• Title/Summary/Keyword: $R_1$-space

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Analysis of browning degree on fresh-cut lotus root (Nelumbo nucifera G.) using image analysis (이미지 분석을 이용한 신선편이 연근의 갈변도 분석)

  • Cho, Jeong-Seok;Kim, Dae-Hyun;Park, Jung-Hoon;Moon, Kwang-Deog
    • Food Science and Preservation
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    • v.20 no.6
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    • pp.760-765
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    • 2013
  • The image analysis as a tool for evaluation of browning degree on fresh-cut lotus root was studied. The fresh-cut lotus root treated as 4 groups (Cont-without any treatment, DB-blanching at $50^{\circ}C$ for 5 min in distilled water, AB-blanching at $45^{\circ}C$ for 5 min in 1% ascorbic acid, CB-blanching at $45^{\circ}C$ for 5 min in 1% citric acid). The samples treated with each methods were packaged with 0.04 mm polyethylene bag ($25cm{\times}30cm$) and stored at $4^{\circ}C$ for 9 days. On the RGB color space, the AB and CB group showed high R, G, B value. On the HSV and CIE $L^*a^*b^*$ color space, the AB and CB group showed low browning area, $a^*$, $b^*$ value and high $L^*$ value. Polyphenol oxidase activity was low in the AB and CB groups in all storage period. This result means that the AB and CB groups were inhibited the development of tissue browning. The result of sensory evaluation also supported this opinion. And the correlation coefficient between sensory evaluation with all color values was over 0.84. Especially, the $L^*$ value showed the highest correlation coefficient (0.93). In conclusion, the image analysis is suitable for analysis of browning degree on fresh-cut lotus root by analyzing diverse color value.

Tidal variations in the cable voltage across the Korea Strait

  • Lyu, Sang-Jin;Kim, Young-Gyu;Kim, Kuh;Book, Jeffrey W.;Choi, Byung-Ho
    • Journal of the korean society of oceanography
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    • v.37 no.1
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    • pp.1-9
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    • 2002
  • Cable voltage was measured simultaneously at Hamada, Japan and Pusan, Korea, using an inservice telephone cable from March to December 1990. The spectral and harmonic analyses of these data sets show that tidal signals are dominant, and that tidal constituents $M_2$ and $O_1$, which are not affected by solar geomagnetic variations, have almost the same amplitude and are of opposite phase to each other. comparing the voltage difference in 1990 with that measured using the now abandoned cable in 1998, there are dominant tidal signals at the same periods in both data sets. They have approximately the same amplitude and phase for $M_2andO_1$. The relationship between the observed voltage and the volume transport through the Korea Strait can be considered robust and stable over time. The conversion factor from voltage to transport is estimated to be $11.9{\times}10^6m^3S^{-1}volt^{-1}$ by comparing the amplitude of model-derived $M_2$ tidal transport with that of the voltage difference in 1998. This value changes to $8.6{\times}10^6m^3S^{-1}volt^{-1}$ when taking into consideration the horizontal electric current effect. This effect depends on the downstream length scale of the flow. To obtain a more reliable and stable conversion factor from voltage to transport, the voltage should be compared with observed sub-tidal transports, which may have long downstream length scales.

Crystal Structure of the Three-Dimensional Metal Complex Inclusion Compound Clathrated Nitrobenzene Guest (Nitrobenzene을 guest로 포접한 3차원 금속착체 포접화합물의 결정구조)

  • Park, Ki-Min;Park, Sang-Yun;Lee, Uk;Iwamoto, Toschitake
    • Journal of the Korean Chemical Society
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    • v.40 no.7
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    • pp.509-514
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    • 1996
  • The three-dimensional metal complex inclusion compound $Cd(pn)Ni(CN)_4{\cdot}0.5NO_2C_6H_5$(pn: 1,2-diaminopropane=propylenediamine) crystallizes in the orthorhombic space group, $Pn2_1$a, (a=13.868(5), b=26.591(4), c=7.840(1)${\AA}$, V=2891(1)${\AA}^3$, Z=4), R=0.054 for 2800 independent reflections. The host structure of the inclusion compound appears the same one(T-type) of inclusion compound with branched aliphatic-guest molecule. The nitrobenzeneguest molecule attains the stable position in the nodal channel of T-type by placing the polar nitro group between the pn-amino groups at the node and the bulky aromatic ring in the antinodal zone of the channel. The substituted aromatic guest molecule is accommodated in the host structure of metal complex $Cd(pn)Ni(CN)_4$ with channel cavity.

