• Journal of Korean Society of Environmental Engineers
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• v.32 no.8
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• pp.739-746
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• 2010

The purposes of this study are 1) to develop an advanced chamber system within ${\pm}10%$ of air velocity at the particulate matter (PM) collection area, 2) to research theoretical characteristics of PM10 and PM2.5 samplers, 3) to assess the performance characteristics of PM10 and PM2.5 samplers through chamber experiments. The total six one-hour experiments were conducted using the cornstarch with an mass median aerodynamic diameter (MMAD) of $20\;{\mu}m$ and an geometric standard deviation of 2.0 at the two different air velocity conditions of 0.67 m/s and 2.15 m/s in the chamber. The aerosol samplers used in the present study are one APM PM10 and one PM2.5 samplers accordance with the US federal reference methods and specially designed three mini-volume aerosol samplers (two for PM10 and one for PM2.5). The overall results indicate that PM10 and PM2.5 mini-volume samplers need correction factors of 0.25 and 0.39 respectively when APM PM samplers considered as reference samplers and there is significant difference between two mini-volume aerosol samplers when a two-way analysis of variance is tested using the measured PM10 mass concentrations. The PM10 and PM2.5 samplers with the cutpoints and slopes (PM10: $10{\pm}0.5\;{\mu}m$ and $1.5{\pm}0.1$, PM2.5: $2.5{\pm}0.2\;{\mu}m$ and $1.3{\pm}0.03$) theoretically collect the ranges of 86~114% and 64~152% considering the cornstarch characteristics used in this research. Furthermore, the calculated mass concentrations of PM samplers are higher than the ideal mass concentrations when the airborne MMADs for the cornstarch used are smaller than the cutpoints of PM samplers and the PM samplers collected less PM in another case. The chamber experiment also showed that PM10 and PM2.5 samplers had the bigger collection ranges of 37~158% and 55~149% than the theocratical calculated mass concentration ranges and the relatively similar mass concentration ranges were measured at the air velocity of 2.15 m/s comparing with the 0.67 m/s.

• Journal of Environmental Science International
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• v.21 no.7
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• pp.855-863
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• 2012

This study analyzed mass concentrations of TSP, PM10 and PM2.5 and elemental constituents according to the isentropic backward trajectories of air parcel from Cheongwonin East Asia during the period January - October, 2011. Mass concentrations of the continental polluted airflow (CP) showed levels of TSP and PM10 mass concentrations higher than the continental background airflow (CB). Also, PM2.5 mass concentrations of anthropogenic fine particles ran higher in CP than in CB. The elemental constituents and elemental constituent ratio ended up varying depending on the origin of atmospheric aerosols generated. The average absolute content of elemental constituents reached its height in CB, the ratio of anthropogenically originating elements (PE) among the all elements (AE) analyzed marked a high in CP, and Mg+Na/AE reached its height in the oceanic airflow (OA). At the same time, TSP, PM10 and PM2.5 mass concentrations, the ratio of PM2.5/TSP and PE/AE element ratio ran higher in CP than CB. Episodes of large-scale transport of atmospheric pollutants as observed at Cheongwon were 8 cases and 22 days. The ratios of PM10, PM2.5 among TSP mass concentrations showed different results and the ratios of PM2.5 showed an increasing trend in the episodes of anthropogenic air pollution transport. Overall, dustfall episodes show a level of elemental constituents higher than those of anthropogenic air pollution.Dustfall episodes were observed to contain more of Fe, Al and Ca originating from continental soils and those of air pollution were observed to contain more of Zn, Mn, Cu and Pb. By difference in contents of absolute elemental constituents, episodes of anthropogenic air pollution showed a high PE/AE rate, and dustfall episodes a high SE/AE rate.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.9 no.5
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• pp.1349-1353
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• 2008

Size-segregated mass and ion concentrations of atmospheric aerosols in Cheonan City were measured using a high volume air sampler equipped with a 5-stage cascade impactor and a ion chromatography between March 2006 and April 2007. The mean values of 24-hr average concentrations of TSP, PM10, PM2.5, and PM1 were 61.7, 55.2, 43.7, $33.2{\mu}g/m^3$, respectively. Mass size distributions of atmospheric aerosols were bimodal distributions with a saddle point in $1.5\;{\sim}\;3.0{\mu}m$ range in diameter separating coarse and fine particle modes. Fine particles, PM2.5 were 70.8% of the total mass of aerosols. Major ion components in aerosols were ${NH_{4}}^+$, $Na^+$, $K^+$, $Ca^{2+}$, $Mg^{2+}$ for cations, and ${SO_{4}}^{2-}$, ${NO_{3}}^-$, $Cl^-$ for anions. ion components occupied 37.4% of coarse particles and 46.2% of fine particles in mass.

