• 한국환경보건학회지
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• 제33권5호
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• pp.408-421
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• 2007

The concentration characteristics of atmospheric particle matters (PM) including $PM_{2.5},\;PM_{10}$, and TSP were evaluated through the measurement data of PM_{2.5}$ (fine particulate), PM_{10-2.5}$ (coarse particulate), and PM_{over-10}$ collected using a MCI (multi-nozzle cascade impactor) sampler of a three-stage filter pack in spring of 2006 in Iksan area. During the sampling period of 10-15 March and 24 days from 8 April to 2 May, 32 samples for PM of each size fractions were collected, and then measured for PM mass concentrations and water-soluble inorganic ion species. Average concentrations of $PM_{2.5},\;PM_{10}$, TSP were $57.9{\pm}44.1mg/m^3$, $96.6{\pm}89.1mg/m^3$, and $114.8{\pm}99.7mg/m^3$, respectively. Water-soluble inorganic ion fractions to PM mass were found to be 36.5%, 18.0%, and 11.1% for $PM_{2.5}$, $PM_{10-2.5}$ and $PM_{over-10}$, respectively. By showing the high concentrations of PM samples during Asian dust events, those three fractions of PM were distinguished between the samples of Asian dust event and the samples of no event. However, the increase of PM concentrations observed during Asian dust events showed a different pattern for some Asian dust events. The differences of those three fractions in the size distribution may depend on differences on place of occurrence of Asian dust storm and course of transport from China continent to Iksan area in Korea. However, the extent of PM mass contribution during Asian dust events was generally dominated by the coarse particles rather than the fine fraction of PM. The variations of water-soluble inorganic ion species concentration in those three PM fractions between the samples of Asian dust event and the samples of no event were also discussed in this study.

• 한국입자에어로졸학회지
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• 제4권1호
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• pp.1-7
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• 2008

Temporal trends of the PM10 and PM2.5 mass concentrations, and the concentrations of chemical species (sulfate, nitrate, ammonium, OC, and EC) in PM2.5 at Seoul are compared with the reported results from other mega cities in the world. The mass concentrations of PM10 and PM2.5 at Seoul show decreasing trend. However, the concentration levels are still higher than other cities except Beijing. The sulfate concentration at Seoul has decreased while those of nitrate and ammonium have increased. The concentrations of OC and EC show no apparent trend.

• 한국환경과학회지
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• 제25권5호
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• pp.727-736
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• 2016

The ambient mass concentration and chemical composition of the $PM_{2.5}$ were determined at the highland site with 1,100 m above sea level on Jeju Island from June 2013 to November 2014. Yearly averaged mass concentration of $PM_{2.5}$ was $11.97{\pm}8.63{\mu}g/m^3$. $PM_{2.5}$ concentrations were highest during the spring, while they tended to be lowest during the summer. Eight water soluble ionic species attributed 45.5% to $PM_{2.5}$ mass. $SO{_4}^{2-}$, $NO_3{^-}$ and $NH_4{^+}$ were major ions, which occupied to 27.9%, 3.7% and 12.3%, respectively. The greatest contributors to total mass concentration of water-soluble ions contained in $PM_{2.5}$ were sulfate, ammonium and nitrate. These three ions accounted for 96.6% in total ions mass concentration of $PM_{2.5}$. We could infer that these three secondary ions exist mostly in the form of $(NH_4)_2SO_4$ and $NH_4NO_3$. $Ca^{2+}$ and $Mg^{2+}$ had a good relationship and with r=0.9. The molar ratio of $Mg^{2+}/Ca^{2+}$ in this study was lower than the value observed in sea water and higher than that in soil dust, indicating that these two ions originated from other sources rather than ocean and soil dust in this study.

• Mass Spectrometry Letters
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• 제10권3호
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• pp.93-101
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• 2019

Algorithms and software for predicting tandem mass spectra have been developed in recent years. In this work, we explore how distinct in silico $MS^2$ spectra are predicted for isomers, i.e. compounds having the same formula and similar molecular structures, to differentiate between them. We used the CFM-ID 2.0/3.0 predictor with regard to (a) test compounds, whose experimental mass spectra had been randomly sampled from the MassBank of North America (MoNA) collection, and to (b) the most widespread isomers of test compounds searched in the PubChem database. In the first validation test, in silico mass spectra constitute a reference library, and library searches are performed for test experimental spectra of "unknowns". The searches led to the true positive rate (TPR) of ($46-48{\pm}10$)%. In the second test, in silico and experimental spectra were interchanged and this resulted in a TPR of ($58{\pm}10$)%. There were no significant differences between results obtained with different metrics of spectral similarity and predictor versions. In a comparison of test compounds vs. their isomers, a statistically significant correlation between mass spectral data and structural features was observed. The TPR values obtained should be regarded as reasonable results for predicting tandem mass spectra of related chemical structures.

• 천문학회지
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• 제29권2호
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• pp.137-156
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• 1996

NGC 6716 is an intermediate-age open cluster in Sagittarius. In this paper, we present the new UBV CCD photometry of the stars in the cluster, which is deeper than previous ones. From the color-color diagram and the color-magnitude diagram, we derived a reddening $E_{B- V} = 0.17\pm0.03$ and a distance modulus of the cluster, $(V - Mv)_o = 9.2\pm0.1$. An age of the cluster is estimated as $8\pm10^7 yrs$ from the latest isochrone. Luminosity function and mass function of the cluster are derived. The gradient of the mass function of bright stars is a bit steep, $\Gamma = -1.85\pm0.05$, and there is no distinct bump and dip in the mass function.

