• 한국결정성장학회지
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• 제5권2호
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• pp.152-164
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• 1995

NaCl과 KCl을 1 : 1 mole비로 한 용융염 합성법으로 $xPb(Fe_{1/2}Nb_{1/2})O_3 - (1 - x)Pb(Mg_{1/3}Nb_{2/3})O_3$(x=0-1.0)을 제조하였으며, 이의 분말 특성 및 유전성을 연구하였다. 용융염 합성법에 의해 제조된 $xPb(Fe_{1/2}Nb_{1/2})O_3 - (1 - x)Pb(Mg_{1/3}Nb_{2/3})O_3$의 분말은 $2 \mu\textrm{m}$ 이하의 평균입도를 갖고 비교적 응집이 적었다. 용융법 합성법으로 제조된 $x0.3Pb(Fe_{1/2}Nb_{1/2})O_3-0.7Pb(Mg_{1/3}Nb_{2/3})O_3$ 세라믹스는 $1000{\times}C$에서 제조가 가능하며, 11,000이상의 유전상수를 갖는다.

• 한국결정성장학회지
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• 제8권4호
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• pp.667-672
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• 1998

Columbite precursor 방법을 이용하여 제조한 Pb(Mg1/3Nb2/3)O3-PbTiO3 세라믹계의 초전특성을 $1000^{\circ}C$에서 $1250^{\circ}C$의 소결온도 범위에서 관찰하였다. Pb(Mg1/3Nb2/3)O3-PbTiO3 계는 전형적인 완화형 강유전특성을 나타내었다. $1250^{\circ}C$에서 2시간 소결한 $Pb(Mg_{1/3}Nb_{2/3})O_3-PbTiO_3$ 세라믹의 경우, 높은 소결밀도와 향상된 초전특성을 얻을수 있었다. $Pb(Mg_{1/3}Nb_{2/3})O_3-PbTiO_3$세라믹은 항온장치를 이용할 경우 초전 센서로의 응용가능성을 나타내었다.

• 한국세라믹학회:학술대회논문집
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• 한국세라믹학회 2000년도 추계총회,초청강연,특별강연,연구발표회
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• pp.66.2-66
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• 2000

• 한국세라믹학회지
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• 제30권9호
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• pp.723-730
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• 1993

The mechanism of formation of perovskite phase and the dielectric properties of PZMN[Pb(Zn, Mg)1/3Nb2/3O3] ceramics were examined using two different types of the columbite precursors, (Mg, Zn)Nb2O6 (MZN) and MgNb2O6＋ZnNb2O6 (MN＋ZN). The formatin of perovskite phase in PbO＋MN＋ZN system is characterized by an initial rapid formation of Mg-rich perovskite phase, followed by a sluggish formation of Zn-rich perovskite phase. On the other hand, thepyrochlore/perovskite transformation in the PbO＋MZN system proceeded uniformly with a spatial homogeneity. The degree of diffuseness of the rhombohedral/cubic phase transitionis higher in the PbO＋MN＋ZN system than in the PbO＋MZN specimen, indicating a broadened compositional distributjion of the B-site catons (Nb+5, Zn+2, Mg+2) in the PbO＋MN＋ZN system.

• 한국세라믹학회지
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• 제33권10호
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• pp.1117-1123
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• 1996

• 한국세라믹학회지
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• 제31권12호
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• pp.1443-1448
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• 1994

Pb(Mg1/3Nb2/3)O3-PbTiO3-BaTiO3 solid solution was formed by mixed-oxide method. The phase during formation was analysed by XRD and formation mechanism was investigated. While heat-treating Pb(Mg1/3Nb2/3)O3 composition, the first, Pb2Nb2O7 and Pb3Nb2O8 pyrochlore phases are formed, and finally Pb(Mg1/3Nb2/3)O3 perovskite phase with containing Pb3Nb4O13 pyrochlore phase is obtained at 80$0^{\circ}C$. When Pb(Mg1/3Nb2/3)O3 composition is modified with PbTiO3 which have strong ionic bonding and high tolerance factor, the amount of pyrochlore phase is decreased by increasing of stability in perovskite structure.