• Journal of Environmental Science International
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• v.17 no.4
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• pp.359-364
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• 2008

PM10 samples were collected from July 2007 to Oct. 2007 at Gwaebopdong(inland area) and Dongsamdong(coastal area), in Busan. This paper investigates the contribution of emission sources to PM10 mass in Busan. Source apportionment results derived from the chemical mass balance(CMB) method. A source profiles applied in this study is organized to minimize the collinearity among sources type via statistical method. Source profiles applied in this study utilized a measured value of fine particle directly sampled from metropolitan area such as Seoul and Incheon, After a CMB modeling, sulfate and nitrate related sources among those contributing to PM10 in Busan showed high contribution by 36.53% in Gwaebopdong and 42.02% in Dongsamdong.

• Asian Journal of Atmospheric Environment
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• v.10 no.4
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• pp.217-225
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• 2016

The purpose of the study was to initially investigate the concentration patterns of $PM_1$, $PM_{2.5}$ and $PM_{10}$ in the Seoul subway lines, and then to figure out the PM behaviors of internal and external sources inside subway tunnels. The PMs were monitored by a light scattering real-time monitor during winter (Jan. 8-26 in 2015) and summer (July 2-Aug. 7 in 2015) in tunnel air, in passenger cabin air, and in the ambient air. The daily average $PM_{10}$, $PM_{2.5}$, and $PM_1$ concentrations on these object lines were $101.3{\pm}38.4$, $81.5{\pm}30.2$, and $59.7{\pm}19.9{\mu}g/m^3$, respectively. On an average, the PM concentration was about 1.2 times higher in winter than in summer and about 1.5 times higher in underground tunnel sections than in ground sections. In this study, we also calculated extensively the average PM mass ratios for $PM_{2.5}/PM_{10}$, $PM_1/PM_{10}$, and $PM_1/PM_{2.5}$; for example, the range of $PM_{2.5}/PM_{10}$ ratio in tunnel air was 0.82-0.86 in underground tunnel air, while that was 0.48-0.68 in outdoor ground air. The ratio was much higher in tunnel air than in outdoor air and was always higher in summer than in winter in case of outdoor air. It seemed from the results that the in/out air quality as well as a proper amount of subway ventilation must be significant influence factors in terms of fine PM management and control for the tunnel air quality improvement.

• Journal of Environmental Science International
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• v.27 no.7
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• pp.597-610
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• 2018

This study observed particulate matter ($PM_{2.5}$ and $PM_{10}$) in the downtown area of Jeju City, South Korea, to understand the chemical composition of particulates based on an analysis of the water-soluble ionic species contained in the particles. The mass fraction of the ionic species in the sampled $PM_{10}$ and $PM_{2.5}$ was 44.3% and 42.2%, respectively. In contrast, in Daegu City and Suwon City, the mass fraction of the ionic species in $PM_{2.5}$ was higher than that in $PM_{10}$. The chloride depletion percentage of $PM_{10}$ and $PM_{2.5}$ in Jeju City was higher than 61% and 66%, respectively. The contribution of sea-salt to the mass of $PM_{10}$ (5.9%) and $PM_{2.5}$ (2.6%) in Jeju City was similar to that in several coastal regions of South Korea. The mass ratio of $Cl^-$ to $Na^+$ in the downtown area of Jeju City was comparable to that in some coastal regions, such as the Gosan Area of Jeju Island, Deokjeok Island, and Taean City. The mass fraction of sea-salt in $PM_{10}$ and $PM_{2.5}$ was very low, and the concentration of sodium and chloride ions in $PM_{10}$ was not correlated with those in $PM_{2.5}$ ($R^2$ < 0.2), suggesting that the effects of sea-salt on the formation of particulate matter in Jeju City might be insignificant. The relationship between $NH_4{^+}$ and several anions such as $SO_4{^{2-}}$, $NO_3{^-}$, and $Cl^-$, as well as the relationship between the measurement and calculation of ammonium ion concentration, suggested that sea-salts may not react with $H_2SO_4$, and $(NH_4)_2SO_4$ may be a major secondary inorganic aerosol component of $PM_{2.5}$ and $PM_{10}$ in Jeju City.

• Journal of Environmental Science International
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• v.19 no.7
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• pp.799-806
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• 2010

In an effort to characterize temporal and spatial variability of $PM_{10}$ and to quantitatively estimate contribution of sea salt aerosol to $PM_{10}$ mass in Busan area, twenty four-hour averaged concentration of $PM_{10}$ were measured in two distinct areas, Gwaebeopdong(inland) and Dongsamdong(seashore), Busan for summer and fall, 2007. It was found that sea salt accounted for 2.9% and 9.5% of $PM_{10}$ mass in Gwaebeopdong and Dongsamdong, respectively for the study period, indicating that contribution of sea salt to $PM_{10}$ mass and total ion concentration in seashore area were consistently higher by a factor of three compared to inland area. Temporal analysis suggested that sea salt contributions to $PM_{10}$ in Dongsamdong were higher in summer due to the southerly sea breeze while there was no significant fluctuation of sea salt contribution for the summer and fall months in Gwaebeopdong. Sea salt enrichment factors($EF_{sea}$) of $K^+$ $Ca^{2+}$ and ${SO_4}^{2-}$ (>10) indicated major contributions from anthropogenic sources and EFs of $Mg^{2+}$ and $Cl^-$ exhibited strong association with oceanic origins for both areas.