• 한국대기환경학회지
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• 제23권6호
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• pp.689-698
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• 2007

Particular attention is paid to the validity of PM-10 measurement using beta attenuation method. In this study, the inter-comparison studies were undertaken for PM-10 sampler with different measuring methods. The three beta attenuation monitoring instruments (BAM1020, FH C-14, and DIGS-150) and filter based gravitational method using High Volume Air Sampler were collocated and mass concentrations were compared from August to November, 2006. The results of the investigation show that beta attenuation monitoring instruments are comparable with gravitational method within 10% of measurement error. For specific conditions under high humidity and high concentrations, the inter-comparison results also showed a relatively good agreement and this can be explained as the effect of inlet heating of beta attenuation instrument. Subsequently, this study shows that beta attenuation monitoring instruments can be equivalently used with reasonable validity when compared gravimetric method.

• 한국환경과학회지
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• 제21권7호
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• pp.815-824
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• 2012

The purpose of this study was to analyze the meteorological characteristics of wintertime high PM10 concentration episodes in Busan. $PM_{10}$ concentration has been reduced for the past four years and recorded near or exceeded 100 ${\mu}g/m^3$ (national standard of $PM_{10}$). High concentration episodes in Busan were 6 case, $PM_{2.5}/PM_{10}$ ratio was 0.36~0.39(mean 0.55). High $PM_{10}$ concentration occurred during higher air temperature, more solar radiation and sunshine, lower relative humidity, and smaller cloud amount. Synoptically, it also occurred when Busan was in the center or the edge of anticyclone and when sea breeze intruded. An analysis of upper air sounding showed that high $PM_{10}$ concentration occurred when surface inversion layer and upper subsidence inversion layer existed, and when boundary layer depth and vertical mixing coefficient were low. An analysis of backward trajectory of air mass showed that high $PM_{10}$ concentration was largely affected by long range transport considering that it occurs when air mass is intruded from China.

• 한국환경보건학회지
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• 제30권2호
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• pp.123-132
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• 2004

The purpose of this study was to characterize background mass concentration of PM$_{10}$ and metallic composition from September 2001 to August 2002 in comparison with Asan and Seoul. Annual mean of PM$_{10}$ concentrations in Asan and Seoul were 47.98 and 75.33$\mu\textrm{g}$/㎥, respectively. The concentrations of PM$_{10}$ were highest in spring season in both cities. The concentrations of measured metals except for As and Pb in Asan were higher than those in Seoul. Yellow dust could affect the mass and metals concentrations of measured PM$_{10}$ in Asan and Seoul. Relationship between measured metals concentrations showed that Si and Fe were associated with natural sources such as soil. Pb, Cu and Zn were closely related to urban anthropogenic sources such as fuel combustion. Especially, relationship between metals showed different association during yellow dust. Proper management for PM$_{10}$ will need in Asan, considered the concentrations of metallic elements in PM$_{10}$ in Asan were relatively higher than those in Seoul.se in Seoul.

• 한국입자에어로졸학회지
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• 제9권2호
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• pp.69-78
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• 2013

In this study, the atmospheric aerosol concentration measured at different relative humidity levels was analyzed. Using an optical particle counter, PM10 and PM2.5 concentration as well as particle size distribution were measured and the relation between these size resolved data and relative humidity was studied. The results showed that mass concentration increases as relative humidity increases. The comparison between PM1, PM2.5 and PM10 showed that the fine particles grow more than coarse particles as relative humidity increases. The results also showed that PM10-2.5 and relative humidity do not show close correlation, which means that the mass increase of PM10 at high relative humidity is mainly due to the growth of PM2.5.

• 한국대기환경학회지
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• 제20권1호
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• pp.17-31
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• 2004

The subway play an important part in serious traffic problems. However, because subway system is a closed environment, many serious air pollution problems occurred in subway stations and injured passenger's health. Therefor, it is a necessary to identify sources and to estimate pollutant sources in order to protect passenger's health and to keep clean subway environment. The purpose of this study was to analyze a air quality in the subway stations and to apply a new receptor methodology for quantitatively estimate of PM10 sources. In this study, the size distributions of particulate matters has been measured by using Aerosizer LD (U.S.A., API, Inc.). It's real time measurement capability of time-of-flight technique offers a significant advantage of user convenience and air pollution management. Also, the mass concentrations of PM 10 has been measured by using mini-vol portable sampler (U.S.A., Airmetrics Co.). The sampling performed in Seoul subway stations during the period of February 2000 and April 2000. The number distribution data used in this study consisted of 26 raw data sets in the Jongno-sam-ga station. Correlation Analysis can be used in subway stations for source separation and identification. Then, number contribution from each source is determined by the particle number balance (PNB). The mass concentration data used in this study consisted of 31 raw data in the 8 different stations. The mass contributions of PM10 sources in the concourse by using PMF/CMB model.