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The Crystal and Molecular Structure of Cholesteryl Pentanoate (콜레스테릴 펜타노에이트의 결정 및 분자구조)

  • An, Jung Tae;Park, Yeong Ja
    • Journal of the Korean Chemical Society
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    • v.34 no.1
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    • pp.1-9
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    • 1990
  • Cholesteryl pentanoate $(C_{32}O_2H_{54})$ is orthorhombic, space group $P2_12_12_1$, with a = 21.930(3), b = 21.404(3), c = 6.419(5) $\AA$, Z = 4, V = 3012.8(5)$\AA$$^3$, $D_c$ = 1.04 g$cm^{-3}$, ${\lambda}(Mo\; K{\alpha}$ = 0.71069 $\AA$, $\mu$ = 0.58 $cm^{-1}$, F(000) = 1048, T = 298, R = 0.086 for 1502 unique observed reflections with I > 1.0 $\sigma$ (I). The structure was solved by direct methods and refined by cascade diagonal least-squares refinement. The C-H bond lengths and the methyl groups are fixed and refined as their ideal geometry. A comparison with other cholesteryl esters gives normal structure for the tetracyclic ring, while the tail regions of the side chain and the ester group which stands on end, show a variation from their normal values, presumably due to thermal effects. The molecules are stacked together by non-bonded van der Waals forces with the shortest intermolecular distance of 3.529 $\AA$.

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The Effect of Seedlings Density in Nursery on Biomass Production and Growth Characteristic of Styrax obassia (생육밀도가 쪽동백나무 유묘의 물질생산량과 생장특성에 미치는 영향)

  • Choi, Jeong-Ho;Yoo, Se-Kuel;Lee, Soo-Won;Oh, Seok-Gui
    • Journal of Bio-Environment Control
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    • v.16 no.3
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    • pp.217-221
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    • 2007
  • To provide the basic data essential for developing varieties of broad-leaved tree, the study investigated the utmost growth requirement for the growth characteristic and biomass production in accordance with planting density of Styrax obassia. The planting density of seedling can be a significant factor in contributing growth of seedling for tree growing in general. While growth of tree according to $1m^2$ planting density of Styrax obassia showed an excellent growth in tree height and the root collar diameter from $49no./m^2$, those low planting density showed decreased tendency with tree height growth while increasing the root collar diameter growth. As similar to the growth characteristic, the biomass production showed significant and statistic difference in $49no./m^2$, showing high volume of biomass production which is $3.12{\pm}0.80g$ compare to other processing section and high figure with T/R ratio which is 1.59. The special trait of photosynthetic also showed relatively high photosynthetic rate in $49no./m^2\;and\;64no./m^2$ of Styrax obassia and as the density increase, photosynthetic efficiency decreased. The plant showed stable and physiological planting pattern, displaying the best photosynthetic rate, which was the final metabolism through reserving proper space in the growth and development environment condition. This obstacle of required space essential for growth substantially deteriorated planting and ultimately, it demonstrated lower tendency of photosynthetic rate, which is the highest level of metabolism.