• Journal of Korean Society of Environmental Engineers
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• v.31 no.2
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• pp.153-160
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• 2009

A PM10 (aerodynamic diameter${\leq}$10 ${\mu}m$) sampler is used to quantify the potential human exposure to suspended particulate matter (PM) and to comply with the governmental regulation. This study was conducted to compare and evaluate the same PM10 cutpoint and different slopes between United States Environmental Protection Agency (USEPA) PM10 sampling criterion and American Conference of Governmental Industrial Hygienists/$Comit\acute{e}$ $Europ\acute{e}en$ de Normalization/International Organization for Standardization thoracic PM10 sampling criterion through theory and experiment. Four PM10 samplers according to the USEPA criterion and one RespiCon sampler in accordance with the thoracic PM10 criterion were used in the present study. In addition, one DustTrak monitor was used to measure real time PM10 mass concentrations. All six aerosol samplers were tested in a PM generation chamber using polydisperse fly ash. Theoretical mass concentrations were calculated by applying the measured particle size distribution characteristics (geometric mean = 6.6 ${\mu}m$, geometric standard deviation = 1.9) of fly ash to each sampling criterion. The measured mass concentrations through a chamber experiment were consistent with theoretical mass concentrations in that a RespiCon sampler with the thoracic PM10 criterion collected less PM than a PM10 sampler with the USEPA criterion. The overall chamber experiment results indicated, when a PM10 sampler was used as a reference sampler, that (1) a RespiCon sampler had a normalizing factor of 1.6, meaning that this sampler underestimated an average 60% of PM10 mass sampled from a PM10 sampler, and (2) a DustTrak real-time monitor using a PM10 inlet had a calibration factor of 2.1.

• Environmental Analysis Health and Toxicology
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• v.28
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• pp.7.1-7.9
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• 2013

Objectives We investigated the particle mass size distribution and chemical properties of air pollution particulate matter (PM) in the urban area and its capacity to induce cytotoxicity in human bronchial epithelial (BEAS-2B) cells. Methods To characterize the mass size distributions and chemical concentrations associated with urban PM, PM samples were collected by a 10-stage Micro-Orifice Uniform Deposit Impactor close to nearby traffic in an urban area from December 2007 to December 2009. PM samples for in vitro cytotoxicity testing were collected by a mini-volume air sampler with $PM_{10}$ and $PM_{2.5}$ inlets. Results The PM size distributions were bi-modal, peaking at 0.18 to 0.32 and 1.8 to $3.2{\mu}m$. The mass concentrations of the metals in fine particles (0.1 to $1.8{\mu}m$) accounted for 45.6 to 80.4% of the mass concentrations of metals in $PM_{10}$. The mass proportions of fine particles of the pollutants related to traffic emission, lead (80.4%), cadmium (69.0%), and chromium (63.8%) were higher than those of other metals. Iron was the dominant transition metal in the particles, accounting for 64.3% of the $PM_{10}$ mass in all the samples. We observed PM concentration-dependent cytotoxic effects on BEAS-2B cells. Conclusions We found that exposure to $PM_{2.5}$ and $PM_{10}$ from a nearby traffic area induced significant increases in protein expression of inflammatory cytokines (IL-6 and IL-8). The cell death rate and release of cytokines in response to the $PM_{2.5}$ treatment were higher than those with $PM_{10}$. The combined results support the hypothesis that ultrafine particles from vehicular sources can induce inflammatory responses related to environmental respiratory injury.

• Journal of Environmental Science International
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• v.12 no.2
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• pp.217-225
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• 2003

Samples of size-fractionated PM10 (airborne particulate matter with aerodynamic diameter less than $10\mu\textrm{m}$) were collected at an urban site in Jeju city from May to September 2002. The mass concentration and chemical composition of the samples were measured. The data sets were then applied to the CMB receptor model to estimate the source contribution of PM10 in Jeju area. The average PM10 mass concentration was 28.80$\mu\textrm{g}/m^3$ ($24.6~33.49\mu\textrm{g}/m^3$), and the FP (fine particle with aerodynamic diameter less than $2.l\mu\textrm{m}$ fraction in PM10 was approximately 8% higher than the CP (coarse particle with aerodynamic diameter greater than $2.l\mu\textrm{m}$ and less than $10\mu\textrm{m}$ fraction in PM10. The CP composition was obviously different from the FP composition, that is, the most abundant water soluble species was nitrate ion in the FP, but sulfate ion in the CP. Also sulfur was the most dominant element in the FP, however, sodium was that in the CP. From CMB receptor model results, it was found that road dust was the largest contributor to the CP mass concentration (45% of the CP) and ammonium nitrate, domestic boiler, and marine aerosol were major sources to the CP mass. However, the secondary aerosol was the most significant contributor to the FP mass concentration (45% of the FP). In this study, it was suggested that the contributions of soil dust and gasoline vehicle became very low due to collinearity with road dust and diesel vehicle, respectively.