• Journal of Environmental Health Sciences
• /
• v.34 no.4
• /
• pp.300-310
• /
• 2008

In order to further determine the mass concentration and ion composition of size-segregated particulate matter (PM) during the non-Asian dust storm of spring, $PM_{2.5}$ (fine particle), $PM_{10-2.5}$ (coarse particle), and $PM_{over-10}$ (PM with an aerodynamic diameter larger than $10{\mu}m$) were collected using a MCI (multi-nozzle cascade impactor) sampler of a three-stage filter pack in the spring season of 2007 in the Iksan area. During the sampling period from 5 April to 21 April, a total of 34 samples for size-segregated PM were collected, and then measured for PM mass concentrations by gravimetric measurements and for water-soluble inorganic ion species by using ion chromatography. Average mass concentrations of $PM_{2.5}$, $PM_{10-2.5}$, $PM_{over-10}$ were $35.4{\pm}11.5{\mu}g/m^3$, $13.3{\pm}5.5{\mu}g/m^3$ and $9.5{\pm}4.7{\mu}g/m^3$, respectively. On average, $PM_{2.5}$ accounted for 74% of $PM_{10}$. Compared with the literature from other areas in Korea, the measured concentration of $PM_{2.5}$ were relatively high. Water-soluble inorganic ion fractions in $PM_{2.5}$, $PM_{10-2.5}$, and $PM_{over-10}$ were found to be 47.8%, 28.5%, and 14.7%, respectively. Among the water-soluble inorganic ion species, $SO_4^{2-}$, $NO_3^-$ and $NH_4^+$ were the main components in $PM_{2.5}$, while $NO_3^-$ dominantly existed in both $PM_{10-2.5}$ and $PM_{over-10}$. Non-seasalt $SO_4^{2-}$ (nss-$SO_4^{2-}$ and $NO_3^-$ were found to mainly exist as the neutralized chemical components of $(NH_4)_2SO_4$ and $NH_4NO_3$ in fine particles.

• Korean Journal of Remote Sensing
• /
• v.36 no.6_3
• /
• pp.1681-1690
• /
• 2020

A scanning lidar system has been developed. The system has two wavelength observation channels of 532 and 1064 nm and is capable of 360-degree horizontal scanning observation. In addition, an analysis method that can classify the measured particle as an indicator of coarse-mode particle (PM2.5-10) and an indicator of fine-mode particles (PM2.5) and calculate the mass concentration of each has been developed by using the backscatter coefficient at two wavelengths. It was applied to the data calculated by observation. The mass concentrations of PM10 and PM2.5, which showed a distribution of 22-110 ㎍/㎥ and 7-78 ㎍/㎥, respectively, were successfully calculated in the Ulsan Onsan Industrial Complex using the developed scanning lidar system. The analyzed results showed similar values to the mass concentrations measured on the ground around the lidar observation area, and it was confirmed that high concentrations of 80-110 ㎍/㎥ and 60-78 ㎍/㎥ were measured at points discharged from factories, respectively.

• Journal of Korean Society for Atmospheric Environment
• /
• v.21 no.3
• /
• pp.329-341
• /
• 2005

The purpose of this study is to study the $PM_{2.5}$ source characteristics affecting the Seoul area using a chemical mass balance (CMB) receptor model. This study was also to evaluate the $PM_{2.5}$ source profiles, which were directly measured and developed. Asian Dust Storm usually occurred in the spring, and very high $PM_{2.5}$ concentrations were observed in the fall among the sampling periods. So the ambient data collected in the spring and fall were evaluated. The CMB model results as well as the $PM_{2.5}$ source profiles were validated using the diagnostic categories, such as: source contribution estimate, t-statistic, R-square, Chi-square, and percent of total mass explained. In the spring months, the magnitude of $PM_{2.5}$ mass contributors was in the following order: Chinese aerosol $(31.7\%)>$ secondary aerosols ($22.3\%$: ammonium sulfate $13.4\%$ and ammonium nitrate $8.9\%)>$ vehicles ($16.1\%$: gasoline vehicle $1.4\%$ and diesel vehicles $14.7\%)>$biomass burning $(15.5\%)>$ geological material $(10.5\%)$. In the fall months, the general trend of the $PM_{2.5}$ mass contributors was the following: biomass burning $(31.1\%)>$ vehicles ($26.9\%$: gasoline vehicle $5.1\%$ and diesel vehicles $21.8\%)>$ secondary aerosols ($23.0\%$: ammonium sulfate $9.1\%$ and ammonium nitrate $13.9\%)>$ Chinese aerosol $(10.7\%)$. The results show that the $PM_{2.5}$ mass in the Seoul area was mainly affected by the Chinese area.