Investigation of Mössbauer Spectra of Ba2Mg0.5Co1.5(Fe0.99In0.01)12O22 (Ba2Mg0.5Co1.5(Fe0.99In0.01)12O22의 뫼스바우어 분광 연구)

  • Lim, Jung-Tae;Kim, Chin-Mo;Kim, Chul-Sung
    • Journal of the Korean Magnetics Society
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    • v.22 no.1
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    • pp.19-22
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    • 2012
  • $Ba_2Mg_{0.5}Co_{1.5}(Fe_{0.99}In_{0.01})_{12}O_{22}$ was prepared by the conventional solid-state reaction method, and studied by x-ray diffractometer, vibrating sample magnetometer, and Mossbauer spectrometer. The crystal structure was determined to be a single-phased rhombohedral with space group R-3m. Magnetization value were $M_s$ = 28.6 emu/g at 295 K. The hysteresis loops indicate that all the samples are ferrimagnetic behaviors. Mossbauer spectra of $Ba_2Mg_{0.5}Co_{1.5}(Fe_{0.99}In_{0.01})_{12}O_{22}$ have been 6-sextet taken at various temperatures ranging from 4.2 to 620 K. Based on the isomer shift (${\delta}$) values of all samples, the charge states were found to be $Fe^{3+}$ state at all temperatures, the Curie temperature was determined to be 630 K by the ZVC curve.

The Crystal Structure of Nicotine Dihydroiodide (Nicotine Dihydroiodide의 結晶構造)

  • Koo, Chung-Hoe;Kim, Hoon-Sup
    • Journal of the Korean Chemical Society
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    • v.9 no.3
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    • pp.134-141
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    • 1965
  • Crystals of nicotine dihydroiodide, are orthorhombic with space group $p2_12_12_1$.The unit cell of dimensions a=7.61, b=11.01, e=17.27${\AA}$, contains four formula units. The structure has been determined by X-ray diffraction method and has been refined to give the R-index, ${\sum}{\mid}{\mid}F_{\circ}{\mid}-{\mid}F_c{\mid}{\mid}{\div}{\sum}{\mid}F_{\circ}{\mid}$, of 0.16 and 0.14 for $F_{okl}\;and\;F_{hol}$ respectively.The mean lengths of C-C and C-N bonds in pyridine ring are 1.40 and $1.35{\AA}$ and those in pyrolidine ring 1.56 and $1.48{\AA}$ respectively, though accurate measurement of bond length has not been attempted. The six atoms in the pyridine ring are coplanar and on the other hand $C_6,\;C_7,\;C_8$ and $N_2$ atoms in pyrrolidine ring form a plane within accuracy of the analysis, and $C_9$ atom is distant $0.22{\AA}$ out of the plane consist of $C_6,\;C_7,\;C_8$ and $N_2$ aoms. The normals to the two planes form an angle of $94^{\circ}$ with each other. Iodine atom is distant $3.55{\AA}$ from nitrogen atom in pyridine ring and the other iodine atom $3.58{\AA}$ from nitrogen atom in pyrrolidine ring, so that the nitrogen and iodine atoms are firmly linked.It seems that the only forces binding nicotine dihydroiodide molecules together in the crystal are Van der Waals forces.

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Synthesis and Electrochemical Properties of $LiNi_{1-y-z}(M_1)_y(M_2)_zO_2$ for the Development of Cathode Materials with Large Capacity (고용량 양극재료 개발을 위한 $LiNi_{1-y-z}(M_1)_y(M_2)_zO_2$의 합성과 전기화학적 특성)

  • Song, Myoung-Youp
    • Transactions of the Korean hydrogen and new energy society
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    • v.18 no.3
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    • pp.325-333
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    • 2007
  • [ $LiNi_{0.995}Al_{0.005}O_2$ ], $LiNi_{0.990}Ti_{0.010}O_2$ and $LiNi_{0.0990}Al_{0.005}Ti_{0.005}O_2$ were synthesized with a combustion method by calcining in an $O_2$ stream at $750^{\circ}C$ for 36 h. The X-ray diffraction patterns of these synthesized samples showed $-NaFeO_2$ structure of rhombohedral system(space group; $R{\bar{3}}\;m$) with no evidence of impurities. Among these samples, $LiNi_{0.995}Al_{0.005}O_2$ exhibited comparatively high first discharge capacity and discharge capacity, and the best cycling performance. $LiNi_{0.995}Al_{0.005}O_2$ had the first discharge capacity of 165.2 mA h/g and a discharge capacity of 116.7 mA h/g at the 50th cycle at 0.1C rate. It showed the first discharge capacity of 141.0 mA h/g and a discharge capacity of 93.5 mA h/g at the 50th cycle at 0.5C rate.

