scrubber design has been demonstrated.

• Applied Chemistry for Engineering
• /
• v.10 no.1
• /
• pp.41-45
• /
• 1999

Simulated liquid waste containing 50 ppm cobalt ion was treated by precipitate flotation using the surfactant of sodium lauryl sulfate. The effects of initial cobalt ion concentration, pH, surfactant concentration, removal time, gas flow rate and foreign ions were estimated on removal efficiency. 35% $H_2O_2$ was added for pre-treatment stage before precipitate flotation. As the result of pre-treatment, optimum removal pH and the pH of treated water being discharged were lowed and optimum removal pH range was broadened. For the result of this experiment, 99.8% removal efficiency was obtained at the condition of 50ppm of initial cobalt ion concentration, pH 9.5, 70 mL/min of gas flow rate, and 30 min of removal time. Attraction between precipitate and surfactant was supposed to be influenced by solubility and chemical affinity among species in sloution as well as zeta potential. The influence of foreign ions such as, $NO_3{^-}$, ${SO_4}^{-2}$, $Na^+$, $Ca^{+2}$ on the removal efficiency was also observed. Removal efficiency by precipitate flotation containing 0.1 M of ${SO_4}^{-2}$ ion decreased to 90% due to the decrease of zeta potential and interruption of precipitation.

• Journal of the Korean Society of Fisheries and Ocean Technology
• /
• v.52 no.3
• /
• pp.248-256
• /
• 2016

The main purpose of this paper was to analyze the removal characteristics of gas/particulate phase pollutants for the present system. Experimentally, we performed to estimate the pressure drop and air pollution removal efficiency with physical variables such as stage number, tube velocity, tube diameter, water spray ($NH_4OH$), and so on. It was concluded that the pressure drop was shown below $111mmH_2O$ lower than that of the existing scrubber (centrifugal spray chamber, over 200 mmAq) at inlet velocity 3.46 m/s and 5 stage. The particular removal efficiency of this system was to be significantly higher at 99.8% in comparison with that of the existing scrubber for 5 stage, inlet velocity 3.46 m/s and $NH_4OH$ (aq) 300 mL/min. It was estimated that the removal efficiencies of $SO_2$ and $NO_2$ were 80% and 70% at system inlet velocity 2.07 m/s and $NH_4OH$ (aq) 300 mL/min respectively. Additionally, the present collection system was to be considered as an effective compact system for simultaneous removal of air pollutants (gas/particulate) due to much higher removal efficiency and appropriate pressure drop without a demister.

• Analytical Science and Technology
• /
• v.15 no.3
• /
• pp.256-262
• /
• 2002

After porous filters were manufactured using cordierite powder whose mean paricle size was 200${\mu}m$, they were loaded with catalysts such as $V_2O_5$, CuO and $LaCoO_3$ by vacuum impregnation method. And the NOx/SOx simultaneous removal efficiency was measured by passing NO and $SO_2$ through catalyst-loaded ceramic filters. The cordierite porous filters had the apparent porosity of 61.6%, the compressive strength of 12.3 MPa and the pressure drop of 147 pa at the face velocity of 5 cm/sec. According to the analysis of NO/$SO_2$ simultaneous removal efficiency, perovskite $LaCoO_3$ catalyst was the most efficient for the simultaneous NO and $SO_2$ removal. The $LaCoO_3$ catalyst-loaded filter could remove more than 90% for NO and more than 80% for $SO_2$.

• Journal of environmental and Sanitary engineering
• /
• v.15 no.2
• /
• pp.34-40
• /
• 2000

In the tungsten industry, molybdenum wire which used as the center supporter for coil shape tungsten wire was removed. Nitric acid dissolution method which used prevalently up to the present, takes nitric acid as major component and use noxious material such as sulfuric acid and hydrochloric acid remove molybdenum wire which used as center supporter by dissolve selectively within the range of no damage on tungsten wire. Mixed acid waste water occurred to the process were difficult to be decomposed by the conventional methords. This mixed acid waste water was treated by ozone, and It was obtained using possible by-product through the treatment waste water. For the three reactors with the same volume ; Blank reactor, Disturbance plate reactor, Packed-bed reactor ; the results were as follows : For the blank reactor COD removal efficiency in the pH = 4 (HRT : 6hr) was 28.5%, COD removal efficiency in the pH = 7 (HRT : 6hr) was 28.6%, and COD removal efficiency in the pH = 10 (HRT : 6hr) was 27.8%. For the disturbance plate reactor COD removal efficiency in the pH = 4 (HRT : 6Min.) was 86.5%, COD removal efficiency in the pH =7 (HRT : 6Min.) was 84.4%, and COD removal efficiency in the pH = 10 (HRT : 60Min.) was 86.8%. For the packed-bed reactor COD removal efficiency in the pH = 4 (HRT : 40Min.) was 76.0%, COD removal efficiency in the pH = 7 (HRT : 40Min.) was 81.3%, and COD removal efficiency in the pH = 10 (HRT : 40Min.) was 84.6%. After O3 treatment using possible by-product(Na2SO4) was 150g/ℓ.

• Journal of Korean Society of Environmental Engineers
• /
• v.22 no.1
• /
• pp.21-31
• /
• 2000

Performance characteristics of a wet air cleaning system were investigated experimentally, and discussed in relation with physicochemical properties of the target pollutants. The system is composed of an air cleaner, a separator, and a medium filter. Removal efficiency of the system was measured for ambient particles and gaseous air pollutants: $SO_2$, NO, $NO_2$, HCHO, and $NH_3$. For particle removal test, particles were introduced into the system through a fan, and the particle size distribution was measured at three locations by using two laser particle counters. Particle removal efficiency for each system component was obtained from the particle size distribution. It was found that the separator primarily removed coarse particles greater than $5{\mu}m$ in diameter, and that the medium filter mainly removed fine particles less than $5{\mu}m$ in diameter. For gas removal test, air with gaseous air pollutant was injected into the outlet of the fan, and the concentration was measured both at the upstream of the air cleaner and at the downstream of the separator. It was found that the gaseous species with high Henry's law coefficients, such as $SO_2$, HCHO, and $NH_3$, showed high removal efficiency, but the gaseous species with low Henry's law coefficients, such as NO and $NO_2$, showed low removal efficiencies. It was also found that negative ions were generated from the air cleaner.