• Journal of Korean Society for Atmospheric Environment
• /
• v.26 no.3
• /
• pp.298-304
• /
• 2010

In order to calculate the aerosol bulk densities of $PM_{1.0}$ and $PM_{10}$, aerosol mass and number concentrations were measured for the period of December 2008~April 2009. $PM_{1.0}$ and $PM_{10}$ mass concentrations were measured using a cascade impactor (Micro-Orifice Uniform Deposit Impactor, MOUDI) while their volume concentrations were calculated based on number concentrations from an environmental dust monitor (EDM). Normal aerosol size distribution fitting functions were retrieved for number size distribution since aerosols < $2.5{\mu}m$ were measured from the EDM. Strong correlation was found between $PM_{1.0}$ mass and volume concentrations obtained with a $R^2$ of 0.95. The calculated average bulk densities of $PM_{1.0}$ and $PM_{10}$ were $1.97{\pm}0.33g/cm^3$ and $2.15{\pm}0.18g/cm^3$, respectively.

• Journal of the Korean earth science society
• /
• v.37 no.7
• /
• pp.434-447
• /
• 2016

This study analyzed mass concentrations of PM10 and PM2.5, as measured at Tae-ahn and Gang-nae, Cheongju in central Korea over the period from 2011 to 2015. Higher mass concentrations of PM10, with the exception of dustfall cases during the period of winter and spring, reflected the influence of a prevailing westerly airflow, while the level of PM10 stayed at a low level in summer, reflecting the influence of North Pacific air mass and frequent rainfall. Accordingly, cases where a daily PM10 average of $81{\mu}gm^{-3}$ or over (exceeding the status of fine dust particles being 'a little bit bad') were often observed during the period of winter and spring, with more cases occurring in parts of Tae-ahn that are located close to the sources of pollutant emission in eastern China. Dustfall usually originated from dust storms made up of particles $2.5{\mu}m$ or over in diameter. However, anthropogenic haze displayed a high composition ratio of particulate less than $2.5{\mu}m$ in diameter. Accordingly, brightness temperature difference (BTD) values from the Communication, Ocean and Meteorological Satellite (COMS) were $-0.5^{\circ}K$ or over in haze with fine particulate. PM10 mass concentrations and NOAA 19 satellite BTD for haze cases were analyzed. Though PM10 mass concentrations were found to be lower than $200{\mu}g\;m^{-3}$, the mass concentration ratio of PM2.5/PM10 was measured as higher than 0.4 and BTD was found to be distributed in the range from -0.3 to $0.5^{\circ}K$. However, the BTD of dustfall cases exceeding $190{\mu}g\;m^{-3}$, were found to be less than 0.4 and BTD was found to be distributed in the range less than $-0.7^{\circ}K$. The result of applying BTD threshold values of the large-scale transport of haze proved to fall into line with the range over which aerosols of MODIS AOD and OMI AI were distributed.

• Journal of Environmental Health Sciences
• /
• v.37 no.3
• /
• pp.209-217
• /
• 2011

Objectives: In this study, the size distribution of airborne particulates ($PM_{10}$) was measured by using Cascade Impactors. The purpose of this study was to assess the size distribution of metal and ionic materials of $PM_{10}$. Methods: Samples were collected in the Kunsan industrial complex from April 2006 to January 2007. Results: The mass fraction of $PM_{10}$ had a bimodal distribution between 2.1-3.1 ${\mu}M$, and the average mass fraction of particles less than 2.1-3.1 ${\mu}M$ was 47%. Average concentrations of PM10 were 68.05 ${\mu}g/m^3$ and seasonal concentration 95.44 ${\mu}g/m^3$ for spring, 49.03 ${\mu}g/m^3$ for summer, 81.99 ${\mu}g/m^3$ for fall, 52.66 ${\mu}g/m^3$ for winter, respectively. Conclusions: Seasonal variations of $PM_{10}$ were significant for showing peak values in spring. The average concentrations of Cd, Cr, Pb, and Fe were 1.54, 4.51, 14.11, and 254.3 $ng/m^3$, respectively. The ratios of fine particles to total mass were 0.47 for $PM_{10}$, 0.45 for Cr, and 0.16 for Fe, 0.91 for Cd and 0.49 for Pb, respectively.