Simultaneous Analysis of 17 Organophosphorous Pesticides in Blood by Automated Head Space-SPME GC/MS (HS-SPME-GC/MS에 의한 혈액중 17종 유기인계 농약의 동시분석법)

  • Rhee, Jong-Sook;Jung, Jin-Mi;Lee, Han-Sun;Yeom, Hye-Sun;Lee, Sang-Ki;Park, Yoo-Sin;Chung, Hee-Sun
    • YAKHAK HOEJI
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    • v.54 no.6
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    • pp.429-440
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    • 2010
  • HS-SPME-GC/MS was studied and optimized for the determination of 17 orgarnophosphorous pesiticides (OPPs: chlorpyrifos, chlorpyrifos-methyl, demeton-s-methyl, diazinon, dimethoate, EPN, fenitrothion, fenthion, malathion, methidathion, monocrotophos, parathion, phenthoate, phosphamidon, sulfotep, terbufos, triazophos) in blood. Optimum SPME parameters were selected: choice of SPME fiber (85 ${\mu}m$ polyacrylate), pH effect (0.5 N HCl), salt effect ($Na_2SO_4$, 0.2 g; 20%), headspace incubation temperature ($80^{\circ}C$), headspace incubation time (1 min), headspace adsorption time (30 min) and GC desorption time (2 min). These parameters were optimized using HS-SPME autosampler coupled with gas chromatography-mass spectrometry (GC-MS). Method validation was carried out in terms of linearity, limit of detection (LOD), limit of quantitation (LOQ) and recovery in blood. The assay was linear over 0.5~5.0 mg/l ($r^2$=0.955~1.000). Limit of detection (LOD) and limit of quantitation (LOQ) in blood were determined 0.03~0.3 mg/l (S/N=3) and 0.1~1.1 mg/l (S/N=10), respectively. Relative recovery with 0.5, 1 and 5 mg/l (in blood) were 90.8%, 98.5% and 94.1%, respectively. This method will be applied to the determination of the orgarnophosphorous pesticides in postmortem blood. The proposed protocol can be an attractive alternative to be used in routine toxicological analysis.

A STATISTICAL ANALYSIS OF SOLAR WIND DYNAMIC PRESSURE PULSES DURING GEOMAGNETIC STORMS (지자기폭풍 기간 동안의 태양풍 동압력 펄스에 관한 통계적 분석)

  • Baek, J.H.;Lee, D.Y.;Kim, K.C.;Choi, C.R.;Moon, Y.J.;Cho, K.S.;Park, Y.D.
    • Journal of Astronomy and Space Sciences
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    • v.22 no.4
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    • pp.419-430
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    • 2005
  • We have carried out a statistical analysis on solar wind dynamic pressure pulses during geomagnetic storms. The Dst index was used to identify 111 geomagnetic storms that occurred in the time interval from 1997 through 2001. We have selected only the events having the minimum Dst value less than -50 nT. In order to identify the pressure impact precisely, we have used the horizontal component data of the magnetic field H (northward) at low latitudes as well as the solar wind pressure data themselves. Our analysis leads to the following results: (1) The enhancement of H due to a pressure pulse tends to be proportional to the magnitude of minimum Dst value; (2) The occurrence frequency of pressure pulses also increases with storm intensity. (3) For about $30\%$ of our storms, the occurrence frequency of pressure pulses is greater than $0.4\#/hr$, implying that to. those storms the pressure pulses occur more frequently than do periodic substorms with an average substorm duration of 2.5 hrs. In order to understand the origin of these pressure pulses, we have first examined responsible storm drivers. It turns out that $65\%$ of the studied storms we driven by coronal mass ejections (CMEs) while others are associated with corotating interaction regions $(6.3\%)$ or Type II bursts $(7.2\%)$. Out of the storms that are driven by CMEs, over $70\%$ show that the main phase interval overlaps with the sheath, namely, the region between CME body and the shock, and with the leading region of a CME. This suggests that the origin of the frequent pressure pulses is often due to density fluctuations in the sheath region and the leading edge of the CME body.