• 한국결정성장학회:학술대회논문집
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• 한국결정성장학회 1996년도 제11차 KACG 학술발표회 Crystalline Particle Symposium (CPS)
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• pp.185-217
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• 1996

Pb(Mg1/3Nb2/3)O3은 높은 유전율과 전기저항 및 유전율의 온도변화율이 적은 Pb계 relaxor의 대표적인 재료로서 적층 세라믹 콘덴서 재료에의 응용이 크게 기대되고 있다. 그러나 산화물 분말을 이용하는 일반적인 세라믹스 합성방법으로는 Pb(Mg1/3Nb2/3)O3의 단일상의 합성이 어렵고, 합성과정에서 저유전율상인 pyrochlore상이 합성이 어렵고, 합성과정에서 저유전율상인 pyrochlore상이 공존하여 Pb(Mg1/3Nb2/3)O3의 전기적 특성을 저하시킨다. 본연구에서는 용액을 이용하여 Pb(Mg1/3Nb2/3)O3의 단일상을 합성하고자 하였다. 출발물질로는 값싼 금속염인 Niobium Oxalate, magnesium Nitrate 및 Lead Nitrate를 선정하고 증류수에 용해하여 혼합용액을 제좋고, 합성방법으로는 초음파 분무 열분해법과 에멀젼법을 이용하였다. 초음파 분무 열분해법에서는 75$0^{\circ}C$에서 합성한 분말을 다시 75$0^{\circ}C$에서 하소하여 Pb(Mg1/3Nb2/3)O3 단일상을 합성할 수 있었으며, 에멀젼법에서는 80$0^{\circ}C$에서 Pb(Mg1/3Nb2/3)O3 단일상을 합성할 수 있었다.

• 한국세라믹학회지
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• 제33권11호
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• pp.1267-1275
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• 1996

Green sheet was prepared by tape casting in the composition of (1-x)Pb(Mg1/3Nb2/3)O3-PbTiO3 system using Pb(Mg1/3Nb2/3)O3 and PbTiO3 synthesized with PbO, Nb2O5 MgO and TiO2 The densest green sheet was obtained in the weight ratio 70:30 of powder to binder. Green sheet wasmultilayered in metal mould and formed into lamination at 7$0^{\circ}C$, 300kg/cm2 The lamination was sintered at 110$0^{\circ}C$ 2hr, Dielectric constant and Curie temperature of disc type sintered body was highered with increasing the amount of PbTiO3 and was in the range of 19000-21000, -7~45$^{\circ}C$ respectively. Green and sintered relative density of lamination was 61% and 95% respectively.

• 한국세라믹학회지
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• 제35권2호
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• pp.123-128
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• 1998

Multilayer ceramic capacitors(MLCC) were prepared by laminating the layer of composition with dif-ferent Curie temperature to improve temperature coefficient in the Pb(Mg1/3Nb2/3)O3-PbTiO3 binary system. Green sheet was formed by tape casting using Pb(Mg1/3Nb2/3)O3-PbTiO3 and PbTiO3 synthesized with solid state reaction of PBO. Nb2O5 MgO and TiO2. Green sheet with electrode of 70Ag-30Pd was laminated under 300 kg/cm2 at 70$^{\circ}C$ and sintered at 1100$^{\circ}C$ for 2hr. Curie temperatues for MLCC with 10 layers of pure PMN and 0.9PMN-0.1PT were lowered to -22$^{\circ}C$ and 36$^{\circ}C$ respectively. MLCC with 7 layers of PMN and 3 layers of 0.9PMN-0.1PT showed nearly zero temperature coefficient of capacitance in the range of -20∼30$^{\circ}C$ and sum of dissipation factor of each layer.

• 한국세라믹학회지
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• 제31권10호
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• pp.1240-1246
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• 1994

While sintering the Pb(Mg1/3Nb2/3)O3-PbTiO3-BaTiO3 system through solid-reaction route, pyrochlore(Pb3Nb4O13) phase while reduces the dielectric constant is inevitably formed. Substitution of Pb(Mg1/3Nb2/3)O3 with PbTiO3 and BaTiO3 can retard the occurrence of pyrochlore phase. The perovskite solid-solution without containing pyrochlore phase can be obtained when we consolidated the materials consisting of PbTiO3 and BaTiO3 at 1200℃ for 2 hours. The sintered body composed of 0.8Pb(Mg1/3Nb2/3)O3-0.1PbTiO3-0.1BaTiO3 composition showed the diffused phase transition(DPT) phenomena and the maximum value of dielectric constant at 0℃ (Tc') with the value of 1.3×104.