• Journal of Korean Society for Atmospheric Environment
• /
• v.21 no.1
• /
• pp.131-140
• /
• 2005

To investigate secondary carbonaceous species within PM$_{10}$ and PM$_{2.5}$ in Seoul urban Metropolitan Area (SMA), Korea. atmospheric particulate matters samples were collected at two sites of SMA at UOS (The University Of Seoul station) sites and IHU (InHa University of Incheon station) during the period of 4 to 14 January and 12 to 22 May, 11 to 15 August 2004, and their characteristics were qualitatively discussed. during January and May and August of 2004. Daily average mass concentration 0.095 mg/㎥ in PM$_{10}$ and 0.053 mg/㎥ in PM$_{2.5}$ for mass respectively. were observed in SMA. The concentrations of carbonaceous species contributed 18.4% and 16.4% of PM$_{2.5}$ and PM$_{10}$ during the sampling period, respectively, of which OC accounted for 68% and 52% more of the total carbon (TC). OC and EC concentrations and their mass percentages were higher in PM$_{2.5}$ than in PM$_{10}$ which could be attributed to generation process. Organic aerosols would constitute up to 38% of PM$_{2.5}$ based on the evaluation of 1.6 for the ratio of OC to organic particulate. Secondary organic carbon (SOC) were estimated to be more than 13% and up to 68% of total OC based on the minimum OC/EC ratio of 1.06/1.11 using least square method. Comparisons of OC and EC with trace elements. As results of carbonaceous species analysis, the dominant factor in view of fine particle (PM$_{10}$/PM$_{2.5}$) is primary emission source such as mobile, fossil fuel combustion etc. during winter time in SMA. But in summer periods, remarkable fine particle increasing factor was secondary organic carbon dependent to photochemical reaction. reaction.n. reaction.

• Particle and aerosol research
• /
• v.7 no.2
• /
• pp.49-57
• /
• 2011

High concentration of PM10 was reported on late July, 2005 in Seoul along with high particulate ion concentrations in PM2.5. To identify the reason for the severe air pollution episode, time series analysis of the PM10 concentration in the monitoring sites over Korea, wind sector analysis, trend analysis of the ion concentrations, and air mass trajectory analysis were carried out. It was found that the episode could be classified into two separate periods; first one between July 22 and 27 and second one between July 28 and 31. During the first period, the PM10 concentrations at Seoul were in good correlation with the PM10 concentration three hours before at Chuncheon. Trajectory analysis showed that air mass moved from north and turned to west at Kangwon province to Seoul. The concentrations of PM10 mass and ionic species were lower than the second period. During the second period, air mass moved from northern China to Seoul directly and the PM10 concentrations all over the mid-Korean peninsula showed the same trend. These observations suggest that the air pollution during the second period was affected by direct transport of air pollutants from northern China. Thus, the air quality at Seoul during both periods were influenced by long-range transport from outside rather than by local sources, but with different transport patterns.

• Journal of Environmental Health Sciences
• /
• v.26 no.2
• /
• pp.108-115
• /
• 2000

The mass fraction of PM10 had a bimodal distribution in the middle of between 2.1 ${\mu}{\textrm}{m}$, and the average mass fraction of particles less than 2.1~3.1 ${\mu}{\textrm}{m}$ was 54.1% for Pb and 890.8 ng/㎥ for Fe, respectively. For the concentration of PM10 and metallic elements by seasonal variation, PM10 showed bimodal distribution, while metallic elements showed different distributions by their sources. The ratios of fine particles to total mass were 0.45 for PM10, 0.41 for Cr, and 0.20 for Fe, 0.57 for Zn, 0.68 for Cd and 0.63 for Pb, respectively. That facts indicated that PM10, Zn, Cd, Cr and Pb were from anthropogenic sources, and Fe was from natural source. The geometric means and geometric standard deviations by seasonal variations were 3.6 ${\mu}{\textrm}{m}$ , 2.31 ${\mu}{\textrm}{m}$ in winter, 3.0 ${\mu}{\textrm}{m}$ , 2.49 ${\mu}{\textrm}{m}$ in spring, 2.7 ${\mu}{\textrm}{m}$ , 2.03 ${\mu}{\textrm}{m}$ in summer respectively. And, total efficiency of cascade impactor by seasonal variations were 49.6% in winter, 45.9% in spring and 44.5% in summer.

• Mass Spectrometry Letters
• /
• v.9 no.3
• /
• pp.73-76
• /
• 2018

The number of matched peaks (NMP) is estimated as the spectral similarity measure in tandem mass spectral library searches of small molecules. In the high resolution mode, NMP provides the same reliable identification as in the case of a common dot-product function. Corresponding true positive rates are ($94{\pm}3$) % and ($96{\pm}3$) %, respectively.